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Mapping built-up area expansion in landslide susceptible zones using automatic land use/land cover classification 利用土地利用/土地覆被自动分类绘制滑坡易发区建成区扩展图
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-06 DOI: 10.1007/s12040-024-02345-9
Lekshmi S Sunil, Minu Treesa Abraham, Neelima Satyam

Abstract

The information on land use/land cover (LULC) is indispensable in regional planning, policy formulation and tracking land use/land cover changes (LULCC). The rapid urbanization of hilly terrains, driven by population growth, has significant implications for landslide risk reduction. Recognizing the need for an innovative approach for extracting LULC information, the present study uses a random forest (RF) classifier to develop a novel, pre-trained and universal tool that automatically generates LULC classification maps based on natural colour satellite imagery without any training input from the end-user. The proposed framework with an overall accuracy of 0.75 and an area under the curve (AUC) score of 0.95 in the receiver operating characteristic curve (ROC) approach was used for mapping built-up area expansion in regions susceptible to rainfall-induced landslides in Idukki block panchayat (administrative division), Kerala, India. By comparing the LULC information for the years 2012 and 2022, it was understood that the built-up area in the location has increased from 12.76% of the total area in 2012 to 26.48% in 2022. It is important to consider the rapid increase in built-up area expansion in the ‘very high’ landslide susceptibility zones in the study area. This clearly demonstrates the need for hazard inclusive planning and tracking of LULCC, for disaster risk reduction.

Research Highlights

  • A pre-trained Land Use/Land Cover (LULC) classification tool is developed using the Random Forest (RF) classifier.

  • Based on natural colour satellite imagery, the tool automatically generates LULC maps for various landscapes worldwide.

  • The tool demonstrates a satisfactory performance, achieving an overall accuracy of 0.75 and an overall ROC AUC score of 0.95.

  • The tool was used to understand the LULC changes in Idukki block panchayat between 2012 and 2022.

摘要 土地利用/土地覆被信息在区域规划、政策制定和跟踪土地利用/土地覆被变化(LULCC)方面不可或缺。在人口增长的推动下,丘陵地带的快速城市化对降低滑坡风险具有重大影响。认识到需要一种创新的方法来提取 LULC 信息,本研究使用随机森林(RF)分类器开发了一种新颖的、预先训练好的通用工具,它可以根据自然彩色卫星图像自动生成 LULC 分类图,而无需最终用户提供任何训练输入。所提出的框架在接收器工作特征曲线(ROC)方法中的总体准确率为 0.75,曲线下面积(AUC)得分为 0.95,被用于绘制印度喀拉拉邦 Idukki 区县(行政区划)易受降雨引起的山体滑坡影响地区的建筑面积扩张图。通过比较 2012 年和 2022 年的 LULC 信息,可以发现该地区的建成区面积已从 2012 年占总面积的 12.76% 增加到 2022 年的 26.48%。考虑到研究区域内 "极高 "滑坡易发区的建成区迅速扩大,这一点非常重要。这清楚地表明,为了减少灾害风险,有必要对土地利用/土地覆被进行灾害包容性规划和跟踪。 研究亮点 使用随机森林(RF)分类器开发了一种预先训练的土地利用/土地覆被分类工具。该工具的性能令人满意,总体准确率达到 0.75,总体 ROC AUC 得分为 0.95。
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引用次数: 0
Environmental dispersion in wetland flow with wind effects under boundary absorptions 边界吸收条件下具有风效应的湿地流环境扩散
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-06 DOI: 10.1007/s12040-024-02332-0
Buddhadeb Mondal, Krishnendu Barman, Bijoy S Mazumder

Wetlands are characterized by flow and environmental dispersion, which are necessary in the water management system. Contaminant transport in wetlands has a significant effect in the field of biology and environmental fluid dynamics for the conservation of fish and wildlife species, erosion prevention, and mainly recreation. When an instantaneous contaminant is released into a wetland, both boundary absorptions and wind have a significant impact on the contaminant dispersion process. The present study highlights the wind effects and boundary absorption on environmental dispersion and stream-wise mean concentration in a width-dominated flow for a shallow wetland. A multi-scale time period is considered to determine the dispersion model, which illustrates the contaminant transport process greatly affected by different ecological parameters like dispersion time, boundary absorption, tortuosity and vegetation drag. It is noted that the stream-wise concentration distribution is almost identical to the transversal concentration distribution due to tortuosity and bottom vegetation effect. It is noticed that the stream-wise concentration of contaminant gradually decreases due to the increase of vegetation parameters and tortuosity. The distribution of flow velocity is derived analytically from the momentum equation for different wind strengths. The effect of boundary absorption strength on stream-wise and mean concentration are discussed. Also, it is evident that the distribution of concentration is complex for boundary absorption under the effects of wind.

