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Polymer dots and derived hybrid nanomaterials: A review 聚合物点及其衍生杂化纳米材料综述
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-04-13 DOI: 10.1177/87560879211010313
Ayesha Kausar
Quantum dots are tiny (∼5 nm) nanoparticles with outstanding electronic, optical, luminescence, and semiconducting properties. Polymer dots are important and unique quantum dots. Polymer dots have been designed and used for advanced hybrid nanomaterials and applications. This review article deliberates scientific trials on design, fabrication, characteristics, and technical solicitations of polymer dot-based nanomaterials. Polymer dots are made from both conducting and non-conducting polymers with appropriate processing techniques. Polymer dots have facile surface modification tendencies. Functional polymer dots have an important use in hybrid/nanocomposite materials. Consequently, polymer dots have been combined with other quantum dots and nanoparticles to form advanced hybrid nanomaterials. Polymer dot-based nanomaterials have unique morphology, conductivity, electrochemical, luminescence, and sensing features. Subsequently, many applications are seen for polymer dot nanomaterials as solar cell, supercapacitor, electronics, probes, gas sensor, biosensor, bioimaging, and drug delivery.
量子点是微小的(~ 5nm)纳米颗粒,具有出色的电子、光学、发光和半导体特性。聚合物点是一种重要而独特的量子点。聚合物点已被设计和用于先进的混合纳米材料和应用。本文综述了聚合物点基纳米材料的设计、制备、特性和技术要求等方面的科学试验。聚合物点由导电和非导电聚合物通过适当的加工技术制成。聚合物点具有易于表面修饰的倾向。功能聚合物点在杂化/纳米复合材料中有着重要的应用。因此,聚合物点已与其他量子点和纳米粒子结合,形成先进的混合纳米材料。聚合物点基纳米材料具有独特的形貌、电导率、电化学、发光和传感特性。随后,聚合物点纳米材料在太阳能电池、超级电容器、电子、探针、气体传感器、生物传感器、生物成像和药物输送等领域的应用也得到了广泛的应用。
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引用次数: 4
Industry News 行业新闻
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-04-01 DOI: 10.1177/87560879211005210
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引用次数: 0
From the Editor 来自编辑
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-04-01 DOI: 10.1177/87560879211005209
J. Wagner
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引用次数: 0
Analysis of the lubrication approximation theory in the calendering/sheeting process of upper convected Jeffery’s material 上对流杰弗瑞材料压延/压片过程中的润滑近似理论分析
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-04-01 DOI: 10.1177/8756087920962545
M. Zahid, Nz Khan, A. Siddiqui, S. Iqbal, A. Muhammad, I. Tlili
This paper analyses an isothermal calendering for an upper convected Jeffery’s Material. Lubrication Approximation Theory (LAT) is applied to simplify the flow equations. Analytical solutions of velocity, flow rate, and pressure gradient are carried out. Outcomes of sheet thickness, detachment point, roll separating force, power input to the roll, and pressure distribution are obtained. The effects of some involved parameters are displayed through graphs and tables. It is noted that the material parameter is a controlling device for sheet thickness, flow rate, detachment point, roll separating force, power input, and the pressure distribution. We observed that as the material parameter increases, the detachment point increases which results in increased sheet thickness.
本文分析了上对流杰弗瑞材料的等温压延工艺。应用润滑近似理论(LAT)对流动方程进行了简化。给出了速度、流量和压力梯度的解析解。得到了薄板厚度、分离点、轧辊分离力、轧辊输入功率和压力分布的结果。通过图形和表格显示了所涉及的一些参数的影响。注意到材料参数是控制薄板厚度、流量、分离点、辊分离力、功率输入和压力分布的装置。我们观察到,随着材料参数的增加,分离点增加,导致板材厚度增加。
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引用次数: 5
Evolving scientific aptitude of poly(ethylene glycol) filled with carbonaceous nanofillers 碳质纳米填料填充聚乙二醇的科学能力演变
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-02-27 DOI: 10.1177/8756087921999094
Ayesha Kausar
There is rising interest in the development of poly(ethylene glycol) based nanocomposites. Poly(ethylene glycol) is a synthetic water soluble polyether polymerized from ethylene glycol monomer. Poly(ethylene glycol) matrix has been reinforced with various carbonaceous nanofillers such as graphene, graphene oxide, carbon nanotube, and nanodiamonds to form nanocomposites. In this state-of-the-art review, poly(ethylene glycol)/carbonaceous nanofiller nanocomposites and progress concerning the derived high performance nanomaterials are presented. The morphology, thermal, mechanical, electrical, and other characteristics are enhanced with the nanocarbon nanofillers. Modifying the poly(ethylene glycol) backbone and functionalizing the carbonaceous nanofiller improve the anticipated nanocomposite. Moreover, better nanoparticle dispersion and interaction with the poly(ethylene glycol) have been focused in this regard. Up till now, poly(ethylene glycol) nanocomposites have been researched for lithium ion battery, sensor, and biomedical applications particularly drug delivery and tissue engineering. Future research on poly(ethylene glycol)/carbonaceous nanofiller nanocomposites may help to overcome the challenges related to nanocomposite design and high performance, and may also open new application areas.
