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EVALUATION OF THE DISPERSANTS EFFECTIVENESS USING THE BAFFLED FLASK TEST 用折流板烧瓶试验评价分散剂的有效性
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-02-03 DOI: 10.3846/jeelm.2022.16317
Natalia Grechishcheva, A. Kuchierskaya, A. Semenov, D. Kuryashov, I. Meritsidi, R. Mingazov
The use of chemical dispersants is one of the most widely used methods for responding to oil spills. The most important characteristic of dispersants is their effectiveness. The dispersant effectiveness is a measure of how well the dispersant breaks up and stabilizes the oil into the water column. In this paper, we studied the dispersing ability of three proprietary dispersants with respect to light and heavy crude oils of Usinsk and Nagornoye fields with a density of 0.816 g/cm3 and 0.896 g/cm3, respectively. The dispersant effectiveness was determined using a Baffled Flask Test; dispersant was applied to the oil slick, mixed, and the concentration of oil in a sample taken from the water column was measured using UV-Visible spectrophotometry. A modification of the standard technique is proposed to minimize the error of the method for the heavy crude oil by eliminating the error associated with inaccuracy of dosing. For this purpose, oil of the Nagornoye field was added to the tested systems not “by volume”, but “by weight”. It was provided better convergence of the experimental results. The standard deviation in the case of dosing of oil “by volume” exceeded 10% and varied from 11.87% to 13.59%. The introduction of oil “by weight” was much lower and varied from 5.66% to 6.30%. Studied dispersants have a higher dispersing ability for the less dense oil of the Usinsk field.
使用化学分散剂是应对石油泄漏最广泛使用的方法之一。分散剂最重要的特点是其有效性。分散剂的有效性是衡量分散剂分解和稳定油进入水柱的程度。本文研究了三种专用分散剂对Usinsk油田和Nagornoye油田轻质原油和重质原油的分散能力,密度分别为0.816g/cm3和0.896g/cm3。使用挡板烧瓶试验测定分散剂的有效性;将分散剂应用于浮油,混合,并使用紫外-可见分光光度法测量从水柱中提取的样品中的油浓度。建议对标准技术进行修改,通过消除与定量不准确相关的误差,将重质原油方法的误差降至最低。为此,纳戈尔诺耶油田的石油不是“按体积”而是“按重量”添加到测试系统中。实验结果具有较好的收敛性。在“按体积”投加油的情况下,标准偏差超过10%,从11.87%到13.59%不等。“按重量”投加的油要低得多,从5.66%到6.30%不等。所研究的分散剂对乌辛斯克油田密度较低的油具有较高的分散能力。
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引用次数: 1
VEGETATION CHANGE IN ROAD SLOPES IN THE MEDITERRANEAN REGION OVER 25 YEARS 25年来地中海地区道路斜坡植被变化
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-02-02 DOI: 10.3846/jeelm.2022.16324
Álvaro Enríquez‐de‐Salamanca
Revegetation effectiveness requires long-term monitoring. We analysed 50 road slopes 5–8 years and 22–25 years after revegetation. Plant cover and diversity increased over time, with differences between slope types; herbaceous cover increased greatly between revegetation works and 2002 and was similar in 2002 and 2019, while woody cover decreased from revegetation to 2002 but increased greatly between 2002 and 2019. Plant colonisation was more intense on embankments, but could also be achieved on roadcuts (2.4 points on average over a maximum of 5). The presence of sown species decreased over time, but the presence of planted species remained stable. Hydroseeding had poor results in terms of the resulting plant cover, but nevertheless succeeded in slowing erosion at least sufficiently to allow early plant establishment and thus the start of colonisation. The similarity between surrounding vegetation and the slopes was greater in roadcuts. Roads are a gateway for invasive plants. Native species can improve the results, but many are missing from the market. Slopes’ plant cover changed over time; long-term studies are required.