湿地的特点是流动和环境分散,这在水管理系统中是必要的。在生物学和环境流体力学领域,湿地中的污染物迁移对保护鱼类和野生动物物种、防止水土流失以及休闲娱乐都有重要影响。当污染物瞬间释放到湿地中时,边界吸收和风都会对污染物的扩散过程产生重大影响。本研究强调了风效应和边界吸收对环境扩散的影响,以及在以宽度为主的水流中浅层湿地的平均浓度。研究考虑了多尺度时间段来确定扩散模型,说明污染物迁移过程受不同生态参数(如扩散时间、边界吸收、迂回度和植被阻力)的影响很大。结果表明,由于迂回和底部植被的影响,流向浓度分布与横向浓度分布几乎相同。值得注意的是,随着植被参数和迂回度的增加,污染物的全流浓度逐渐降低。不同风力下的流速分布由动量方程分析得出。讨论了边界吸收强度对全流和平均浓度的影响。此外,在风的作用下,边界吸收的浓度分布显然是复杂的。
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引用次数: 0
Long-term study of spatial and temporal variations in biomass burning over the Indian region using MODIS products 利用 MODIS 产品对印度地区生物质燃烧的时空变化进行长期研究
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-05 DOI: 10.1007/s12040-024-02351-x
SWAPNIL S POTDAR, DEVENDRAA SIINGH, R P SINGH

Spatiotemporal variations of biomass burning (BB) over the Indian region using satellite-based data from the Moderate Resolution Imaging Spectroradiometer (MODIS) for the period 2003–2021 are analyzed and studied. We have used fire products with a high confidence level (≥ 80%), which is free from false alarm fires. The total fire counts (TFC), fire radiative power (FRP), and burned area (BA) for different land use and land cover (LULC) types over six different regions, namely Central India (CI), Indian Gangetic Plain (IGP), North-East India (NEI), North India (NI), South India (SI) and West India (WI) are studied. The biomass burning shows spatial, seasonal and inter-annual variations. Within the regions, different hotspots are identified for cropland burning, forest burning, etc. It is observed that in the IGP and WI regions, burning activity shows bi-modal seasonal behaviour, which coincides with crop burning after harvesting seasons, while other regions show a single mode. Non-parametric long-term analysis in TFC and TFRP (derived by adding FRP of all the fire hotspots in a respective year) shows a positive trend over all the regions except in the NEI region. The decreasing TFC with increasing precipitation is also observed in all the considered regions, which is attributed to enhanced moisture and decreased temperature. The present study provides the scientific basis for addressing the origin and type of biomass burning in different regions of India, and it is quite useful for developing procedures, awareness, and planning for reducing BB, which is quite harmful to human health as well as the environment.

利用中分辨率成像分光仪(MODIS)提供的 2003-2021 年印度地区生物质燃烧(BB)的卫星数据,对其时空变化进行了分析和研究。我们使用了高置信度(≥ 80%)的火灾产品,其中不含误报火灾。我们研究了印度中部(CI)、印度恒河平原(IGP)、印度东北部(NEI)、印度北部(NI)、印度南部(SI)和印度西部(WI)六个不同地区不同土地利用和土地覆被类型的总火灾次数(TFC)、火灾辐射功率(FRP)和燃烧面积(BA)。生物质燃烧呈现出空间、季节和年际变化。在这些区域内,耕地燃烧、森林燃烧等热点地区各不相同。据观察,在 IGP 和 WI 地区,焚烧活动呈现双模季节性行为,与收获季节后的作物焚烧相吻合,而其他地区则呈现单一模式。对 TFC 和 TFRP(将相应年份所有火灾热点的 FRP 相加得出)的非参数长期分析表明,除东北地区外,所有地区的 TFC 和 TFRP 均呈正趋势。在所有研究区域,随着降水量的增加,TFC 也呈下降趋势,这归因于湿度的增加和温度的降低。本研究为解决印度不同地区生物质燃烧的起源和类型问题提供了科学依据,对于制定减少对人类健康和环境造成严重危害的 BB 的程序、意识和规划非常有用。
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引用次数: 0
Automated detection of landslide events from multi-source remote sensing imagery: Performance evaluation and analysis of YOLO algorithms 从多源遥感图像中自动检测滑坡事件:YOLO 算法的性能评估和分析
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-02 DOI: 10.1007/s12040-024-02327-x
Naveen Chandra, Himadri Vaidya

