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Plasma Coatings Based on Self-Fluxing NiCrBSi Alloy with Improved Wear Resistance Properties 基于自熔NiCrBSi合金的提高耐磨性等离子体涂层
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.15407/pmach2023.03.054
Pavlo A. Sytnykov
The structure and properties of plasma coatings sprayed with a composite material based on a self-fluxing NiCrBSi alloy (PG-10N-01 alloy) modified with a composite material obtained by self-propagating high-temperature synthesis were studied. Titanium powders, carbon black, aluminum, iron oxide, PT-NA-01 thermosetting powder and PGOSA-0 refractory clay were used as the initial components of modified with a composite material. Mixing and mechanical activation of the initial powders was carried out in a BM-1 ball mill for 15 minutes at 130 rpm in a ratio of 1 to 40 of the mass of the charge to the mass of the falling bodies (steel balls with a diameter of 6 mm). Initiation of the self-propagating high-temperature synthesis was carried out using a special device by introducing a heated nichrome spiral. The process of coatings spraying was performed on the MPN-004 microplasma spraying unit at a current of 45 A, a voltage of 30 V with a distance of 100 mm on samples made of 65G steel with a thickness of 3 mm. Argon was used as a plasma-forming and shielding gas. In order to substantiate the feasibility of the self-propagating high-temperature synthesis, a part of the samples was sprayed with a self-fluxing alloy PG-10N-01 with the addition of a mechanical mixture of starting powders. It was established that as a result of plasma spraying of the PG-10N-01 alloy and the composite material of the modified with a composite material + PG-10N-01 composition, coatings with a dense and multiphase structure are formed. The microstructure of the PG-10N-01 alloy coating consists of a solid solution based on nickel (γ-Ni) with inclusions of nickel borides Ni3B and chromium carbides Cr3C2. When adding modified with a composite material in a nickel-based solid solution, in addition to the phases indicated above, borides of titanium TiB2, carbides of titanium TiC and silicon SiC were detected. Their presence leads to an increase in the microhardness of such coatings and their greater wear resistance under conditions of abrasive wear in comparison with the spraying coating of the PG-10H-01 alloy.
研究了自蔓延高温合成复合材料改性自熔NiCrBSi合金(PG-10N-01合金)复合材料喷涂等离子涂层的组织和性能。以钛粉、炭黑、铝、氧化铁、PT-NA-01热固性粉末和PGOSA-0耐火粘土为初始组分进行复合材料改性。初始粉末的混合和机械活化在BM-1型球磨机中以130转/分的速度进行15分钟,装药质量与落体质量(直径为6毫米的钢球)的比例为1:40。采用一种特殊的装置,通过引入加热镍铬合金螺旋来引发自传播高温合成。在MPN-004微等离子喷涂装置上,以45 a电流、30 V电压、100 mm距离对厚度为3 mm的65G钢试样进行涂层喷涂。氩气被用作等离子体形成和保护气体。为了验证自蔓延高温合成的可行性,在部分样品上喷涂自熔合金PG-10N-01,并加入机械混合的起始粉末。结果表明,等离子喷涂PG-10N-01合金和复合材料+ PG-10N-01组分改性后的复合材料可形成致密的多相结构涂层。PG-10N-01合金涂层的显微组织为镍(γ-Ni)固溶体,夹杂有硼化镍Ni3B和碳化铬Cr3C2。在镍基固溶体中加入改性复合材料,除上述相外,还检测到钛TiB2的硼化物、钛TiC的碳化物和硅SiC的碳化物。与PG-10H-01合金的喷涂涂层相比,它们的存在提高了涂层的显微硬度,并且在磨料磨损条件下具有更大的耐磨性。
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引用次数: 0
Calculation of the Tubular Elements Made of Pressed Profiles 压型管状构件的计算
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.15407/pmach2023.03.028
Mykhailo M. Hrebennikov, Oleksandr H. Dibir, Anatolii O. Kyrpikin, Mykola I. Pekelnyi
This paper is dedicated to ensuring the strength of cargo equipment elements of transport aircraft. The strength of rollers of roller conveyors, which are made of standard pressed aluminum tubular profiles or composite tubular elements, is considered. The main disadvantage of these semi-finished products is the deviation of the diameter of these standard aluminum profiles, which leads to the emergence of eccentricity Δ between the axes of the outer and inner surfaces. The influence of eccentricity on the change in the values of normal and tangential stresses is considered. This analysis was carried out for standard diameters of tubular profiles at values Δ equal to half of the standard limit deviation of the outer diameter D. Calculations of normal and tangential stresses and their comparison with nominal stresses that occur in the absence of misalignment have been carried out. Calculations were made of the value c of the removal of the center of rigidity from the center of the circle of the outer border of the cross-section at different cross-section sizes of standard profiles with values of Δ equal to half of the standard limit deviation of the outer diameter D inclusively. The calculations showed an increase in tangential stresses τ in some cases by 64% and even by 213%. The obtained results indicate that the presence of Δ≠0 will have a negative effect on the resource of these elements. In order to eliminate the negative consequences, it is necessary to increase the requirements for the shape deviation of the tubular profiles in the input control.
