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High-performance ITO thin films for on-cell touch sensor of foldable OLED displays 用于可折叠OLED显示器上单元触摸传感器的高性能ITO薄膜
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-21 DOI: 10.1080/15980316.2021.1999867
Dong-pil Park, W. Park, Jang-kun Song, Sang Soo Kim
ITO thin films must have good electro-optical and mechanical characteristics to use them as integrated touch sensors for flexible OLED displays. We fabricated ITO thin films on a separation-layer-coated glass substrate under various deposition or annealing conditions, and then transferred them to cyclo-olefin polymer films to evaluate their electro-optical and mechanical characteristics. ITO films with a thickness of approximately 136 nm deposited at 250°C showed a sheet resistance of 36 Ω/□, light transmittance of 88%, and 2.4% of elongation at break. The 136 nm thick ITO films deposited at 150 °C and transferred on 50 μm thick COP film survived 500 h of 85 °C, 85% relative humidity under 180-degree bending preservation test, endured at 200,000-time repetitive bending test with a curvature radius of 1.5 mm. These high-performance ITO thin films can be applied to fabricate on-cell touch sensors for foldable OLED displays.
ITO薄膜必须具有良好的电光和机械特性,才能用作柔性OLED显示器的集成触摸传感器。我们在不同的沉积或退火条件下,在涂有分离层的玻璃基板上制备了ITO薄膜,然后将其转移到环烯烃聚合物膜上,以评估其电光和机械特性。厚度约136的ITO膜 在250°C下沉积的nm显示出36的薄层电阻 Ω/□, 透光率为88%,断裂伸长率为2.4%。136 nm厚的ITO薄膜 °C,并在50 μm厚COP薄膜存活500 第h页,共85页 °C,180度弯曲保存试验下85%的相对湿度,承受20万次曲率半径为1.5的重复弯曲试验 这些高性能ITO薄膜可用于制造用于可折叠OLED显示器的单元上触摸传感器。
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引用次数: 6
Effects of the phosphorescent sensitizer on charge dynamics in deep blue phosphor-sensitized-fluorescent organic light-emitting diodes 磷光敏化剂对深蓝磷敏化荧光有机发光二极管电荷动力学的影响
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-13 DOI: 10.1080/15980316.2021.2000514
Hakjun Lee, K. Hwang, Ki Ju Kim, You Na Song, Young Kwan Kim, Taekyung Kim
In phosphor-sensitized-fluorescent organic light-emitting diodes (PSF-OLEDs), triplet excitons generated in the emitting layer (EML) are harvested by the sensitizer and the excitonic energy is efficiently transferred to the fluorescent dopant molecules. Since a phosphorescent sensitizer is typically doped at around 10 wt.%, the sensitizer not only affects cascade energy transfer but also electrical transporting in the PSF-OLEDs. However, the electrical role of phosphorescent metal complex molecules in the EML is unclear. In this study, we report the impact of the phosphorescent sensitizer on the electrical properties of PSF-OLEDs. Through a comprehensive analysis using impedance spectroscopy in conjunction with current density (J)-voltage (V)-luminance (L) properties of the PSF-OLED, it was revealed that 10 wt.% phosphorescent sensitizer forms an electron transporting pathway inside the EML. Thus, the sensitizer molecules transform a unipolar single host into a bipolar mixed host. In other words, the phosphorescent sensitizer is an n-type host in the PSF-OLEDs. As a result, the charge balance and the operating voltage were simultaneously and significantly improved in the PSF-OLEDs.
