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Challenges in surface-enhanced Raman scattering detection of pesticide carbendazim and ways to overcome 多菌灵表面增强拉曼散射检测面临的挑战及克服方法
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-10-01 DOI: 10.1117/1.JNP.16.046002
O. Kulakovich, A. Matsukovich, L. Trotsiuk
Abstract. Considerable details in the sampling procedure for the detection of the pesticide carbendazim by surface-enhanced Raman scattering (SERS) were developed. Experimental parameters and recommendations were selected to minimize side processes of carbendazim photodestruction as well as to reduce the background signal from the silver substrate. It was found from the comparison of experimental and density functional theory calculations data that the position of the SERS bands in the carbendazim spectrum depends on the nature of the applied solvent due to different orientations of carbendazim with respect to the surface of silver nanoparticle film. Adsorption from a chloroform solution is preferable to form an aqueous solution for SERS because random adsorption of molecules on a silver surface provides robust carbendazim identification, displaying a larger number of bands in the SERS spectrum, a higher “signal-to-noise” ratio, and then the processes of carbendazim photodestruction slow down.
摘要详细介绍了表面增强拉曼散射(SERS)检测农药多菌灵的采样程序。选择了实验参数和建议,以最大限度地减少多菌灵光破坏的副作用,并减少来自银衬底的背景信号。通过实验和密度泛函理论计算数据的比较发现,由于多菌灵相对于银纳米颗粒膜表面的不同取向,SERS谱带在多菌灵光谱中的位置取决于所施加溶剂的性质。从氯仿溶液中吸附优选形成SERS的水溶液,因为分子在银表面上的随机吸附提供了强大的多菌灵鉴定,在SERS光谱中显示出更多的谱带,更高的“信噪比”,然后多菌灵的光破坏过程减慢。
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引用次数: 2
Mimicking the structure of Morpho butterfly wing surface: a highly reflective nanostructure assembled by nanospheres 模拟大闪蝶翅膀表面结构:由纳米球组装的高反射纳米结构
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-10-01 DOI: 10.1117/1.JNP.16.046005
Yaohui Wang, Linfeng Jiang, XiaoHong Li
Abstract. Inspired by the surface structure of Morpho butterfly wings, we theoretically propose a biomimetic nanosphere structure with high optical reflectivity. By adjusting the geometric parameters and material parameters of the nanostructure, we obtain reflectivity >99  %   in a certain band; the high-reflection bandwidth depends on the period width, filling factor, and number of nanospheres. Its high-reflectivity bandwidth is less dependent on the incidental light angle compared with general single-layer or multilayer coatings for reflection enhancement. Unlike the biomimetic structures that are completely the same as the Morpho butterfly surface, this simplified structure can be assembled in ways other than photolithography and electron-beam lithography. We also analyzed several deviations of the structure, and the results show that our design allowed these deviations, which is helpful to achieving the effect of the structure in the preparation process. At the same time, the equivalent medium theory was used to analyze the nanostructure. The nanosphere structure has excellent potential applications in optical devices that require high reflectivity, such as laser resonant cavity and optical filters.
