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Degradation of S-metolachlor and its Effects on Soil Enzymes and Microbial Communities in Vegetable Field Soil s -甲草胺的降解及其对菜地土壤酶和微生物群落的影响
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/29
Jiguang Huang, Lijuan Zhou Hui Miao Ye Cui, Li Feng
S-metolachlor is a promising alternative to metolachlor. However, the extensive use of S-metolachlor as herbicide in vegetable fields in China has caused concerns about its environmental fate. Here we investigated the effects of temperature, relative humidity (RH) and PH on the degradation rate of S-metolachlor in vegetable soil. The degradation rates of S-metolachlor increased with increasing temperatures and RH and either acidic or basic PH facilitates S-metolachlor degradation. The degradation of S-metolachlor under these conditions followed the first-order kinetics resulting in the half-lives (T-1/2) ranging from 12.18 d to 70.71 d at 5–35°C, and 27.28 d to 53.72 d at RH 30–90%; and 29.62–19.69 d at pH 6–8. Stronger response of soil enzymes including catalase, dehydrogenase, urease and cellulase to S-metolachlor was detected in soil with high organic matter. PLFA profiles showed that, totally, the microbe populations including actinomycetes, fungi and bacteria increased gradually in the first 14 days after the treatment and decreased from 14d to 28d after the treatment. All the S-metolachlor treatments caused the increase of aerobe and anaerobe. High S-metolachlor concentration, 13.9 mg/kg, could cause significant variation at the first 2 weeks, stimulating growth of the entire soil microbial community. These findings might have practical implications for the fate of S-metolachlor residue in vegetable fields. Environmental factors, especially temperature, relative humidity and pH should be considered in combination with the appropriate application dose of S-metolachlor for achieving satisfactory weed-control efficacy, reducing runoff, and minimizing effects on environmental quality.
s -甲草胺是一种很有前途的甲草胺替代品。然而,中国蔬菜田广泛使用s -甲草胺作为除草剂,引起了人们对其环境命运的担忧。研究了温度、相对湿度和PH对s -甲草胺在蔬菜土壤中降解速率的影响。s -异甲草胺的降解速率随温度和相对湿度的升高而升高,酸性或碱性PH均有利于s -异甲草胺的降解。在此条件下,s -异甲草胺的降解符合一级动力学,在5-35℃条件下,半衰期(T-1/2)为12.18 ~ 70.71 d,在RH 30-90%条件下,半衰期为27.28 ~ 53.72 d;pH 6 ~ 8时29.62 ~ 19.69 d。高有机质土壤过氧化氢酶、脱氢酶、脲酶和纤维素酶对s -甲草胺的响应较强。PLFA谱图显示,放线菌、真菌和细菌等微生物数量在处理后的前14天逐渐增加,在处理后的14 ~ 28天逐渐减少。所有s -甲草胺处理均引起好氧菌和厌氧菌的增加。13.9 mg/kg的高s -甲草胺浓度可在前2周引起显著变化,刺激整个土壤微生物群落的生长。这些发现可能对菜田中s -甲草胺残留的命运具有实际意义。考虑环境因素,特别是温度、相对湿度和pH值,结合s -甲草胺的适当施用剂量,达到满意的除草效果,减少径流,尽量减少对环境质量的影响。
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引用次数: 2
Analysis on Influence Factors of Mining Subsidence in Backfilling under Thick Loose Layer 厚松散层下充填开采沉陷影响因素分析
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/31
Quan Wu, L. Jing, Quansen Wu
Mining subsidence, mine solid waste emissions caused by the direct cause of ecological environment deterioration in mining area, effective control and reduce the surface subsidence and reasonable control and utilization of mine wastes, and realize green mining is a fundamental way to reduce the damage of the ecological environment in mining area. To solve this problem, using FLAC3D three dimensional numerical simulation method, the above four factors were changed to simulate the surface movement and deformation, and the influence of the above four factors on the maximum surface subsidence was discussed. By using the orthogonal experiment, the importance of the four factors is queued, and the correlation degree ranking of the maximum subsidence value is obtained. The influence degree of the factors on the maximum surface subsidence is: the filling ratio, the thickness of the key stratum, the strength of the filling body and the thickness of the loose layer. In this paper, the content of the "three under" pressure coal mining area of production practice to provide basic data, can improve the recovery rate of coal resources, reduce the cost of filling, the maximum economic benefits. Has important practical significance to protect the ground structure, reduce the ecological damage, and realize the sustainable development of coal mine.
