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CHARACTERISATION OF SYNTHESIZED PROTECTED FAT FROM USED COOKING PALM OIL AND PALM OLEIN FOR ANIMAL FEED APPLICATION 用过的烹调棕榈油和动物饲料用棕榈油合成保护脂肪的特性研究
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-08-04 DOI: 10.21894/jopr.2023.0033
M. K
In the present work, a new protected fat was produced from used cooking palm oil (UCO) by using modified fusion method. Used cooking oil protected fat (UCOPF) was compared with produced palm olein protected fat (POPF) and commercial protected fat (CPF). The quality of protected fat produce was investigated using Fourier transform infrared (FTIR) and X-ray diffraction (XRD) studies. FTIR and XRD results confirmed the well-formation of protected fat from UCO and the XRD analysis revealed fatty acid from UCO bind well with calcium ion. FTIR spectroscopy indicated carboxylate bands at 1542 and 1575 cm –1 showed the calcium ions associated with the COO-ions in the monodendate and bidendate structures in PF. Differential scanning calorimetry (DSC) study was conducted to find out the thermal behaviour of the produced UCOPF and the results clearly indicated good thermal stability. DSC indicated onset of melting at 151°C and 148°C for samples prepared UCOPF and POPF, respectively and it was slightly lower than CPF (157°C). Smooth and porous surfaces morphology of UCOPF and POPF was confirmed using scanning electron microscope (SEM) analysis. From the results it was evident that UCO can be utilised to produce protected fat as a safe animal feed.
本文采用改良融合法制备了一种新型的棕榈油保护脂肪。将废旧食用油保护脂肪(UCOPF)与生产的棕榈油保护脂肪(POPF)和商业保护脂肪(CPF)进行了比较。采用傅里叶变换红外(FTIR)和x射线衍射(XRD)研究了保护脂肪产品的质量。FTIR和XRD结果证实UCO保护脂肪形成良好,XRD分析表明UCO脂肪酸与钙离子结合良好。FTIR光谱显示,在1542和1575 cm -1的羧酸带上,钙离子与co -离子在单枝状和双枝状结构中相结合。差示扫描量热法(DSC)研究了所制备的UCOPF的热行为,结果表明其具有良好的热稳定性。DSC显示,制备的UCOPF和POPF分别在151°C和148°C开始熔化,略低于CPF(157°C)。扫描电镜(SEM)分析了UCOPF和POPF表面的光滑和多孔形貌。结果表明,UCO可用于生产受保护的脂肪,作为一种安全的动物饲料。
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引用次数: 0
EFFECT OF GRAPHITE MICROPARTICLES AS ADDITIVE IN AN INDIRECT DIESEL ENGINE FUELLED WITH PURE PALM OIL 石墨微粒作为添加剂在以纯棕榈油为燃料的间接柴油发动机中的作用
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-07-28 DOI: 10.21894/jopr.2023.0030
R. A. Prahmana
Research lately has shown the prospects of graphite as an additive for diesel engines due to its favourable characteristics. Moreover, using pure palm oil (PPaO) as the primary fuel in diesel engines is not recommended because of numerous disadvantages. To overcome such a problem, the effect of graphite oxide (GO) and graphite powder (GP) microparticle as an additive on PPaO was investigated by analysing the diesel engine combustion performance and emissions. GO was prepared using the Hummers method. The use of PPaO as a single fuel led to a significant increase in opacity by up to 127.0% compared to diesel fuel (DF). However, adding GO and GP as fuel additives can significantly reduce opacity by up to 63.9%, improve thermal efficiency by up to 20.4%, and increase specific fuel consumption by up to 40.1% compared to DF. These results indicate that GO and GP have promising potential as effective fuel additives for PPaO, leading to increased combustion efficiency, and reduced hazardous emissions in diesel engine applications.
