Abradable coatings are essentially sealing materials and are deposited by thermal spray techniques. The main function of these coatings is to control the clearance of the gas path of the gas turbine engines. The abradable coating prevents turbine blade damage by abrading itself when there is an offset or vibration during turbine operation. Since the coating is meant to abrade, the preferred coating material is relatively softer than the turbine blade material. As these coatings are prone to solid particle erosion at high temperatures, the erosion response of these coatings at elevated temperatures needs to be investigated. In order to achieve this objective, MCrAlY boron nitride polymer coating was deposited employing an air plasma spraying technique on a Ni-base alloy substrate. The important features of the microstructure and mechanical properties of the coating were examined, and the coating was subjected to erosion at various temperatures under different erosion conditions. The results indicate a ductile erosion behaviour for an abradable top coat. The erosion rate increases with the temperature of the coating. The detailed results of the investigation are presented, and the erosion mechanisms are studied.
{"title":"Elevated temperature erosion of abradable seal coating","authors":"B. Malvi, M. Roy","doi":"10.5599/jese.1388","DOIUrl":"https://doi.org/10.5599/jese.1388","url":null,"abstract":"Abradable coatings are essentially sealing materials and are deposited by thermal spray techniques. The main function of these coatings is to control the clearance of the gas path of the gas turbine engines. The abradable coating prevents turbine blade damage by abrading itself when there is an offset or vibration during turbine operation. Since the coating is meant to abrade, the preferred coating material is relatively softer than the turbine blade material. As these coatings are prone to solid particle erosion at high temperatures, the erosion response of these coatings at elevated temperatures needs to be investigated. In order to achieve this objective, MCrAlY boron nitride polymer coating was deposited employing an air plasma spraying technique on a Ni-base alloy substrate. The important features of the microstructure and mechanical properties of the coating were examined, and the coating was subjected to erosion at various temperatures under different erosion conditions. The results indicate a ductile erosion behaviour for an abradable top coat. The erosion rate increases with the temperature of the coating. The detailed results of the investigation are presented, and the erosion mechanisms are studied.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"32 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84641191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Omar, Suhana Mohamed, Y. Yusuf, Toibah Abdul Rahim, Z. Mustafa, S. Ismail, I. Abu Bakar, Santirraprahkash Selvamani
Current attention has focused on the preparation of thick ceramic coating of nanostructured materials as feedstock material using the thermal spray process. The cold spray method has appeared as a promising process to form ceramic nanostructured coating without significantly changing the microstructure of the initial feedstock materials due to its low processing temperature. However, deposition of ceramic powders by cold spray is not easy due to the brittle characteristics of the material. In this study, TiO2 coatings were deposited on unannealed stainless steel substrates and substrates that were annealed from room temperature to 700 °C prior to spraying. The adhesion strength was evaluated to investigate the bonding mechanism. The influence of the remaining surface oxide layer of chromium oxide, Cr2O3, which is thermodynamically preferred for stainless steel, on the bonding mechanism involved was investigated. The results showed that by increasing the annealing substrate temperature of stainless steel, the adhesion strength of the coatings (thicker oxide) is also increased. As a result, the bonding between the cold-sprayed TiO2 particle and the steel substrate is given by the chemical bonding of an inter-oxide reaction.
