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Arsenic Pollution in Nagae River after Volcanic Eruption of Mt. Iou 柳山火山喷发后长江河的砷污染
Pub Date : 2021-01-01 DOI: 10.2965/JSWE.44.43
Chikahide Komura, T. Hama, Yukihiro Ichinose, T. Kubota
The water quality of the river basins situated in volcanic areas and exposed to volcanic activity can be affected by the acidic water, resulting in the pollution of surface water. On April 19th, 2018, the first eruption in 250 years of Mt. Iou, one of the Kirishima volcanos, caused the discharge of mud and acidic water into the Nagae River, contaminating the water with arsenic at a high concentration that exceeded the environmental standard ( 10 µg L -1 ) . In this study, we investigated the changes in arsenic concentration in the streamflow process, the relationship between pH and Electrical Conductivity ( EC ) , and the runoff characteristics through a continuous observation. The results indicate that the river water was diluted and improved during the streamflow process owing to dilution as a result of influx of water from tributaries, the arsenic concentration has a correlation with pH and EC, particularly, in the upstream area and on nonrainy days, and the arsenic concentration correlates with iron, aluminum, and manganese concentrations. Consequently, arsenic accumulates at the bottom of the riverbed on nonrainy days, and its concentration becomes high owing to the resuspension of the river sediment on rainy days.
地处火山地区、受火山活动影响的河流流域的水质会受到酸性水的影响,造成地表水的污染。2018年4月19日,雾岛火山之一的Iou火山250年来首次喷发,导致泥浆和酸性水排放到长江中,砷的浓度超过了环境标准(10 μ g L -1)。本研究通过连续观测研究了径流过程中砷浓度的变化、pH值与电导率(EC)的关系以及径流特征。结果表明:在径流过程中,由于支流水的冲淡,河水被稀释并得到改善;砷浓度与pH和EC存在相关性,特别是在上游地区和非阴雨天;砷浓度与铁、铝、锰浓度存在相关性。因此,在非雨天,砷在河床底部积聚,在雨天,由于河流沉积物的再悬浮,砷的浓度变得很高。
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引用次数: 2
Effect of Multilayered Structure of Filtration Beds on Sewage Treatment Performance in a Multistage Constructed Wetland 多层过滤床结构对多级人工湿地污水处理性能的影响
Pub Date : 2021-01-01 DOI: 10.2965/jswe.44.85
Tasuku Suzuki, T. Taniguchi, K. Nakano
In this research, the performance characteristics of the multilayered filtration bed ( MLF ) and non-multilayered filtration bed ( n-MLF ) in a pilot-scale multistage constructed wetland for treating sewage were compared, and the effect of the multilayered structure on the water purification performance was elucidated. It was confirmed that the effect of the multilayered structure on the aerated treatment performance of, for example, BOD and NH 4+ -N removal was negligible under the vertical flow condition, but not under the hybrid condition comprising both vertical and horizontal flows. MLF was easier to become anaerated than n-MLF, resulting in a lower aerated treatment performance under the hybrid condition. Furthermore, the effect of a lack of vegetation on MLF manifested as a lower nitrogen removal performance. Although the specific removal unit for BOD and phosphorus under the vertical flow condition in MLF increased 1.5fold compared with that in n-MLF, the removal performance of nitrogen could not be improved. The specific energy consumption for sewage treatment by the constructed wetland in this work was low at 0.32 kWh m -3 , demonstrating the effectiveness of the constructed wetland in accomplishing the decarbonization of sewage works.