植被恢复效果需要长期监测。我们分析了50条道路边坡在植被恢复后的5-8年和22-25年。植物盖度和多样性随时间的推移而增加,但坡型之间存在差异;植被覆盖度与2002年相比大幅增加,2002年和2019年基本持平,而木本覆盖度与2002年相比有所下降,但2002年和2019年之间大幅增加。植物定殖在路堤上更为强烈,但在道路上也可以实现(最多5个平均2.4个点)。播种物种的存在随着时间的推移而减少,但种植物种的存在保持稳定。就所产生的植物覆盖而言,加氢播种的效果很差,但尽管如此,它成功地减缓了侵蚀,至少足以让植物早期生长,从而开始殖民。路堑周围植被与斜坡的相似性更大。道路是入侵植物的入口。本地物种可以改善结果,但许多物种在市场上缺失。坡面植被随时间变化;需要长期研究。
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引用次数: 1
RELATIONSHIP BETWEEN GENETIC AND ENVIRONMENTAL CHARACTERISTICS OF LITHUANIAN POPULATIONS OF PURPLE LOOSESTRIFE (LYTHRUM SALICARIA) 李种群遗传与环境特征的关系
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-02-02 DOI: 10.3846/jeelm.2022.16303
L. Jocienė, E. Krokaitė, D. Shakeneva, T. Rekašius, V. Stanys, J. B. Šikšnianienė, D. Žvingila, A. Paulauskas, E. Kupčinskienė
The present study evaluated genetic diversity of Lithuanian populations of Lythrum salicaria in relation to parameters of riparian environment. Growing along Nemunas, Seaside and Lielupė river basins, 15 populations were examined using amplified fragment length polymorphism markers. Molecular data were related to the river basins, type of land use and cover, natural vice versa regulated fragments of the rivers. Population mean genetic diversity parameters were as follows: percentage of polymorphic loci (57.2), expected heterozygosity (0.183), polymorphismc information content (0.218). Mantel test revealed correlation (R2 = 0.0986, p = 0.01) between genetic and geographic distance of populations. Greater genetic diversity within, rather than among populations (ΦPT = 0.213) was observed. According to the Bayesian clustering, studied populations are admixtures of two gene pools. Analysis of molecular variance revealed significant differentiation between populations belonging to distinct river basins, between populations from natural vs. regulated fragments of the rivers.
本研究利用河岸环境参数评价了立陶宛水杨曲(Lythrum salicaria)居群的遗传多样性。利用扩增片段长度多态性标记对生长在Nemunas、Seaside和lielupnik河流域的15个种群进行了检测。分子数据与河流流域、土地利用类型和覆被有关,反之亦然。群体平均遗传多样性参数为:多态性位点百分率(57.2)、期望杂合度(0.183)、多态性信息含量(0.218)。Mantel检验表明,种群遗传距离与地理距离呈正相关(R2 = 0.0986, p = 0.01)。种群内遗传多样性大于种群间遗传多样性(ΦPT = 0.213)。根据贝叶斯聚类,研究群体是两个基因库的混合物。分子变异分析显示,不同流域的种群之间、自然种群与调节种群之间存在显著差异。
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引用次数: 6
COMBINED ACTION OF ADSORPTION AND CATALYTIC OXIDATION IN ALUMINUM DYE REMOVAL BY GROUNDWATER TREATMENT WASTE 吸附与催化氧化联合作用在地下水处理废水中去除铝染料的研究
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-01-27 DOI: 10.3846/jeelm.2022.16286
Edita Sodaitienė, D. Kaušpėdienė, A. Gefenienė, R. Ragauskas, R. Ramanauskas
The performance of groundwater treatment waste (GWTW) as an adsorbent and catalyst in the decoloration of aluminum dye Sanodure green LWN (SG) solution was investigated. The raw GWTW was more suitable for dye removal than calcined at 800 °C temperature. The catalytic activity of GWTW in Fenton-like reactions in sunlight increases with decreasing pH from 5.5 to 2.5 and increasing temperature from 20 to 60 °C. The rate of 70% decoloration in the first 5 min and 92% after 50 min of 100 mg/L SG dye solution was reached at 50 °C and pH 3. Kinetics of the SG dye color removal fitted well with the double exponential and two-stage pseudo-first-order kinetic models. The activation energy of the first stage of the SG dye degradation reaction is 30.45 kJ/mol. GWTW could be re-used for the pre-treatment of dye-contaminated wastewater before entering the wastewater treatment plant.
