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Development of a CFD Simulation Framework for Aerothermal Analyses of Electric Vehicle Battery Packs 电动汽车电池组空气热分析CFD仿真框架的开发
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-11-08 DOI: 10.1115/1.4063800
Adit Misar, Ayushi Jain, Jun Xu, Mesbah Uddin
Abstract The rise of electric vehicles has driven the extensive adoption of lithium-ion batteries (LIBs) due to their favorable attributes—compactness, low resistance, high power density, and minimal self-discharge. To enhance LIB reliability, an efficient battery thermal management system is imperative. This paper introduces a finite volume-based aerothermal analysis framework for a 32-cell high-energy density LIB pack. We also explore the effectiveness of various turbulence models in capturing local hotspots, discharge rates, and current levels across different geometries and inlet velocities. Our approach involves modeling the battery using Simcenter Battery Design Studio and importing it into Simcenter star-ccm+ for aerothermal simulations in which temperature distribution, discharge rates, current levels, and maximum temperature across are monitored for aligned, cross, and staggered configurations of the battery pack under varying inlet velocities. Our findings highlight the significant impact of boundary condition modeling on simulation stability. Also we observed that the standard k–ε model provides the most accurate predictions, with prediction accuracy within 3–10% of experimental data. Moreover, we identify substantial dependencies between heat generation and discharge current, as well as thermal gradients and inlet velocity. Finally, we conclude that the aligned cell arrangement offers the best thermal uniformity and cooling efficiency.
电动汽车的兴起推动了锂离子电池(LIBs)的广泛采用,因为它具有紧凑、低电阻、高功率密度和最小自放电的优点。为了提高电池的可靠性,高效的电池热管理系统势在必行。介绍了一种基于有限体积的32芯高能量锂电池气动热分析框架。我们还探讨了各种湍流模型在捕获局部热点、放电率和不同几何形状和进口速度的电流水平方面的有效性。我们的方法包括使用Simcenter电池设计工作室对电池进行建模,并将其导入Simcenter star-ccm+进行空气热模拟,其中温度分布、放电率、电流水平和最大温度通过不同入口速度下电池组的排列、交叉和交错配置进行监测。我们的研究结果强调了边界条件建模对仿真稳定性的重要影响。我们还观察到,标准k -ε模型提供了最准确的预测,预测精度在实验数据的3-10%以内。此外,我们确定了热量产生和放电电流之间的实质性依赖关系,以及热梯度和入口速度。最后,我们得出结论,排列的电池排列提供了最佳的热均匀性和冷却效率。
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引用次数: 0
Experimental study of the thermal management system of an air-cooled Li-ion battery pack with triangular spoilers 带有三角形扰流板的风冷锂离子电池组热管理系统的实验研究
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-11-06 DOI: 10.1115/1.4063998
Satya Verma, Samir Saraswati
Abstract This research experimentally examines the thermal behaviour of an air-cooled Li-ion battery pack with triangular spoilers. The objective is to enhance temperature uniformity and reduce the maximum temperature of the battery pack by redirecting airflow towards regions of higher temperatures using triangular spoilers. The effects of spoiler angles (a) and spoiler positions (Ds) on the thermal performance of a 24V, 10Ah aligned battery pack are investigated. The parameters used to evaluate the thermal performance are; temperature variation along as well as transverse to the airflow direction and temperature variation around the circumference of the cell. The maximum temperature (Tmax), average temperature (Tavg.), maximum temperature difference (ΔTmax), and standard deviation of the temperature (σT) are the other performance parameters that are assessed. It is observed that the temperature of the battery pack decreases along the airflow direction with both the increase in α and Ds. It happens due to the enhancement in the heat transfer rate caused by higher turbulence kinetic energy. The non-uniformity in the cell temperature around the circumference improves by 0.4 K and 1.8 K with the change in α and Ds, respectively. It is found that Tmax and Tavg. of the battery pack are reduced by a maximum value of 2.5 K and 1.55 K, respectively, compared to the case when no spoiler is used. The maximum reduction in ΔTmax and σT is found to be 2.4 K and 1.02, respectively.