本文致力于保证运输机货运设备元件的强度。考虑了由标准压制铝型材或复合管状元件制成的滚筒输送机的辊筒强度。这些半成品的主要缺点是这些标准铝型材的直径存在偏差,从而导致内外表面轴线之间出现偏心Δ。考虑了偏心对法向应力和切向应力变化的影响。该分析是对标准管材直径Δ等于外径d标准极限偏差的一半的值进行的。计算了法向和切向应力,并将其与没有不对中情况下的标称应力进行了比较。计算了不同标准型材截面尺寸下截面外缘圆心离刚性中心的偏移量c值,其值Δ等于外径D的标准极限偏差的一半。计算表明,在某些情况下,切向应力τ增加了64%,甚至213%。所得结果表明,Δ≠0的存在会对这些元素的资源产生负面影响。为了消除负面影响,有必要在输入控制中增加对管状型材形状偏差的要求。
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引用次数: 0
Multicriteria Parametric Optimization of Nonlinear Robust Control with Two Degrees of Freedom by a Discrete-Continuous Plant 离散连续对象二自由度非线性鲁棒控制的多准则参数优化
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.15407/pmach2023.03.042
Borys I. Kuznetsov, Ihor V. Bovdui, Olena V. Voloshko, Tetyana B. Nikitina, Borys B. Kobylianskyi
A multicriteria parametric optimization of nonlinear robust control with two degrees of freedom by a discrete-continuous plant has been developed to increase accuracy and reduce sensitivity to uncertain plant parameters. Such plants are mounted on a moving base, on which sensors for angles, angular velocities and angular accelerations are installed. To increase the accuracy of control, systems with two degrees of freedom, which include control with feedback and a closed-loop, and with direct connections and open-loop control of the setting and disturbing effects, are used. The multicriteria optimization of nonlinear robust control with two degrees of freedom by a discrete-continuous plant is reduced to the solution of the Hamilton-Jacobi-Isaacs equations. The robust control target vector is calculated as a solution of a zero-sum antagonistic vector game. The vector payoffs of this game are direct indexes performance vector presented in the system in different modes of its operation. The calculation of the vector payoffs of this game is related to the simulation of the synthesized nonlinear system for different operating modes of the system, input signals and values of the plant parameters. The solutions of this vector game are calculated on the basis of the system of Pareto-optimal solutions, taking into account the binary relations of preferences, on the basis of the stochastic metaheuristic of Archimedes optimization algorithm by several swarms. Thanks to the synthesis of nonlinear robust control with two degrees of freedom by a discrete-continuous object, it is shown that the use of synthesized controllers made it possible to increase the accuracy of control of an electromechanical system with distributed parameters of the mechanical part to reduce the time of transient processes by 1.5–2 times, reduce dispersion of errors by 1.3 times and reduce the sensitivity of the system to changes in the plant parameters in comparison with typical controllers used in existing systems. Further improvement of control accuracy is restrained by energy limitations of executive mechanisms and information limitations of measuring devices.