研究了地下水处理废水(GWTW)作为吸附剂和催化剂对铝染料Sanodure绿色LWN(SG)溶液脱色的性能。原料GWTW比在800°C温度下煅烧更适合去除染料。GWTW在阳光下类Fenton反应中的催化活性随着pH从5.5降低到2.5和温度从20升高到60°C而增加。100 mg/L SG染料溶液在50°C和pH值为3的条件下,前5分钟脱色率达到70%,50分钟后脱色率达到92%。SG染料脱色动力学符合双指数和两阶段拟一阶动力学模型。SG染料降解反应第一阶段的活化能为30.45kJ/mol。GWTW可以在进入废水处理厂之前重新用于染料污染废水的预处理。
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引用次数: 0
SYNTHESIS OF FEOOH AND FEOOH@ZNO BY HYDROTHERMAL METHOD AND THE ADSORPTION OF S2- IN WASTEWATER FEOOH和FEOOH@ZNO水热法与废水中S2的吸附
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-01-24 DOI: 10.3846/jeelm.2022.16251
Baocai Ge, Fen Li, F. Meng, Ying Yang, Cailian Yu
FeOOH and FeOOH@ZnO were prepared by hydrothermal synthesis, and their structures and adsorption properties toward S2− were studied. The results showed that too high hydrothermal temperature was not conducive to the adsorption of S2−. However, using sodium dodecyl sulfate (SDS) for FeOOH preparation and adding nanometer ZnO (FeOOH@ZnO) could significantly improve the adsorption of S2− by FeOOH, and adsorption removal rate was close to 90.0% and adsorption amount was 87.5 mg·g−1. The structural analysis showed that the modification of FeOOH by SDS and the addition of nano-ZnO resulted in the reduction in size of the FeOOH particles, forming amorphous inclusion structure with ZnO present inside and FeOOH outside. The specific surface area of FeOOH@ZnO was found to be higher than that of FeOOH. Therefore, it is beneficial to the adsorption of S2−. XPS fitting results showed that ferrous deposits appeared in the process of adsorption of S2− by FeOOH@ZnO, and it was considered that the oxygen of Fe = O was replaced with sulfur.
FeOOH和FeOOH@ZnO采用水热合成方法制备了它们,并研究了它们的结构和对S2−的吸附性能。结果表明,过高的水热温度不利于S2−的吸附。然而,使用十二烷基硫酸钠(SDS)制备FeOOH并添加纳米ZnO(FeOOH@ZnO)能显著提高FeOOH对S2−的吸附,吸附去除率接近90.0%,吸附量为87.5mg·g−1。结构分析表明,SDS对FeOOH的改性和纳米ZnO的加入使FeOOH颗粒的尺寸减小,形成了内有ZnO、外有FeOOH无定形包裹体结构。的比表面积FeOOH@ZnO发现其高于FeOOH。因此,有利于S2−的吸附。XPS拟合结果表明,在S2−FeOOH@ZnO,并且认为Fe=O的氧被硫取代。
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引用次数: 1
USE OF THE SSIB4/TRIFFID MODEL COUPLED WITH TOPMODEL TO INVESTIGATE THE EFFECTS OF VEGETATION AND CLIMATE ON EVAPOTRANSPIRATION AND RUNOFF IN A SUBALPINE BASIN OF SOUTHWESTERN CHINA SSIB4/trifid模型与topp模型相结合研究植被和气候对西南亚高山流域蒸散和径流的影响
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-01-21 DOI: 10.3846/jeelm.2022.15227
Huiping Deng, L. Dan, Huan-guang Deng, Yan Xiao, Qian Wang
It is important to understand the response of vegetation dynamics and surface water budget to the changing climate. To investigate the effects of vegetation and climate change on evapotranspiration and runoff on a basin scale, the SSiB4T/TRIFFID (SSiB4/TRIFFID coupled with TOPMODEL) is used to perform long-term dynamic simulations of vegetation succession and the water balance under different climate scenarios for a subalpine basin. The results of all experiments show that fraction of vegetation changes from a dominance of C3 grasses to tundra shrubs and then gradually approaches equilibrium with a dominance of forests. Change to evapotranspiration is very sensitive to temperature changes but is not sensitive to precipitation changes when the temperature remains unchanged. Runoff is very sensitive to changes in both temperature and precipitation. In the increase of temperature, evapotranspiration of forests increases the most among the three vegetation types. From the control run to the [T+5, (1+40%)P] run (A temperature increase of 5 °C, an increase in precipitation of 40%), the role of forests in increasing runoff changes to a reduction in runoff.
