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Ecological Risk Assessment of Copper in Coastal Areas of Japan: How will Bioavailability Considerations Change the Assessment Results? 日本沿海地区铜的生态风险评估:生物利用度因素如何改变评估结果?
Pub Date : 2019-01-01 DOI: 10.2965/JSWE.42.105
R. Tai, W. Naito, S. Masunaga
We conducted ecological risk assessment of copper in coastal areas of Japan. For risk assessment, we used a method in the initial environmental risk assessment conducted by the Ministry of the Environment, Japan, and several methods considering bioavailability, used for setting water quality criteria in Europe and the United States. The hazard quotient ( HQ ) method was used for risk characterization. Risk assessment was conducted using 1,622 copper concentration values from the Japanese coastal areas over the past 31 years that we were able to collect. As a result, the area with HQ exceeding 1 was 70.2% of the total in the screening level evaluation; considering bioavailability, it was 3.6 to 4.0%, and the risk characterization result changed depending on the hazard assessment method. Also, considering bioavailability, it was clear that there is a difference in the risk characterization result because water quality varies depending on the location even within the same bay. These results suggest that it is important to obtain toxicological data of species inhabiting Japan and copper concentrations in Japanese coastal areas and to examine what kind of evaluation method should be used for risk assessment.
我们对日本沿海地区的铜进行了生态风险评估。对于风险评估,我们使用了日本环境省进行的初始环境风险评估中的一种方法,以及欧洲和美国用于制定水质标准的几种考虑生物利用度的方法。采用危害商(HQ)法进行风险表征。我们利用过去31年日本沿海地区收集到的1,622个铜浓度值进行了风险评估。因此,在筛选水平评价中,HQ超过1的区域占总区域的70.2%;生物利用度为3.6 ~ 4.0%,不同的危险度评价方法不同,风险表征结果也不同。此外,考虑到生物利用度,很明显,风险表征结果存在差异,因为即使在同一海湾内,水质也因位置而异。这些结果表明,获取居住在日本的物种的毒理学数据和日本沿海地区的铜浓度,并研究采用何种评估方法进行风险评估具有重要意义。
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引用次数: 1
Nutrients Runoff from a Forested Catchment during an Extreme Storm Event: A Case Study of the Headwaters of the Shimanto River in the Western Part of Kochi Prefecture, Japan in July, 2011 极端风暴事件中森林流域的养分径流:2011年7月日本高知县西部岛曼托河源头的案例研究
Pub Date : 2019-01-01 DOI: 10.2965/jswe.42.219
Yoshiki Shinomiya, Yuichi Yokoyama
We investigated the loads of suspended solids ( SS ) , total ( TN ) and dissolved ( DN ) nitrogen during an extreme storm event ( total rainfall, 742 mm ) on 18 and 19 July 2011 in a forested mountain headwater catchment of the Shimanto River in the western part of Kochi Prefecture, Japan. We compared the extreme storm event with the normal event ( total rainfall, below 100 mm ) and the storm event ( total rainfall, 100 – 300 mm ) . The experimental catchment ( 73 ha ) has an underlayer of sandstone and is mainly covered with a secondary forest that comprises evergreen trees. Samples of streamwater were collected every two hours using an automatic water sampler during six events ( total rainfall, 44 – 742 mm ) . The load of TN during the extreme storm event was about 5 kg ha -1 event -1 , which is similar to the domestic average annual TN load ( 4.9 kg ha -1 yr -1 ) . The proportion of DN to TN in the specific cumulative load decreased sharply from 97% – 99% in the normal event and 77% – 97% in the storm event to 5% in the extreme storm event phase. The results clearly show that the load of particulate nitrogen was markedly greater than the load of DN during the extreme storm event.