为了提高控制精度,降低对不确定对象参数的敏感性,提出了一种离散连续对象二自由度非线性鲁棒控制的多准则参数优化方法。这种装置安装在一个移动的基座上,基座上安装了测量角度、角速度和角加速度的传感器。为了提高控制的精度,采用了两自由度系统,包括反馈控制和闭环控制,以及直接连接和开环控制的整定和扰动效应。将离散连续对象的二自由度非线性鲁棒控制多准则优化问题简化为Hamilton-Jacobi-Isaacs方程的求解。鲁棒控制目标向量是一个零和对抗向量博弈的解。该博弈的收益向量是系统在不同运行模式下表现出来的直接指标性能向量。该博弈的矢量收益计算涉及到对系统不同运行模式、输入信号和电厂参数值的综合非线性系统进行仿真。该矢量对策的解是在pareto最优解系统的基础上,考虑到二元偏好关系,在阿基米德优化算法的随机元启发式的基础上计算的。通过对离散连续对象的二自由度非线性鲁棒控制的综合,表明综合控制器的使用可以提高机械部分参数分布的机电系统的控制精度,将瞬态过程的时间缩短1.5-2倍。与现有系统中使用的典型控制器相比,将误差分散减少1.3倍,并降低系统对工厂参数变化的灵敏度。控制精度的进一步提高受到执行机构能量限制和测量装置信息限制的制约。
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引用次数: 0
Changes in the Thermal and Stress-Strain State of the HPC Rotor of a Powerful NPP Turbine after the Blades Damage 大功率核电站汽轮机叶片损伤后HPC转子热应力应变状态的变化
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.15407/pmach2023.03.015
Olha Yu. Chernousenko, Vitalii A. Peshko, Oleksandr P. Usatyi
In practice, during the operation of steam turbines, accidental damage to the blades of the rotors and stators of powerful steam turbines occurs. The main causes of emergency stops of steam turbines were vibration fatigue of the blades material, erosive damage to the blades body, and resonance problems during the power equipment operation. Based on this study, the assessment of changes in the thermal and stress-strain state of power equipment elements, which at nuclear power plants significantly affect the continued operation of the turbine after its damage, are quite relevant. Changes in the thermal and stress-strain state, which may occur after damage to the rotor of high-pressure cylinder (HPC rotor) of the K-1000-60/3000 turbine power unit of the LMZ in the station conditions, have been considered and analyzed and will provide an opportunity to assess the individual resource and continue the power unit operation. In the calculated assessment of changes in the thermal and stress-strain state of the HPC rotor, taking into account the data of the technical audit regarding damage, a geometric model of the rotor was created. Studies were conducted for three options of designs: the original option (five stages of the HPC rotor), the option without the blades of the last stage and the option without the fifth stage (with four first stages). For the project design, when working at the nominal parameters of the steam, the most stressed areas are the unloading holes of the 5th stage (σi=202.8 MPa), axial hole of the rotor in the area of the 5th stage (σi=195.2 MPa), as well as the 5th-degree welding fillet from the side of the end seals (σi=200.3 MPa) and unloading holes of the 4th and 3rd stages with a stress intensity of about 170–185 MPa. The high values of the stress intensity in the area of the 5th stage can be explained by the significant concentration of the mass of both the stage itself and its blades, which provoke significant centrifugal forces when working at the nominal rotation frequency. For a HPC rotor without blades of the 5th stage, there is a shift of the maximum stress intensity to the area of the unloading holes of the 4th and 3rd stages, as well as the axial hole of the shaft under the same stages. The maximum stress value is σi max=184.8 MPa. At the same time, the intensity of stresses in the area of unloading holes of the 5th degree decreased almost by half, to the level of 124 MPa.