Landslides are among the most dangerous and catastrophic natural hazards with countless concerns. In disaster rescue operations, fast and precise identification of landslides is necessary for timely and effective preventive actions. The landslide risk is anticipated to be reduced through their prediction, monitoring, and accurate detection using remote sensing technology. Moreover, deep learning algorithms have shown excellent improvement in various remote sensing applications. Recent scientific and intelligent technological innovations are needed to be applied to disaster management and assessment, particularly landslides. Therefore, this study aims to extract the landslide hazard information from multiple data sources, i.e., satellite and unmanned aerial vehicle (UAV) images, using a single staged object detection model, i.e., YOLOv5, YOLOv6, YOLOv7, and YOLOv8. The data from distinct platforms are utilized to infer the synergies between them. The results of each database are evaluated quantitatively using standard methods, i.e., precision, recall, f-score, and mean average precision, whereas visual analysis of results is conducted for qualitative assessment. Based on the experimental results, the highest f-score is represented by YOLOv7 (0.995) and YOLOv5 (0.921) for satellite and UAV-based data, respectively. The quantitative results are further compared with previous research work to exhibit the novelty and competence of the proposed research. Our work demonstrates the application and feasibility of the YOLO model in landslide information extraction for quick hazard recovery operations.

山体滑坡是最危险、最具灾难性的自然灾害之一,令人担忧。在灾害救援行动中,必须快速准确地识别山体滑坡,以便采取及时有效的预防措施。通过遥感技术对山体滑坡进行预测、监测和精确检测,有望降低山体滑坡的风险。此外,深度学习算法在各种遥感应用中都有出色的改进。需要将最新的科学和智能技术创新应用于灾害管理和评估,尤其是山体滑坡。因此,本研究旨在从多种数据源(即卫星和无人机(UAV)图像)中提取山体滑坡危险信息,采用单一的分阶段物体检测模型,即 YOLOv5、YOLOv6、YOLOv7 和 YOLOv8。利用来自不同平台的数据来推断它们之间的协同作用。使用标准方法(即精确度、召回率、f-score 和平均精确度)对每个数据库的结果进行定量评估,同时对结果进行可视化分析以进行定性评估。根据实验结果,YOLOv7(0.995)和 YOLOv5(0.921)分别代表了卫星数据和无人机数据的最高 f-score。定量结果与之前的研究工作进行了进一步比较,以展示拟议研究的新颖性和能力。我们的工作证明了 YOLO 模型在山体滑坡信息提取中的应用和可行性,可用于快速灾害恢复行动。
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引用次数: 0
A novel approach for assessment of seismic induced liquefaction susceptibility of soil 评估地震诱发土壤液化敏感性的新方法
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-02 DOI: 10.1007/s12040-024-02341-z
Divesh Ranjan Kumar, Pijush Samui, Avijit Burman, Rahul Biswas, Sai Vanapalli

Liquefaction is one of the natural hazards that occurs due to earthquakes and has a significant impact on the loss of human lives and various civil infrastructures. In this study, metaheuristic ANN with optimization techniques (i.e., ANN-GWO, ANN-GTO, ANN-GAO, ANN-HHO, ANN-SSA, and ANN-SMA), machine learning techniques are used to predict the probability of liquefaction (({P}_{L})) from the SPT-based dataset. A dataset of 834 case histories, including seven geotechnical and seismic parameters, was used for training and testing different metaheuristic algorithms. The performance of the proposed machine learning algorithm used at every stage of analysis includes statistical parameters evaluation, score analysis, actual vs. predicted curve, error matrix, Taylor diagram, OBJ criteria, DDR criteria, and AIC criteria. The ANN-GTO model has been found to be the best model for the prediction of the probability of liquefaction potential of soil. However, all proposed models can successfully predict the liquefaction potential of soil with reasonably good accuracy. The proposed models can be used as a key tool in the prediction of the liquefaction susceptibility of any soil deposit.