人们对聚乙二醇基纳米复合材料的开发越来越感兴趣。聚乙二醇是由乙二醇单体聚合而成的一种合成水溶性聚醚。在聚乙二醇基体中加入各种碳质纳米填料,如石墨烯、氧化石墨烯、碳纳米管和纳米金刚石,形成纳米复合材料。本文综述了聚乙二醇/碳基纳米填料纳米复合材料及其衍生的高性能纳米材料的研究进展。纳米碳纳米填料增强了材料的形貌、热学、机械、电学和其他特性。改性聚乙二醇骨架和功能化碳基纳米填料改善了预期的纳米复合材料。此外,纳米颗粒更好的分散和与聚乙二醇的相互作用也在这方面得到了关注。到目前为止,聚乙二醇纳米复合材料已被研究用于锂离子电池、传感器和生物医学应用,特别是药物输送和组织工程。未来对聚乙二醇/碳质纳米填料纳米复合材料的研究将有助于克服纳米复合材料设计和高性能方面的挑战,并可能开辟新的应用领域。
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引用次数: 1
Oriented and annealed poly(lactic acid) films and their performance in flexible printed and hybrid electronics 取向和退火聚乳酸薄膜及其在柔性印刷和混合电子中的性能
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-02-01 DOI: 10.1177/8756087920988569
Enni Luoma, M. Välimäki, Teijo Rokkonen, Hannu Sääskilahti, J. Ollila, J. Rekilä, K. Immonen
Flexible and hybrid electronics (FHE) are widely utilized from wearable to automotive applications. Instead of commonly used poly(ethylene terephthalate) (PET) film, bio-based and biodegradable polymer, poly(lactic acid) (PLA), is a most promising novel substrate alternative for FHE. From the point of heat curable conductive inks, the poor heat resistance and inherent brittleness are the major drawbacks of PLA. By increasing the PLA film crystallinity through orientation and annealing, its properties can be improved. Two commercial grades, standard PLA (PLA) and a high heat PLA (hhPLA), plus one stereocomplex PLA (scPLA) blend were used to compare PLA performance with different optical purities and crystallinity for printed FHE. Machine direction orientation (MDO), biaxial orientation (BO) and annealing improved the stability of the laboratory and pilot scale manufactured PLA films. MDO was more effective in improving stiffness and strength while BO resulted in more ductile behaviour. In hhPLA the crystallinity increased from 0% to 50% improving tensile strength by 83%, tensile modulus by 52% and strain at break from 3.7% to 114% with 3 × 3 BO and annealing. The scPLA blend contained homo- and stereocomplex crystallites and a double melting peak behaviour provided higher temperature stability through final melting at 220°C. Its optical transparency reached 95%, remaining high up to 250 nm wavelength. In roll-to-roll printing, the PLA and hhPLA films were dried at 100°C prior the printing and this decreased the MD elongation from 2.55% and 0.27% to 0.00–0.05%. The sheet resistance of printed silver was <40 mΩ/sq with additional drying for printed and hybrid integrated light-emitting diode (LED) foils. Printed LED foils on PLA had dimensional and electrical performance comparable to PET, even though lower drying temperatures were used.
