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Quantitative Investigation on Pyrolytic Behaviors of Agricultural Residues from Rice Husk and Various Performances of Their Relevant Ash Residues 稻壳农用秸秆的热解行为及其相关灰渣各种性能的定量研究
Pub Date : 2017-01-01 DOI: 10.12783/issn.1544-8053/14/1/5
Xiwen Yao, Kaili Xu, Yu Liang
In this study, the thermal process behavior of rice husk as a sustainable feedstock for bio-syngas production and the physicochemical properties of rice husk ash generated from thermal process as possible precursors for utilizations were intensively investigated. A preliminary analysis of the influences of heating rate on kinetics and on the formation of bio-syngas was also performed. The thermogravimetric results of rice husk indicate that its decomposition occurs in four stages, and the main weight loss occurs within 210–400°C. The emission intensities of CO, CO2, CH4, and H2 at 20°C/min are much higher than those of 5°C/min, indicating that pyrolysis at higher heating rates is more suitable for bio-syngas production. Chemical and phase analysis exhibits the presence of cristobalite, quartz, and tridymite as the major crystal phases of SiO2, which reveals the potential of rice husk ash as an alternative for silicon compounds. The porous structure analysis indicates that carbon residues developed from rice husk ash are good candidates for activated carbon production. Through analyzing its thermal properties, the internal reactions occurring within ash particles are predicted accurately, which is helpful to better understand the transformation and fusion mechanism of inorganic components in the complex-composition ash.
在本研究中,深入研究了稻壳作为生物合成气生产的可持续原料的热过程行为,以及热过程产生的稻壳灰作为可能利用的前体的物理化学性质。初步分析了加热速率对动力学和生物合成气形成的影响。稻壳的热重分析结果表明,稻壳的分解分4个阶段,主要失重发生在210 ~ 400℃。20℃/min时CO、CO2、CH4和H2的排放强度远高于5℃/min时的排放强度,说明较高升温速率的热解更适合生物合成气的生产。化学和物相分析表明,SiO2的主要晶相为方石英、石英和钇铝石,这表明稻壳灰具有替代硅化合物的潜力。多孔结构分析表明,稻壳灰残炭是制备活性炭的良好候选材料。通过对其热性能的分析,准确预测了灰颗粒内部发生的反应,有助于更好地理解复合组成灰中无机组分的转化和融合机理。
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引用次数: 0
Study on the Effect of Crop Production on the Air Quality in Wuhan 武汉市农作物生产对空气质量的影响研究
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/S1/5
Song Tao
According to the data about annual average air pollution and the main crop yield between 1997 and 2013 in Wuhan City, we studied the impact of crop production on the air quality in Wuhan City. The results showed grains production’s increase will increase annual average nitrogen dioxide in the air. Increase of oil production will reduce annual average nitrogen dioxide in the air. In addition, increases of emissions of industrial dust and soot will raise the annual average particulate matter in the air. Increase of emissions of industrial nitrogen oxides will augment the annual average nitrogen dioxide in the air.
根据武汉市1997 - 2013年的年平均空气污染和主要农作物产量数据,研究了农作物生产对武汉市空气质量的影响。结果表明,粮食产量的增加会增加空气中年均二氧化氮的含量。石油产量的增加将减少空气中年平均二氧化氮含量。此外,工业粉尘和煤烟排放的增加将提高空气中年平均颗粒物的含量。工业氮氧化物排放量的增加将增加空气中二氧化氮的年平均含量。
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引用次数: 0
Analysis of Land Use Structure in Liaoning Province Based on Lorenz Curves and Gini Coefficient 基于Lorenz曲线和基尼系数的辽宁省土地利用结构分析
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/S1/7
Xiaofan Zhao, Y. Xu
Land resources and land use activities support the social and economic development in any region. In order to explore the distribution of land use structure, we can apply the Lorenz curves and Gini coefficient to accomplish. In this study, we selected the land use data in 14 prefecture cities in Liaoning Province of China from 2010 to 2015. Based on the Lorenz curve and the Gini coefficient, we analyzed quantitatively the land use structure in 14 prefecture cities of Liaoning province. Results indicated that cultivated land, forest land and construction land were evenly distributed, while garden land, grass land and unused land were distributed in a more concentrated state in space scale. On time scale, the Gini coefficient of forest land, garden land and grass land were increasing, and the degree of distribution dispersion has increased, while the Gini coefficient of cultivated land, construction land and unused land has reduced, whose distribution tended to equilibrium. Some suggestion for rational land use and structural adjustment has been provided by analyzing the spatial and temporal distribution of land use in Liaoning Province.