本研究在中试多级人工湿地中比较了多层过滤床(MLF)和非多层过滤床(n-MLF)处理污水的性能特点,并阐明了多层结构对水净化性能的影响。结果表明,在垂直流动条件下,多层结构对BOD和nh4 + -N去除等曝气处理性能的影响可以忽略不计,但在垂直和水平混合流动条件下则不能忽略。混合条件下,MLF比n-MLF更易曝气,导致曝气处理性能较差。此外,缺乏植被对MLF的影响表现为较低的脱氮性能。垂直流动条件下,MLF对BOD和磷的比去除率比n-MLF提高了1.5倍,但对氮的去除率没有提高。本工程人工湿地处理污水的比能耗较低,为0.32 kWh m -3,说明人工湿地在完成污水工程脱碳方面的有效性。
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引用次数: 0
Characteristics of Disinfection By-products in Effluents from Wastewater Treatment Plants in Kyoto City 京都市污水处理厂出水消毒副产物特征
Pub Date : 2021-01-01 DOI: 10.2965/jswe.44.103
K. Hosoda, T. Segawa
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引用次数: 0
Distribution of Oxygen-Deficient Water and Estimation of Its Area in Lake Kitaura 基图拉湖缺氧水分布及其面积估算
Pub Date : 2021-01-01 DOI: 10.2965/jswe.44.157
Shunsuke Komuro, T. Kitamura, Takao Oouchi, E. Masunaga, Daiki Asaoka, K. Ayukawa, Yasuhide Mikami, Y. Seike, Miyuki Yuzawa, T. Fukushima
Detailed distributions of oxygen-deficient water were observed using a high-resolution tow-yo instrument, YODA Profiler, in Lake Kitaura to investigate the formation of oxygen-deficient water. The results of observations showed that oxygen-deficient water widely appeared at a depth of deeper than 4 m, and the dissolved oxygen ( DO ) concentration in deep areas was particularly low. Furthermore, it was suggested that high phosphorus ( PO 4 -P ) concentrations were eluted from sediments in areas of oxygen-deficient water. The DO concentration at 10 cm above the lake bottom tended to be lower than that at 50 cm above the lake bottom. The oxygen-deficient water in Lake Kitaura is greatly affected by the water depth, which implies that the ratio of the area of oxygen-deficient water can be inferred by lake bathymetry and observed DO profiles. The area of oxygen-deficient water reached 55.9 % at 50 cm above the bottom and 63.2 % at 10 cm above the bottom of the total area of Lake Kitaura.
利用高分辨率拖曳仪器YODA Profiler在Kitaura湖观测了缺氧水的详细分布,以研究缺氧水的形成。观测结果表明,4 m以上深度广泛出现缺氧水,且深层溶解氧(DO)浓度特别低。此外,缺氧水域沉积物中高浓度磷(po4 -P)被洗脱。湖底以上10 cm处的DO浓度有低于50 cm处的趋势。Kitaura湖缺氧水体受水深影响较大,可以通过湖底测深和实测DO剖面推测其缺氧水体面积的比例。在基图拉湖总面积中,湖底以上50 cm处缺氧面积达55.9%,湖底以上10 cm处缺氧面积达63.2%。
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引用次数: 0
Factor Analysis of Seasonal Fluctuations in Water Quality and Fish Mortality Events within Shallow Eutrophic Water under Freezing Conditions 冻结条件下浅层富营养化水体水质季节波动及鱼类死亡事件的因子分析
Pub Date : 2021-01-01 DOI: 10.2965/jswe.44.165
Morio Tsuji, Masaki Suzuki
Fish mortality was investigated in a shallow, constantly stored-water-type regulating pond located in a cold region in mid-March 2018 after ice had melted. In general, fish mortality occurs when water temperatures increase; however, in this case, it occured under freezing conditions. In this study, we attempted to understand the actual water quality by referring to the results of water quality surveys conducted throughout the year and the factors leading to the accident. The studied pond is eutrophic with treated wastewater. Phytoplankton proliferated during the non-freezing season by consuming nutrients in the treated wastewater, and organic matter derived from the phytoplankton accumulated as bottom mud. In early March 2018, the dissolved oxygen (DO) concentration in the bottom layer was almost 0 mg L, while it was also under 1.2 mg L in the upper layer. Concurrently, NH4-N leached out from the reduced bottom mud, and its concentration in the bottom layer increased to 25.4 mg L. The pH of the bottom layer increased to 8.96, and the free ammonia concentration was estimated to be about 3.0 mg L. These results indicate that the low DO and elevated NH4-N concentrations under freezing conditions directly caused this fish mortality incident.