{"title":"A preliminary study into the effect of oxide chemistry on the bonding mechanism of cold-sprayed titanium dioxide coatings on SUS316 stainless steel substrate","authors":"N. Omar, Suhana Mohamed, Y. Yusuf, Toibah Abdul Rahim, Z. Mustafa, S. Ismail, I. Abu Bakar, Santirraprahkash Selvamani","doi":"10.5599/jese.1423","DOIUrl":"https://doi.org/10.5599/jese.1423","url":null,"abstract":"Current attention has focused on the preparation of thick ceramic coating of nanostructured materials as feedstock material using the thermal spray process. The cold spray method has appeared as a promising process to form ceramic nanostructured coating without significantly changing the microstructure of the initial feedstock materials due to its low processing temperature. However, deposition of ceramic powders by cold spray is not easy due to the brittle characteristics of the material. In this study, TiO2 coatings were deposited on unannealed stainless steel substrates and substrates that were annealed from room temperature to 700 °C prior to spraying. The adhesion strength was evaluated to investigate the bonding mechanism. The influence of the remaining surface oxide layer of chromium oxide, Cr2O3, which is thermodynamically preferred for stainless steel, on the bonding mechanism involved was investigated. The results showed that by increasing the annealing substrate temperature of stainless steel, the adhesion strength of the coatings (thicker oxide) is also increased. As a result, the bonding between the cold-sprayed TiO2 particle and the steel substrate is given by the chemical bonding of an inter-oxide reaction. \u0000 ","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"61 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88957817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the current study, a glassy carbon electrode (GCE) modified with graphene-CoS2 nanocomposite was investigated for electrochemical sensing of ascorbic acid. The electrochemical performance of the modified electrode was examined using differential pulse voltammetry (DPV), linear sweep voltammetry (LSV) and chronoamperometry (CHA) techniques. The electrochemical behavior of ascorbic acid at the graphene-CoS2/GCE displayed a higher oxidation current and lower oxidation potential than bare GCE. Under the optimal experimental conditions, the sensor presented a good linear response between the current and the ascorbic acid concentration range of 0.15–245.0 μM, with a low detection limit of 0.05 μM. Finally, the graphene-CoS2 nanocomposite-modified GCE was applied for the determination of ascorbic acid in real samples and displayed excellent recoveries.
{"title":"A sensitive and simple electrochemical technique for detecting ascorbic acid content in pharmaceutical and biological compounds","authors":"S. Z. Mohammadi, Farideh Mousazadeh","doi":"10.5599/jese.1366","DOIUrl":"https://doi.org/10.5599/jese.1366","url":null,"abstract":"In the current study, a glassy carbon electrode (GCE) modified with graphene-CoS2 nanocomposite was investigated for electrochemical sensing of ascorbic acid. The electrochemical performance of the modified electrode was examined using differential pulse voltammetry (DPV), linear sweep voltammetry (LSV) and chronoamperometry (CHA) techniques. The electrochemical behavior of ascorbic acid at the graphene-CoS2/GCE displayed a higher oxidation current and lower oxidation potential than bare GCE. Under the optimal experimental conditions, the sensor presented a good linear response between the current and the ascorbic acid concentration range of 0.15–245.0 μM, with a low detection limit of 0.05 μM. Finally, the graphene-CoS2 nanocomposite-modified GCE was applied for the determination of ascorbic acid in real samples and displayed excellent recoveries.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"107 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79329800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Rasekaran, P. Kumaresan, S. Nithiyanantham, Vatakkaputhanmadom Krishnaiyer Subramanian, Sankar Kalpana
In the present paper, an innovative approach to enhance the photocatalytic efficiency and energy of photovoltaics by modifying the surface morphology of TiO2 is demonstrated. The photovoltaic device provides sustainable power efficiency in TiO2 (TO) and Cd-TiO2 (CTO) thin films grown through spray pyrolysis. The structural and optical properties of the prepared undoped and Cd doped TiO2 thin films were studied. The morphology and content of the produced samples were studied using scanning electron microscopy (SEM with EDAX). A UV-Vis spectrophotometer was used to record the optical absorption spectra of TiO2 nanoparticles. XRD analysis showed that TO and CTO had anatase structures, and the average crystalline size was calculated as 132.0 nm. The photocatalytic efficiency of TO and CTO for degradation of Rodhamine B (RhB) dye was examined. Also, power-voltage (P-V) and photocurrent-voltage (I-V) output current intensity relations were discussed.