摘要受形态蝶翅膀表面结构的启发,我们从理论上提出了一种具有高光学反射率的仿生纳米球结构。通过调整纳米结构的几何参数和材料参数,我们获得了>99的反射率  %   在某个波段;高反射带宽取决于周期宽度、填充因子和纳米球的数量。与用于增强反射的一般单层或多层涂层相比,其高反射率带宽较少依赖于偶然光角度。与与Morpho蝴蝶表面完全相同的仿生结构不同,这种简化的结构可以通过光刻和电子束光刻以外的方式组装。我们还分析了结构的几个偏差,结果表明我们的设计允许这些偏差,这有助于在制备过程中实现结构的效果。同时,利用等效介质理论对纳米结构进行了分析。纳米球结构在需要高反射率的光学器件中具有极好的潜在应用,如激光谐振腔和光学滤波器。
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引用次数: 0
Synthesis and characteristics of BaYF5:Yb3+, Er3+@BaYF5 nanoparticles as a new near-infrared fluorescence bioimaging probe 新型近红外荧光生物成像探针BaYF5:Yb3+,Er3+@BaYF5纳米粒子的合成与表征
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-10-01 DOI: 10.1117/1.JNP.16.046009
Liqing Yang, X. Yang, F. Gao, Q. Fan
Abstract. Fluorescent bioimaging technology has been widely used in clinic because of its high sensitivity, quick feedback, and no radiation. Among them, NIR-II imaging has lower absorption, tissue scattering, self-fluorescence, and higher signal-to-noise ratio. As a precursor of nanoprobe, BaYF5 is an excellent material due to its low phonon energy, which makes it easy to achieve rare earth ion energy level transition and obtain strong upconversion luminescence. A near-infrared II (NIR-II) rare earth fluoride nanoparticle (NP) BaYF5  :  Yb3  +  , Er3  +    @  BaYF5 has been constructed. The luminescence principle of the material was deeply analyzed, and the influence of different doping ion ratio on fluorescence intensity was explored. Finally, the optimal doping ratio for this matrix material was obtained. In addition, according to the surface properties of the materials, the water solubility and biocompatibility of the NPs were significantly improved by the modification. Our work also systematically tested and analyzed the cytotoxicity, hematotoxicity, and tissue toxicity of the NPs and finally realized the high-resolution fluorescence imaging in living mice. This NP can be used as an effective and safe NIR-II contrastive agent, which provides the possibility for the detection and monitoring of physiological activity under deep tissue in vivo.
摘要荧光生物成像技术具有灵敏度高、反馈快、无辐射等优点,在临床上得到了广泛的应用。其中,NIR-II成像具有较低的吸收、组织散射、自荧光和较高的信噪比。作为纳米探针的前驱体,BaYF5是一种优异的材料,因为它具有较低的声子能量,可以很容易地实现稀土离子的能级跃迁并获得强的上转换发光。近红外II(NIR-II)稀土氟化物纳米粒子(NP)BaYF5  :  Yb3  +  , Er3  +    @  BaYF5已经建成。深入分析了该材料的发光原理,探讨了不同掺杂离子比对荧光强度的影响。最后,得到了该基体材料的最佳掺杂率。此外,根据材料的表面性质,改性显著提高了纳米颗粒的水溶性和生物相容性。我们的工作还系统地测试和分析了NPs的细胞毒性、血液毒性和组织毒性,最终实现了活体小鼠的高分辨率荧光成像。该NP可作为一种有效、安全的NIR-II对比剂,为体内深层组织下生理活性的检测和监测提供了可能。
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引用次数: 0
Enhancing light emission near low-refractive-index contrast nanostructures via mirror-symmetry breaking 通过镜面对称破缺增强低折射率对比纳米结构附近的光发射
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-10-01 DOI: 10.1117/1.JNP.16.046001
Hardik Vyas, Ajay Kumar, R. Hegde
Abstract. A platform of recent interest and large application potential is one in which the light emitters are directly integrated with an optical metasurface. Plasmonic metals and high-refractive-index, dielectric Mie metasurfaces have been explored in this connection but have their challenges. We propose low-refractive-index, contrast nanostructured thin films for studying metasurface-emitter systems, specifically focusing on two configurations of practical importance: LED white light generation using color converting polymers and fluorescence-based sensing in aqueous media. To achieve light emission enhancement in a low-index contrast, low optical absorption setting, we exploit the excitation of quasi-bound states in the continuum modes in a mirror-symmetry broken grating. Our numerical study predicts widely tuneable sharp-linewidth emission enhancements, near-zero quenching, and large and controllable active volume in the grating vicinity, which are significant improvements in comparison with both plasmonic and high-index contrast, all-dielectric platforms. When compared with simple gratings, mirror-symmetry broken gratings give four times larger radiative enhancement. Our results are of interest in furthering experimental activity and realizing applications such as light converter for efficient white LEDs and smart detection electronics-integrated substrates for sensing.