研究了2011年7月18日和19日在日本高知县西部岛曼托河森林山源集水区发生的一次极端暴雨事件(总降雨量为742 mm)中悬浮固体(SS)、总氮(TN)和溶解氮(DN)的负荷。我们将极端风暴事件与正常事件(总降雨量,低于100毫米)和风暴事件(总降雨量,100 - 300毫米)进行了比较。实验集水区(73公顷)有砂岩的下层,主要覆盖着由常绿树木组成的次生林。在6个事件(总降雨量44 - 742毫米)中,使用自动水采样器每两小时采集一次溪水样本。极端风暴期间全氮负荷约为5 kg ha -1 event -1,与国内年均全氮负荷(4.9 kg ha -1 yr -1)相近。DN / TN在比累积负荷中的比例从正常期的97% ~ 99%和风暴期的77% ~ 97%急剧下降到极端风暴期的5%。结果清楚地表明,在极端风暴事件中,颗粒氮的负荷明显大于DN的负荷。
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引用次数: 1
Investigation on Cause of Lead Contamination in Irrigation Reservoir under Shooting Range Using Lead Isotope Ratio 利用铅同位素比对射击场灌溉水库铅污染原因的研究
Pub Date : 2019-01-01 DOI: 10.2965/JSWE.42.35
O. Nagafuchi, K. Nakazawa, Ken’ichi Shinozuka
To clarify the origin of lead ( Pb ) in an irrigation reservoir with a shooting range in upstream, sediments of a small stream located in the shooting range, sediments and soil from upstream of the shooting range, sediments in the irrigation reservoir, and river water have been observed. It is well known that the Pb stable isotope ratio has an original value in each Pb mine. The Pb stable isotope ratios in soil and sediment were totally different between the samples from upstream and downstream of the shooting range. On the basis of the composition ratios of Pb and other metals ( zinc and copper ) used in the brass coating of bullets, the distance index ( D.I. ) was calculated and the results were applied for cluster analysis. Both D.I. and cluster analysis results indicated that soil and sediment samples from the upstream and downstream are clearly different. Our results indicate that our integrated approach of using the Pb isotope ratio, D.I. and cluster analysis is a good indicator of the origin of Pb contamination in soil and sediment.
为明确上游有射击场的灌溉水库中铅的来源,对射击场内的小溪沉积物、射击场上游的沉积物和土壤、灌溉水库中的沉积物和河水进行了观测。众所周知,每个铅矿的铅稳定同位素比值都有一个初始值。射击场上游和下游样品土壤和沉积物中Pb稳定同位素比值完全不同。根据子弹黄铜涂层中铅和其他金属(锌和铜)的组成比例,得到了距离指数(D.I.)。计算结果用于聚类分析。聚类分析结果表明,上游和下游的土壤和沉积物样品存在明显差异。结果表明,利用Pb同位素比值、D.I.和聚类分析相结合的方法可以很好地反映土壤和沉积物中Pb污染的来源。
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引用次数: 0
Evaluation of Nitrification Performance Using Nitrifying-DHS Reactor with Various Sponge-Pore Sizes for Breeding Tank of Marine Aquaria 海洋水族馆养殖池不同海绵孔径硝化- dhs反应器硝化性能评价
Pub Date : 2019-01-01 DOI: 10.2965/JSWE.42.7
A. Furukawa, M. Hatamoto, Jun Kusaka, Kawamata Mutsumi, M. Mori, T. Hoaki, Takashi Yamaguchi
The effect of sponge-pore size for a combined downflow hanging sponge (DHS) and upflow sludge blanket (USB) filtering system for the nitrification and denitrification, respectively, of a marine aquaculture system was evaluated. The nitrifying DHS reactor maintained the concentrations of total ammonia nitrogen and NO2 -N of the breeding water at 0.08 mg-N L and 0.05 mg-N L, respectively. The DO concentration in the breeding water was about 6.17 mg L without direct aeration of the tank. Despite the high DO of the denitrifying USB reactor influent, the nitrogen-removal performance was good and the NO3 -N concentration in the breeding water was maintained below the theoretical value. Regarding the effect of sponge-pore size for nitrification by the DHS reactor, the sponge with the smallest pore size, named CFH-30, had the fastest nitrification rate and sludge growth rate. Microbial community analysis of sludge contained in sponge revealed that sponge with the largest pore size had the highest detection rates for ammoniaoxidizing archaea and nitrite-oxidizing bacteria.