采矿沉陷,矿山固体废弃物排放造成矿区生态环境恶化的直接原因,有效控制和减少地表沉陷,合理控制和利用矿山废弃物,实现绿色采矿是减少矿区生态环境破坏的根本途径。针对这一问题,采用FLAC3D三维数值模拟方法,改变上述4个因素来模拟地表移动和变形,并讨论了上述4个因素对地表最大沉降的影响。通过正交试验,对4个因素的重要性进行排序,得到最大沉降值的关联度排序。各因素对地表最大沉降量的影响程度分别为:充填率、关键层厚度、充填体强度和松散层厚度。本文的内容为“三下”承压煤矿矿区的生产实践提供了基础数据,可以提高煤炭资源回收率,降低充填成本,实现经济效益最大化。对保护地面结构,减少生态破坏,实现煤矿可持续发展具有重要的现实意义。
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引用次数: 0
Dephosphorization in the Reduction and Melting Separation of High Phosphorus Hematite Carbon Bearing Pellets 高磷赤铁矿含碳球团还原熔融分离中的脱磷研究
Pub Date : 2017-01-01 DOI: 10.12783/issn.1544-8053/14/1/25
X. She, Guang-Wang Qing-guo Xue Jung-Wook Cho, Jingping Wan
The rotary hearth furnace iron nugget process is a new technology with a huge potential to efficiently utilize high phosphorus hematite. In this paper, the influences of the basicity and additives on the phosphorus content and distribution in the iron nuggets and the slag were investigated. At first CaCO3 was added to the pellets and then Na2CO3 and CaF2 were also added in the experiments. The experimental results showed that the increase in the basicity and the addition of Na2CO3 and CaF2 were shown to be effective to inhibit the apatite reduction in high phosphorus iron ores and to reduce the phosphorus content in the nuggets. When the pellets containing 4% Na2CO3 and 4% CaF2 with the basicity at 1.4 were reduced at the temperature of 1400°C for 12 min, the phosphorus content in the iron nuggets was only 0.4% and the dephosphorization rate reached 81.2%.
转底炉铁核工艺是一项极具潜力的高效利用高磷赤铁矿的新技术。本文研究了碱度和添加剂对铁块和矿渣中磷含量和分布的影响。首先在球团中加入CaCO3,然后在实验中加入Na2CO3和CaF2。实验结果表明,提高碱度、添加Na2CO3和CaF2可有效抑制高磷铁矿中磷灰石的还原,降低矿块中磷含量。含4% Na2CO3和4% CaF2、碱度为1.4的球团在1400℃下还原12 min,铁块中磷含量仅为0.4%,脱磷率达到81.2%。
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引用次数: 0
Influence of Curing Condition on Compressive Strength of Low-calcium Fly Ash-based Geopolymer Concrete 养护条件对低钙粉煤灰基地聚合物混凝土抗压强度的影响
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/S1/10
Zhang Hongen, Shijia Ling, W. Qingyuan
This paper aims to investigate the influence of curing condition on compressive strength of low-calcium fly ash-based geopolymer concrete (FAGC) by preparing six mixtures. The results also show that the specimens cured at room temperature for one day and then cured at high temperature will be helpful to obtain materials with higher strength than that of directly cured specimens at high temperature. Additionally, cured at room temperature for one day and then cured at high temperature would weaken the adverse effect of wet curing on the growth of compressive strength.
通过配制6种低钙粉煤灰基地聚合物混凝土(FAGC),研究养护条件对其抗压强度的影响。结果还表明,常温固化1天后再进行高温固化有利于获得比直接高温固化更高强度的材料。另外,室温固化1天后再进行高温固化,可以减弱湿法固化对抗压强度增长的不利影响。
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引用次数: 2
Study on the Removal Performance of Natural Manganese Ore and Iron-Oxidizing Bacteria on the Arsenic 天然锰矿石及铁氧化菌对砷的去除性能研究
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/45
Hu Yongbin, Qiu Qiang Xu Wei Gao Huiqin She Rui Niu Chenyu, Tu Shuxin
In this study, through the leaching of iron oxidizing bacteria with natural manganese ore, by the using of X-ray fluorescence, the X-ray diffraction analysis, and scanning electron microscopy testing technology to characterize the prepared eroded manganese ore, which also gives a further research on the removal performance and mechanism of the eroded manganese ore on the arsenic. The results of the experiment showed that the saturated adsorption capacity of eroded manganese ore on the As(III) and As(V) were 18.52 mg/g and 19.23 mg/g respectively. The Langmuir adsorption model adsorption gives a good description on the removal of arsenic by the eroded manganese ore. The removal rate of arsenic is positively correlated with temperature, when the pH value is near neutral, the best removal performance of eroded manganese ore on the arsenic can be achieved, and the coexisting cation (Ca2+, Mg2+) can promote the removal rate of arsenic. With the characterization experiment, it shows that the main components (Mn, Si, Fe, Al) of manganese ore did not change before and after immersion, but the content of MnO decreased by 11.62%, Fe2O3 increased by 13.38%, the content of hydroxyl increase, porosity increased by 31.81%, porosity ratio increased 0.472.