土地资源和土地利用活动支撑着任何地区的社会经济发展。为了探索土地利用结构的分布,我们可以应用洛伦兹曲线和基尼系数来完成。本研究选取了中国辽宁省14个地级市2010 - 2015年的土地利用数据。基于Lorenz曲线和基尼系数,对辽宁省14个地级市的土地利用结构进行了定量分析。结果表明:耕地、林地和建设用地在空间尺度上分布较为均匀,而园林、草地和未利用地在空间尺度上分布较为集中;在时间尺度上,林地、园地和草地的基尼系数呈增加趋势,分布分散程度增加,耕地、建设用地和未利用地的基尼系数减小,分布趋于均衡。通过对辽宁省土地利用时空分布的分析,提出了合理土地利用和结构调整的建议。
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引用次数: 0
Measurement of China’s Carbon Emissions Efficiency and the Study of Its Influencing Factors 中国碳排放效率测度及其影响因素研究
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/26
Hua Wang, Z. Wang, Xin He
This paper attempts to take China, an emerging economy in the process of industrialization and emission reduction, as an example to measure its carbon emission efficiency and related influence factors, as a reference for the developing countries to develop green economy. Based on the measurement of carbon emission, this article firstly analyzes several emission efficiency indicators: CEP, ML index and TGR. Then this article adopts Tobit model to analyze the influencing factors of these indicators. In the end, we give some suggestions for the improvement of carbon emission efficiency.
本文试图以中国这个处于工业化和减排过程中的新兴经济体为例,测算其碳排放效率及其影响因素,为发展中国家发展绿色经济提供参考。本文在碳排放测度的基础上,首先分析了碳排放效率的几个指标:CEP、ML指数和TGR。然后采用Tobit模型对这些指标的影响因素进行分析。最后,提出了提高碳排放效率的建议。
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引用次数: 0
Investigation of the Leaching Characteristics of Heavy Metals from Waste Printed Circuit Boards through Column Testing with Simulated Acid Rain 模拟酸雨柱试验研究废弃印刷电路板中重金属的浸出特性
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/11/1/17
Guo-hua Zhao, Jie Luo, Gui Chen
Waste printed circuit boards (PCBs) contain various heavy metals; hence, randomly discarded PCBs in open fields induce probable environmental risks when precipitation occurs, particularly acid rain (AR). We applied the column leaching method under simulated AR leaching to study the leaching characteristics of Cu, Pb and Zn in waste PCBs. Cu and Pb were easily leached by AR (pH 2 and 3) but not by distilled water (pH 5.6; CK treatment). By contrast, Zn could be leached readily even in CK treatment. AR with low pH exerted good leaching effects on Cu, Pb, and Zn. The heavy metal contents in the leachates were in the order of Cu > Pb > Zn. The maximum leaching concentrations of Cu, Pb, and Zn were 34.7, 4.06, and 1.15 mg/L, respectively, which are higher than drinking water standard set by the US Environmental Protection Agency. Therefore, waste PCBs can be considered a new source of heavy metal and pose potential environmental risks.
废弃印刷电路板(pcb)中含有多种重金属;因此,当降水,特别是酸雨(AR)发生时,露天场地随机丢弃的多氯联苯可能会造成环境风险。采用模拟AR浸出柱浸出法,研究了废多氯联苯中Cu、Pb、Zn的浸出特性。AR (pH 2和3)容易浸出Cu和Pb,蒸馏水(pH 5.6;CK处理)。相比之下,锌在CK处理下也容易浸出。低pH AR对Cu、Pb、Zn的浸出效果较好。渗滤液中重金属含量依次为Cu > Pb > Zn。Cu、Pb和Zn的最大浸出浓度分别为34.7、4.06和1.15 mg/L,均高于美国环保局规定的饮用水标准。因此,废弃多氯联苯可被认为是一种新的重金属来源,具有潜在的环境风险。
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引用次数: 3
Performance Prediction Model for Designing a Multiple Electro-cyclone System 多电旋流器系统设计的性能预测模型
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/38
Seungkyung Park
Electro-cyclones allow simple and cost effective removal of fine particles by improving the collection efficiency of conventional cyclones with the application of external electric fields. However, understanding of design and operational parameters for optimizing the performance of electro-cyclones are still limited due to the complexity of the removal mechanism and the lack of prediction models. In this study, the particle collection efficiency of electro-cyclones has been analyzed using simple theoretical models, and the system configuration of multiple electro-cyclones has been evaluated especially for the removal of fine particles less than 5 µm which are limited in conventional cyclones. Based on the Stairmand high efficiency cyclone design, the effects of external electric field on a single and multiple units were investigated. Parallel operations of multiple electro-cyclones, consisting of 10 units, potentially provided the cut off diameter less than 0.3 µm by lowering flow rate and operation load for each unit. For a multiple configuration, the collection efficiency was improved as the number of units increased, while the flow speed variation due to the parallel operation was insignificant.