研究了下流悬挂海绵(DHS)和上流污泥毯(USB)联合过滤系统中海绵-孔径对海水养殖系统硝化和反硝化的影响。硝化DHS反应器使养殖水中总氨氮和NO2 -N浓度分别维持在0.08 mg-N L和0.05 mg-N L。在不直接曝气的情况下,养殖水中DO浓度约为6.17 mg L。反硝化USB反应器进水DO高,但除氮效果良好,养殖水中NO3 -N浓度维持在理论值以下。海绵-孔径对DHS反应器硝化作用的影响,孔径最小的海绵CFH-30硝化速率和污泥生长速度最快。对海绵中所含污泥的微生物群落分析表明,孔径最大的海绵对氨氧化古细菌和亚硝酸盐氧化细菌的检出率最高。
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引用次数: 0
Characteristics of River Sites with Elevated Concentrations of Linear Alkylbenzene Sulfonate: Implications for Water Environmental Management for Protection of Aquatic Life 线性烷基苯磺酸盐浓度升高的河流地点特征:对水环境管理和水生生物保护的影响
Pub Date : 2019-01-01 DOI: 10.2965/jswe.42.201
Y. Iwasaki, H. Honda, Tohru Nishioka, Y. Ishikawa, Masayuki Yamane
Nationwide evaluation of the exceedance of environmental water quality standards ( EQS ) in the water environment plays a key role in establishing EQSs and effluent regulations. To understand the characteristics of river sites with annual mean concentrations of linear alkylbenzene sulfonate ( LAS ) that exceed the EQS, we compared ( 1 ) channel width as an indicator of river size, ( 2 ) surrounding land use, and ( 3 ) biochemical oxygen demand ( BOD ) as an indicator of organic pollution between “LAS-contaminated sites” with annual mean LAS concentrations of > 0.02 mg L -1 and “uncontaminated sites” with concentrations of ≤ 0.02 mg L -1 using water quality monitoring results from 2015-2016. Results indicated that, compared with uncontaminated sites, LAS-contaminated sites were found more frequently ( 1 ) in rivers with smaller and less variable channel width, ( 2 ) in rivers located in urban and residential areas with less forested and agricultural areas, and ( 3 ) in organic-polluted rivers indicated by higher annual mean of BOD. Generally, aquatic organisms in the natural environment are affected by many physicochemical factors including chemicals. Thus, as we demonstrated, the investigation of the physicochemical characteristics of water quality monitoring sites with higher concentrations of the chemicals of concern is valuable for evaluating management options that are substantially effective for protecting aquatic life.
在全国范围内开展水环境水质超标评价是制定环境水质标准和污水排放法规的关键。为了了解线性烷基苯磺酸盐(LAS)年平均浓度超过EQS的河流站点的特征,我们比较了(1)河道宽度(作为河流大小的指标),(2)周围土地利用,(3)生化需氧量(BOD)作为2015-2016年平均LAS浓度> 0.02 mg L -1的“LAS污染场地”与浓度≤0.02 mg L -1的“未污染场地”的有机污染指标。结果表明,与未污染的河流相比,las污染的河流出现频率更高:(1)河道宽度较小且变化较小的河流,(2)位于城市和居民区的河流,森林和农业区较少,(3)在有机污染的河流中,BOD的年平均值较高。一般来说,自然环境中的水生生物受到包括化学物质在内的许多物理化学因素的影响。因此,正如我们所证明的那样,对关注的化学物质浓度较高的水质监测点的物理化学特征进行调查,对于评估对保护水生生物实质上有效的管理选择是有价值的。
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引用次数: 1
Effect of Nutrient Loads on Upper Trophic Level Species in Lake Biwa: Analysis Using Food Chain Model by Monte Carlo Method 营养负荷对琵琶湖上营养层物种的影响——基于蒙特卡罗方法的食物链模型分析
Pub Date : 2019-01-01 DOI: 10.2965/jswe.42.133
Yuichi Sato, K. Hayakawa
It has been pointed out that some waterbodies face “oligotrophication” owing to a decrease in nutrient loads. In this study, we predicted the effect of a change in future nutrient loads on variables such as the biomass of upper-trophic-level species, using the food chain model. The target area is Lake Biwa, where fish catches have fallen in recent years concurrent with a decrease in nutrient loads. Three models with different structures were developed and 100 patterns of parameter sets were selected for each model by the Monte Carlo method. As a result, the change in the biomass of phytoplankton, regardless of the model structure, tended to be roughly proportional to the change in nutrient loads in general. On the other hand, for the fish, differences in model structures and their prey strongly affected the biomass, and although inflow load increased, the biomass decreased in some cases. Considering the uncertainty of the prediction, we suggested that the addition of nutrients with the aim of increasing the fish populations would cause undesirable results in Lake Biwa such as a combination of deteriorating water quality and no increase in the fish populations.