柔性和混合电子(FHE)广泛应用于从可穿戴设备到汽车应用。生物基和可生物降解聚合物聚乳酸(PLA)取代了常用的聚对苯二甲酸乙酯(PET)薄膜,是一种最有前途的新型FHE衬底替代品。从热固化导电油墨的角度来看,PLA的主要缺点是耐热性差和固有的脆性。通过取向和退火来提高聚乳酸薄膜的结晶度,可以改善其性能。使用两种商业等级,标准PLA (PLA)和高热PLA (hhPLA),以及一种立体配合物PLA (scPLA)共混物来比较PLA在印刷FHE中具有不同光学纯度和结晶度的性能。机器定向(MDO)、双轴定向(BO)和退火提高了实验室和中试规模制造的PLA薄膜的稳定性。MDO在提高刚度和强度方面更有效,而BO的延展性更强。在3 × 3 BO和退火条件下,hpla的结晶度从0%提高到50%,拉伸强度提高83%,拉伸模量提高52%,断裂应变从3.7%提高到114%。scPLA共混物含有同源和立体络合物晶体,双熔融峰行为在220°C的最终熔化时提供了更高的温度稳定性。其光学透明度达到95%,在250 nm波长处保持高透明度。在卷对卷印刷中,PLA和hhPLA薄膜在印刷前在100°C下干燥,这将MD伸长率从2.55%和0.27%降低到0.00-0.05%。对于印刷和混合集成发光二极管(LED)箔,印刷银的片电阻<40 mΩ/sq。印制在PLA上的LED箔具有与PET相当的尺寸和电气性能,即使使用较低的干燥温度。
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引用次数: 19
Numerical approach for the calendering process using Carreau-Yasuda fluid model 采用carau - yasuda流体模型的压延过程数值方法
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-01-21 DOI: 10.1177/8756087920988748
M. Javed, N. Ali, S. Arshad, Shahbaz Shamshad
This paper presents a numerical study of the calendering mechanism. The calendered material is represented using the Carreau-Yasuda fluid model. The governing flow equations in the calendering process are made first dimensionless then the lubrication approximation theory (LAT) is used to simplify them. The simplified flow equations are transformed into stream function and then are numerically solved. A numerical method is constructed with Matlab’s built-in-bvp4c routine to find the stream function and pressure gradient. We use the Runge-Kutta algorithm to calculate the pressure and mechanical quantities related to the calendering process. In this analysis the pressure distribution increases with increasing Weissenberg number, however the pressure domain length decreases as the Weissenberg number increases. The pressure inside the nip region decreases from its Newtonian value when the power law index is less than one (shear thinning), and the pressure profile increases from its Newtonian pressure when the power law index is greater than one(shear thickening). How the Carreau-Yasuda fluid model parameters influence the velocity and related calendering process quantities are also discussed via graphs.
本文对压延机理进行了数值研究。压延材料用carau - yasuda流体模型表示。首先将压延过程中的控制流动方程建立为无因次方程,然后利用润滑近似理论对其进行简化。将简化后的流动方程转化为流函数,然后进行数值求解。利用Matlab自带的bvp4c程序构造了一种求流函数和压力梯度的数值方法。我们使用龙格-库塔算法来计算与压延过程相关的压力和力学量。在此分析中,压力分布随Weissenberg数的增加而增大,但压力域长度随Weissenberg数的增加而减小。当幂律指数小于1时(剪切变薄),压痕区域内的压力从牛顿值开始减小,当幂律指数大于1时(剪切变厚),压痕区域内的压力剖面从牛顿值开始增大。通过图形讨论了卡劳-安田流体模型参数对速度和相关压延工艺量的影响。
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引用次数: 7
Analysis of calendering process of non-isothermal flow of non-Newtonian fluid: A perturbative and numerical study 非牛顿流体非等温流压延过程分析:微扰与数值研究
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-01-14 DOI: 10.1177/8756087920979024
S. Khaliq, Z. Abbas
This paper numerically solves the third-order fluid flow during calendering with slip condition at the rolls. The basic equations are transformed into dimensionless forms and simplified by adopting LAT (Lubrication Approximation Theory). The flow equations are then solved with the perturbation technique. Whereas a finite difference scheme along with TDMA (Tridiagonal Matrix Algorithm) is implemented to solve the energy equation. Engineering parameters like power input, exit distance, and roll separating force are computed. The impact of slip parameter α and material parameter β on the velocity profile, pressure, pressure gradient, temperature profile, power input, detachment point, and roll separating force is portrayed through graphs and discussed. It is noticed that both the parameters α and β exhibit opposite behaviors and give insight to the mechanisms that control the physical and engineering parameters.