本研究通过铁氧化菌浸出天然锰矿石,利用x射线荧光、x射线衍射分析、扫描电镜检测等技术对制备的侵蚀锰矿石进行表征,进一步研究了侵蚀锰矿石对砷的去除性能及机理。实验结果表明,侵蚀锰矿石对As(III)和As(V)的饱和吸附量分别为18.52 mg/g和19.23 mg/g。Langmuir吸附模型很好地描述了侵蚀锰矿石对砷的去除,砷的去除率与温度呈正相关,当pH值接近中性时,侵蚀锰矿石对砷的去除效果最佳,共存阳离子(Ca2+、Mg2+)对砷的去除率有促进作用。表征实验表明,浸矿前后锰矿石的主要成分(Mn、Si、Fe、Al)没有变化,但MnO含量下降了11.62%,Fe2O3含量增加了13.38%,羟基含量增加,孔隙度增加了31.81%,孔隙度比增加了0.472。
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引用次数: 1
Enrichment of Ammonia-Oxidizing Bacteria and Microbial Diversity Analysis by High-Throughput Sequencing 氨氧化细菌富集及微生物多样性高通量测序分析
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/10
Renda Yao, Mengyu Yu Yi Liu Hong Yang, H. Shi
A fully automatic miniature fermenter was operated to enrich ammoniaoxidizing bacteria (AOB) using the activated sludge obtained from the A2/O process in a wastewater treatment plant (WWTP) as the seed sludge. The results revealed that the AOB community can be enriched by a continuous ammonia feeding mode for intermittent operation, resulting in the appropriate regulation of free ammonia (FA) and free nitrous acid (FNA) levels. The maximum ammonia oxidation rate was over 170 mg/ (L·h) and nitrite accumulation ratio over 80%. High-throughput sequencing showed that Nitrosomonas belonging to AOB, were highly enriched after 27 days, having increased from 0.24% to 53.03%.
以某污水处理厂A2/O工艺获得的活性污泥为种子污泥,在全自动微型发酵罐上富集氨氧化菌(AOB)。结果表明,间歇式连续供氨模式可丰富AOB群落,适当调节游离氨(FA)和游离亚硝酸盐(FNA)水平。最大氨氧化速率大于170 mg/ (L·h),亚硝酸盐积累率大于80%。高通量测序结果显示,亚硝基单胞菌属AOB, 27天后富集,从0.24%增加到53.03%。
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引用次数: 3
Study on Damage Evolution Law of Rock Mechanics Parameters Under Water-Rock Interaction 水岩相互作用下岩石力学参数损伤演化规律研究
Pub Date : 2017-01-01 DOI: 10.12783/issn.1544-8053/14/S1/22
Zhe Qin, W. Fu, Xuxin Chen
The open pit locating in Cangshang was closed in 2005 because the reusing of pumping water resulted in the cyclic change of slope water level. In order to study the influence of water level fluctuation on mechanics parameters of the slope rocks, two kinds of typical rocks are selected to have the uniaxial compression tests of different saturation-dehydration circulation. The damage evolution law of rock mechanics parameters under water-rock interaction is found, whose results show that the mechanical properties of rock are weakened obviously by the water-rock interaction. In addition, the stronger the water-rock interaction becomes, the more obvious the weakening phenomenon is. Due to the different sensitivity to various parameters of water-rock interaction, the extent of elastic modulus decrease is the largest and uniaxial anti-compressive strength takes the second place while Poisson's ratio is essentially constant. Moreover, the uniaxial compressive strength and modulus of elasticity present exponential distribution with times of saturation-dehydration circulation. With the increase of the saturationdehydration times, the damage value increases accordingly while the increment tends to zero. Generally, the rock mechanical properties are hardly affected by water-rock interaction in the latter period; there are differences among the damage degree of various qualities of rocks, the better the quality, the smaller the damage, and the less the times reaching 95% limit damage value.