在磷敏化荧光有机发光二极管(psf - oled)中,在发光层(EML)中产生的三重态激子被敏化剂捕获,激子能量被有效地转移到荧光掺杂分子中。由于磷光敏化剂通常在10wt左右掺杂。%,敏化剂不仅影响级联能量传递,而且影响psf - oled中的电传递。然而,磷光金属络合物分子在EML中的电作用尚不清楚。在这项研究中,我们报告了磷光敏化剂对psf - oled电学性能的影响。通过阻抗谱结合电流密度(J)-电压(V)-亮度(L)特性对PSF-OLED进行综合分析,发现10wt。磷光敏化剂在EML内部形成电子传递途径。因此,敏化剂分子将单极单宿主转化为双极混合宿主。换句话说,磷光敏化剂在psf - oled中是一个n型宿主。结果表明,psf - oled的电荷平衡和工作电压同时得到了显著改善。
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引用次数: 4
Biodegradable all-polymer field-effect transistors printed on Mater-Bi Mater Bi上印制的可生物降解全聚合物场效应晶体管
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-10-02 DOI: 10.1080/15980316.2021.1990145
Elena Stucchi, Ksenija Maksimovic, L. Bertolacci, F. Viola, A. Athanassiou, M. Caironi
The growing demand of disposable electronics raises serious concerns for the corresponding increase in the amount of electronic waste, with severe environmental impact. Organic and flexible electronics have been proposed long ago as a more sustainable and energy-efficient technological platform with respect to established ones. Yet, such technology is leading to a drastic increase of plastic waste if common approaches for flexible substrates are followed. In this scenario, biodegradable solutions can significantly limit the environmental impact, actively contributing to eliminate the waste streams (plastic or electronic) associated with disposal of devices. However, achieving suitably scalable processes to pattern mechanically robust organic electronics onto largely available biodegradable substrates is still an open challenge. In this work, all-organic and highly flexible field-effect transistors, inkjet printed onto the biodegradable and compostable commercial substrate Mater-Bi, are demonstrated. Because of the thermal instability of Mater-Bi, no annealing steps are applied, producing devices with limited carrier mobility, yet showing correct n-type behavior and robustness to bending and crumpling. The degradation behavior of the final system shows unaltered biodegradability level according to ISO 14851. These results represent a promising step toward sustainable flexible and large-area electronics, combining energy and materials efficient processes with largely available biodegradable substrates.
一次性电子产品需求的增长引发了人们对电子垃圾数量相应增加的严重担忧,并对环境产生了严重影响。有机和柔性电子产品早就被认为是一个比现有技术更可持续、更节能的技术平台。然而,如果采用柔性基板的通用方法,这种技术将导致塑料垃圾的急剧增加。在这种情况下,可生物降解的解决方案可以显著限制环境影响,积极有助于消除与设备处理相关的废物流(塑料或电子)。然而,实现适当的可扩展工艺,将机械坚固的有机电子器件图案形成在大量可用的可生物降解基底上,仍然是一个悬而未决的挑战。在这项工作中,展示了所有有机和高度柔性的场效应晶体管,喷墨印刷在可生物降解和可堆肥的商业基底Mater Bi上。由于Mater-Bi的热不稳定性,没有应用退火步骤,生产出具有有限载流子迁移率的器件,但显示出正确的n型行为和对弯曲和起皱的鲁棒性。根据ISO 14851,最终系统的降解行为显示出不变的生物降解性水平。这些结果代表着朝着可持续的柔性和大面积电子产品迈出了有希望的一步,将能源和材料高效的工艺与大量可生物降解的基材相结合。
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引用次数: 6
Thin-film electronics based on all-2D van der Waals heterostructures 基于全二维范德华异质结构的薄膜电子学
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-10-02 DOI: 10.1080/15980316.2021.1982782
Xinling Liu, Xiaoming Yang, Weihui Sang, Hai Huang, Wenwu Li, Yen‐Fu Lin, J. Chu
Two-dimensional (2D) layered materials including metal, semiconductor, and insulator have received extensive attention in recent years. The weak van-der-Waals (vdW) interactions between 2D materials layers enable them to isolate monolayers and restack into artificial 2D vdW heterostructures in the desired sequence. These assembled all-2D vdW heterostructures are promising platforms for fabricating next-generation electronics as well as optoelectronics. In particular, the all-2D vdW heterostructure devices composed entirely of 2D layered material have received extensive attention due to their natural thickness, atomically sharp heterointerfaces, and excellent mechanical flexibility. Herein, we firstly introduce 2D vdW heterostructures and their preparation methods. Secondly, the recent progress of field-effect transistors (FETs) and photodetectors based on all-2D vdW heterostructures are summarized. Finally, we discuss some challenges of all-2D vdW heterostructure-based devices for practical applications and offer personal perspectives toward the future development of thin-film electronics.