电旋风通过应用外部电场提高传统旋风的收集效率,可以简单而经济地去除细颗粒。然而,由于去除机制的复杂性和缺乏预测模型,对优化电旋风性能的设计和操作参数的理解仍然有限。在本研究中,使用简单的理论模型分析了电旋风的颗粒收集效率,并评估了多个电旋风的系统配置,特别是对于传统旋风中限制的小于5µm的细颗粒的去除。以Stairmand型高效旋风分离器设计为基础,研究了外加电场对单机组和多机组的影响。由10台组成的多台电旋风并联运行,通过降低每台电旋风的流量和运行负荷,有可能使截止直径小于0.3µm。对于多机组配置,随着机组数量的增加,收集效率有所提高,而并联运行引起的流速变化不显著。
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引用次数: 0
Characterization of CuInS2 Films Prepared by Electroplating and Sulfurization 电镀和硫化制备CuInS2薄膜的表征
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/S1/12
Kegao Liu, Hui Liu Jing Li Chao Xu, Yong Xu
As a ternary compound, CuInS2 with band gap about 1.5 eV, has chalcopyrite crystal structure, high absorption coefficient and low toxicity of sulfur, therefore, CuInS2 is a promising absorbing layer used in solar cells with thin films. Electroplating method has many advantages of low cost and easy operation etc. CuInS2 precursor samples were prepared by electroplating with raw materials of CuCl2·2H2O, InCl3 and Na2S2O3·5H2O etc., and the precursor films were heat treated in sulfur atmosphere. The phases of product samples were determined by X-ray diffraction (XRD) and the surface morphology was observed by scanning electron microscopy (SEM), and the elemental content of the film was analyzed by energy dispersive spectroscopy (EDS). Results show that uniform and dense CuInS2 precursor films can be obtained under conditions of CuCl2·2H2O, InCl3, Na2S2O3·5H2O and C6H5Na3O7·2H2O with contents of 10 mmol/L, 10 mmol/L, 100 mmol/L and 1.25 mmol/L respectively, pH 3.5 and deposition potential –1.0 V. CuInS2 film with good crystallinity was obtained by sulfurizing precursor film at 350 oC for 6h, has different XRD peaks for (112), (024/220) and (116/132) crystal planes respectively. Many lumps with uniform size are found, and there are little holes distributing on the surface after heat treatment. The precursor and sulfurized films were all found containing copper, indium and sulfur elements. It is found that the sulfur content in the films was obviously increased after sulfurizing.