本文展示了一种通过改变TiO2表面形貌来提高光伏电池光催化效率和能量的创新方法。该光伏装置为通过喷雾热解生长的TiO2 (TO)和Cd-TiO2 (CTO)薄膜提供了可持续的电力效率。研究了制备的未掺杂和掺杂Cd的TiO2薄膜的结构和光学性能。用扫描电子显微镜(SEM with EDAX)研究了样品的形貌和含量。采用紫外可见分光光度计记录TiO2纳米粒子的光吸收光谱。XRD分析表明，TO和CTO具有锐钛矿结构，平均晶粒尺寸为132.0 nm。考察了TO和CTO光催化降解罗汉明B (RhB)染料的效率。并讨论了功率电压(P-V)和光电流电压(I-V)输出电流强度的关系。
{"title":"Spray pyrolisis deposition and characterization of Cd-TiO2 thin film for photocatalytic and photovoltaic applications","authors":"M. Rasekaran, P. Kumaresan, S. Nithiyanantham, Vatakkaputhanmadom Krishnaiyer Subramanian, Sankar Kalpana","doi":"10.5599/jese.1120","DOIUrl":"https://doi.org/10.5599/jese.1120","url":null,"abstract":"In the present paper, an innovative approach to enhance the photocatalytic efficiency and energy of photovoltaics by modifying the surface morphology of TiO2 is demonstrated. The photovoltaic device provides sustainable power efficiency in TiO2 (TO) and Cd-TiO2 (CTO) thin films grown through spray pyrolysis. The structural and optical properties of the prepared undoped and Cd doped TiO2 thin films were studied. The morphology and content of the produced samples were studied using scanning electron microscopy (SEM with EDAX). A UV-Vis spectrophotometer was used to record the optical absorption spectra of TiO2 nanoparticles. XRD analysis showed that TO and CTO had anatase structures, and the average crystalline size was calculated as 132.0 nm. The photocatalytic efficiency of TO and CTO for degradation of Rodhamine B (RhB) dye was examined. Also, power-voltage (P-V) and photocurrent-voltage (I-V) output current intensity relations were discussed.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"23 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89619816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Blue energy can be harvested from salinity gradients between saline water and freshwater by reverse electrodialysis (RED). RED as a conversion technique to generate blue energy has received increasing attention in recent decades. As part of the RED system, ion exchange membranes (IEMs) are key elements to the success of future blue energy generation. However, its suboptimal performance often limits the applications and stagnates the development of the technology. The key properties of IEMs include ion exchange capacity, permselectivity, and electrical resistance. The enhancement of such physical and electrochemical properties is crucial for studying energy production with acceptable output efficiency on a commercial scale. Recently, many studies have tried blending nanotechnology into the membrane fabrication process. Hybridizing inorganic nanomaterials with an organic polymeric material showed the great potential of improving electrical conductivity and permselectivity, as well as other membrane characteristics for power performance. In this short review, recent developments on the IEM synthesis in association with potential nanomaterials are reviewed and raising issues regarding the application and commercialization of RED-based energy production are discussed.
{"title":"Ion-exchange membranes for blue energy generation: A short overview focused on nanocomposite","authors":"J. Hong, Tae-Won Park","doi":"10.5599/jese.1447","DOIUrl":"https://doi.org/10.5599/jese.1447","url":null,"abstract":"Blue energy can be harvested from salinity gradients between saline water and freshwater by reverse electrodialysis (RED). RED as a conversion technique to generate blue energy has received increasing attention in recent decades. As part of the RED system, ion exchange membranes (IEMs) are key elements to the success of future blue energy generation. However, its suboptimal performance often limits the applications and stagnates the development of the technology. The key properties of IEMs include ion exchange capacity, permselectivity, and electrical resistance. The enhancement of such physical and electrochemical properties is crucial for studying energy production with acceptable output efficiency on a commercial scale. Recently, many studies have tried blending nanotechnology into the membrane fabrication process. Hybridizing inorganic nanomaterials with an organic polymeric material showed the great potential of improving electrical conductivity and permselectivity, as well as other membrane characteristics for power performance. In this short review, recent developments on the IEM synthesis in association with potential nanomaterials are reviewed and raising issues regarding the application and commercialization of RED-based energy production are discussed.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"36 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74084344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A novel MnO2 nanorods modified screen-printed electrode was fabricated and used as a voltammetric sensor for Sudan determination. MnO2 nanorods were characterized using Field emission-scanning electron microscopy (FE-SEM). Electrochemical measurements were performed using cyclic voltammetry (CV), linear sweep voltammetry (LSV), differential pulse voltammetry (DPV), and chronoammperometry (CA). The MnO2 nanorods on the electrode surface act as an excellent catalyst for the Sudan oxidation reaction. Our modified electrode presents good electrocatalytic activity toward Sudan, a short response time of <10 s, a low detection limit of around 0.08 µM, and linear detection range from 0.25 to 300.0 µM.