近年来,包括金属、半导体和绝缘体在内的二维(2D)层状材料受到了广泛的关注。2D材料层之间的弱范德华(vdW)相互作用使它们能够分离单层并以所需序列重新组装成人工2D vdW异质结构。这些组装的全二维vdW异质结构是制造下一代电子器件和光电子器件的有前途的平台。特别地,完全由2D层状材料组成的全2D vdW异质结构器件由于其自然厚度、原子尖锐的异质界面和优异的机械柔性而受到广泛关注。本文首先介绍了二维vdW异质结构及其制备方法。其次,综述了基于全二维vdW异质结构的场效应晶体管和光电探测器的最新进展。最后,我们讨论了基于全二维vdW异质结构的器件在实际应用中的一些挑战,并对薄膜电子的未来发展提供了个人观点。
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引用次数: 2
Development of a scalable tabletop display using projection-based light field technology 基于投影的光场技术的可扩展桌面显示器的开发
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-08-31 DOI: 10.1080/15980316.2021.1965048
Hamong Shim, Dong-kil Lee, Jongbok Park, S. Yoon, Hoemin Kim, Kwang-soo Kim, Daerak Heo, Beomjun Kim, Joonku Hahn, Youngmin Kim, W. Jang
We present a light-field display optical system design, state-of-the-art hardware technology, and computational software that are readily scalable (due to their modular structure) and provide naturally immersive and volumetric display systems. We explain the integration of 72 microprojectors into the tabletop display system. In addition, we used 6 workstations for all images and 18 high-performance graphics processing units. Sophisticated image generation through author tooling and the pixel re-arrangement algorithm in the Unity engine enabled us to produce complete three-dimensional images from the radiant rays of two-dimensional pixels using diffuser screens and microlens arrays.
我们提出了一种光场显示光学系统设计、最先进的硬件技术和计算软件,它们易于扩展(由于其模块化结构),并提供自然沉浸式和体积显示系统。我们解释了将72个微型投影仪集成到桌面显示系统中。此外,我们为所有图像使用了6个工作站和18个高性能图形处理单元。通过作者工具和Unity引擎中的像素重新排列算法生成复杂的图像,使我们能够使用漫射屏和微透镜阵列从二维像素的辐射线生成完整的三维图像。
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引用次数: 4
Flexible polymer network liquid crystals using imprinted spacers bonded by UV-curable reactive mesogen for smart window applications 柔性聚合物网络液晶采用印迹间隔剂结合紫外光固化反应介介剂的智能窗口应用
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-08-09 DOI: 10.1080/15980316.2021.1960648
T. Ishinabe, Hayato Isa, Y. Shibata, H. Fujikake
We propose junction-type, vertically aligned polymer network liquid crystals using plastic substrates for flexible smart windows, in which the spacers are formed with the imprinting method and are bonded to the substrate surface by UV-curable reactive mesogen (RM). We clarified that the optical property can be improved by suppressing the aggregation of RMs around the spacers through thinning of the coating of the RM and the simultaneous improvement of the wettability of the parallel alignment film. We achieved excellent haze properties of 3.0% with voltage off and 92.7% with voltage on, and high curvature performance with a small curvature radius of 9.0 mm.