液化是地震造成的自然灾害之一,对人类生命和各种民用基础设施的损失有重大影响。在这项研究中,元启发式优化 ANN(即 ANN-GWO、ANN-GTO、ANN-GAO、ANN-HHO、ANN-SSA 和 ANN-SMA)和机器学习技术被用来预测基于 SPT 数据集的液化概率(({P}_{L}))。834 个案例数据集包括七个岩土和地震参数,用于训练和测试不同的元启发式算法。所提出的机器学习算法在每个分析阶段的性能包括统计参数评估、得分分析、实际与预测曲线、误差矩阵、泰勒图、OBJ 标准、DDR 标准和 AIC 标准。研究发现,ANN-GTO 模型是预测土壤液化潜势概率的最佳模型。然而,所有提出的模型都能成功地预测土壤的液化潜势,且准确度相当高。所提出的模型可作为预测任何土壤沉积液化敏感性的重要工具。
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引用次数: 0
Investigating the spatial distribution of flood inundation and landforms using topographic position index (TPI) and geomorphon-based automated landform classification methods 利用地形位置指数(TPI)和基于地貌的自动地貌分类方法调查洪水淹没和地貌的空间分布情况
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-28 DOI: 10.1007/s12040-024-02343-x
Laxmi Gupta, Jagabandhu Dixit

The landform of the region highly influences the dynamics of the flood and plays a crucial role in directing the water flow, affecting the speed and volume of runoff. Assam, located in northeast India, experiences floods yearly due to adverse climatic conditions and complex terrain features. The objective of the present study is to understand the landform classification of Assam using the topographic position index (TPI) and geomorphon-based automated classification of landform (ACL) method and its spatial distribution with slope, geology, soil, LULC, and flood inundation. The ACL method shows that gentle slopes or flat areas occupy the maximum area ranging from 56.17 to 68.10% for TPI‐based slope position classes, and for geomorphon, slope feature occupies 20.61–25.39% of the total area. The spatial distribution of TPI and geomorphon-based landform classification was different because TPI compares the elevation of a point to the average elevation of its neighbourhood, while geomorphon classifies the landscape into predefined landform classes based on terrain shape and the spatial arrangement of elevation values. In both models, valleys are the most dominant landform class and are mainly present in the Central and Barak valley of Assam. The built-up areas and waterbodies on vulnerable landform classes increase their flood susceptibility. About 38.08% of the inundated area was found in wide valleys and 31% of the inundated area lies under flat landforms. The present study can be effective in land use planning, sustainable natural resource management, disaster risk management, and mitigation strategies.

该地区的地貌对洪水的动态影响很大,在引导水流、影响径流速度和流量方面起着至关重要的作用。阿萨姆邦位于印度东北部,由于不利的气候条件和复杂的地形特征,每年都会发生洪水。本研究的目的是利用地形位置指数(TPI)和基于地貌的地貌自动分类法(ACL)了解阿萨姆邦的地貌分类及其与坡度、地质、土壤、土地利用、土地利用变化和洪水淹没的空间分布。ACL 方法表明,在基于 TPI 的坡度位置分类中,缓坡或平坦区域所占面积最大,占总面积的 56.17% 至 68.10%;在地貌分类中,坡度特征占总面积的 20.61% 至 25.39%。基于 TPI 的地貌分类和基于地貌的地貌分类在空间分布上有所不同,这是因为 TPI 将一个点的高程与其邻近地区的平均高程进行比较,而地貌则根据地形形状和高程值的空间排列将景观划分为预定义的地貌类别。在这两种模型中,山谷是最主要的地貌类别,主要存在于阿萨姆邦的中部和巴拉克山谷。易受影响的地貌等级上的建筑密集区和水体增加了其洪水易感性。约 38.08% 的淹没区位于宽谷中,31% 的淹没区位于平坦地貌中。本研究可用于土地利用规划、可持续自然资源管理、灾害风险管理和减灾战略。
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引用次数: 0
Gold occurrence and pyrite trace elements in the Xiejiagou gold deposit, Jiaodong Peninsula, China: Implications for the mineralization process 中国胶东半岛谢家沟金矿床的金赋存与黄铁矿痕量元素:对成矿过程的影响
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-28 DOI: 10.1007/s12040-024-02328-w
Lei Chen, Dongsheng Ding, Wei Jian