最近的研究表明,由于其良好的特性,石墨作为柴油发动机添加剂的前景广阔。此外,不建议使用纯棕榈油(PPaO)作为柴油发动机的主要燃料,因为它有许多缺点。为了解决这一问题,通过分析柴油机燃烧性能和排放,研究了氧化石墨(GO)和石墨粉(GP)微粒作为添加剂对PPaO的影响。采用Hummers法制备氧化石墨烯。与柴油(DF)相比,使用PPaO作为单一燃料导致不透明度显著增加高达127.0%。然而,与DF相比,添加GO和GP作为燃料添加剂可以显著降低高达63.9%的不透明度,提高高达20.4%的热效率,并增加高达40.1%的比油耗。这些结果表明,氧化石墨烯和GP作为PPaO的有效燃料添加剂具有很大的潜力,可以提高柴油发动机的燃烧效率,减少有害排放。
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引用次数: 0
POME TREATMENT USING AB-101 MICROBIAL CONSORTIUM: PERFORMANCE AND PROPOSED MECHANISM 用ab-101菌群处理果仁:性能和可能的机制
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-07-28 DOI: 10.21894/jopr.2023.0029
Ummi Kalsum Hasanah MOHD NADZIM
Due to the high organic load content, palm oil mill effluent (POME) has undergone various treatment systems. Most palm oil millers prefer to add a new approach to improve the existing treatment system but the investment and operation costs are too high to be incurred. Therefore, this study emphasizes the AB-101 microbial consortium performance in treating POME under the original operating parameters (0.2% AB-101 volume percentage, 7.5% molasses volume percentage and 100 ppm bio-activator dosage). The percentage reductions of POME characteristics under the original operating factor were 67.6% biochemical oxygen demand (BOD), 59.2% chemical oxygen demand (COD), 82.8% total suspended solids (TSS) and 66.7% oil and degrease (O&G). Meanwhile, POME treated with AB-101 under the optimal operating parameters (0.01% AB-101 volume percentage, 9.85% molasses volume percentage and 43.8 ppm bio-activator dosage) showed better characteristics of 92.9% BOD, 65.3% COD, 93.4% TSS and 95.5% O&G. Based on the proposed mechanism, lignocellulose degradation was greater when AB-101 was added into POME which improved the primary treatment of POME through enhanced anaerobic digestion.
由于有机负荷含量高,棕榈油厂废水(POME)经过了各种处理系统。大多数棕榈油加工厂倾向于增加一种新的方法来改善现有的处理系统,但投资和运营成本太高,无法产生。因此,本研究强调了AB-101微生物群落在原始操作参数(0.2%AB-101体积百分比、7.5%糖蜜体积百分比和100ppm生物活化剂剂量)下处理聚甲醛的性能。在原始操作因子下,POME特性的降低百分比为67.6%的生化需氧量(BOD)、59.2%的化学需氧量(COD)、82.8%的总悬浮固体(TSS)和66.7%的油和脱脂(O&G)。同时,在最佳操作参数(0.01%AB-101体积百分比、9.85%糖蜜体积百分比和43.8ppm生物活化剂剂量)下,AB-101处理POME的BOD、COD、TSS和O&G分别达到92.9%、65.3%、93.4%和95.5%。基于所提出的机理,当AB-101加入到聚甲醛中时,木质纤维素降解更大,这通过增强厌氧消化改善了聚甲醛的初级处理。
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引用次数: 0
OIL PALM ECONOMIC PERFORMANCE IN MALAYSIA AND R&D PROGRESS IN 2022 2022年马来西亚油棕榈经济表现与研发进展
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-06-28 DOI: 10.21894/jopr.2023.0028
G. K. AHMAD PARVEEZ
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引用次数: 1
APPLICATION OF Euglena sp. ISOLATED FROM YOGYAKARTA, INDONESIA ON NUTRIENT REMOVAL FROM PALM OIL MILL EFFLUENT (POME) 印尼日惹产Euglena sp.在棕榈油厂废液中去除营养物中的应用
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-06-22 DOI: 10.21894/jopr.2023.0025
Afifah Nur Aini Putri
Palm oil mill effluent (POME) was the main source of liquid waste in Indonesia. It could be utilized as microalgae medium. Euglena sp., fast-growing microalgae, produces high-value product metabolites. In this research, POME is used as a culture medium because of its rich macronutrients and micronutrient content. In addition, POME also contains high Biological Oxygen Demands (BOD) and Chemical Oxygen Demands (COD). This research was conducted to study BOD and COD in POME after and before treatment, growth rate, biomass and content of carbohydrates, lipids and proteins in Euglena sp. that was cultured in a POME medium. Euglena sp. cultured in Cramer-Myers (CM) medium was used as control. POME medium concentrations used in this research were 0.50%, 0.75%, 1.00% and 1.25%. The results showed that Euglena sp. was able to reduce BOD and COD. Medium 1.25% POME was the best treatment for nutrient removal, growth, and nutritional value. Based on the Logistic modelling, the highest specific growth rate (μ) was achieved in 1.25% POME with μ 0.6894 day and R2 0.99.
