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2008 International Symposium on Electrical Insulating Materials (ISEIM 2008)最新文献

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Investigation on the dielectric properties of CaCu3Ti4+xO12+2x cuu3ti4 +xO12+2x介电性能研究
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664570
T. Xu, J.Y. Li, S.T. Li
Investigation on the dielectric properties of CaCu3Ti4+xO12+2x was carried out when x was altered in the range from -0.5 to 0.5. For x= -0.5, it was found through XRD that besides primary CCTO phase, there are also CuO and CaTiO3 phases. For x= 0.5, additional TiO2 was found besides dominating CCTO phase. When x increases from -0.5 to 0.5, it was found that dielectric constant decreases, varistor voltage and non-linear coefficient increase while the dielelctric loss decreases. According to IBLC theory, it is suggested that the change of the grain boundary structure results in different barrier height and surface state when x changes.
对ccu3ti4 +xO12+2x在-0.5 ~ 0.5范围内的介电性能进行了研究。当x= -0.5时,通过XRD发现,除了原始的CCTO相外,还存在CuO和CaTiO3相。当x= 0.5时,除了主要的CCTO相外,还发现了TiO2。当x从-0.5增大到0.5时,介质常数减小,压敏电阻电压和非线性系数增大,介质损耗减小。根据IBLC理论,当x变化时,晶界结构的变化导致了势垒高度和表面态的变化。
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引用次数: 0
High field conduction behavior of nanocomposite of low-density polyethylene and Ag nanoparticles 低密度聚乙烯与银纳米复合材料的高场导电性
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664558
Qiaohua Wang, Y. Yin, Zhe Li, Xuguang Li, P. Jiang
High field conduction of the composite of nano Ag/low-density polyethylene (LDPE) and pure polyethylene is studied, as well as the effect of the contents of nano Ag on high field conduction. Schottky effect, Poole-Frenkel effect, space-charge-limited conduction (SCLC), and ion hopping conduction are used to fit the results. It is pointed out that both space-charge-limited conduction and Poole-Frenkel effect do not fit well for all of the samples. However, it is found that Schottky effect fits well for nano Ag/LDPE composites, and the ion hoping distance of the nanocomposite calculated from the experience data shows that ion hopping conduction fits for the composite of nano Ag/LDPE.
研究了纳米Ag/低密度聚乙烯(LDPE)和纯聚乙烯复合材料的高场导电性,以及纳米Ag含量对高场导电性的影响。采用Schottky效应、Poole-Frenkel效应、空间电荷限制传导(SCLC)和离子跳跃传导来拟合结果。指出空间电荷限制传导和Poole-Frenkel效应并不适用于所有样品。然而,我们发现肖特基效应很适合于纳米Ag/LDPE复合材料,并且根据经验数据计算的纳米复合材料的离子希望距离表明,离子跳跃传导适合于纳米Ag/LDPE复合材料。
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引用次数: 1
A simulation for packet formation in XLPE films XLPE薄膜中包形成的模拟
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664442
K. Kaneko, Y. Suzuoki
Periodic packet formation in an oxidized cross-linked polyethylene (XLPE) was discussed through a computer simulation, where negative space-charge packet is assumed to be due to deficiency in mobile holes. Under high field, a positive carrier (hole) is generated from the acceptor (impurity) site to a hopping site and trapped there once. It is detrapped by hopping or recombines with the parent ion. At the same time, the acceptor is negatively ionized and behaves as an immobile negative charge. The packet-like behavior was reproduced by introducing extra coefficient of diffusion term. The mechanisms of carrier generation and problems of computer simulation were discussed.
通过计算机模拟讨论了氧化交联聚乙烯(XLPE)中周期性包的形成,其中假定负空间电荷包是由于缺乏移动孔造成的。在高场下,从受体(杂质)位点到跳跃位点产生一个正载流子(空穴),并在跳跃位点被捕获一次。它通过跳跃或与母离子重新结合而被捕获。同时,受体被负电离,表现为不移动的负电荷。通过引入额外的扩散系数,再现了包状行为。讨论了载波产生的机理和计算机模拟中存在的问题。
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引用次数: 0
New mixed rules on composite materials 复合材料混合新规
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664499
V. Holcman, M. Raska, L. Grmela, K. Liedermann
The paper studies dielectric properties of elastomer filled with Ni spherical particles of different sizes within the range 35 - 115 mum. The experimental analysis is followed by the examination permittivity/conductivity mixing rules. A new mixing formula for the composite system consisting of spherical metallic particles and polymer matrix is presented. This formula includes both Ni particle content and Ni particle size as two independent variables.