在实际操作中,大功率汽轮机的动、定子叶片在运行过程中经常发生意外损坏。汽轮机紧急停机的主要原因是叶片材料的振动疲劳、叶片体的侵蚀损伤以及动力设备运行中的共振问题。基于本研究,对核电站动力设备元件的热状态和应力应变状态变化进行评估具有重要意义,这些变化对汽轮机损坏后的继续运行有重要影响。考虑并分析了LMZ K-1000-60/3000汽轮发电机组高压缸(HPC转子)转子在站场工况下可能发生的热态和应力应变状态的变化,为单机资源评估和机组继续运行提供了契机。在计算评估HPC转子的热状态和应力应变状态变化时,考虑损伤技术审核数据,建立了转子的几何模型。研究了三种设计方案:原始方案(HPC转子的五级)、不含末级叶片的方案和不含第五级的方案(第一级的四级)。本工程设计在蒸汽标称参数下工作时,受应力最大的区域为第5级卸料孔(σi=202.8 MPa)、第5级转子轴向孔(σi=195.2 MPa)、端封侧第5度焊接角(σi=200.3 MPa)和第4、3级卸料孔,应力强度约为170 ~ 185 MPa。第5级区域的高应力强度值可以通过级本身及其叶片的质量显著集中来解释,这在公称旋转频率下工作时会产生显著的离心力。对于无第5级叶片的HPC转子,最大应力强度向第4级和第3级卸荷孔区域以及同一级下轴向孔区域偏移。最大应力值为σi max=184.8 MPa。与此同时,第5度卸荷孔区域的应力强度下降了近一半,达到124 MPa的水平。
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引用次数: 0
Analysis of the Efficiency of a Power Generating Plant Operating on the Basis of the Brayton Thermodynamic Cycle and Energy Recuperation 基于布雷顿热力循环和能量回收的电厂运行效率分析
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.15407/pmach2023.03.006
Andrii V. Rusanov, Valerii S. Fedoreiko, Dariusz Kardaś, Andrii O. Kostikov, Viktoriia O. Tarasova, Roman A. Rusanov, Maryna O. Chuhai, Mykhailo I. Sukhanov, Serhii P. Tretiak
The thermal scheme of a power generating plant with a remote heat exchanger operating according to the Brayton cycle with energy recuperation is considered. It is assumed that the plant will work on non-certified (cheap) biofuel. It is shown that, in contrast to the usual Brayton cycle, in the cycle with energy recuperation, the greatest influence on the thermal efficiency is the heating temperature of the working medium and the internal efficiency of the main components of the plant, such as the compressor and the turbine. Also, in contrast to the usual Brayton cycle, a higher efficiency of the plant is achieved with smaller degrees of pressure reduction (increase) in the turbine (compressor). It was established that even at a relatively low temperature of the working medium heating (500 ºC), with high efficiency of the compressor and turbine, it is possible to achieve good characteristics of the power plant as a whole. At a temperature of up to 850 ºC, a thermal efficiency of 40% is achieved, but in this case the cost of materials and production increases. For a final conclusion about the possibility of using the proposed plant and its efficiency, it is necessary to conduct additional studies, in particular, of its main elements, such as a compressor, turbine, heat exchanger and others.
考虑了采用布雷顿循环带能量回收的远程热交换器的电厂热方案。据推测,该工厂将生产未经认证的(廉价的)生物燃料。结果表明,与通常的布雷顿循环相比,在有能量回收的循环中,对热效率影响最大的是工质的加热温度和电厂主要部件(如压缩机和汽轮机)的内部效率。此外,与通常的布雷顿循环相比,在涡轮机(压气机)中较小程度的压力降低(增加)可以实现更高的工厂效率。确定了即使在较低的工质加热温度下(500℃),在压缩机和汽轮机效率较高的情况下,也有可能实现电厂整体的良好特性。在高达850ºC的温度下,热效率达到40%,但在这种情况下,材料和生产成本增加。为了得出关于使用拟议工厂的可能性及其效率的最终结论,有必要进行额外的研究,特别是对其主要部件,如压缩机、涡轮机、热交换器等进行研究。
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引用次数: 0
Integrated Studies of Electrophysical Processes in Steam Turbines 汽轮机电物理过程的综合研究
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.15407/pmach2023.03.033
Anatolii O. Tarelin, Oleh Weres
The paper deals with comprehensive research in the field of electrization of wet steam flow in a turbine. The experience of the conducted studies on laboratory stands and full-scale objects (CHP and TPP) in Ukraine and the USA is introduced and generalized. It was shown that in the process of steam electrization, the charge density in the flow can reach very high values (an order of magnitude appears to be higher than in a thundercloud), and this phenomenon mainly has a negative effect on the turbine operation. Statistical data on the charge formation of the steam flow in the low-pressure cylinder of the turbine are presented. Results of the research to establish the main electrophysical factors of influence on the surface strength of the blade, such as electric fields, charge density and their polarity, are presented. The research results showed that such factors as the presence of a positively charged steam flow, constant and variable electric fields, which were most often recorded at operating turbines of CHPs and TPPs, significantly (by two or more times) intensify erosion-corrosion processes on the metal surfaces of the blades, thus reducing their working resource. Thermodynamic processes are studied both under conditions of natural electrification of a high-speed flow, which reduce the efficiency by about 0.3–0.35%, and under the influence of artificially created electric charges, which make it possible to increase the efficiency of the steam expansion process in the turbine by 2 or more percent. Various options of local input of electrical energy for steam ionization in the turbine are considered. At the same time, it is noted that for the practical implementation of these approaches, further careful design improvements and tests on model and full-scale installations are required. Water chemistry regimes are also considered in the context of their influence on the flow charge formation process, as well as on reliability and efficiency indicators of the turbine. Experimentally at an 800 MW turbine plant in the USA, it was shown that a change in the pH of the medium affects the intensity and polarity of the charge formation of the steam flow. The paper introduces the physical features of this phenomenon and notes the importance of these processes influence on the strength characteristics of the blades. Information on new methods and technologies that could lead to an increase in the operational efficiency and reliability of wet steam turbines, such as methods for input and removal of electrical energy into the flow; rational choice of water chemistry regimes; space charge neutralization, etc., is provided. These comprehensive electrophysical studies, considered in conjunction with thermal processes, can be characterized as a new scientific direction in the theory of steam turbines – thermal electrophysics.