摘要本文通过实验研究了带三角形扰流板的气冷锂离子电池组的热行为。其目的是通过使用三角形扰流板将气流重定向到温度较高的区域,从而提高温度均匀性并降低电池组的最高温度。研究了扰流片角度(a)和扰流片位置(Ds)对24V, 10Ah对准电池组热性能的影响。热性能评价参数为:沿气流方向以及横向的温度变化以及电池周围的温度变化。最高温度(Tmax)、平均温度(Tavg.)、最大温差(ΔTmax)和温度标准差(σT)是评估的其他性能参数。随着α和Ds的增大,电池组温度沿气流方向呈下降趋势。这是由于湍流动能增大导致换热速率增大所致。随着α和Ds的变化,电池周长温度的不均匀性分别提高了0.4 K和1.8 K。发现Tmax和Tavg。与不使用扰流板的情况相比,电池组的温度最大分别降低了2.5 K和1.55 K。ΔTmax和σT的最大降幅分别为2.4 K和1.02。
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引用次数: 0
Experimental and Theoretical Analysis of Immersion Cooling of a Li-Ion Battery Module 锂离子电池模块浸没冷却的实验与理论分析
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-10-27 DOI: 10.1115/1.4063914
Swapnil Salvi, Bapiraju Surampudi, Andre Swarts, Jayant Sarlashkar, Ian Smith, Terry Alger, Ankur Jain
Abstract Overheating of Li-ion cells and battery packs is an ongoing technological problem for electrochemical energy conversion and storage devices and systems, including in electric vehicles. Immersion cooling is a promising thermal management technique to address these challenges. This work presents experimental and theoretical analysis of the thermal and electrochemical impact of immersion cooling of a small module of Li-ion cells. Significant reduction in both surface and core temperature due to immersion cooling is observed, consistent with theoretical and simulation models developed here. However, immersion cooling is also found to result in a small but non-negligible increase in capacity fade of the cells. A number of hypotheses are formed and systematically tested through comparison of experimental measurements with theoretical modeling and simulations. Electrochemical Impedance Spectroscopy measurements indicate that the accelerated cell aging due to immersion cooling is likely to be due to enhanced lithium plating. Therefore, careful consideration of the impact of immersion cooling on long-term performance may be necessary. The results presented in this work quantify both thermal and electrochemical impacts of an important thermal management technique for Li-ion cells. These results may be of relevance for design and optimization of electrochemical energy conversion and storage systems.
锂离子电池和电池组的过热是电化学能量转换和存储设备和系统(包括电动汽车)持续存在的技术问题。浸入式冷却是一种很有前途的热管理技术,可以解决这些挑战。本文对小型锂离子电池模块浸入式冷却的热学和电化学影响进行了实验和理论分析。由于浸入式冷却,观察到表面和堆芯温度显著降低,这与这里开发的理论和模拟模型一致。然而,浸没冷却也会导致电池容量衰减的微小但不可忽略的增加。通过实验测量与理论建模和模拟的比较,形成并系统地验证了许多假设。电化学阻抗谱测量表明,浸没冷却导致的电池加速老化可能是由于强化的锂镀层。因此,仔细考虑浸没冷却对长期性能的影响可能是必要的。在这项工作中提出的结果量化了锂离子电池的重要热管理技术的热和电化学影响。这些结果对电化学能量转换和存储系统的设计和优化具有一定的指导意义。
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引用次数: 0
Dynamic electrochemical action of Low temperature Plasma exposed NaFePO4/activated BCC Nanocomposites in Cathode applications 低温等离子体暴露NaFePO4/活化BCC纳米复合材料在阴极中的动态电化学作用
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-10-27 DOI: 10.1115/1.4063909
S Saveetha, KA Vijayalakshmi
Abstract Activated BCC was composed with NaFePO4 cathode material in two distinct ratios. XRD, FTIR, FESEM, and BET were used to examine the crystal structure, functional groups, morphological features and surface area of the composites. The material's surface characteristics, such as wettability, adhesion, and conductivity analysis was proved the energy storage capacity of the material and these characteristics were magnified by the exposure to DC glow discharge plasma. In this work, the NaFePO4/activated BCC was subjected to DC glow discharge plasma with various plasma producing gases. The electrochemical investigation shows that the air plasma treated composite produces the best results when compared to the untreated sample. The enhancement of the diffusivity of the composite reveals that the plasma treated materials are appropriate for energy storage devices.