2018年3月中旬,在冰融化后,在位于寒冷地区的一个浅的、不断储水型调节池中调查了鱼类死亡率。一般来说,水温升高会导致鱼类死亡;然而,在这种情况下,它发生在冻结条件下。在这项研究中,我们试图通过全年的水质调查结果和导致事故的因素来了解实际的水质。污水处理后的池塘富营养化。在非冻结季节,浮游植物通过消耗处理过的废水中的营养物质而增殖,浮游植物产生的有机物作为底泥积累。2018年3月初,底层溶解氧(DO)浓度接近0 mg L,上层也在1.2 mg L以下。同时,还原后的底泥析出NH4-N,底泥中NH4-N的浓度上升至25.4 mg l,底泥pH值上升至8.96,游离氨浓度约为3.0 mg l,表明低温条件下低DO和NH4-N浓度升高直接导致了此次鱼类死亡事件。
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引用次数: 0
Relationship between Potassium Permanganate Consumption and Total Organic Carbon in Bath Water in Public Bathhouses and Similar Facilities 公共澡堂及类似设施洗澡水中高锰酸钾用量与总有机碳的关系
Pub Date : 2021-01-01 DOI: 10.2965/jswe.44.175
Akira Oshima
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引用次数: 0
Developing a Method of Detecting Cyanamide and Monitoring Its Concentrations in Rivers in Osaka 大阪市河流中氰胺检测及浓度监测方法的建立
Pub Date : 2021-01-01 DOI: 10.2965/JSWE.44.9
J. Ono, Koji Ito, Shigeru Suzuki, Y. Yabuki
The concentrations of cyanamide in environmental water have not been reported owing to a lack of its analytical method. We have developed an analytical method for detecting cyanamide in river water and sea water, which includes the derivatization of cyanamide into dansyl-cyanamide, clean-up with a silica gel solid-phase extraction cartridge, and measurement by liquid chromatography/tandem quadrupole mass spectrometry ( LC-MS/MS ) . The method was applied to the determination of cyanamide concentration in river water at nine different locations in Osaka Prefecture. Cyanamide was detected at all locations, and its concentration ranged from a value below the method detection limit ( MDL ) to 4.2 ng mL -1 . The concentrations were much lower than the registration standards of agricultural chemicals concerning prevention of damage to aquatic flora and fauna ( 670 ng mL -1 ) , and thus, the risk of cyanamide pollution to aquatic flora and fauna in the rivers was assumed to be negligible.
由于缺乏分析方法,环境水体中氰胺的浓度尚未见报道。我们建立了一种检测河水和海水中氰酰胺的分析方法,该方法包括将氰酰胺衍生为丹酰氰酰胺,用硅胶固相萃取筒进行净化,并通过液相色谱/串联四极杆质谱(LC-MS/MS)进行测定。将该方法应用于大阪府9个不同地点河水中氰胺浓度的测定。在所有地点均检测到氰胺,其浓度范围为低于方法检测限(MDL)至4.2 ng mL -1。该浓度远低于农用化学品防止水生动植物损害登记标准(670 ng mL -1),因此可以认为氰胺污染对河流中水生动植物的风险可以忽略不计。
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引用次数: 0
Prediction of Urban Non-point Pollution Load by Statistical Analysis of Data of Published Research and Its Reliability Evaluation –Statistical Analysis of Mean Load and Verification and Modification of Previously Proposed Model Using Newly Obtained Data– 基于已发表研究数据统计分析的城市非点源污染负荷预测及其可靠性评价——平均负荷统计分析及新数据对原有模型的验证与修正
Pub Date : 2021-01-01 DOI: 10.2965/JSWE.44.1
N. Ozaki, K. Wada, M. Murakami, F. Nakajima, H. Furumai
To verify a statistical model for predicting urban pollutant runoff developed in our previous research, newly obtained runoff data were compared with those predicted by the model. The proposed model previously was a regression model using parameters representing geological, rainfall, and hydrological characteristics. The targeted pollutants were COD, SS, TN, and TP, and their event mean concentrations (EMCs) for each rainfall were predicted. From the comparison, the model was found to predict the EMC to one order of magnitude. Moreover, the yearly mean EMC was evaluated from only the mean and standard deviation of all data for each index. The error ratio of the prediction of the mean of 50 rainfall events was within 50%. Furthermore, in order to consider the possible differences among different catchment areas, the EMC values for three catchment areas newly obtained were compared statistically with nationwide values obtained previously. Significant differences were found for one area out of the three which thus emphasizes the importance of the consideration of catchment area differences. Thereafter, the number of runoff samples in a specific watershed area required to detect the mean EMC difference from the nationwide database was derived statistically. This number was calculated to be 10 at most for detecting more than double or less than half of the database means. Lastly, a modified model that includes watershed area differences using a generalized linear mixed model was proposed.
