Yancheng Lou, Zhigang Zhang, Andrew M. Walker, Stephen Stackhouse, Meng Chen, Hongping He
The incorporation of water in high-pressure minerals is essential for the water cycle within the interiors of terrestrial planets. Majoritic garnet, a major component in the mantles of Earth and Mars, plays a significant role in this context. In this study, we use first-principles simulations to explore water incorporation mechanisms in MgSiO3-majorite, which is a key end-member of majoritic garnet, at conditions up to 2,000 K and 20 GPa. By dealing with the relationship between chemical potential and the Gibbs free energy changes for the reactions at equilibrium conditions, we determine the ratios of the seven potential hydrous defects. Our results reveal that the Si2 and Si3 defects, which are of the hydrogarnet-type, dominate water incorporation in MgSiO3-majorite. In addition, we evaluate the effects of these hydrous defects on seismic wave velocities. The presence of Si2 and Si3 defects, with an expected water concentration of ∼700 ppm, has a small effect on both P-wave and S-wave velocities. Nevertheless, the influence of water on lateral variations in the seismic wave velocities of MgSiO3-majorite, which is opposite to that found for ringwoodite, offers a potential tool for investigating compositional heterogeneities in hydrated regions of planetary mantles.
{"title":"Water Incorporation Mechanisms and Effects in MgSiO3-Majorite Under High Temperature and Pressure Conditions","authors":"Yancheng Lou, Zhigang Zhang, Andrew M. Walker, Stephen Stackhouse, Meng Chen, Hongping He","doi":"10.1029/2025JB032448","DOIUrl":"https://doi.org/10.1029/2025JB032448","url":null,"abstract":"<p>The incorporation of water in high-pressure minerals is essential for the water cycle within the interiors of terrestrial planets. Majoritic garnet, a major component in the mantles of Earth and Mars, plays a significant role in this context. In this study, we use first-principles simulations to explore water incorporation mechanisms in MgSiO<sub>3</sub>-majorite, which is a key end-member of majoritic garnet, at conditions up to 2,000 K and 20 GPa. By dealing with the relationship between chemical potential and the Gibbs free energy changes for the reactions at equilibrium conditions, we determine the ratios of the seven potential hydrous defects. Our results reveal that the Si2 and Si3 defects, which are of the hydrogarnet-type, dominate water incorporation in MgSiO<sub>3</sub>-majorite. In addition, we evaluate the effects of these hydrous defects on seismic wave velocities. The presence of Si2 and Si3 defects, with an expected water concentration of ∼700 ppm, has a small effect on both P-wave and S-wave velocities. Nevertheless, the influence of water on lateral variations in the seismic wave velocities of MgSiO<sub>3</sub>-majorite, which is opposite to that found for ringwoodite, offers a potential tool for investigating compositional heterogeneities in hydrated regions of planetary mantles.</p>","PeriodicalId":15864,"journal":{"name":"Journal of Geophysical Research: Solid Earth","volume":"131 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2025-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145887673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Weijie Zhang, Zhaoxia Jiang, Xixi Zhao, Zhong Zheng, Qingsong Liu
Variations in the paleointensity of the Earth's magnetic field are intrinsically linked to the evolution of planetary interior dynamics and surface environmental conditions. However, the reliability of absolute paleointensity experiments is often compromised by the non-ideal magnetic behavior of multi-domain grains and alteration of magnetic minerals. To mitigate these challenges, besides conventional rock magnetic methods, this study also employs Visible and Near-Infrared Reflectance (VNIR) spectroscopy as a rapid screening tool to identify thermally unstable mineral phases that can distort experimental results. Systematic rock magnetic analyses reveal that samples with more pronounced single-domain-like magnetic properties achieve significantly higher success rates in paleointensity experiments. The implementation of VNIR-based screening increased the average success rate of analyzed samples by a factor of 1.9 compared to magnetic selection alone. We recommend using VNIR screening with Mrs/Ms ≥ 0.16 as the sample selection criterion, which can increase the success rate threefold while maintaining sufficient sample availability. By integrating VNIR spectroscopy with conventional rock magnetic methodologies, this study presents a robust approach to enhance the reliability and success rates of paleointensity determinations.