摘要以NaFePO4为正极材料,以两种不同的比例组成活化BCC。采用XRD、FTIR、FESEM和BET等方法对复合材料的晶体结构、官能团、形貌特征和表面积进行了表征。材料的表面特性,如润湿性、附着力和电导率分析证明了材料的储能能力,并且这些特性在暴露于直流辉光放电等离子体时被放大。在这项工作中,NaFePO4/活化的BCC在不同的等离子体产生气体下进行直流辉光放电等离子体。电化学研究表明,与未处理的样品相比,空气等离子体处理的复合材料效果最好。复合材料扩散系数的增强表明,等离子体处理的材料适合用于储能器件。
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引用次数: 0
Lithium battery liquid-cooled thermal management system of stepped-channel based on lightweight 基于轻量化的阶梯通道锂电池液冷热管理系统
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-10-20 DOI: 10.1115/1.4063848
Long Zhou, Shengnan Li, Ankur Jain, Guoqiang Chen, Desui Guo, Jincan Kan, Yong Zhao
Abstract This study proposes a stepped channel liquid-cooled battery thermal management system based on lightweight. The impact of channel width, cell-to-cell lateral spacing, contact height, and contact angle on the effectiveness of the TCS is investigated through using numerical simulation. The weight sensitivity factor is adopted to evaluate the effect of TCS weight (mTCS) on the maximum temperature (Tmax) of battery pack. Results suggest that the channel width plays the most critical role, followed by cell-to-cell lateral spacing and contact angle, while the contact height has minimal influence. Four parameters that affect the thermal balance performance of battery pack, including the number of channels, and baffles, baffle angle, and coolant inlet velocity, are presented using orthogonal experiment. Results indicate that the number of channels and baffle angle have a significant influence on the thermal balance of battery pack, while thermal performance is largely insensitive to coolant inlet velocity and number of baffles. Based on the analysis stated in this work, an improved design of the TCS is presented that reduces weight by 54.08% while increasing Tmax only by 2.52 K.
摘要提出了一种基于轻量化的阶梯通道液冷电池热管理系统。通过数值模拟研究了通道宽度、单元间横向间距、接触高度和接触角对TCS效能的影响。采用权重敏感因子评价TCS重量对电池组最高温度的影响。研究结果表明,通道宽度的影响最为关键,其次是细胞间横向间距和接触角,而接触高度的影响最小。采用正交试验法研究了影响电池组热平衡性能的4个参数:通道数、挡板数、挡板角度和冷却剂进口速度。结果表明:通道数量和挡板角度对电池组热平衡有显著影响,而冷却剂进口速度和挡板数量对电池组热性能影响不大;在此基础上,提出了一种改进的TCS设计方案,其重量减少了54.08%,而Tmax仅增加了2.52 K。
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引用次数: 0
High-Accuracy Battery SOC Estimation Strategy Based on Deep Belief Network Cascaded with Extended Kalman Filter 基于扩展卡尔曼滤波级联深度信念网络的电池荷电状态高精度估计策略
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-10-13 DOI: 10.1115/1.4063431
Xiaoyu Liu, Lang Chen, Lijun Zhu, Jian Wang, Long Chen, Xiankai Zeng, Ziang Song, Lujun Wang
Abstract Battery state of charge (SOC) estimation is one of the main functions of the battery management system in electric vehicles. If the actual SOC of the battery differs significantly from the estimated value, it can lead to improper battery usage, resulting in unexpected rapid voltage drops or increases, which can affect driving safety. Therefore, high-accuracy SOC estimation is of great importance for battery management and usage. Currently used SOC estimation methods suffer from issues such as strong dependence on model parameters, error propagation from measurements, and sensitivity to initial values. In this study, we propose a high-precision SOC estimation strategy based on deep belief network (DBN) feature extraction and extended Kalman filter (EKF) for smooth output. The proposed strategy has been rigorously tested under different temperature conditions using the dynamic stress test (DST) and urban dynamometer driving schedule (US06) driving cycles. The mean absolute error (MAE) and root-mean-square error (RMSE) of the proposed strategy are controlled within 1.1% and 1.2%, respectively. This demonstrates the high-precision estimation achieved. To further validate the generality of this strategy, we also apply it to graphene batteries and conduct tests under US06 and highway fuel economy test (HWFET) driving cycles at temperatures of 25 °C and −10 °C. The test results show MAE of 0.47% and 2.01%, respectively.