CuInS2是一种带隙约为1.5 eV的三元化合物,具有黄铜矿晶体结构、高吸收系数和低硫毒性,是一种很有前途的薄膜太阳能电池吸收层。电镀法具有成本低、操作方便等优点。以CuCl2·2H2O、InCl3、Na2S2O3·5H2O等为原料,采用电镀法制备CuInS2前驱体样品,并在含硫气氛中对前驱体膜进行热处理。用x射线衍射仪(XRD)测定产物样品的物相,用扫描电镜(SEM)观察其表面形貌,用能谱仪(EDS)分析膜的元素含量。结果表明:CuCl2·2H2O、InCl3、Na2S2O3·5H2O和C6H5Na3O7·2H2O的含量分别为10、10、100和1.25 mmol/L, pH为3.5,沉积电位为-1.0 V时,可以得到均匀致密的CuInS2前驱体膜;前驱体膜在350℃下硫化6h,得到结晶度较好的CuInS2薄膜,在(112)、(024/220)和(116/132)晶面上分别有不同的XRD峰。热处理后表面有细小的孔洞分布,块状多,大小均匀。前驱体和硫化膜均含有铜、铟和硫元素。结果表明,硫化后膜中的硫含量明显增加。
{"title":"Characterization of CuInS2 Films Prepared by Electroplating and Sulfurization","authors":"Kegao Liu, Hui Liu Jing Li Chao Xu, Yong Xu","doi":"10.12783/ISSN.1544-8053/14/S1/12","DOIUrl":"https://doi.org/10.12783/ISSN.1544-8053/14/S1/12","url":null,"abstract":"As a ternary compound, CuInS2 with band gap about 1.5 eV, has chalcopyrite crystal structure, high absorption coefficient and low toxicity of sulfur, therefore, CuInS2 is a promising absorbing layer used in solar cells with thin films. Electroplating method has many advantages of low cost and easy operation etc. CuInS2 precursor samples were prepared by electroplating with raw materials of CuCl2·2H2O, InCl3 and Na2S2O3·5H2O etc., and the precursor films were heat treated in sulfur atmosphere. The phases of product samples were determined by X-ray diffraction (XRD) and the surface morphology was observed by scanning electron microscopy (SEM), and the elemental content of the film was analyzed by energy dispersive spectroscopy (EDS). Results show that uniform and dense CuInS2 precursor films can be obtained under conditions of CuCl2·2H2O, InCl3, Na2S2O3·5H2O and C6H5Na3O7·2H2O with contents of 10 mmol/L, 10 mmol/L, 100 mmol/L and 1.25 mmol/L respectively, pH 3.5 and deposition potential –1.0 V. CuInS2 film with good crystallinity was obtained by sulfurizing precursor film at 350 oC for 6h, has different XRD peaks for (112), (024/220) and (116/132) crystal planes respectively. Many lumps with uniform size are found, and there are little holes distributing on the surface after heat treatment. The precursor and sulfurized films were all found containing copper, indium and sulfur elements. It is found that the sulfur content in the films was obviously increased after sulfurizing.","PeriodicalId":17101,"journal":{"name":"Journal of Residuals Science & Technology","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75165173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, Structure and Biological Activity of a Ca(II) Coordination Polymer with Pyrazole-3,5-dicarboxylate as Ligand 以吡唑-3,5-二羧酸酯为配体的Ca(II)配位聚合物的合成、结构和生物活性
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/6
Tai Xi-Shi, Jia Zong-Qing, W. Xin
Using pyrazole-3,5-dicarboxylic acid and Ca(ClO4)2·H2O as materials, a novel Ca(II) coordination polymer, {[Ca(L)(H2O)4]·(H2O)}n (1) was synthesized and characterized. The results reveals that Ca(II) complex forms 1D chained structure. The 1D chain further formed a three-dimensional network structure by π-π stacking interaction. The antitumor effect of complex 1 against three human tumor cells has been investigated.
以吡唑-3,5-二羧酸和Ca(ClO4)2·H2O为原料,合成了一种新型Ca(II)配位聚合物{[Ca(L)(H2O)4]·(H2O)}n(1),并对其进行了表征。结果表明,Ca(II)配合物形成一维链状结构。一维链进一步通过π-π叠加相互作用形成三维网络结构。研究了复合物1对三种人肿瘤细胞的抗肿瘤作用。
{"title":"Synthesis, Structure and Biological Activity of a Ca(II) Coordination Polymer with Pyrazole-3,5-dicarboxylate as Ligand","authors":"Tai Xi-Shi, Jia Zong-Qing, W. Xin","doi":"10.12783/ISSN.1544-8053/14/1/6","DOIUrl":"https://doi.org/10.12783/ISSN.1544-8053/14/1/6","url":null,"abstract":"Using pyrazole-3,5-dicarboxylic acid and Ca(ClO4)2·H2O as materials, a novel Ca(II) coordination polymer, {[Ca(L)(H2O)4]·(H2O)}n (1) was synthesized and characterized. The results reveals that Ca(II) complex forms 1D chained structure. The 1D chain further formed a three-dimensional network structure by π-π stacking interaction. The antitumor effect of complex 1 against three human tumor cells has been investigated.","PeriodicalId":17101,"journal":{"name":"Journal of Residuals Science & Technology","volume":"24 1","pages":"47-50"},"PeriodicalIF":0.0,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77951973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Design of Asphalt Light Component Pre-filled Filler Based on Oil Shale Waste Residue 基于油页岩废渣的沥青轻组分预充填料设计
Pub Date : 2017-01-01 DOI: 10.12783/issn.1544-8053/14/1/8
Yazhi Xu, Zhuang Zheng, Xuedong Guo
The asphalt light component pre-filled filler is prepared based on oil shale waste residue. The performance of the light component pre-filled filler is evaluated based on ultimate and fatigue failure parameters, such as the ultimate bending failure strength and strain of asphalt mastic, and the bending creep stiffness variation ratio m of asphalt mastic. Test results show that the light component pre-filled filler can weaken the effect of aging on the asphalt property parameters, which is a feasible measure of the anti-aging of asphalt.