我们提出了用于柔性智能窗的使用塑料基板的结型垂直排列聚合物网络液晶,其中间隔物通过压印方法形成,并通过UV可固化反应性介晶(RM)结合到基板表面。我们阐明了通过减薄RM的涂层来抑制RM在间隔物周围的聚集,并同时提高平行取向膜的润湿性,可以改善光学性能。我们在电压关闭时获得了3.0%的优异雾度性能,在电压打开时获得了92.7%的雾度性能 毫米。
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引用次数: 4
Solution-processed deep-blue (y∼0.06) fluorophores based on triphenylamine-imidazole (donor-acceptor) for OLEDs: computational and experimental exploration 用于OLED的基于三苯胺咪唑(供体-受体)的溶液处理深蓝(y~0.06)荧光团:计算和实验探索
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-08-04 DOI: 10.1080/15980316.2021.1959429
Jaipal Devesing Girase, Sandhya Rani Nayak, Jairam Tagare, Shahnawaz, Mangey Ram Nagar, J. Jou, S. Vaidyanathan
Developing solution-processable deep-blue emitters for organic light-emitting diodes (OLEDs) is still a challenging task. In this context, two new solution-processable deep-blue emitters, N, N-diphenyl-4’-(1-(3-(trifluoromethyl)phenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)-[1,1’-biphenyl]-4-amine(4-PIMCFTPA) and 4’-(4,5-diphenyl-1-(3-(trifluoromethyl)phenyl)-1H-imidazol-2-yl)-N,N-diphenyl-[1,1’-biphenyl]-4-amine (4-BICFTPA), were successfully designed and synthesized by incorporating phenanthroimidazole (PI)/diphenylimidazole (BI)-triphenylamine (TPA), which is functional at the N1 position of the imidazole, with Ph-mCF3. The thermal, photophysical, and electrochemical properties of both fluorophores were systematically explored. These fluorophores showed a deep-blue emission in the solution as well as in the solid state. The highest occupied molecular orbital (HOMO) – lowest unoccupied molecular orbital (LUMO) energy level of the fluorophores was calculated using electrochemical studies and compared with the theoretical calculation [the density functional theory (DFT)]. The asymmetrically twisted conformation of 4-PIMCFTPA between PI-TPA efficiently showed a high photoluminescence quantum yield. OLED (undoped and doped) devices were fabricated with the newly synthesized emitters, and 4-PIMCFTPA demonstrated better electroluminescence (EL) performance than the BI-based emitter. Thus, the OLED based on 4-PIMCFTPA (1 wt% in the CBP host) had the best EL performance, with a maximum external quantum efficiency 1.7% and CIE coordinates of (0.17, 0.06).
开发用于有机发光二极管(OLED)的可解决方案处理的深蓝色发射器仍然是一项具有挑战性的任务。在这种情况下,两种新的可溶液处理的深蓝色发射体,N,N-二苯基-4’-(1-(3-(三氟甲基)苯基)-1H-菲[9,10-d]咪唑-2-基)-[1,1'-联苯]-4-胺(4-PIMCFTPA)和4’-(4,5-二苯基-1-(3-(三氟甲基)苯)-1H-咪唑-2-基,通过将在咪唑的N1位具有功能的菲并咪唑(PI)/二苯基咪唑(BI)-三苯胺(TPA)与Ph-mCF3结合,成功地设计和合成了。系统地探索了这两种荧光团的热、光物理和电化学性质。这些荧光团在溶液中以及在固态中显示出深蓝色发射。使用电化学研究计算荧光团的最高占据分子轨道(HOMO)-最低未占据分子轨(LUMO)能级,并与理论计算[密度泛函理论(DFT)]进行比较。4-PIMCFTPA在PI-TPA之间的不对称扭曲构象有效地显示出高的光致发光量子产率。用新合成的发射极制备了OLED(未掺杂和掺杂)器件,4-PIMCFTPA表现出比基于BI的发射极更好的电致发光(EL)性能。因此,基于4-PIMCFTPA(在CBP主体中为1wt%)的OLED具有最佳的EL性能,最大外量子效率为1.7%,CIE坐标为(0.170.06)。
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引用次数: 14
Recent progress on metal halide perovskite field-effect transistors 金属卤化物钙钛矿场效应晶体管研究进展
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-29 DOI: 10.1080/15980316.2021.1957725
Huihui Zhu, A. Liu, Yong‐Young Noh
Metal halide perovskite semiconductors could potentially be used to create field-effect transistors (FETs) with high carrier mobilities. This review summarizes progress achieved recently in three-dimensional (3D) lead-based and two-dimensional (2D) tin-based perovskite FETs, and identifies the evolution of electrical characteristics and stability, then discusses outstanding challenges and provides an outlook on the possibilities offered by this electronic material family for use in backplane drivers for active matrix displays.