{"title":"Enhancing the Success Rate of Paleointensity Measurements by Integrating Visible and Near-Infrared Reflectance Spectroscopy and Rock Magnetism","authors":"Weijie Zhang, Zhaoxia Jiang, Xixi Zhao, Zhong Zheng, Qingsong Liu","doi":"10.1029/2025JB031530","DOIUrl":"10.1029/2025JB031530","url":null,"abstract":"<p>Variations in the paleointensity of the Earth's magnetic field are intrinsically linked to the evolution of planetary interior dynamics and surface environmental conditions. However, the reliability of absolute paleointensity experiments is often compromised by the non-ideal magnetic behavior of multi-domain grains and alteration of magnetic minerals. To mitigate these challenges, besides conventional rock magnetic methods, this study also employs Visible and Near-Infrared Reflectance (VNIR) spectroscopy as a rapid screening tool to identify thermally unstable mineral phases that can distort experimental results. Systematic rock magnetic analyses reveal that samples with more pronounced single-domain-like magnetic properties achieve significantly higher success rates in paleointensity experiments. The implementation of VNIR-based screening increased the average success rate of analyzed samples by a factor of 1.9 compared to magnetic selection alone. We recommend using VNIR screening with M<sub>rs</sub>/M<sub>s</sub> ≥ 0.16 as the sample selection criterion, which can increase the success rate threefold while maintaining sufficient sample availability. By integrating VNIR spectroscopy with conventional rock magnetic methodologies, this study presents a robust approach to enhance the reliability and success rates of paleointensity determinations.</p>","PeriodicalId":15864,"journal":{"name":"Journal of Geophysical Research: Solid Earth","volume":"130 12","pages":""},"PeriodicalIF":4.1,"publicationDate":"2025-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145830178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J.-Y. Collot, G. Ratzov, F. Michaud, A. Galve, J.-N. Proust, M. Gonzalez, J.-F. Lebrun, M. Laigle, B. Marcaillou
Seismic reflection and bathymetry collected along the Ecuador–Colombia obliquely convergent margin allow the first characterization of the NNE-trending, near-trench strike-slip Ancon Fault in the possible source region of the 1906-Mw8.6–8.8 and 1979-Mw8.2 earthquakes, which produced devastating tsunamis. This study aims at highlighting the possible tsunami contribution of the fault during subduction earthquakes. The fault, which correlates with a zone of strong interseismic, inter-plate coupling, is 200-km-long, segmented and bordered by remarkable slump scars. It bounds a tectonic sliver characterized by structural and rheological variations. The south-fault segment bounds a pop-up structure that comprises an up-to-25-km-wide accretionary wedge, and a mid-slope oceanic basement block uplifted by dextral transpression. The Ancon Fault becomes dominantly reverse in a seamount collision zone, where the East-directed Galera fault takes over toward the central-fault segment. This segment shows extension reflecting a releasing fault bend. The northern-fault segment is transpressive and fans out northward. It separates the fore-arc basin from a near-trench, ∼20-km-wide, pop-up oceanic basement block. Morphology, geological structures and sediment dating support a late-Pleistocene/Holocene activity of the Ancon Fault. The fault could have ruptured concurrently with the 1906 and possibly 1979 earthquakes, and contributed to the tsunamis by producing lateral displacement and differential uplift of the tectonic sliver in a similar way as a normal fault rupture contributed to the 2011 Tohoku-Oki tsunami. Transpressional uplift and landslides associated with the rupture of strike-slip faults are plausible contributing factors to tsunamis offshore North Ecuador-South Colombia and should be considered in seismic hazard models.
{"title":"A Possible Tsunamigenic Near-Trench Strike-Slip Fault, Offshore North Ecuador–South Colombia","authors":"J.-Y. Collot, G. Ratzov, F. Michaud, A. Galve, J.-N. Proust, M. Gonzalez, J.-F. Lebrun, M. Laigle, B. Marcaillou","doi":"10.1029/2024JB030779","DOIUrl":"10.1029/2024JB030779","url":null,"abstract":"<p>Seismic reflection and bathymetry collected along the Ecuador–Colombia obliquely convergent margin allow the first characterization of the NNE-trending, near-trench strike-slip Ancon Fault in the possible source region of the 1906-Mw8.6–8.8 and 1979-Mw8.2 earthquakes, which produced devastating tsunamis. This study aims at highlighting the possible tsunami contribution of the fault during subduction earthquakes. The fault, which correlates with a zone of strong interseismic, inter-plate coupling, is 200-km-long, segmented and bordered by remarkable slump scars. It bounds a tectonic sliver characterized by structural and rheological variations. The south-fault segment bounds a pop-up structure that comprises an up-to-25-km-wide accretionary wedge, and a mid-slope oceanic basement block uplifted by dextral transpression. The Ancon Fault becomes dominantly reverse in a seamount collision zone, where the East-directed Galera fault takes over toward the central-fault segment. This segment shows extension reflecting a releasing fault bend. The northern-fault segment is transpressive and fans out northward. It separates the fore-arc basin from a near-trench, ∼20-km-wide, pop-up oceanic basement block. Morphology, geological structures and sediment dating support a late-Pleistocene/Holocene activity of the Ancon Fault. The fault could have ruptured concurrently with the 1906 and possibly 1979 earthquakes, and contributed to the tsunamis by producing lateral displacement and differential uplift of the tectonic sliver in a similar way as a normal fault rupture contributed to the 2011 Tohoku-Oki tsunami. Transpressional uplift and landslides associated with the rupture of strike-slip faults are plausible contributing factors to tsunamis offshore North Ecuador-South Colombia and should be considered in seismic hazard models.</p>","PeriodicalId":15864,"journal":{"name":"Journal of Geophysical Research: Solid Earth","volume":"130 12","pages":""},"PeriodicalIF":4.1,"publicationDate":"2025-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://agupubs.onlinelibrary.wiley.com/doi/epdf/10.1029/2024JB030779","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145812995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}