在35 ~ 115 μ m范围内,研究了不同尺寸Ni球形颗粒填充弹性体的介电性能。实验分析之后是介电常数/电导率混合规则的检验。提出了一种新的由球形金属颗粒与聚合物基体组成的复合体系的混合公式。该公式同时包含Ni颗粒含量和Ni粒度两个自变量。
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引用次数: 0
Film morphology of dibenzochrysene 二苯并甲苯的膜形态
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664498
K. Fujita, M. Kimura, H. Yoshokawa, T. Mori
For organic field effect transistors (OFETs), pentacene is often used as a typical semiconductor material and reported to have as high carrier mobility as a-Si. Dibenzochrysene (DBC) as well as pentacene consist of only aromatic rings. DBC can be synthesized by simple procedure and has higher solubility than pentacene. We studied film morphology of DBC fabricated by deposition or spin-coating. It was found that the morphology of DBC film depended on a deposition rate. The films fabricated by the deposition rate of 0.002 nm/s and by spin-coating were island structure and amorphous, respectively. The morphology of DBC films changed with time. The post films showed higher crystalline than before. We also studied the effect of buffer layer on the suppression of molecular migration.
对于有机场效应晶体管(ofet),并五苯通常被用作典型的半导体材料,据报道其载流子迁移率与a- si一样高。二苯并芘(DBC)和并戊二烯都是由芳香环组成的。合成方法简单,具有比并五苯更高的溶解度。研究了沉积法和旋涂法制备DBC的膜形态。结果表明,DBC膜的形貌与沉积速率有关。沉积速率为0.002 nm/s和自旋镀膜制备的薄膜分别为岛状结构和非晶结构。DBC膜的形态随时间的变化而变化。后膜的结晶性高于前膜。我们还研究了缓冲层对分子迁移的抑制作用。
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引用次数: 0
Interfacial polarization and its influence on effective complex permittivity of mixtures 界面极化及其对混合物有效复介电常数的影响
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664540
Xiaolin Chen, Yonghong Cheng, Kai Wu, Shengnan Wu
A two-component composite material is simulated by 8times8times8 cubic cells, containing a spherical inclusion in each of them. A series of produced random numbers are regarded as the radii of these spherical inclusions to simulate the size distribution of inclusions. The finite element method (FEM) is applied to solve the potential distribution and the effective permittivity is calculated by the energy balance. Because the developed simulation model is anisotropic, in order to get the macroscopical dielectric properties of isotropic composites, a statistical mean method for the permittivities in three orthogonal orientations is adopted to calculate the effective permittivity. Based on the simulation model and calculation procedure, the interfacial polarization and its influence on the effective complex permittivity of composites are investigated.
双组分复合材料由8times8times8立方单元模拟,每个单元中包含一个球形夹杂物。将生成的一系列随机数作为球形夹杂物的半径,模拟夹杂物的尺寸分布。采用有限元法求解电势分布,利用能量平衡计算有效介电常数。由于所建立的模拟模型是各向异性的,为了得到各向同性复合材料的宏观介电性能,采用三个正交方向上介电常数的统计平均方法计算有效介电常数。基于仿真模型和计算方法,研究了复合材料的界面极化及其对复合材料有效复介电常数的影响。
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引用次数: 5
Preliminary study for space charge behavior of different types of polyethylene resin 不同类型聚乙烯树脂空间电荷行为的初步研究
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664546
Zhien Zhu, Yewen Zhang, F. Zheng, Z. An
Though the space charge behavior of polyethylene under high DC or AC has been investigated and measured by many researchers, the results between different research groups have little comparability to each other. So itpsilas difficult to achieve a universal conclusion. A lot of experimental data and former research experiences we can acquire so far indicate that many factors affect space charge behavior in a certain extent, such as doping with some types of inorganic nano powders, heating treatment process and the materials of electrode, but there is little substantial change. The space charge behavior is extremely related to the types of polyethylene probably, i.e. the types of polyethylene lead to the difference of research results on the space charge behavior. This paper focuses on the space charge distribution in high electrical field and the isothermal decay in some kinds of LDPE including Exxon-Mobil LLDPE 4004, Sino-SPC JD 200 etc. by using the Pressure Wave Propagation Method.
虽然许多研究者对聚乙烯在高直流或交流条件下的空间电荷行为进行了研究和测量,但不同研究组之间的结果几乎没有可比性。因此很难得出一个普遍的结论。目前我们所能获得的大量实验数据和以往的研究经验表明,在一定程度上影响空间电荷行为的因素很多,如掺杂某些类型的无机纳米粉体、热处理工艺、电极材料等,但基本没有实质性的变化。空间电荷行为可能与聚乙烯的种类密切相关,即聚乙烯的种类导致了空间电荷行为研究结果的差异。本文利用压力波传播法研究了埃克森美孚LLDPE 4004、中国- spc JD 200等几种低密度聚乙烯在强电场下的空间电荷分布和等温衰减。
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引用次数: 1
Temporal change of accumulated charge and diffusion of drug in tape for percutaneous absorption 药物经皮吸收带中累积电荷和扩散的时间变化
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664517
T. Kobayashi, T. Takai, Y. Murakami, M. Nagao, M. Satou, Y. Itou
To investigate possibility of the space charge measurement in the tape with a drug for percutaneous absorption and possibility of the control in space charge movement that might be corresponding to the drug movement by the external signal, the space charge was measured in the tape added a drug for percutaneous absorption. The positive space charge caused by addition a drug was accumulated in the sample and travels to the cathode under the DC voltage. The apparent mobility in an acrylic adhesive was faster with increasing the drug content as well as the result from the conduction current measurement. It was considered that the conductivity increased in an acrylic adhesive by the movement of the drug, bringing higher carrier density and/or higher mobility. The accumulated charge was also measured under the voltage. The accumulated charge in the sample with a diffusion time at short time after the voltage application was bigger than that without a diffusion time. From these results, it was suggested that there was a possibility that the electrical field would control the movement of a drug.