摘要最近感兴趣且具有巨大应用潜力的平台是将发光体与光学超表面直接集成的平台。等离子体金属和高折射率电介质Mie超表面已经在这方面进行了探索,但也存在挑战。我们提出了用于研究超表面发射器系统的低折射率、对比度纳米结构薄膜,特别关注两种具有实际重要性的配置:使用颜色转换聚合物产生LED白光和在水介质中基于荧光的传感。为了在低折射率对比度、低光吸收设置下实现发光增强,我们利用镜像对称破碎光栅中连续模中准束缚态的激发。我们的数值研究预测了可广泛调谐的尖锐线宽发射增强、近零猝灭以及光栅附近的大而可控的活性体积,与等离子体激元和高折射率对比度全介质平台相比,这些都是显著的改进。与简单光栅相比,镜像对称破碎光栅的辐射增强是普通光栅的四倍。我们的研究结果有助于进一步开展实验活动,并实现高效白光LED的光转换器和用于传感的智能检测电子集成基板等应用。
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引用次数: 0
Analysis of interface mode localization in disordered photonic crystal structure 无序光子晶体结构中界面模式局域化分析
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-10-01 DOI: 10.1117/1.JNP.16.046007
Amit kumar Goyal, M. Husain, Y. Massoud
Abstract. A disordered photonic crystal (D-PhC) structure is analyzed to study the interface mode localization characteristics. The design comprises a bilayer-disordered PhC structure, where layers are arranged in Thue–Morse sequence (TMS). The impact of local symmetric substructures on eigenstates coupling is also considered over a wider wavelength range. The mode hybridization study is carried out for varying refractive index contrast values of TMS structures at an operating wavelength of 550, 632.8, and 750 nm, respectively. The dispersion analysis confirms the localization of bulk guided, and edge-guided modes for different incidence angles at the structural local resonators. Further, increasing the RI contrast value leads to generation of hybrid interface modes of very high electric field intensity. Thus, showing its potential applications in both sensing and light guiding applications. Moreover, because of the higher surface electric field intensity this structure can also be used for fluorescence-based detection and surface-enhanced Raman spectroscopy as well.
摘要对一种无序光子晶体(D-PhC)结构进行了分析,研究了界面模式的局域化特性。该设计包括双层无序PhC结构,其中层以Thue–Morse序列(TMS)排列。在更宽的波长范围内,还考虑了局部对称子结构对本征态耦合的影响。分别在550632.8和750nm的工作波长下,对TMS结构的不同折射率对比度值进行模式杂交研究。色散分析证实了结构局部谐振器处不同入射角的体导和边缘导模的局部化。此外,增加RI对比度值导致产生非常高电场强度的混合界面模式。因此,显示了其在传感和光导应用中的潜在应用。此外,由于较高的表面电场强度,该结构也可用于基于荧光的检测和表面增强拉曼光谱。
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引用次数: 6
Analysis of thermal performance and charge balance in all-inorganic quantum dot light-emitting devices 全无机量子点发光器件的热性能及电荷平衡分析
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-10-01 DOI: 10.1117/1.JNP.16.046008
S. Rani, J. Kumar
Abstract. The quantum dot light-emitting devices (QLEDs) have emerged as a promising candidate for electroluminescent devices due to their excellent optical properties, high efficiency, and tunable bandgaps. The QLEDs with increased and prolonged brightness have potential applications in lighting and display devices. However, the stability of these devices is still a matter of concern, and some factors that affect the luminescence from the device involve electric field and temperature-dependent conduction mechanism. Thermal degradation, quenching within the quantum dots, the design of charge transport layers and the charge balance between them are also some factors that affect the efficacy of these devices. The high working temperature of QLEDs is among the most challenging degradation mechanisms, thus an analysis has been carried out regarding the working temperature within the QLEDs, and the methods to minimize these effects have been studied. Another challenge is achieving charge balance within the device and different device structures have been analyzed to achieve the best results regarding charge balance within the device. A few potential strategies have been suggested to reduce the constraints faced in these electroluminescent devices.