本文对汽轮机湿蒸汽流的电气化问题进行了全面的研究。介绍和概括了乌克兰和美国在实验室展台和全尺寸物体(CHP和TPP)上进行研究的经验。结果表明,在蒸汽带电过程中,流动中的电荷密度可以达到非常高的值(比雷云中的电荷密度高一个数量级),这一现象主要对汽轮机的运行产生负面影响。给出了汽轮机低压缸内蒸汽流充注形成的统计数据。给出了影响叶片表面强度的主要电物理因素,如电场、电荷密度及其极性的研究结果。研究结果表明,热电联产和TPPs运行时最常记录的带正电的蒸汽流、恒定电场和变电场等因素,会显著(两倍或两倍以上)加剧叶片金属表面的侵蚀腐蚀过程,从而减少叶片的工作资源。热力学过程研究了两种情况,一种是在高速流动的自然带电条件下,这将使效率降低约0.3-0.35%;另一种是在人工产生电荷的影响下,这可能使涡轮中的蒸汽膨胀过程的效率提高2%或更多。考虑了汽轮机蒸汽电离电能局部输入的各种选择。同时指出,为了切实实施这些办法,需要进一步仔细改进设计,并对模型和全尺寸装置进行试验。还考虑了水化学机制对流动电荷形成过程的影响,以及对涡轮机可靠性和效率指标的影响。在美国一座800mw汽轮机厂进行的实验表明,介质pH值的变化会影响蒸汽流电荷形成的强度和极性。本文介绍了这种现象的物理特征,并指出了这些过程对叶片强度特性影响的重要性。有关可提高湿蒸汽轮机运行效率和可靠性的新方法和新技术的信息,例如将电能输入和排出流的方法;水化学机制的合理选择提供空间电荷中和等。这些综合电物理研究,结合热过程考虑,可以被描述为汽轮机理论的一个新的科学方向-热电物理。
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引用次数: 0
Bending and Buckling Analysis of Functionally Graded Plates using a New Shear Strain Function with Reduced Unknowns 基于减少未知量的新剪切应变函数的功能梯度板弯曲屈曲分析
Q4 Engineering Pub Date : 2023-09-15 DOI: 10.24191/jmeche.v20i3.23903
Ali Meftah Meftah
In this article, functionally graded plates’ buckling and bending analyses are investigated using a new shape function. The parabolic transverse shear stresses throughout the thickness are regarded by this function as meeting the shear stress-free surface conditions and enabling an accurate distribution of shear deformation according to the thickness of the plate without integrating shear correction factors. Compared to previous shear theories, this higher-order shear theory has the fewest unknowns. The equations for the functionally graded plates are produced by employing the Hamiltonian principle, and the solutions are obtained using Napier’s technique. The outcomes of the current analysis are provided and contrasted with those found in the literature.