仓上露天矿因抽水回用导致边坡水位循环变化,于2005年关闭。为了研究水位波动对边坡岩石力学参数的影响,选取两种典型岩石进行了不同饱和-脱水循环的单轴压缩试验。发现了水-岩相互作用下岩石力学参数的损伤演化规律,结果表明,水-岩相互作用使岩石的力学性能明显减弱。此外,水岩相互作用越强,弱化现象越明显。由于对水岩相互作用各参数的敏感性不同,弹性模量下降幅度最大,单轴抗压强度次之,泊松比基本保持不变。单轴抗压强度和弹性模量随饱和-脱水循环次数呈指数分布。随着饱和脱水次数的增加,损伤值随之增大,但增量趋于零。一般来说,后期水岩相互作用对岩石力学性质影响不大;不同质量岩石的损伤程度存在差异,质量越好,损伤越小,达到95%极限损伤值的次数越少。
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引用次数: 0
Validation and Application of Ultrasound-assisted Extraction Coupled with ICP-MS for Determination of Toxic Metals in Fine Particles 超声辅助萃取- ICP-MS法测定细颗粒中有毒金属的验证与应用
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/27
S. Liang, Ke Ding, Peng Ji
Analysis of chemical compositions of fine particle matters (PM2.5) in contaminated atmospheres has increasingly become a great concern of both scientific and technological importance because the contaminant concentrations of PM2.5 are playing an important role in affecting PM2.5-induced adverse effects on environment and human health. In this paper, ultrasound-assisted extraction coupled with ICP-MS was developed for a simultaneous quantification of 12 toxic elements (Be, Al, Cr, Mn, Ni, As, Se, Sb, Tl, Pb, Hg and Cd) in PM2.5 samples. The proposed method was validated with several parameters, namely linearity of calibration, precision and accuracy, limit of detection (LOD) and limit of quantification (LOQ). The accuracy of the proposed method was validated with recovery tests of different samples spiked with corresponding elements at known concentrations (5, 10 and 20 μg/L) and the average percent recovery varied in the range of 87.3–101.3%. The results showed that this method was a multi-element technique featuring high precision and accuracy as well as low LOD. This proposed method was applied to a simultaneous determination of the 12 target elements in atmospheric fine particles collected from a heavily polluted urban residential area in China, and showed that the particles were rich in Al, Pb and Mn, followed by As, Sb, Cr, Cd, Se and Ni. The main advantages of the ultrasound-assisted extraction process were fast sample treatment and low consumption of reagents in the extraction process.
由于PM2.5的污染物浓度在影响PM2.5对环境和人体健康的不良影响中起着重要作用,因此对污染大气中细颗粒物(PM2.5)化学成分的分析日益成为一个备受关注的科学和技术问题。采用超声辅助萃取- ICP-MS同时测定PM2.5样品中Be、Al、Cr、Mn、Ni、As、Se、Sb、Tl、Pb、Hg、Cd等12种有毒元素。用标定线性度、精密度和准确度、检出限(LOD)和定量限(LOQ)等参数对方法进行了验证。在已知浓度(5、10和20 μg/L)下,对不同样品添加相应元素的回收率进行了验证,平均回收率在87.3 ~ 101.3%之间。结果表明,该方法是一种精密度、准确度高、低LOD的多元素技术。将该方法应用于中国某城市重度污染居住区大气细颗粒物中12种目标元素的同时测定,结果表明,大气细颗粒物中Al、Pb、Mn含量最高,As、Sb、Cr、Cd、Se、Ni含量次之。超声辅助提取工艺的主要优点是样品处理速度快,提取过程中试剂消耗少。
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引用次数: 1
Evaluating Dairy Manure as Initial Fertility Driver for Mudflat Soil Amendment 评价牛粪作为泥滩土壤改良的初始肥力驱动力
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/4
Yanchao Bai
The mudflats along the East Coast of China can be important alternative sources for arable lands if amended by large amount of organic fertilizers. Rich in organic matter and other nutrients, dairy manure has been considered as the economic choice for an initial fertility driver. Therefore, the goal of this study was to evaluate the impact of dairy manure amendment (DMA) as an initial fertility driver at application rates of 0, 30, 75, 150, and 300 t ha–1 on soil physicochemical properties, biomass and growth of ryegrass (Lolium perenne L.) grown in mudflat soil. The results showed that the DMA decreased soil bulk density in comparison to the unamended soil. The organic matter (OM) content in mudflat soil increased with increasing DMA rates. The salinity of mudflat soil decreased with increasing DMA rates, and the salinity at 30, 75, 150 and 300 t ha–1 DMA rates, corresponded to decreases of 26.1%, 35.8%, 37.8% and 45.4%, compared to 8.63 g kg–1 in the unamended soil. Electric conductivity (EC) of mudflat soil decreased with increasing DMA rate, while cation exchange capacity (CEC) increased duo to DMA. The contents of total N, total P, alkaline N, and available P in mudflat soil increased with increasing DMA rates. The increment of green herbage yield of ryegrass at 210 DAS at 30, 75, 150, and 300 t ha–1 DMA rates were 257.7%, 303.5%, 414.8%, and 516.6%, compared to the unamended soil (p < 0.05). Soil total Cu and Zn increased while total Mn, Ni, and Cr remained unchanged in response to DMA due to the high Cu and Zn content in the dairy manure. However, The DMA increased most of available metals except for Ni. In summary, land application of dairy manure as initial fertility driver could be an effective and safe way to amend mudflat soil, due to the rapid development of soil initial fertility, which enhanced green manure ryegrass (Lolium perenne L.) growth.