有人指出,由于营养负荷的减少,一些水体面临“少营养化”。在这项研究中,我们使用食物链模型预测了未来营养负荷变化对高营养水平物种生物量等变量的影响。目标区是琵琶湖,那里的渔获量近年来下降,同时营养负荷也在减少。采用蒙特卡罗方法建立了3个不同结构的模型,并为每个模型选择了100个参数集模式。因此,无论模式结构如何,浮游植物生物量的变化大体上倾向于与养分负荷的变化成正比。另一方面,对于鱼类来说,模型结构和猎物的差异对生物量的影响很大,虽然流入负荷增加,但在某些情况下生物量减少。考虑到预测的不确定性,我们认为以增加鱼类种群为目的添加营养物质会导致琵琶湖水质恶化和鱼类种群没有增加的不良结果。
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引用次数: 0
Consideration of Transport of Ammonium Nitrogen in a Tidal River 潮汐河中铵态氮运移的研究
Pub Date : 2019-01-01 DOI: 10.2965/JSWE.42.117
H. Yamanishi, Yuka Aoki
This study was aimed at investigating the influence of a sewage treatment plant’s seasonal operation on the water quality and nutrient transport of a tidal river. Cross-sectional observations were carried out in the Honjoe River, which flows into Ariake Bay in Japan. Field surveys and experiments focusing on the transport of ammonium nitrogen ( NH 4 + -N ) in the tidal river were performed. As a result, suspended solid ( SS ) sediment formation close to the river, including in the vegetation areas, was accelerated and exhibited the potential local accumulation of NH 4 + -N with SS. In addition, some experiments revealed an empirical equation for the removal rate of NH 4 + -N. According to the equation, the NH 4 + -N sedimentation rates tended to be low when the salinity and initial SS were high. Furthermore, the removal rate of NH 4 + -N calculated using the empirical equation agreed qualitatively with the field results.
本研究旨在探讨污水处理厂季节性运作对潮汐河水质及养分输送的影响。横断面观测是在流入日本有明湾的本乔河进行的。对潮河中铵态氮(nh4 + -N)的运移进行了野外调查和实验研究。结果表明,河流附近(包括植被区)的悬浮固体(SS)沉积物形成速度加快,并表现出SS对nh4 + -N的潜在局部积累。此外,一些实验还揭示了nh4 + -N去除率的经验方程。由方程可知,当盐度和初始SS较高时,nh4 + -N沉降速率趋于较低。此外,利用经验方程计算的nh4 + -N去除率与现场结果定性一致。
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引用次数: 0
Disaggregation of Granular Sludge during Methane Fermentation Treatment for Methanol-containing Wastewater 含甲醇废水甲烷发酵过程中颗粒污泥的分解
Pub Date : 2019-01-01 DOI: 10.2965/JSWE.42.67
Kazumasa Kamachi, H. Shinjô, Y. Tsukamoto, T. Tatsuzawa
It is a challenge to maintain the granular sludge during the treatment of wastewater containing methanol by UASB, since few methanogens can utilize methanol as a substrate. In this study, for the treatment of actual wastewater containing methanol, the change in the microbial community and particle distribution of granular sludge were observed during the acclimatization process of seed granular sludge for the continuous operation of an UASB (Up-flow Anaerobic Sludge Blanket) system with sludge returning after solid-liquid separation. Methanosarcina-like methanogens in the granular sludge became dominant during the acclimatization, and the dominant species was found to be Methanomethylovorans. After their DNA exceeded 80%, the collapse of the granular sludge progressed and the particle diameter became less than 0.5 mm. However, stable performance still could be obtained because of sludge returning after solid-liquid separation, even after the collapse of granular sludge.