Te–Bi bearing minerals are commonly present in many hydrothermal gold deposits and can provide important physicochemical constraints on their mineralization. The gold mineralization in the Xiejiagou gold deposit is hosted in the Mesozoic Linglong granite and consists of auriferous quartz veins and subordinate disseminated ores in the vein-proximal alteration zone. Three types of pyrite were identified that formed in stage I, II, and III. Gold occurs mostly as native gold and electrum (Ag > 20 wt.%) inclusions in or filling microfractures in pyrite. The abundant auriferous pyrite-quartz veins contain an assemblage of tsumoite and hessite. The tsumoite occurs as irregular inclusions in the Py1 and is intergrown with the chalcopyrite. The hessite occurs as irregular inclusions or along the margins of the Py2, and it coexists with the gold and galena. The tellurium fugacity continually decreased from stage I (log fTe2 = −8.8 to −10.7) to stage III (log fTe2 = −13.8 to −17.0). The sulfur fugacity increased from stage I (log fS2 = −8.6 to −11.4) to stage II (log fS2 = −7.2 to −11.4), and then, it decreased from stage II to stage III (log fS2 = −9.8 to −13.0). These data indicate the conditions of the gold precipitation during the ore formation process. A detailed study of gold distribution in texturally different pyrite and the paragenetic association of tellurides provide valuable information on the distribution pattern of gold and in understanding the processes of gold deposition and evolution.

含Te-Bi的矿物通常存在于许多热液金矿床中,可为其成矿提供重要的物理化学制约。谢家沟金矿床的金矿化赋存于中生代玲珑花岗岩中,由含金石英脉和脉状近端蚀变带中的次生浸染状矿石组成。经鉴定,在第一、第二和第三阶段形成了三种类型的黄铁矿。金主要以原生金和银(Ag > 20 wt.%)包裹体的形式出现在黄铁矿中或填充在黄铁矿的微裂隙中。丰富的含金黄铁矿-石英矿脉中含有黝帘石和辉锑矿的集合体。黝帘石以不规则的包裹体形式出现在 Py1 中,并与黄铜矿相互交错。辉锑矿以不规则包裹体的形式或沿 Py2 的边缘出现,与金和方铅矿共生。碲富集度从第一阶段(log fTe2 = -8.8 至 -10.7)持续下降到第三阶段(log fTe2 = -13.8 至 -17.0)。硫富集度从第一阶段(log fS2 = -8.6 至 -11.4)上升到第二阶段(log fS2 = -7.2 至 -11.4),然后从第二阶段下降到第三阶段(log fS2 = -9.8 至 -13.0)。这些数据表明了金在矿石形成过程中的沉淀条件。详细研究金在不同质地黄铁矿中的分布以及碲化物的副成因关联,可为了解金的分布模式以及金的沉积和演化过程提供有价值的信息。
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引用次数: 0
Gradient descent fusion for gravity and magnetic data 梯度下降融合重力和磁力数据
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-24 DOI: 10.1007/s12040-024-02334-y
Chandra Prakash Dubey, Laxmi Pandey, K V Rajalakshmi

Subsurface characterization is a crucial aspect of geophysical exploration, enabling the identification and understanding of valuable geological bodies and resources. In this context, joint inversion of gravity and magnetic data has emerged as a powerful geophysical exploration technique, allowing for a more coherent and consistent interpretation of subsurface structures. The study focuses on understanding residual gravity and magnetic anomalies by employing the gradient descent-based joint inversion approach. A MATLAB program was developed to determine the inverse gravitational and magnetic anomalies using the gradient descent approach. We explored the potential of 2D rectangular prisms as a popular geometry to represent mineralized bodies and oil and gas structures. To overcome the non-uniqueness issues, we designed code for joint inversion of gravity and magnetic data. Synthetic data was inverted using the gradient descent technique and compared with the least-squares approach. Numerical simulations and real data application successfully reconstructed the geometry of the prisms. An illustrative example of a prism fault was used for further evaluation. Real data from the Oka complex in Quebec, Canada, was collected from the literature and subjected to joint and individual gravity and magnetic modelling. The results highlighted the influence of heterogeneous mass distribution on matching forward anomalies. The high gravity anomaly in the Oka complex was attributed to carbonatite and silicate rocks. The presence of two intrusive centres within the complex caused the magnetic high. This work demonstrates the effectiveness of the gradient descent approach as it consistently outperformed the conventional method, offering a robust solution for subsurface characterization in geophysical exploration.