本文用一种新的形状函数研究了功能梯度板的屈曲和弯曲分析。该函数认为沿厚度分布的抛物线形横向剪应力满足无剪应力表面条件,在不积分剪切修正系数的情况下,可以根据板的厚度精确分布剪切变形。与以往的剪切理论相比,这种高阶剪切理论的未知数最少。利用哈密顿原理建立了功能梯度板的方程,并利用纳皮尔法求出了方程的解。提供了当前分析的结果,并与文献中的结果进行了对比。
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引用次数: 0
Reducing The Risk of Agglomeration and Shrinkage Ceramic Body from Al2O3-ZrO2 Composition 降低Al2O3-ZrO2组分陶瓷体团聚和收缩的风险
Q4 Engineering Pub Date : 2023-09-15 DOI: 10.24191/jmeche.v20i3.23909
Norfauzi Tamin
This study introduces the effect of ceramic composition that consists of Alumina (Al2O3)-Zirconia (ZrO2)-Chromia (Cr2O3) compositions on agglomerate and shrinkage for cutting tool development. Shrinkage is a problem in the development of ceramic cutting tools other than the occurrence of particle agglomerate on the body structure. Finer grain size significantly contributes to the ceramic body's shrinkage and agglomeration. This study analyzed grain size and its relationship with shrinkage and agglomerates. The powders were ball-milled with 80 wt% Al2O3 -20 wt% ZrO2 -0.6 wt% Cr2O3 and then compacted and sintered at 1400 °C to examine their shrinkage and investigate microstructure by scanning electron microscopy (SEM) machine. The results show that ZrO2 has a larger particle size of 6.10 μm and Cr2O3 has a finer measure of 1.24 μm. When blended with the ball mill, the mix of Al2O3- ZrO2-Cr2O3 was obtained is 7.30 μm, showing that the ball mill can uniformly mix all the particles and reduce the risk of agglomeration. The microstructural analysis found that Cr2O3 covers and fills up the space between Al2O3 and ZrO2 compared to without Cr2O3. The combination of agglomerate and shrinkage of Al2O3-ZrO2-Cr2O3 was responsible for the performance of the ceramic cutting tool fabricated.
本研究介绍了由氧化铝(Al2O3)-氧化锆(ZrO2)-铬酸盐(Cr2O3)组成的陶瓷成分对刀具开发中的团聚和收缩的影响。收缩是陶瓷刀具发展中的一个问题,而不是在刀具本体结构上出现颗粒结块。较细的晶粒尺寸对陶瓷体的收缩和团聚有显著影响。本文分析了晶粒尺寸及其与收缩和团聚的关系。采用80 wt% Al2O3 -20 wt% ZrO2 -0.6 wt% Cr2O3对粉末进行球磨,然后在1400℃下进行压紧烧结,通过扫描电镜(SEM)观察其收缩率和微观结构。结果表明:ZrO2晶粒尺寸较大,为6.10 μm; Cr2O3晶粒尺寸较小,为1.24 μm;当与球磨机混合时,得到的Al2O3- ZrO2-Cr2O3的混合物为7.30 μm,表明球磨机可以均匀混合所有颗粒,降低团聚的风险。显微组织分析发现,与不含Cr2O3相比,Cr2O3覆盖并填充了Al2O3和ZrO2之间的空间。Al2O3-ZrO2-Cr2O3的团聚和收缩的结合是陶瓷刀具性能的主要原因。
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引用次数: 0
Synthesisation of Zinc Oxide Nanowires via Hybrid Microwave-Assisted Sonochemical Technique at Various Microwave Power 微波辅助声化学合成氧化锌纳米线的研究
Q4 Engineering Pub Date : 2023-09-15 DOI: 10.24191/jmeche.v20i3.23913
Mohd Firdaus Malek
Zinc oxide nanowires (ZnO NWs) have been successfully synthesized via a hybrid microwave-assisted sonochemical technique (HMAST) using zinc acetate dehydrate as starting material. The optimized parameters were set at 12.5 mM solution concentration and a rapid deposition time of 60 minutes. The microwave power was varied from 100 to 800 Watts and the effect of microwave power on the morphological, structural, and optical properties ofthe ZnO NWs has also been studied. Results showed an aligned, uniformly distributed hexagonal wurtzite structure of ZnO NWs was produced, which were augmented at 600 W microwave power, having the smallest diameter size of 29.66 nm. The XRD graph showed that the ZnO NWs produced are highly crystalline, exhibiting the sharpest and narrowest intensity of (002) peaks and a crystallite size of 18.60 nm. The transmittance spectra obtained by UV-Vis would be 89.72%, having a sharp absorption edge, implying the lower particle size of ZnO as well as exhibiting high absorbance in the ultraviolet region, indicating good crystallinity. From the findings, it can be confirmed that the microwave-assisted method helped in improving the formation of higher quality ZnO NWs that can be befittingly applied in many devices such as photocatalysts and sensors due to their excellent electrochemical properties.