了解植被动态和地表水收支对气候变化的响应具有重要意义。为了研究植被和气候变化对流域尺度上蒸散发和径流的影响,利用SSiB4T/TRIFFID (SSiB4/TRIFFID耦合TOPMODEL)对不同气候情景下亚高山流域植被演替和水分平衡进行了长期动态模拟。所有实验结果表明,植被比例由C3禾本科为主向灌丛为主逐渐趋于平衡,并以森林为主。温度不变时,蒸散发变化对温度变化非常敏感,对降水变化不敏感。径流对温度和降水的变化都非常敏感。随着温度的升高,三种植被类型中森林的蒸散量增加最多。从对照径流到[T+5, (1+40%)P]径流(温度升高5°C,降水增加40%),森林增加径流的作用转变为减少径流。
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引用次数: 0
DYNAMIC SIMULATION AND RANKING OF USING RESIDENTIAL-SCALE SOLAR WATER HEATER IN IRAN 伊朗住宅规模太阳能热水器使用动态仿真及排序
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-01-17 DOI: 10.3846/jeelm.2022.15483
S. Rezapour, M. Jahangiri, Arezoo Ghadiri Shahrezaie, A. Goli, Rouhollah Yadollahi Farsani, K. Almutairi, Hoa Xuan Ao, Seyyed Jalaladdin Hosseini Dehshiri, Seyyed Shahabaddin Hosseini Dehshiri, A. Mostafaeipour, K. Techato
A decrease in the utilization of fossil energies, mainly by replacing them with renewable energy sources (RESs), is regarded as a potential energy source in today’s applications. RESs are broadly utilized for heating purposes and particularly with applications in solar water heater (SWH). Despite the accessibility of SWH technologies and their affordable prices in Iran, there is no comprehensive study to explain the potential of Iranian regions to supply hot water for household applications. This one-year work, hence, attempts the first dynamical simulation of a solar heating system to provide sanitary hot water (SHW) as well as hot water demanded to heat 47 stations in Iran. Weather data were extracted from METEONORM and environmental-technical analyses performed by thermal solar (TSOL) software. Stations were ranked based on CCR and BCC models in data envelopment analysis (DEA) method using GAMS V 24.1. As with results, a total of 223.1 MWh solar heat is generated annually from all stations that prevent the emission of 64.5 t CO2 every year. According to CCR and BCC models, Bandar Abbas, Chabahar, Fasa, Iranshahr, Kermanshah, Khoramabad, Sarab, Shahr-e-kord, Yasuj, Zanjan, and Zahedan are the best in this regard. Also according to the economic analysis, the average price of home solar heating in Iran is 0.160 $/kWh.
在今天的应用中,减少化石能源的利用,主要是用可再生能源代替化石能源,被认为是一种潜在的能源。RESs广泛用于加热目的,特别是在太阳能热水器(SWH)中的应用。尽管在伊朗,SWH技术的可获得性和可承受的价格,但没有全面的研究来解释伊朗地区为家庭提供热水的潜力。因此,这项为期一年的工作尝试首次对太阳能加热系统进行动态模拟,以提供卫生热水(SHW)以及伊朗47个站所需的热水。气象数据提取自METEONORM,环境技术分析由热太阳能(TSOL)软件进行。采用GAMS V 24.1数据包络分析(DEA)方法,基于CCR和BCC模型对站点进行排名。其结果是,所有站每年总共产生223.1兆瓦时的太阳能热量,每年防止排放64.5吨二氧化碳。根据CCR和BCC模型,阿巴斯港、恰巴哈尔、法萨、伊朗沙赫尔、克尔曼沙阿、霍拉马巴德、萨拉布、沙赫尔-e-kord、Yasuj、赞詹和扎黑丹在这方面是最好的。同样根据经济分析,伊朗家庭太阳能供暖的平均价格为0.160美元/千瓦时。
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引用次数: 7
INVESTIGATION AND MODELING OF TRANSPORT NOISE DEPENDENCE ON TRAFFIC SPEED AND IMPACT ON POPULATION ANNOYANCE 交通噪声对交通速度的依赖性及其对人群烦恼度影响的研究与建模
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-01-13 DOI: 10.3846/jeelm.2022.16275
Tomas Vilniškis, Andrej Naimušin, T. Januševičius
Transport noise is a serious problem in cities and has a negative impact on both health and economics. In addition to the aforementioned unnoticed health effects, traffic noise has also been identified as one of the leading causes of sleep disorders, annoyance and negative cardiovascular effects. This research consists of three parts: part one involves onsite measurements of traffic noise in Trakai town; part two simulates traffic noise at different average vehicle speeds; part three assesses the number of people affected by traffic noise. The carried-out simulation has demonstrated that the noise level changes very slightly at different average vehicle speeds. It should be noticed that more noise is generated at average vehicle speed of 30 km/h rather than at 50 km/h. The assessment of the annoyance level has disclosed that an average vehicle speed of 30 km/h should cause the highest level of annoyance (highest – 26.8%).