地表下特征描述是地球物理勘探的一个重要方面,它有助于识别和了解有价值的地质体和资源。在此背景下,重力和磁力数据的联合反演已成为一种强大的地球物理勘探技术,可对地下结构进行更加连贯一致的解释。本研究采用基于梯度下降的联合反演方法,重点了解残余重力和磁力异常。我们开发了一个 MATLAB 程序,利用梯度下降法确定反演重力和磁力异常。我们探索了二维矩形棱柱作为一种常用几何体来表示矿化体和油气结构的潜力。为了克服非唯一性问题,我们设计了重力和磁力数据联合反演代码。使用梯度下降技术对合成数据进行反演,并与最小二乘法进行比较。数值模拟和实际数据应用成功地重建了棱镜的几何形状。在进一步评估中使用了棱镜断层的示例。从文献中收集了加拿大魁北克奥卡综合体的真实数据,并对其进行了联合和单独重力和磁力建模。结果凸显了异质体分布对匹配前向异常的影响。奥卡综合体的高重力异常归因于碳酸盐岩和硅酸盐岩。复合体中两个侵入中心的存在导致了高磁性。这项工作证明了梯度下降方法的有效性,因为该方法的性能一直优于传统方法,为地球物理勘探中的地下特征描述提供了一个可靠的解决方案。
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引用次数: 0
Evidence of deep subsurface carbon–sulfur geochemistry in a sediment core from the eastern Arabian Sea 阿拉伯海东部沉积岩芯中的深层地下碳硫地球化学证据
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-18 DOI: 10.1007/s12040-024-02330-2
Aninda Mazumdar, Aditya Peketi, Namrata Khadke, Subhashree Mishra, Kalyani Sivan, Ankita Ghosh, Sai Pavan Kumar Pillutla, Mohammad Sadique, Anjali Zatale

Deep biospheric anaerobic microbial sulfate reduction and oxidative sulfur cycling have been studied in long sediment cores mainly acquired as part of IODP explorations. The most remarkable observation in many of these studies is the existence of an active sulfur cycle in the deep subsurface sediments that have very low organic carbon content and are presumably refractory. Here, we investigate the interstitial sulfate concentrations and sulfur isotope ratios in a 290 m-long sediment core collected from the eastern Arabian Sea at a water depth of 2663 m. Continuous decrease in porewater-sulfate concentrations with depth (up to 75 mbsf) coupled with enrichment in δ34SSO4 values suggests organoclastic sulfate reduction (OSR) processes attributed to the activity of sulfate-reducing bacteria (SRB) and retention of labile organic substrates amenable to the SRBs. Below a depth of 75 mbsf, the absence of further reduction in sulfate concentration indicates insufficient labile substrate to drive sulfate-reduction activity. An increase in sulfate concentrations at the deeper subsurface (below 128.5 mbsf) coupled with decreasing δ34SSO4 values may be attributed to the oxidation of Fe-sulfide to sulfate. The increase in porewater alkalinity in the lower part of the core has been linked to the silicate degradation process by CO2 produced via the dissolution of CaCO3. Compilation of previous studies from this core, along with our investigation, intrigues future research on organic matter reactivity and microbiological activity in deeper subsurface under oligotrophic depositional regimes.

对深层生物圈厌氧微生物硫酸盐还原和氧化硫循环的研究主要是在国际大洋钻探计划 (IODP)勘探过程中获得的长沉积岩芯中进行的。在许多此类研究中,最引人注目的观察结果是在有机碳含量极低、可能具有耐火性的深层地下沉积物中存在着活跃的硫循环。孔隙水硫酸盐浓度随深度(最深 75 mbsf)的持续降低以及 δ34SSO4 值的富集表明,有机脆硫酸盐还原(OSR)过程归因于硫酸盐还原菌(SRB)的活动以及适合 SRB 的易变有机基质的保留。在 75 mbsf 深度以下,硫酸盐浓度没有进一步降低,表明没有足够的可溶性基质来驱动硫酸盐还原活动。在更深的地下(128.5 mbsf 以下),硫酸盐浓度增加,δ34SSO4 值下降,这可能是由于硫化亚铁被氧化成硫酸盐所致。岩芯下部孔隙水碱度的增加与 CaCO3 溶解产生的 CO2 使硅酸盐降解过程有关。对该岩心以前的研究以及我们的调查进行汇编,有助于今后对低营养沉积机制下更深地下的有机物反应性和微生物活动进行研究。
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引用次数: 0
Geochemical trends in sedimentary environments using PCA approach 利用 PCA 方法分析沉积环境中的地球化学趋势
IF 1.9 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-18 DOI: 10.1007/s12040-024-02306-2
Deepshikha Srivastava, Chandra Prakash Dubey, Upasana Swaroop Banerji, Kumar Batuk Joshi