以油页岩废渣为原料制备沥青轻组分预填充填料。根据沥青胶合料的极限弯曲破坏强度和应变、沥青胶合料的弯曲蠕变刚度变化率m等极限和疲劳破坏参数,对轻组分预充填料的性能进行了评价。试验结果表明,轻组分预填充填料能减弱老化对沥青性能参数的影响,是一种可行的沥青抗老化措施。
{"title":"Design of Asphalt Light Component Pre-filled Filler Based on Oil Shale Waste Residue","authors":"Yazhi Xu, Zhuang Zheng, Xuedong Guo","doi":"10.12783/issn.1544-8053/14/1/8","DOIUrl":"https://doi.org/10.12783/issn.1544-8053/14/1/8","url":null,"abstract":"The asphalt light component pre-filled filler is prepared based on oil shale waste residue. The performance of the light component pre-filled filler is evaluated based on ultimate and fatigue failure parameters, such as the ultimate bending failure strength and strain of asphalt mastic, and the bending creep stiffness variation ratio m of asphalt mastic. Test results show that the light component pre-filled filler can weaken the effect of aging on the asphalt property parameters, which is a feasible measure of the anti-aging of asphalt.","PeriodicalId":17101,"journal":{"name":"Journal of Residuals Science & Technology","volume":"9 1","pages":"59-66"},"PeriodicalIF":0.0,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81693582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on Expressway Crack Segmentation Algorithm Combined with Pulse-Coupled Neural Network and Cross-Entropy Algorithm 脉冲耦合神经网络与交叉熵算法相结合的高速公路裂缝分割算法研究
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/S1/6
Baocheng Wang, Jiawei Sun
The expressway crack identification is significantly important for the expressway safety maintenance, and the crack detection is one of key technologies for the crack identification. This paper proposed an expressway crack detection method based on improved Pulse-Coupled Neural Network (PCNN), used minimum cross-entropy algorithm to obtain the optimal iterations of PCNN algorithm, and then complete the segmentation of expressway images by combining the simplified PCNN algorithm. The results showed that this method could inhibit the background noise and better extract continuous crack edge to provide good characteristics for crack identification in the next step.
高速公路裂缝识别对高速公路安全维护具有重要意义,而裂缝检测是裂缝识别的关键技术之一。本文提出了一种基于改进脉冲耦合神经网络(PCNN)的高速公路裂纹检测方法,利用最小交叉熵算法获得PCNN算法的最优迭代,然后结合简化后的PCNN算法完成高速公路图像的分割。结果表明,该方法能较好地抑制背景噪声,提取连续裂纹边缘,为下一步的裂纹识别提供良好的特征。
{"title":"Study on Expressway Crack Segmentation Algorithm Combined with Pulse-Coupled Neural Network and Cross-Entropy Algorithm","authors":"Baocheng Wang, Jiawei Sun","doi":"10.12783/ISSN.1544-8053/14/S1/6","DOIUrl":"https://doi.org/10.12783/ISSN.1544-8053/14/S1/6","url":null,"abstract":"The expressway crack identification is significantly important for the expressway safety maintenance, and the crack detection is one of key technologies for the crack identification. This paper proposed an expressway crack detection method based on improved Pulse-Coupled Neural Network (PCNN), used minimum cross-entropy algorithm to obtain the optimal iterations of PCNN algorithm, and then complete the segmentation of expressway images by combining the simplified PCNN algorithm. The results showed that this method could inhibit the background noise and better extract continuous crack edge to provide good characteristics for crack identification in the next step.","PeriodicalId":17101,"journal":{"name":"Journal of Residuals Science & Technology","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81819153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of Residuals Science & Technology
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