{"title":"MnO2 nanorods modified screen-printed electrode for the electrochemical determination of Sudan dye in food sample","authors":"S. A. Ahmadi, P. Mohammadzadeh Jahani","doi":"10.5599/jese.1415","DOIUrl":"https://doi.org/10.5599/jese.1415","url":null,"abstract":"A novel MnO2 nanorods modified screen-printed electrode was fabricated and used as a voltammetric sensor for Sudan determination. MnO2 nanorods were characterized using Field emission-scanning electron microscopy (FE-SEM). Electrochemical measurements were performed using cyclic voltammetry (CV), linear sweep voltammetry (LSV), differential pulse voltammetry (DPV), and chronoammperometry (CA). The MnO2 nanorods on the electrode surface act as an excellent catalyst for the Sudan oxidation reaction. Our modified electrode presents good electrocatalytic activity toward Sudan, a short response time of <10 s, a low detection limit of around 0.08 µM, and linear detection range from 0.25 to 300.0 µM.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"19 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88722048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
High-velocity air fuel (HVAF) coating processes have advantages over conventional high-velocity oxygen fuel (HVOF) processes, resulting in coatings with superior properties. The present review first provides a concise overview of HVAF coatings, highlighting their advantages over HVOF coatings. Then, the fundamentals of solid particle, slurry, and cavitation erosion are briefly introduced. Finally, the performance of HVAF coatings for erosion-resistant applications is discussed in detail. The emerging research consistently reports HVAF-coatings having higher erosion resistance than HVOF-coatings, which is attributed to their elevated hardness and density and improved microstructural features that inhibit the surface damages caused by erosion. The dominant wear mechanisms are mainly functions of particle impact angle. For instance, the removal of the binder phase at high impact angles causes the accumulation of plastic strain on hard particles (e.g., WC particles) in the matrix, forming micro-cracks between the hard particles and the matrix, eventually decreasing the erosion resistance of HVAF coatings. The binder phase of HVAF-coatings significantly affects erosion resistance, primarily due to their inherent mechanical properties and bearing capacity of hard particles. Optimizing spraying parameters to tailor the microstructural characteristics of these coatings appears to be the key to enhancing their erosion resistance. The relationship between microstructural features and erosion mechanisms needs to be clarified to process coatings with tailored microstructural features for erosion-resistant applications.