交通噪音是城市中的一个严重问题,对健康和经济都有负面影响。除了上述未被注意到的健康影响外,交通噪音也被确定为睡眠障碍、烦恼和负面心血管影响的主要原因之一。本研究由三部分组成:第一部分为Trakai镇交通噪声的现场测量;第二部分模拟了不同平均车速下的交通噪声;第三部分评估了受交通噪声影响的人数。所进行的模拟表明,在不同的平均车速下,噪音水平变化很小。应该注意的是,在平均车速为30km/h时产生的噪音比在50km/h时更多。对烦恼程度的评估表明,30 km/h的平均车速应引起最高程度的烦恼(最高26.8%)。
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引用次数: 0
NITRATE REMOVAL IN WOODCHIP DENITRIFICATION BIOREACTOR – AN APPROACH COMBINING MATHEMATICAL MODELLING AND PI CONTROL 木屑反硝化生物反应器中硝酸盐去除——一种数学建模与PI控制相结合的方法
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-01-10 DOI: 10.3846/jeelm.2022.15295
Anatolij Nečiporenko, F. Ivanauskas, J. Dabulytė-Bagdonavičienė, A. Povilaitis, V. Laurinavicius
A mathematical model of nitrate removal in woodchip denitrification bioreactor based on field experiment measurements was developed in this study. The approach of solving inverse problem for nonlinear system of differential convection-reaction equations was applied to optimize the efficiency of nitrate removal depending on bioreactor’s length and flow rate. The approach was realized through the developed algorithm containing a nonlocal condition with an incorporated PI controller. This allowed to adjust flow rate for varying inflow nitrate concentrations by using PI controller. The proposed model can serve as a useful tool for bioreactor design. The main outcome of the model is a mathematical relationship intended for bioreactor length selection when nitrate concentration at the inlet and the flow rate are known. Custom software was developed to solve the system of differential equations aiming to ensure the required nitrate removal efficiency.
基于现场试验,建立了木片反硝化生物反应器去除硝酸盐的数学模型。采用求解微分对流反应方程非线性系统逆问题的方法,根据生物反应器的长度和流速来优化硝酸盐去除效率。该方法是通过包含非局部条件的算法和包含PI控制器来实现的。这允许通过使用PI控制器来调节不同流入硝酸盐浓度的流速。所提出的模型可作为生物反应器设计的有用工具。该模型的主要结果是当入口的硝酸盐浓度和流速已知时,用于生物反应器长度选择的数学关系。开发了自定义软件来求解微分方程组,旨在确保所需的硝酸盐去除效率。
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引用次数: 0
SIMULATION RESEARCH ON CARBON EMISSIONS TRADING BASED ON BLOCKCHAIN 基于区块链的碳排放权交易仿真研究
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-01-06 DOI: 10.3846/jeelm.2022.15107
Qing Zhou,Qi Zhang
Global warming caused by greenhouse gases is one of the problems that need to be solved urgently. Blockchain technology can achieve automatic quota certification and settlement, providing a new direction for carbon emissions trading. This paper provides a quantitative analysis of blockchain-based carbon emissions trading through the Repast simulation platform. Firstly, it designs the blockchain-based carbon emissions trading simulation framework from a macro perspective, including identity and quota certification, quota trading, risk prevention and smart contracts management. Then, it establishes a blockchain-based carbon emissions trading simulation model and formulates the behavior rules of the government, investors and company agents and market transaction processes. Finally, it simulates the carbon emissions trading based on public chain and private chain on the Repast platform, and analyzes the simulation results.
温室气体引起的全球变暖是亟待解决的问题之一。区块链技术可以实现自动配额认证和结算,为碳排放交易提供了新的方向。本文通过Repast仿真平台对基于区块链的碳排放交易进行了定量分析。首先,从宏观角度设计基于区块链的碳排放交易模拟框架,包括身份与配额认证、配额交易、风险防范和智能合约管理。然后,建立了基于区块链的碳排放交易仿真模型,制定了政府、投资者和公司代理人的行为规则和市场交易流程。最后,在Repast平台上对基于公链和私有链的碳排放权交易进行了仿真,并对仿真结果进行了分析。
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引用次数: 3
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Journal of Environmental Engineering and Landscape Management
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