为了研究加有药物经皮吸收带的空间电荷测量的可能性,以及外部信号控制空间电荷运动与药物运动相对应的可能性,我们测量了加有药物经皮吸收带的空间电荷。由于添加药物而产生的正空间电荷在样品中积累,并在直流电压下向阴极移动。随着药物含量的增加和导电电流测量结果的增加,丙烯酸胶粘剂的表观迁移率更快。人们认为,在丙烯酸粘合剂中,由于药物的移动,电导率增加,从而带来更高的载流子密度和/或更高的迁移率。还测量了在电压作用下的累积电荷。施加电压后,有扩散时间的样品在短时间内积累的电荷量大于没有扩散时间的样品。从这些结果来看,有人认为电场有可能控制药物的运动。
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引用次数: 0
Role of additive for polycyclic compound in the suppression of electrical tree generation in LDPE 多环化合物添加剂在抑制LDPE电树生成中的作用
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664596
Y. Yamano, M. Ilzuka
The influence of addition of polycyclic compounds into LDPE upon electrical tree initiation was investigated to demonstrate the fundamental role of the aromatic compound in the tree initiation process. Five kinds of the polycyclic compounds were used in this study; naphthalene (Np), anthracene (An), 9,10-bromoanthracene (Br-An), tetracene (Te) and pentacene (Pn). The experimental results indicated that the tree initiation voltage (TIV) depend on the kind of polycyclic compounds added to LDPE. TIV for ldquoPE/Anrdquo is the highest, and is about 3.5 times higher than that for ldquoPErdquo (without additive). TIV for ldquoPE/Br-Anrdquo is the secondly highest. However, the scatter for ldquoPE/Br-Anrdquo is much wider than that for ldquoPE/Anrdquo. TIVs for ldquoPE/Terdquo and ldquoPE/Pnrdquo are not significantly higher than that for ldquoPErdquo. The addition of ldquoNprdquo has almost no effect on the increase in TIV. The mechanisms for the increase in TIV are discussed based on the experimental results with the pi-electron effects for absorption of kinetic energy of the hot electron and observations of deposit of the additive in the test materials by AFM and SEM.
研究了在LDPE中加入多环化合物对电树引发的影响,以证明芳香化合物在树引发过程中的基本作用。本研究使用了5种多环化合物;萘(Np)、蒽(An)、9,10-溴蒽(Br-An)、四烯(Te)和五苯(Pn)。实验结果表明,树起始电压(TIV)与加入到LDPE中的多环化合物种类有关。ldquoPE/ andrquo的TIV最高,约为ldquoPErdquo(无添加剂)的3.5倍。ldquoPE/ br - andquo的TIV是第二高的。然而,ldquoPE/ br - andrquo的散点比ldquoPE/ andrquo的散点宽得多。ldquoPE/Terdquo和ldquoPE/Pnrdquo的tiv值不显著高于ldquoPErdquo。ldquoNprdquo的加入对TIV的增加几乎没有影响。根据pi电子效应对热电子动能吸收的实验结果以及AFM和SEM观察到的添加剂在测试材料中的沉积情况,讨论了TIV增加的机理。
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引用次数: 1
Multimode surface plasmon excitation on metallic diffraction gratings 金属衍射光栅的多模表面等离子激元激发
Pub Date : 2008-10-31 DOI: 10.1109/ISEIM.2008.4664572
A. Baba, K. Kanda, T. Ohno, Y. Ohdaira, K. Shinbo, K. Kato, F. Kaneko
In this study, we report on multimode surface plasmon excitation on metallic diffraction gratings where the grating pitch is much larger than standard grating coupling surface plasmon excitation technique. With the gratings, multimode surface plasmons can be excited at the same time in the wavelength region using a white light source irradiation on the gratings. The grating coupling surface plasmon excitation was also studied by comparing with the theoretical surface plasmon dispersion curves.
在本研究中,我们报道了金属衍射光栅的多模表面等离子激元激发,其中光栅间距比标准光栅耦合表面等离子激元激发技术大得多。利用该光栅,利用白光照射光栅,可以在波长区域内同时激发多模表面等离子体。通过与理论表面等离子体色散曲线的比较,研究了光栅耦合表面等离子体激发。
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引用次数: 0
期刊
2008 International Symposium on Electrical Insulating Materials (ISEIM 2008)
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