摘要量子点发光器件(qled)由于其优异的光学性能、高效率和可调谐的带隙而成为电致发光器件的一个有前途的候选器件。具有提高和延长亮度的qled在照明和显示设备中具有潜在的应用前景。然而,这些器件的稳定性仍然是一个值得关注的问题,影响器件发光的一些因素涉及电场和温度依赖的传导机制。热降解、量子点内部的猝灭、电荷传输层的设计以及电荷之间的平衡也是影响器件效率的因素。高工作温度是qled最具挑战性的降解机制之一,因此对qled内部的工作温度进行了分析,并研究了最小化这些影响的方法。另一个挑战是实现器件内的电荷平衡,已经分析了不同的器件结构,以实现器件内电荷平衡的最佳结果。已经提出了一些潜在的策略来减少这些电致发光器件所面临的限制。
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引用次数: 0
Lattice-plasmon effect on entanglement behavior in a plasmonic system 等离子体系统中晶格-等离子体效应对纠缠行为的影响
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-10-01 DOI: 10.1117/1.JNP.16.046006
A. Salmanogli
Abstract. In this study, we designed a plasmonic system containing an array of nanoparticles (NPs) coupled to a quantum dot (QD) to generate entangled photons. The interaction of incoming light with the array of NPs generates a modified plasmon resonance, so-called lattice-plasmon (interaction of the NPs near-field with the photonic mode). Due to its unique optical properties, the lattice-plasmon strongly manipulates the output modes’ entanglement behavior. This is mainly because of the influence of the lattice-plasmon on the transition and dephasing rates of the quantum dot. It is shown that it can be possible to manipulate the QD decay rates via the optical properties of the lattice-plasmon. Also, to manage the output modes entanglement, the emphasis is put on the retarded field effect, which dramatically impacts the lattice-plasmon optical properties. It is theoretically found that engineering the optical properties of the lattice-plasmon facilitates the manipulation of the entanglement behavior.
摘要在这项研究中,我们设计了一个等离子体系统,该系统包含一组纳米粒子(NPs)与量子点(QD)耦合,以产生纠缠光子。入射光与NPs阵列的相互作用产生了一种修正的等离子体共振,即所谓的晶格等离子体共振(NPs近场与光子模式的相互作用)。由于其独特的光学性质,晶格等离子体对输出模式的纠缠行为有很强的操纵作用。这主要是由于晶格等离子体对量子点的跃迁速率和消相速率的影响。结果表明,可以通过晶格等离子体的光学特性来控制量子点衰减速率。此外,为了控制输出模式的纠缠,重点研究了延迟场效应,延迟场效应对晶格等离子体光学特性的影响。理论上发现,对晶格等离子体的光学特性进行工程处理有助于对纠缠行为的操纵。
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引用次数: 0
Bismuth-based broadband metamaterial absorber 铋基宽带超材料吸收体
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-07-01 DOI: 10.1117/1.JNP.16.036004
Fan Wang, H. Fan, Xianghua Zeng
Abstract. A numerical simulation of a metamaterial broadband absorber is performed using the finite-difference time-domain method. The absorber adopts a four-layer structure with titanium dioxide (TiO2) rectangular pairs, a bismuth (Bi) layer, a silicon dioxide (SiO2) layer, and a titanium nitride (TiN) layer from top to bottom, respectively, and the TiO2 rectangular pairs are periodically and symmetrically arranged in a rectangular array. The optimization results show that the average absorption of the designed absorber is 97.6% in the wavelength range of 500 to 3500 nm and the average absorption can reach 99% in the wavelength range of 811 to 3162 nm (2351 nm). The coupling of local surface plasmon resonance and propagating plasmon resonance and the good absorption and broadband absorption properties exhibited by metallic Bi were further found by analyzing the distribution of electromagnetic fields. The designed absorber has polarization and temperature-insensitive properties and a simple structure and is easily fabricated.