Investigating the geochemical composition of bulk sediments stands as a crucial method for unraveling the complexities of various sedimentary processes. However, the intricacies arising from extensive datasets and alterations in sediment due to diverse factors often impede the clear identification of underlying patterns in geochemical fluctuations. In addressing these, employing multivariate statistical analyses has proven to be an invaluable tool for elucidating intricate patterns within large dataset. In this study, we focus on the utilization of Principal Component Analysis (PCA), a multivariate statistical technique, to uncover the underlying sedimentary processes influencing distinct geochemical dataset. Specifically, our attention is directed towards the examination of geochemical data from the previously published geochemical data of metasediments from Shimla and Chail group (referred to as SCM) and the mudflat sediments of Diu Island (referred to as DMS). Our PCA outcomes reveal that the initial three principal components (PC1, PC2, and PC3) account for 52.51% and 79.30% of the total variance within the SCM and DMS geochemical data, respectively. Notably, the negative loading of SiO2, alongside positive loadings of incompatible elements and those associated with mafic rocks on PC1 within the SCM dataset, indicates sediment origins ranging from felsic to intermediate sources. Additionally, the coexistence of Th, U, Zr, and Sc, exhibiting positive loadings in PC1 and PC2, suggests a significant influence of reworking and recycling from felsic to intermediate sources. In the context of the DMS dataset, PCA analysis highlights the dominant influence of in-situ productivity and mafic sediment sources along the positive axis of PC1. Conversely, the negative axis of PC1 is shaped by intermediate and potentially other sources. Further granularity in interpretation reveals the positive axis of PC2 being attributed to weathering proxies, while the dominance of plagioclase minerals in the clayey fraction controls the positive axis of PC3. Through this investigation, our study underscores the essential role of PCA-assisted geochemical data analysis in unraveling the intricate web of processes contributing to the variance observed within sedimentary systems. By effectively distilling the multifaceted factors driving geochemical variability, this approach emerges as a pivotal asset in enhancing our understanding of sedimentary dynamics.

调查大量沉积物的地球化学组成是揭示各种沉积过程复杂性的重要方法。然而,广泛的数据集和各种因素导致的沉积物变化所产生的错综复杂的问题,往往会妨碍清楚地识别地球化学波动的基本模式。在解决这些问题时,采用多元统计分析已被证明是在大型数据集中阐明复杂模式的宝贵工具。在本研究中,我们重点利用主成分分析(PCA)这一多元统计技术来揭示影响不同地球化学数据集的潜在沉积过程。具体来说,我们的注意力集中在对之前公布的西姆拉和柴尔群(简称 SCM)的玄武岩地球化学数据以及迪乌岛(简称 DMS)的泥滩沉积物地球化学数据的研究上。我们的 PCA 结果显示,最初的三个主成分(PC1、PC2 和 PC3)分别占 SCM 和 DMS 地球化学数据总方差的 52.51% 和 79.30%。值得注意的是,在 SCM 数据集的 PC1 中,SiO2 的负载荷以及不相容元素和与岩浆岩有关的元素的正载荷表明,沉积物的来源从长岩到中岩都有。此外,Th、U、Zr 和 Sc 同时出现在 PC1 和 PC2 中,并显示出正负载,这表明从长石源到中间源的再加工和再循环具有重要影响。就 DMS 数据集而言,PCA 分析凸显了 PC1 正轴上原位生产力和岩浆沉积物来源的主要影响。相反,PC1 的负轴则由中间来源和潜在的其他来源形成。进一步的粒度解释显示,PC2 的正轴归因于风化代用指标,而粘土质部分的斜长石矿物则控制着 PC3 的正轴。通过这项调查,我们的研究强调了 PCA 辅助地球化学数据分析在揭示沉积系统内导致所观察到的差异的错综复杂过程方面的重要作用。通过有效地提炼出驱动地球化学变异的多方面因素,这种方法在增强我们对沉积动力学的理解方面具有举足轻重的作用。
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引用次数: 0
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Journal of Earth System Science
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