摘要电池荷电状态估计是电动汽车电池管理系统的主要功能之一。如果电池的实际SOC与估计值相差较大,则可能导致电池使用不当,导致意外的电压快速下降或升高,从而影响驾驶安全。因此,高精度的SOC估算对于电池的管理和使用具有重要意义。目前使用的SOC估计方法存在对模型参数的依赖性强、测量误差传播和对初始值的敏感性等问题。在这项研究中,我们提出了一种基于深度信念网络(DBN)特征提取和扩展卡尔曼滤波(EKF)的高精度SOC估计策略。采用动态应力测试(DST)和城市测力计驾驶时间表(US06)驾驶循环,在不同温度条件下对所提出的策略进行了严格测试。该策略的平均绝对误差(MAE)和均方根误差(RMSE)分别控制在1.1%和1.2%以内。这证明了实现的高精度估计。为了进一步验证该策略的普遍性,我们还将其应用于石墨烯电池,并在US06和公路燃油经济性测试(HWFET)下在25°C和- 10°C的温度下进行了测试。测试结果表明,MAE分别为0.47%和2.01%。
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引用次数: 0
DEVELOPMENT OF BORON CONTAINING ELECTROLYTE ADDITIVE FOR LITHIUM ION BATTERIES 锂离子电池含硼电解质添加剂的研制
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-10-05 DOI: 10.1115/1.4063429
Zahid Sarigol, Gulay Ozkan, Goksel Ozkan
Abstract In this study, triphenylphosphine boron trifluoride (BF3 · PPh3) was synthesized to be used as an electrolyte additive in Li/LiCoO2 half-cells. Fourier-transform infrared spectroscopy, X-ray diffraction, nuclear magnetic resonance, and X-ray photoelectron spectroscopy analysis techniques were used to determine the structure and composition of the synthesized substance. The battery performance was investigated by adding certain amounts of BF3 · PPh3 in 1 M LiPF6-ethylene carbonate/dimethyl carbonate/diethyl carbonate (1:1:1 by volume) electrolyte. CR2032 coin cells were assembled with the electrodes and electrolytes prepared in the laboratory. The electrochemical behaviors of the battery were investigated via cyclic voltammetry and charge–discharge tests. The addition of 0.5 wt% and 1 wt% BF3 · PPh3 in the electrolyte improved the lithium-ion battery’s ionic conductivity and capacity retention. The results show that BF3 · PPh3 has potential applications in lithium-ion batteries.
摘要本研究合成了三苯基膦三氟化硼(BF3·PPh3)作为Li/LiCoO2半电池的电解质添加剂。采用傅里叶变换红外光谱、x射线衍射、核磁共振、x射线光电子能谱等分析技术对合成物质的结构和组成进行了测定。在1 M lipf6 -碳酸乙烯/碳酸二甲酯/碳酸二乙酯(体积比1:1:1)电解质中加入一定量的BF3·PPh3,考察电池性能。用实验室制备的电极和电解质组装CR2032硬币电池。通过循环伏安法和充放电试验对电池的电化学行为进行了研究。在电解液中分别添加0.5 wt%和1 wt%的BF3·PPh3,提高了锂离子电池的离子电导率和容量保持率。结果表明,BF3·PPh3在锂离子电池中具有潜在的应用前景。
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引用次数: 0
Nano graphite-doped Spartina alterniflora-based hard carbon as high performance anode for sodium-ion batteries 纳米石墨掺杂互花米草硬碳作为钠离子电池的高性能阳极
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-10-05 DOI: 10.1115/1.4063397
Hongkuan Cheng, Qihang Shu, Huanyu Wei, Xingzhang Luo, Suzhen Huang, Zheng Zheng
Abstract Anode materials based on hard carbon are the focus of research in the field of batteries, and bio-hard carbon is one of the most important materials. In this study, we use the invasive species Spartina alterniflora as raw material and doped with nano-graphite to produce high-performance anode materials. It can achieve a first coulomb efficiency of 67%, which is nearly 10% higher than Spartina alterniflora without nano-graphite doped. The specific capacity is close to 300 mA h g−1 under the current of 20 mA g−1. By comparison, we found that the modified Spartina alterniflora has great sodium storage capacity, and the study also proved that Spartina alterniflora material can be modified into a high-performance anode material with high economic value.