棕榈油厂废水(POME)是印度尼西亚液体废物的主要来源。可作为微藻培养基。Euglena sp.,一种快速生长的微藻,产生高价值的产品代谢物。在本研究中,因其丰富的宏量营养素和微量营养素含量而被用作培养基。此外,POME还具有较高的生物需氧量(BOD)和化学需氧量(COD)。本研究研究了在POME培养基中培养的Euglena sp.处理前后POME中的BOD和COD、生长速率、生物量以及碳水化合物、脂质和蛋白质含量。以CM培养基培养的Euglena sp.为对照。本研究采用的POME培养基浓度分别为0.50%、0.75%、1.00%和1.25%。结果表明,绿藻具有降低BOD和COD的作用。培养基中1.25%的POME处理在去除营养物、生长和营养价值方面效果最好。Logistic模型表明,在1.25%的POME条件下,比生长率(μ)最高,为μ 0.6894 d, R2为0.99。
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引用次数: 0
KINETIC STUDY OF SELF-ESTERIFIED PALMBASED C12 FATTY ACID AND DIETHYLENE GLYCOL USING CONVENTIONAL AND MICROWAVE HEATING 棕榈基c12脂肪酸与二甘醇自酯化的常规和微波加热动力学研究
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-06-22 DOI: 10.21894/jopr.2023.0026
N. A. Abas
Diethylene glycol dilaurate (DEG-DL), which is derived from palm oil, may be produced using either esterification or a transesterification technique. Moreover, either a catalytic or non-catalytic reaction can help the process, along with or without the use of a solvent. However, currently the production of DEG-DL is still using the conventional method with a longer time to produce a good quality ester. In this work, the DEG-DL production was done using a solvent-free microwave heating method in the absence of a catalyst. The solvent-free microwave heating method exhibited itself as an effective method to produce DEG-DL with a shorter reaction time from 22 hr to 2 hr compared to conventional heating. The DEG-DL produced has been characterised using FTIR and 1H-NMR as well as its acid value to observe the trend. The effects of kinetic and thermodynamic parameters of the ester were investigated and compared between both heating methods. Based on the result obtained, the kinetic reaction fitted the pseudo-first-order well with 24% decreased in the activation energy and the pre-exponential factor increased by 93% when comparing conventional and microwave heating methods. The DEG-DL produced is a potential ingredient to be used as coalescent aid in latex paint formulations.
二月桂酸二甘醇(DEG-DL)来源于棕榈油,可以使用酯化或酯交换技术生产。此外,催化反应或非催化反应都有助于该过程,无论是否使用溶剂。然而,目前DEG-DL的生产仍然使用传统的方法,需要更长的时间才能生产出高质量的酯。在这项工作中,DEG-DL的生产是在没有催化剂的情况下使用无溶剂微波加热方法进行的。与传统加热相比,无溶剂微波加热方法是一种生产DEG-DL的有效方法,反应时间从22小时缩短到2小时。使用FTIR和1H-NMR对产生的DEG-DL及其酸值进行了表征,以观察其趋势。研究了两种加热方法对酯的动力学和热力学参数的影响,并进行了比较。根据所得结果,与传统加热方法和微波加热方法相比,动力学反应符合拟一级反应,活化能降低了24%,指数前因子增加了93%。生产的DEG-DL是一种潜在的成分,可用于乳胶漆配方中的聚结助剂。
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引用次数: 0
PERFORMANCE OF SELFED AND INTERCROSSED OIL PALM DELI ULU REMIS PROGENIES BASED ON SELECTED AGRONOMIC TRAITS 基于农艺性状选择的油棕自交和杂交后代的表现
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-06-22 DOI: 10.21894/jopr.2023.0023