{"title":"High-velocity air fuel coatings for steel for erosion-resistant applications","authors":"Y. Y. Avcu, Mert Güney, E. Avcu","doi":"10.5599/jese.1369","DOIUrl":"https://doi.org/10.5599/jese.1369","url":null,"abstract":"High-velocity air fuel (HVAF) coating processes have advantages over conventional high-velocity oxygen fuel (HVOF) processes, resulting in coatings with superior properties. The present review first provides a concise overview of HVAF coatings, highlighting their advantages over HVOF coatings. Then, the fundamentals of solid particle, slurry, and cavitation erosion are briefly introduced. Finally, the performance of HVAF coatings for erosion-resistant applications is discussed in detail. The emerging research consistently reports HVAF-coatings having higher erosion resistance than HVOF-coatings, which is attributed to their elevated hardness and density and improved microstructural features that inhibit the surface damages caused by erosion. The dominant wear mechanisms are mainly functions of particle impact angle. For instance, the removal of the binder phase at high impact angles causes the accumulation of plastic strain on hard particles (e.g., WC particles) in the matrix, forming micro-cracks between the hard particles and the matrix, eventually decreasing the erosion resistance of HVAF coatings. The binder phase of HVAF-coatings significantly affects erosion resistance, primarily due to their inherent mechanical properties and bearing capacity of hard particles. Optimizing spraying parameters to tailor the microstructural characteristics of these coatings appears to be the key to enhancing their erosion resistance. The relationship between microstructural features and erosion mechanisms needs to be clarified to process coatings with tailored microstructural features for erosion-resistant applications.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"1 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90221488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sandeep Kumar, R. Bhatia, Hazoor Singh, Roshan Lal Virdi
The main purpose of this study was to fabricate carbon nanotubes (CNTs) reinforced zirconnium yttrium coatings on boiler tube steel and to investigate the microstructural and mechanical properties of these coatings. Plasma sprayed conventional ZrO2-Y2O3, ZrO2-Y2O3 and 1 wt.% CNT and ZrO2-Y2O3 and 4 wt.% CNT were prepared and deposited successfully on boiler tube steel material T-91 (ASTM SA-213) by plasma thermal spray technology. Microhardness, porosity, XRD (X-ray diffraction), SEM/EDAX (scanning electron microscopy/energy dispersive X-ray spectroscopy), X-ray mapping and cross-sectional analyses were used to analyse the specimens. The hardness of CNT reinforced ZrO2-Y2O3 increased with the increase in the percentage of CNT, whereas the porosity of the composite coatings decreased with the increase in the CNT percentage. The observed increase in hardness may be attributed to the content of CNT in the composite coating. The present research gives important information related to the fabrication and physical characteristics of CNT-reinforced ZrO2-Y2O3 coatings deposited on T-91 boiler tube steel.
{"title":"Microstructural and mechanical properties of CNT-reinforced ZrO2-Y2O3 coated boiler tube steel T-91","authors":"Sandeep Kumar, R. Bhatia, Hazoor Singh, Roshan Lal Virdi","doi":"10.5599/jese.1228","DOIUrl":"https://doi.org/10.5599/jese.1228","url":null,"abstract":"The main purpose of this study was to fabricate carbon nanotubes (CNTs) reinforced zirconnium yttrium coatings on boiler tube steel and to investigate the microstructural and mechanical properties of these coatings. Plasma sprayed conventional ZrO2-Y2O3, ZrO2-Y2O3 and 1 wt.% CNT and ZrO2-Y2O3 and 4 wt.% CNT were prepared and deposited successfully on boiler tube steel material T-91 (ASTM SA-213) by plasma thermal spray technology. Microhardness, porosity, XRD (X-ray diffraction), SEM/EDAX (scanning electron microscopy/energy dispersive X-ray spectroscopy), X-ray mapping and cross-sectional analyses were used to analyse the specimens. The hardness of CNT reinforced ZrO2-Y2O3 increased with the increase in the percentage of CNT, whereas the porosity of the composite coatings decreased with the increase in the CNT percentage. The observed increase in hardness may be attributed to the content of CNT in the composite coating. The present research gives important information related to the fabrication and physical characteristics of CNT-reinforced ZrO2-Y2O3 coatings deposited on T-91 boiler tube steel.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"115 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90584605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Z. Mohammadi, Farideh Mousazadeh, Maryam Mohammadhasani-Pour
In this work, an electrochemical sensor was established for the detection of folic acid based on Ni-BTC (BTC = benzene-1,3,5-tricarboxylic acid) metal-organic framework (MOF) modified screen-printed electrode (SPE). Electrochemical techniques (cyclic voltammetry (CV), differential pulse voltammetry (DPV), linear sweep voltammetry (LSV) and chronoamperemetry (CHA) were used for the detection of folic acid at Ni-BTC MOF modified SPE. The results indicate that the as-prepared sensor has a good electrocatalytic effect on the detection of folic acid. This electrochemical sensor showed a dynamic linear response range from 0.08 to 635.0 µM and the detection limit was estimated to be 0.03±0.001 µM. Moreover, the feasibility of Ni-BTC MOF/SPE sensor to detect folic acid in real samples was also evaluated by the standard addition method.