本文对轧辊处存在滑移的压延过程中的三阶流体流动问题进行了数值求解。将基本方程转化为无量纲形式,并采用LAT(润滑近似理论)进行简化。然后用微扰技术求解流动方程。采用有限差分格式和三对角矩阵算法求解能量方程。计算了输入功率、出口距离、轧辊分离力等工程参数。用图形描述了滑移参数α和材料参数β对速度分布、压力、压力梯度、温度分布、功率输入、分离点和轧辊分离力的影响,并进行了讨论。注意到α和β参数都表现出相反的行为,并为控制物理和工程参数的机制提供了见解。
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引用次数: 13
Mathematical modeling of Johnson-Segalman fluid in blade coating process 叶片涂布过程中Johnson-Segalman流体的数学建模
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-01-05 DOI: 10.1177/8756087920983551
M. Kanwal, Xinhua Wang, H. Shahzad, M. Sajid, Chen Yiqi
This article deals with the blade coating process for Johnson-Segalman (JS) fluid using plane coater. Flow equations are simplified with the Lubrication approximation theory (LAT). The equations are normalized using suitable scales. Reduced equations are solved numerically using the shooting technique. Also, for small Weissenberg numbers, a perturbation solution is obtained. How Weissenberg number and slip parameter influence the pressure gradient, velocity, pressure, load, and thickness are expressed graphically and via table. In the present work, load on the blade is crucial as it controls the thickness quality. One observes that an increased Weissenberg number decreases load, while the coating thickness increases when compared to the viscous case.
本文研究了利用平面涂布机对强生-塞格曼流体进行叶片涂布的工艺。用润滑近似理论(LAT)对流动方程进行了简化。用合适的尺度对方程进行归一化。采用射击技术对简化方程进行了数值求解。对于小的Weissenberg数,也得到了一个摄动解。Weissenberg数和滑移参数对压力梯度、速度、压力、载荷和厚度的影响分别用图形和表格表示。在目前的工作中,叶片上的载荷是至关重要的,因为它控制着厚度质量。人们观察到,与粘性情况相比,增加的Weissenberg数会降低载荷,而涂层厚度会增加。
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引用次数: 6
From the Editor 来自编辑
IF 3.1 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-01-01 DOI: 10.1177/8756087920988463
J. Wagner
Layered silicates present interaction sites at both faces and edges of the nanolayers and silane coupling agents that locate at both sites lead to polymer nanocomposites with superior melt strength and properties. This work’s objective was (a) to investigate the effectiveness of solvent-free, vapor phase, silane treatment of the nanolayers for formulating masterbatches and (b) to compare the mechanical properties of 1mil thick blown films from polypropylene copolymer nanocomposites with such coupling, to films from the neat polypropylene. The nanocomposite blown film tensile modulus and tensile strength improved along both the draw direction and the transverse direction. In addition, their elongation to failure was close to 500% along both directions, in contrast to values of 500% along MD and 170% along TD for the neat PP copolymer. These trends may be understood in terms of the crystalline lamellar orientation distribution in the films. FESEM images revealed that cross-hatched lamellae were absent from the unfilled PP blown film and were pervasive in the nanocomposite blown film. The nanolayers were oriented in the film plane with the longer dimension largely along the MD. The lower extent of lamellar orientation around nanolayers may be attributed to the strong reduction in the polymer chain mobility attached to the nanolayers. Wagner 5
层状硅酸盐在纳米层的表面和边缘都存在相互作用位点,硅烷偶联剂位于这两个位点,导致聚合物纳米复合材料具有优异的熔融强度和性能。这项工作的目的是(a)研究无溶剂、气相、硅烷处理纳米层的有效性,以配制母粒;(b)比较具有这种偶联的1mil厚聚丙烯共聚物纳米复合材料吹膜与纯聚丙烯膜的机械性能。纳米复合吹塑膜的拉伸模量和拉伸强度沿拉伸方向和横向均有提高。此外,它们的断裂延伸率在两个方向上都接近500%,而纯PP共聚物在MD方向上的延伸率为500%,在TD方向上的延伸率为170%。这些趋势可以从薄膜中晶体片层取向分布的角度来理解。FESEM图像显示,未填充的PP吹膜中没有交叉孵化的片层,而在纳米复合吹膜中普遍存在。纳米层在膜平面上取向较长,主要沿MD方向取向。纳米层周围的层状取向程度较低可能是由于纳米层所附着的聚合物链迁移率大大降低。瓦格纳5
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引用次数: 0
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Journal of Plastic Film & Sheeting
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