N. A.
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引用次数: 0
NUTRITIONAL COMPOSITION OF ANTHESISING MALE INFLORESCENCE OF OIL PALM Elaeis guineensis ESSENTIAL FOR DEVELOPMENT OF Elaeidobius kamerunicus Faust: FIRST REPORT 油棕棕雄性合成花序的营养成分对kamerunicus Faust发育至关重要
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-06-22 DOI: 10.21894/jopr.2023.0027
Muhamad Haziq Hadif Zulkefli
Rearing of Elaeidobius kamerunicus, the pollinator of oil palm, requires the anthesising male inflorescence of oil palm as the breeding and feeding ground. Various studies have reported on the weevils utilising the male inflorescence as feed to sustain its development. However, for routine rearing, the use of male inflorescence is inconvenient as it has to be continuously collected from the field. Thus, this pioneering study was conducted to determine the nutritional composition of anthesising male inflorescence of oil palm (Elaeis guineensis Jacq.) which is essential for E. kamerunicus life development. First, proximate analysis was performed to determine the nutritional composition of anthesising male inflorescence. Next, the nutritional profiles of amino acids, fatty acids and carbohydrates were determined and analysed separately. The average proximate analysis of anthesising male inflorescence of oil palm recorded a high moisture content of 75%, followed by carbohydrate, protein, fat and ash. The amino acid profile revealed the presence of 18 amino acids with lysine having the highest content. The spikelet also recorded a total of 32 fatty acids with oleic acid recording the highest value. Nevertheless, the carbohydrate profile was not determined as its presence was in trace amount only. This study provided new knowledge and reference standard on the nutritional composition of anthesising male inflorescence of oil palm that is essential for
油棕传粉昆虫油棕的培育需要油棕开花的雄性花序作为繁殖和觅食地。各种研究报告了象鼻虫利用雄性花序作为饲料来维持其发育。然而,对于常规饲养,雄性花序的使用是不方便的,因为它必须从田地里连续收集。因此,本项开创性研究旨在确定油棕(Elaeis guineensis Jacq.)开花雄性花序的营养成分,这对油棕的生命发育至关重要。首先,对开花雄性花序的营养成分进行了近似分析。接下来,分别测定和分析了氨基酸、脂肪酸和碳水化合物的营养成分。油棕开花雄性花序的平均接近分析表明,水分含量高达75%,其次是碳水化合物、蛋白质、脂肪和灰分。氨基酸图谱显示存在18个氨基酸,赖氨酸含量最高。小穗还记录了总共32种脂肪酸,其中油酸记录的值最高。然而,由于碳水化合物仅以微量存在,因此并未确定碳水化合物的分布。本研究为油棕榈开花雄性花序的营养成分提供了新的认识和参考标准
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引用次数: 0
NANOCELLULOSE SYNTHESIS BY ONE POT METHOD WITH Fe CATALYST AND GELATINE CAPPING AGENT 用铁催化剂和明胶封盖剂一锅法合成纳米纤维素
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-06-22 DOI: 10.21894/jopr.2023.0024
L. Elizabeth
Nanocellulose has recently drawn attention because of its outstanding physical and mechanical properties. Even though nanocellulose is already a ubiquitous material in research, its synthesis and agglomeration still hinder the process of commercialisation. A shorter process will provide savings for larger scale production, and adding a capping agent can facilitate storage and handling on a commercial scale. In this study, the synthesis of nanocellulose was carried out using a one-pot method where the delignification and hydrolysis of cellulose were carried out in the same reactor. Delignification and bleaching used 30% (v/v) H2O2 at 90oC for 5 hr. Meanwhile, hydrolysis using 8% (w/w) H2SO4 and 3% (w/w) of Fe(NO3)3.9H2O 0.22 M as a catalyst, held for 1 hr at 75oC, resulted in the lowest lignin composition 49.7% (w/w). Several analyses were carried out for the nanocellulose. TEM analysis showed the nanocellulose size from 5 to 70 nm. FTIR analysis showed that the nanocellulose was alike cellulose commercial. XRD analysis showed the crystallinity of nanocellulose is still relatively low (35.7%). The addition of a capping agent to nanocellulose showed a reduction of agglomeration for the ratio of nanocellulose to gelatin 1.00:0.75.
纳米纤维素由于其优异的物理力学性能,近年来引起了人们的关注。尽管纳米纤维素已经是研究中普遍存在的材料,但其合成和团聚仍然阻碍了商业化进程。更短的工艺将为大规模生产节省成本,添加封端剂可以促进商业规模的储存和处理。在本研究中,使用一锅法合成纳米纤维素,其中纤维素的脱木素和水解在同一反应器中进行。脱木素和漂白使用30%(v/v)H2O2在90℃下保持5小时。同时,使用8%(w/w)H2SO4和3%(w/w)Fe(NO3)3.9H2O 0.22 M作为催化剂在75℃下保持1小时的水解产生最低的木质素组成49.7%(w/w)。对纳米纤维素进行了几次分析。TEM分析显示纳米纤维素的尺寸为5至70nm。FTIR分析表明,纳米纤维素与商品纤维素相似。XRD分析表明,纳米纤维素的结晶度仍然相对较低(35.7%)。当纳米纤维素与明胶的比例为1.00:0.75时,向纳米纤维素中添加封端剂可以减少团聚。
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引用次数: 0
CONSOLIDATION OF DEEP EUTECTIC SOLVENTS WITH MICROWAVE FOR THE EXTRACTION OF FERULIC ACID FROM THE FRUITLETS OF OIL PALM 微波固化深共晶溶剂提取油棕果实中阿魏酸的研究
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-05-19 DOI: 10.21894/jopr.2023.0022
NG MEI HAN
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引用次数: 0
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Journal of Oil Palm Research
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