摘要基于硬碳负极材料的重点研究领域的电池,和bio-hard碳是最重要的材料之一。本研究以入侵物种互花米草为原料,掺杂纳米石墨制备高性能阳极材料。其第一库仑效率可达67%,比未掺杂纳米石墨的互花米草提高近10%。在20ma g−1电流下,比容量接近300ma h g−1。通过比较,我们发现经改性的互花米草具有很大的储钠能力,研究也证明了互花米草材料可以改性为具有较高经济价值的高性能阳极材料。
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引用次数: 0
State of charge estimation of lithium–ion battery based on IDRSN and BiGRU 基于IDRSN和BiGRU的锂离子电池充电状态估计
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-10-05 DOI: 10.1115/1.4063173
Jiahao Zhang, Jiadui Chen, Ling He, Dan Liu, Kai Yang, Qinghua Liu
Abstract The estimation of state of charge (SOC) is a critical issue in the energy management of electric vehicle (EV) power batteries. However, the current accuracy of SOC estimation methods does not meet the requirements of practical applications. Therefore, this study proposes an improved lithium-ion battery SOC estimation method that combines deep residual shrinkage network (DRSN) and bidirectional gated recurrent unit (BiGRU) to enhance the SOC estimation accuracy. First, we insert the bidirectional gated recurrent unit neural network between the global average pooling layer and the output fully connected layer of the deep residual shrinkage network. This improvement enhances the model’s expressiveness, robustness, and data learning effect. Second, we develop a new activation function called “∂_swish” to replace the original ReLU activation function in the deep residual shrinkage network. The ∂_swish activation function improves the accuracy of the deep network model and reduces the risk of overfitting by utilizing its regularization effect. Finally, we conduct experimental tests at three different temperatures using the FUDS driving cycle dataset and the DST-US06-FUDS continuous driving cycle dataset. The algorithm model’s convergence speed is verified by comparing it with other models. The results show that compared to other models, the proposed method significantly improves SOC estimation accuracy at three different temperatures. In addition, the method demonstrates a high convergence speed.
摘要在电动汽车动力电池能量管理中,荷电状态(SOC)估计是一个关键问题。然而,目前SOC估算方法的精度还不能满足实际应用的要求。因此,本研究提出了一种改进的锂离子电池荷电状态估计方法,该方法将深度剩余收缩网络(DRSN)和双向门控循环单元(BiGRU)相结合,以提高荷电状态估计精度。首先,在深度残余收缩网络的全局平均池化层和输出全连接层之间插入双向门控循环单元神经网络。这种改进增强了模型的表现力、鲁棒性和数据学习效果。其次,我们开发了一个新的激活函数“∂_swish”来取代深度剩余收缩网络中原来的ReLU激活函数。∂_swish激活函数利用其正则化效果,提高了深度网络模型的精度,降低了过拟合的风险。最后,我们使用FUDS驾驶循环数据集和DST-US06-FUDS连续驾驶循环数据集在三种不同温度下进行了实验测试。通过与其他模型的比较,验证了算法模型的收敛速度。结果表明,与其他模型相比,该方法显著提高了三种不同温度下的SOC估计精度。此外,该方法具有较快的收敛速度。
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引用次数: 0
A review on low-temperature performance management of lithium-ion batteries 锂离子电池低温性能管理研究进展
4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2023-10-03 DOI: 10.1115/1.4063611
Jincheng Zhan, Yifei Deng, Yaohui Gao, Jiaoyi Ren, Yuang Liu, Rao Shun, Weifeng Li, Zhenhai Gao, Yupeng Chen
Abstract Lithium-ion batteries (LIBs) are widely used in electric vehicles, energy storage power stations and other portable devices for their high energy densities, long cycle life and low self-discharge rate. However, they still face several challenges. Low-temperature environments have slowed down the use of LIBs by significantly deteriorating their normal performance. This review aims to resolve this issue by clarifying the phenomenon and reasons of the deterioration of LIBs performance at low temperatures. From the perspective of system management, this review summarizes and analyzes the common performance-improving methods from two aspects including preheating and charging optimization, then depicts the future development of methods in this regard. This review is expected to inspire further studies for the improvement of the LIB performance at low temperatures.
摘要锂离子电池以其能量密度高、循环寿命长、自放电率低等特点,广泛应用于电动汽车、储能电站等便携式设备中。然而,他们仍然面临着一些挑战。低温环境会显著降低锂电池的正常性能,从而减慢其使用速度。本文旨在通过阐明低温下锂离子电池性能恶化的现象和原因来解决这一问题。本文从系统管理的角度出发,从预热和充电优化两方面对常用的性能提升方法进行了总结和分析,并对这方面方法的未来发展进行了展望。这一综述有望为进一步提高锂离子电池低温性能的研究提供启发。
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引用次数: 0
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Journal of Electrochemical Energy Conversion and Storage
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