金属卤化物钙钛矿半导体有可能用于制造具有高载流子迁移率的场效应晶体管(fet)。本文总结了三维(3D)铅基和二维(2D)锡基钙钛矿场效应管的最新进展,确定了电特性和稳定性的演变,然后讨论了突出的挑战,并展望了这种电子材料家族用于有源矩阵显示器背板驱动器的可能性。
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引用次数: 12
Recent advances in printable carbon nanotube transistors for large-area active matrices 用于大面积有源矩阵的可打印碳纳米管晶体管的最新进展
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-28 DOI: 10.1080/15980316.2021.1957032
Kevin Schnittker, M. Tursunniyaz, J. Andrews
Active-matrices serve as the backplane circuitry for large-area display technologies and distributed sensors. Recently, there has been significant interest in developing flexible, additively manufactured active matrices for the burgeoning flexible electronics industry. Carbon nanotubes (CNTs) are prime candidate materials for semiconducting elements of transistors due to their solution processability, carrier mobility, and mechanical flexibility. There have been many recent accomplishments in the development of CNT inks and in their deposition via printing that enable their use in thin-film transistors (TFTs), and their appropriate performance make them suitable for use in large-area active matrices. In this review, we provide an overview of the field, with a specific focus on recent advancements in CNT sorting, ink preparation, and printing techniques. We also provide a benchmarking study of printed CNT devices presented in literature after 2017. Next, we discuss printable CNT-TFTs used for active-matrix applications. Finally, we provide a concluding perspective on the outlook and challenges for printed CNT-TFT active matrices.
有源矩阵作为大面积显示技术和分布式传感器的背板电路。最近,对于新兴的柔性电子工业,人们对开发柔性、增材制造的有源矩阵有了很大的兴趣。碳纳米管(CNTs)由于其溶液可加工性、载流子迁移性和机械灵活性而成为晶体管半导体元件的主要候选材料。近年来,碳纳米管油墨在薄膜晶体管(tft)中的应用取得了许多成就,其良好的性能使其适用于大面积有源矩阵。在这篇综述中,我们提供了该领域的概述,特别关注碳纳米管分类、油墨制备和印刷技术的最新进展。我们还提供了2017年后文献中提出的印刷碳纳米管器件的基准研究。接下来,我们讨论用于有源矩阵应用的可打印碳纳米管- tft。最后,我们对印刷碳纳米管- tft有源矩阵的前景和挑战进行了总结。
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引用次数: 7
Assessment of the effect on the human body of the flicker of OLED displays of smartphones 智能手机OLED显示器闪烁对人体影响的评估
IF 3.7 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-13 DOI: 10.1080/15980316.2021.1950854
Minhyuk Kim
This paper considers the effects on the human body of the flicker of organic light-emitting diode (OLED) displays. Related studies have been conducted due to reports of cases of adverse health effects of the use of artificial lighting. Interest in this problem recently intensified with the development of various new displays and the longer exposure time of people to them. Therefore, the previous studies on the effects of artificial lighting on the human body are described in this paper, and based on them, the dimming technique for liquid-crystal displays and OLED displays of smartphones is explained and the effect of the flicker of OLED displays on the human body is assessed.
本文考虑了有机发光二极管(OLED)显示器的闪烁对人体的影响。由于有报告称使用人工照明对健康产生不良影响,因此进行了相关研究。最近,随着各种新型显示器的开发和人们接触它们的时间的延长,人们对这个问题的兴趣加剧了。因此,本文介绍了以往关于人工照明对人体影响的研究,并在此基础上解释了智能手机液晶显示器和OLED显示器的调光技术,评估了OLED显示器闪烁对人体的影响。
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引用次数: 3
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