为了验证我们之前建立的预测城市污染物径流的统计模型,我们将新获得的径流数据与模型预测的数据进行了比较。先前提出的模型是使用代表地质、降雨和水文特征的参数的回归模型。目标污染物为COD、SS、TN和TP,并预测了每次降雨的事件平均浓度(EMCs)。通过比较,发现该模型能将电磁兼容预测到一个数量级。此外,仅从各指标所有数据的平均值和标准差来评估年平均EMC。对50次降雨事件的平均值的预测误差率在50%以内。此外,为了考虑不同流域之间可能存在的差异,将新获得的三个流域的EMC值与全国范围内的EMC值进行了统计比较。三个区域中有一个区域存在显著差异,从而强调了考虑集水区差异的重要性。在此基础上,从全国数据库中统计得出了检测平均EMC差异所需的特定流域径流样本数量。如果检测到数据库平均值的两倍以上或不到一半,则计算出该数字最多为10。最后,提出了基于广义线性混合模型的流域面积差异修正模型。
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引用次数: 1
Trial Operation of Water-quality Forecasting System Based on Fecal Pollution Indicators for a Beach in Odaiba Marine Park 基于粪便污染指标的台场海洋公园某海滩水质预报系统试运行
Pub Date : 2021-01-01 DOI: 10.2965/JSWE.44.59
Chizuru Kitayama, Kenji Morita, H. Fukuchi, SungAe Lee, H. Furumai
Fecal pollution caused by combined sewer overflows has been observed at urban waterfronts after rainfall and results in fecal pollution levels exceeding bathing water quality standards. To guarantee the swimmablility of urban waterfronts, it is necessary to predict the situation of fecal contamination to ensure safe bathing. Therefore, we aimed to develop a water-quality forecasting system for the beach in Odaiba Marine Park using Escherichia coli as a fecal indictor to determine whether people can submerge their faces in the seawater on the day of bathing. First, rainfall events in the 23 cities of Tokyo over the past 10 years were categorized by cluster analysis, considering their temporospatial distribution characteristics. Then, E. coli concentration changes in the park were calculated using a 3D hydrodynamic and water-quality model for each categorized rainfall group. Using the calculation results for various tidal conditions, we constructed a database of E. coli concentration changes. It was confirmed that the E. coli concentration predicted using the database for a corresponding rainfall group agrees with the concentration peak calculated using the model within a safe margin. Using the constructed database, we carried out a trial operation of the water-quality forecasting system for the beach in 2018 and verified its effectiveness.
雨水过后,在城市滨水区观察到合流下水道溢流造成的粪便污染,导致粪便污染水平超过洗浴用水质量标准。为了保证城市滨水区的可游泳性,有必要对粪便污染情况进行预测,以确保安全沐浴。因此,我们旨在开发台场海洋公园海滩的水质预报系统,以大肠杆菌为粪便指标,确定人们在洗澡当天是否可以将脸浸入海水中。首先,利用聚类分析方法对东京都23个城市近10年的降水事件进行了时空分布特征分类。然后,使用三维水动力和水质模型计算了每个分类降雨组的公园内大肠杆菌浓度变化。利用不同潮汐条件下的计算结果,建立了大肠杆菌浓度变化数据库。结果表明,利用数据库预测的相应降雨组的大肠杆菌浓度与利用模型计算的浓度峰值在安全范围内一致。利用构建的数据库,我们于2018年对海滩水质预报系统进行了试运行,验证了其有效性。
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引用次数: 0
Impact of Nutrient Reduction on Organic Matter (COD and TOC) in Coastal Embayments: Effect of the Reduction and Its Working Mechanism 营养物减量对海岸带有机物(COD和TOC)的影响:减量效应及其工作机制
Pub Date : 2021-01-01 DOI: 10.2965/jswe.44.185
T. Fujiwara, Motoharu Suzuki, Kei Okubo
Because of the reduction of nutrients in marine areas nationwide, the rates of achieving total nitrogen ( TN ) and total phosphorus ( TP ) water quality standards have reached 96% and 95%, respectively. Nevertheless, the achievement rate of the chemical oxygen demand ( COD ) standard has remained almost unchanged over the last 30 years. The cause of this discrepancy was investigated in Osaka Bay and the following was found. Eutrophication measures such as “TN reduction to suppress the occurrence of high-concentration phytoplankton blooms ( red tide ) ” are working effectively. This was seen in the water quality indicators associated with particulate organic matter. In contrast, the amount of dissolved organic matter has not decreased. The reduction of nutrients has resulted in a rise in the C: N ratio of organic matter, caused by the constancy of the organic carbon concentration and the decrease in organic nitrogen concentration. A discrepancy between COD and TOC trends has also occurred. It was common to Tokyo Bay and Ise Bay that COD has not decreased because nutrient reduction induces a change in the quality of organic matter.
由于全国海域营养物减少,总氮(TN)和总磷(TP)水质达标率分别达到96%和95%。然而,近30年来,化学需氧量(COD)标准的达标率几乎没有变化。在大阪湾调查了这一差异的原因,发现了以下情况。“减少总氮抑制高浓度浮游植物华(赤潮)的发生”等富营养化措施正在有效发挥作用。这在与有机颗粒物相关的水质指标中可见一斑。相比之下,溶解有机物的数量并没有减少。营养物质的减少导致有机质C: N比值的上升,这是由于有机碳浓度的恒定和有机氮浓度的降低造成的。COD和TOC的变化趋势也存在差异。东京湾和伊势湾的共同点是,由于营养物减少导致有机物质的变化,COD没有下降。
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引用次数: 1
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Journal of Japan Society on Water Environment
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