{"title":"Electrochemical detection of folic acid using a modified screen printed electrode","authors":"S. Z. Mohammadi, Farideh Mousazadeh, Maryam Mohammadhasani-Pour","doi":"10.5599/jese.1360","DOIUrl":"https://doi.org/10.5599/jese.1360","url":null,"abstract":"In this work, an electrochemical sensor was established for the detection of folic acid based on Ni-BTC (BTC = benzene-1,3,5-tricarboxylic acid) metal-organic framework (MOF) modified screen-printed electrode (SPE). Electrochemical techniques (cyclic voltammetry (CV), differential pulse voltammetry (DPV), linear sweep voltammetry (LSV) and chronoamperemetry (CHA) were used for the detection of folic acid at Ni-BTC MOF modified SPE. The results indicate that the as-prepared sensor has a good electrocatalytic effect on the detection of folic acid. This electrochemical sensor showed a dynamic linear response range from 0.08 to 635.0 µM and the detection limit was estimated to be 0.03±0.001 µM. Moreover, the feasibility of Ni-BTC MOF/SPE sensor to detect folic acid in real samples was also evaluated by the standard addition method.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"12 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80476951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the present work, a nanocomposite of two-dimensional WSe2 nanosheets with poly(3,4‑ethylenedioxythiophene (WSe2@PEDOT) was prepared by facile hydrothermal method and characterized in terms of structural and morphological analyses. This nanocomposite was used to modify glassy carbon electrode for the construction of an electrochemical sensing platform for simultaneous determination of dopamine (DA) and uric acid (UA) in the presence of ascorbic acid (AA). It was found that the incorporation of PEDOT into WSe2 nanosheets exhibited enhanced electrochemical behaviors and electro¬catalytic activity against DA and UA. Using differential pulse voltammetry (DPV) measurements, the WSe2@PEDOT modified electrode displayed wide linear detection ranges of 16 to 466 µM for DA and 20 to 582.5 µM for UA. The electrode also exhibited high selectivity against DA and UA in the presence of major interference of ascorbic acid and other interferent substances.
{"title":"A WSe2@Poly(3,4-ethylenedioxythiophene) nanocomposite based-electrochemical sensor for simultaneous detection of dopamine and uric acid","authors":"Yasin Tangal, Deniz Çoban, Sadık Çoğal","doi":"10.5599/jese.1375","DOIUrl":"https://doi.org/10.5599/jese.1375","url":null,"abstract":"In the present work, a nanocomposite of two-dimensional WSe2 nanosheets with poly(3,4‑ethylenedioxythiophene (WSe2@PEDOT) was prepared by facile hydrothermal method and characterized in terms of structural and morphological analyses. This nanocomposite was used to modify glassy carbon electrode for the construction of an electrochemical sensing platform for simultaneous determination of dopamine (DA) and uric acid (UA) in the presence of ascorbic acid (AA). It was found that the incorporation of PEDOT into WSe2 nanosheets exhibited enhanced electrochemical behaviors and electro¬catalytic activity against DA and UA. Using differential pulse voltammetry (DPV) measurements, the WSe2@PEDOT modified electrode displayed wide linear detection ranges of 16 to 466 µM for DA and 20 to 582.5 µM for UA. The electrode also exhibited high selectivity against DA and UA in the presence of major interference of ascorbic acid and other interferent substances.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"21 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81286039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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