中国东部沿海泥滩如果大量施用有机肥,可以成为重要的替代耕地资源。由于富含有机物和其他营养物质,奶牛粪便被认为是最初的生育驱动因素的经济选择。因此,本研究的目的是评价乳粪肥改良剂(DMA)作为初始肥力驱动剂,在0、30、75、150和300 t hm - 1施用量下对生长在泥滩土壤中的黑麦草(Lolium perenne L.)土壤理化性质、生物量和生长的影响。结果表明,与未加改性的土壤相比,加改性后的土壤容重明显降低。泥滩土壤有机质(OM)含量随DMA速率的增加而增加。随着DMA速率的增加,泥滩土壤的盐度呈下降趋势,在DMA速率为30、75、150和300 t ha-1时,泥滩土壤的盐度分别比未处理的8.63 g kg-1降低了26.1%、35.8%、37.8%和45.4%。泥滩土壤电导率(EC)随DMA速率的增加而降低,阳离子交换容量(CEC)随DMA速率的增加而增加。泥滩土壤全氮、全磷、碱氮和速效磷含量随DMA速率的增加而增加。210 DAS条件下黑麦草在30、75、150和300 t ha-1 DMA速率下的绿草产量比未改良土壤分别增加了257.7%、303.5%、414.8%和516.6% (p < 0.05)。由于牛粪中Cu和Zn含量较高,土壤总Cu和Zn增加,而总Mn、Ni和Cr保持不变。然而,DMA增加了除Ni以外的大部分可用金属。综上所述,由于土壤初始肥力的快速发展,促进了绿肥黑麦草(Lolium perenne L.)的生长,乳粪肥作为初始肥力驱动剂的土地施用可能是一种有效且安全的泥滩土壤改良方式。
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引用次数: 1
Hydraulic Fracturing Technology and Environmental Protection 水力压裂技术与环境保护
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/24
Weitao Liu, Xiangxi Meng, Hui Zhang
Hydraulic fracturing technology is an effective means of changing the structure of coal and rock, which is a key issue in solving the technical problem of coal mine. The technology can not only change the structure of the coal and rock mass, reduce the pressure on the hard roof, reduce the concentration of coal dust, protect the working environment, increase the natural ignition cycle, and avoid fire accidents, but can also prevent any residual material from polluting the groundwater and soil during excavation. In this paper, the effects of the water injection parameters and fracture inclination angle on hydraulic fracturing are firstly studied by numerical simulation, before hydraulic fracturing on the hard roof is subjected to a field test. The results show that the cracking effect is obvious, the hard roof pressure and coal dust concentration are reduced.
水力压裂技术是改变煤岩结构的有效手段,是解决煤矿技术难题的关键。该技术不仅可以改变煤岩体结构,降低硬顶板压力,降低煤尘浓度,保护工作环境,增加自然点火周期,避免火灾事故,而且可以防止任何残余物质在开挖过程中污染地下水和土壤。本文首先通过数值模拟研究了注水参数和裂缝倾角对水力压裂的影响,然后对硬顶板进行了水力压裂现场试验。结果表明,该方法的开裂效果明显,降低了顶板硬压和煤尘浓度。
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引用次数: 2
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