摘要采用时域有限差分法对超材料宽带吸收体进行了数值模拟。吸收剂采用四层结构,由上至下分别为二氧化钛(TiO2)矩形对、铋(Bi)层、二氧化硅(SiO2)层和氮化钛(TiN)层,且TiO2矩形对周期性对称排列成矩形阵列。优化结果表明,所设计吸收剂在500 ~ 3500nm波长范围内的平均吸收率为97.6%,在811 ~ 3162 nm (2351 nm)波长范围内的平均吸收率可达99%。通过对电磁场分布的分析,进一步发现金属铋具有局部表面等离子体共振和传播等离子体共振的耦合特性以及良好的吸收和宽带吸收特性。所设计的吸收体具有极化和温度不敏感的特性,结构简单,易于制作。
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引用次数: 2
Thulium/holmium fiber laser with Ti2AlN MAX phase-coated arc-shaped fiber for mode-locked pulse generation 用于锁模脉冲产生的Ti2AlN MAX相位涂层弧形光纤的铊/钬光纤激光器
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-07-01 DOI: 10.1117/1.JNP.16.036006
H. Ahmad, Neshat Sadafi, N. Yusoff, M. Z. Samion, M. F. Ismail, W. Chong
Abstract. A mode-locked thulium–holmium fiber laser operating in the 2.0-μm wavelength region was demonstrated using a MAX phase titanium aluminum nitride (Ti2AlN)-based saturable absorber (SA). The Ti2AlN was prepared in the solution form and then drop-casted onto a homemade arc-shaped fiber, which served as the SA device. The mode-locked pulses were generated when the pump power was at 119 mW, and the pulses were sustained up to a pump power of 249 mW. The mode-locked fiber laser using the Ti2AlN-based SA operated with a center wavelength of 1900.6 nm, having a repetition rate and a pulse width of 12.14 MHz and 1.61 ps, respectively. At the maximum pump power, the mode-locked pulses had maximum pulse energy of 0.35 nJ and peak power of 216 W. We propose the generation of short pulses using a MAX phase-based SA that could be useful for various applications in the eye-safe region.
摘要使用基于MAX相氮化钛铝(Ti2AlN)的可饱和吸收体(SA),演示了在2.0μm波长范围内工作的锁模铥-钬光纤激光器。以溶液形式制备Ti2AlN,然后将其滴注到自制的弧形纤维上,作为SA装置。当泵浦功率为119mW时,产生锁模脉冲,脉冲持续到249mW的泵浦功率。使用基于Ti2AlN的SA的锁模光纤激光器的中心波长为1900.6nm,重复频率和脉冲宽度分别为12.14MHz和1.61ps。在最大泵浦功率下,锁模脉冲的最大脉冲能量为0.35 nJ,峰值功率为216 W。我们建议使用基于MAX相位的SA来产生短脉冲,这可能对眼睛安全区域的各种应用有用。
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引用次数: 0
Coding photonic paths based on valley-protected topological phonic crystal 基于谷保护拓扑声子晶体的光子路径编码
IF 1.5 4区 物理与天体物理 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-07-01 DOI: 10.1117/1.JNP.16.036009
Yun-tuan Fang, Jia-Chen Liu
Abstract To achieve a flexible and reconfigurable topological edge state waveguide, we construct a valley photonic crystal (VPC) with liquid crystal filled rods. The permittivity of the two inequivalent rods in a unit is determined through the external voltage, which leads to a VPC with different valley topological phases. The external voltage is controlled by the codes of “0” and “1” on a control panel. Through programming the codes, arbitrary paths of topological edge states are achieved. The results were demonstrated by field propagation simulations.
摘要为了实现柔性和可重构的拓扑边缘态波导,我们构造了一种带有液晶填充棒的谷光子晶体(VPC)。一个单元中两个不等棒的介电常数是通过外部电压确定的,这导致了具有不同谷拓扑相位的VPC。外部电压由控制面板上的代码“0”和“1”控制。通过编程实现了拓扑边状态的任意路径。通过场传播模拟验证了结果。
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引用次数: 1
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Journal of Nanophotonics
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