在UASB处理含甲醇废水的过程中,由于很少有产甲烷菌可以利用甲醇作为底物,因此维持颗粒污泥是一个挑战。本研究以实际含甲醇废水为例,观察了种子型颗粒污泥在连续运行UASB(上流式厌氧污泥毯)系统中,固液分离后污泥回流的驯化过程中,颗粒污泥微生物群落和颗粒分布的变化。在驯化过程中,颗粒污泥中的类甲烷菌成为优势产甲烷菌,优势种为甲基化甲烷菌。当它们的DNA超过80%后,颗粒污泥继续坍塌,颗粒直径小于0.5 mm。然而,由于固液分离后的污泥回流,即使颗粒污泥坍塌后,仍能获得稳定的性能。
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引用次数: 0
Investigation of Seasonal Changes and Ecological Risk Assessments of Neonicotinoid Pesticides in Rivers in Osaka, Japan 日本大阪地区河流中新烟碱类农药的季节变化及生态风险评价
Pub Date : 2019-01-01 DOI: 10.2965/jswe.42.227
K. Oyama, Y. Yabuki, A. Banno
Concentrations of neonicotinoids and fipronil in river water were investigated in rural areas, the lower reach of the sewage disposal plant and principal rivers in Osaka Prefecture. As a result, pesticides other than nitenpyram and thiacloprid were detected at all sampling sites. Concentrations of imidacloprid increased drastically in June and concentrations of dinotefuran increased drastically from August to September. These periods were contemporaneous with spraying periods of these pesticides in rice fields. It was determined that none of the pesticide concentrations exceeded the water quality standards in Japan or Predicted Environmental Concentrations (PEC), which were calculated by the Ministry of the Environment, in all survey spots. On the other hand, more than 5% of the aquatic organisms are expected to be affected by neonicotinoids in rural area rivers from late May to June according to the calculation from species sensitivity distribution (SSD) of multiple influence of aquatic arthropods.
对大阪府农村地区、污水处理厂下游和主要河流的河水中新烟碱类和氟虫腈的浓度进行了调查。结果,在所有采样点均检测到除虫胺和噻虫啉以外的其他农药。吡虫啉浓度在6月急剧上升,敌敌畏浓度在8 - 9月急剧上升。这些时期与这些农药在稻田的喷洒时期是同步的。所有调查地点的农药浓度均未超过日本的水质标准或环境部计算的预测环境浓度(PEC)。另一方面,根据水生节肢动物多重影响的物种敏感性分布(SSD)计算,预计5月下旬至6月农村河流中有5%以上的水生生物受到新烟碱类杀虫剂的影响。
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引用次数: 3
Setting of Optimal Dosage of Polymer Flocculant in Centrifugal Dewatering Process for Digested Sewage Sludge 污泥消化离心脱水中高分子絮凝剂最佳投加量的确定
Pub Date : 2019-01-01 DOI: 10.2965/jswe.42.269
Yoshihiro Suzuki, Keigo Endo, Wakana Taiko, K. Nukazawa, Yuichi Furuhashi, Nobuaki Chuganji
In the present study, we investigated the relationship between 11 properties of digested sludge and the optimal dosage ratio of polymer flocculant, assuming a conditioning process for sludge fed into a dewatering centrifuge. Furthermore, the study was focused on the supernatant phase ( mixed phase of colloidal matter and dissolved matter ) obtained by centrifugal separation of sludge, and a list of the properties of the supernatant phase was created. We then attempted to identify the properties that govern the optimal dosage. As a result, no correlation between total solids and the optimal injection ratio was observed. Therefore, the dosage was defined as the absolute quantity of polymer flocculant per 100 grams of sludge ( g/100 g sludge = % per sludge weight ) . As a result of examining its relationship with various properties, the strongest correlation was observed between the anion concentration of the supernatant phase and the optimal quantity of polymer flocculant, with r=0.73. A correlation was also found between the optimal quantity of polymer flocculant and the turbidity of the supernatant phase ( r=0.68 ) . We thus found that the optimal quantity of polymer flocculant can be predicted simply by centrifuging the raw sludge and measuring the turbidity of the supernatant phase.
在本研究中,我们研究了消化污泥的11种性质与高分子絮凝剂的最佳投加比之间的关系,假设污泥进入脱水离心机进行调节过程。此外,对污泥离心分离得到的上清相(胶体物质和溶解物质的混合相)进行了研究,并创建了上清相的性质列表。然后,我们试图确定控制最佳剂量的性质。结果表明,固体总量与最佳注入比之间没有相关性。因此,将投加量定义为每100克污泥中高分子絮凝剂的绝对投加量(g/100克污泥= % /污泥重量)。通过考察其与各种性能的关系,发现上清相阴离子浓度与高分子絮凝剂最佳投加量的相关性最强,r=0.73。高分子絮凝剂的最佳投加量与上清相浊度之间存在相关性(r=0.68)。因此,我们发现聚合物絮凝剂的最佳用量可以简单地通过对原污泥进行离心和测量上清相的浊度来预测。
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引用次数: 0
期刊
Journal of Japan Society on Water Environment
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