以醋酸锌脱水为原料,采用微波辅助声化学技术合成氧化锌纳米线(ZnO NWs)。优化后的工艺参数为溶液浓度12.5 mM,快速沉积时间60分钟。在100 ~ 800瓦的微波功率范围内,研究了微波功率对ZnO NWs形貌、结构和光学性能的影响。结果表明:在600 W微波功率下,ZnO纳米粒子得到了排列均匀的六方纤锌矿结构,其最小直径为29.66 nm;XRD谱图表明,制备的ZnO NWs具有较高的结晶性,表现出(002)峰最锐和最窄的强度,晶粒尺寸为18.60 nm。紫外可见透射光谱为89.72%,吸收边缘较陡,说明ZnO粒径较小,紫外区吸光度较高,结晶度较好。从研究结果可以证实,微波辅助方法有助于改善高质量ZnO NWs的形成,由于其优异的电化学性能,可以合适地应用于光催化剂和传感器等许多器件。
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引用次数: 0
The Characterization of the Sandwich Composite Consisted of Coconut Fibre-Polyester Resin and its Variations of Wood Core 椰子纤维-聚酯树脂夹心复合材料的表征及其木芯的变化
Q4 Engineering Pub Date : 2023-09-15 DOI: 10.24191/jmeche.v20i3.23912
The traditional fishing vessels in Indonesia are usually made of wood material. The weakness of this vessel material is that it is easily weathered when exposed to seawater. For this reason, it is necessary to have vessel material engineering from composite sandwiches. This study aimed to prepare and investigate the flexural test, impact test, optical microscopy (OM), and scanning electron microscopy (SEM) observations of sandwich composites based on coconut fibre-polyester resin and wood core. The fabrication uses a hand lay-up method with a constant volume fraction (20% coconut coir fibre) and wood core variations type. The primary wood variations used are albizia chinensis, mahogany, shorea, and camphor. The Surface modification of fibre and wood core was conditioned without treatment and with treatment with about 5% NaOH solution for 2 hours. The study showed that the highest bending and impact strength was sandwich composite with camphor wood cores with alkali treatment for 39.75 MPa and 37.22 J/cm2, respectively. The OM observations showed that the core and skin interface area failed to delaminate after flexural and impact tests. SEM observations also showed thatthe bond alkalization treatment between the matrix and the fibres was quite good. In the composite skin fracture area, there is a lot of fibre brake, and a little thread pulls out. The skin matrix also shows the presence of voids. Generally, this sandwich composite is feasible for application as a material for traditional fishing vessels.
印度尼西亚的传统渔船通常由木质材料制成。这种容器材料的缺点是暴露在海水中很容易风化。因此,有必要从复合材料夹层中进行容器材料工程。本研究旨在制备和研究椰子纤维-聚酯树脂-木芯夹层复合材料的弯曲试验、冲击试验、光学显微镜(OM)和扫描电镜(SEM)观察结果。制造使用恒定体积分数(20%椰子纤维)和木芯变化类型的手工铺层方法。使用的主要木材变体是合欢、红木、杉木和樟木。纤维和木芯的表面改性分为不处理和5% NaOH溶液处理2小时。研究表明,碱处理樟木芯夹层复合材料的抗弯强度和冲击强度最高,分别为39.75 MPa和37.22 J/cm2。OM观察表明,在弯曲和冲击试验后,核心和皮肤界面区域未能分层。SEM观察还表明,基体与纤维之间的键合碱化处理效果良好。在复合蒙皮断裂区,有大量的纤维制动,有少量的螺纹拔出。皮肤基质也显示空洞的存在。总的来说,这种夹层复合材料作为传统渔船的材料是可行的。
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Journal of Mechanical Engineering
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