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Trace Metals Risk Evaluation and Pollution Identification inSurficial Sediment from the Haikou Bay, South China Sea 南海海口湾表层沉积物痕量金属风险评价及污染识别
Pub Date : 2016-01-01 DOI: 10.12783/issn.1544-8053/13/1/10
Ping Shi, Linglong Cao Jian Xie Haitao Tian Yanhui Zhai Jun Shi
Potential contamination risks and relevance of source identification for fivetrace metals (As, Cd, Cr, Cu, and Pb) from surficial sediments obtained in Haikou Baywere investigated by applying a set of multivariate analysis methods for the first time. Itwas demonstrated that metal concentrations reflecting distribution features for the metalsof interest were slightly higher on the east side than those on the west side. A risk assessmentconclusion revealed potential contamination areas were present in the vicinityof highly intense human development activities. Speciation obtained by an optimizedBCR sequential extraction technique demonstrated that As and Cr were dominated byresidual fraction. However, Pb, Cu, and Cd were mainly composed with non-residualfractions and of high bioavailability indicating these trace metals had significant anthropogenicsources. The relationship between content characteristics and trace metal fractionswas revealed by Pearsons’ correlation analysis. Hierarchical cluster analysis suggestedthat Pb, Cu, and Cd had similar sources relevant to anthropogenic sources andconfirmed by chemical speciation analysis. Results provide a base for the local authorityin the area of interest to monitor long term contribution of trace metals in coastal sedimentsand then apply strategies to address the polluted sediments.
首次应用多变量分析方法,对海口湾表层沉积物中As、Cd、Cr、Cu、Pb 5种微量金属的潜在污染风险及来源鉴定的相关性进行了研究。结果表明,反映感兴趣金属分布特征的金属浓度在东侧略高于西侧。一项风险评估结论显示,在高度密集的人类发展活动附近存在潜在的污染区域。通过优化的bcr序列萃取技术得到的物种形态分析表明,As和Cr以残余组分为主。然而,铅、铜和镉主要由非残留组分组成,具有高生物利用度,表明这些微量金属具有重要的人为来源。通过pearson相关分析揭示了其含量特征与微量金属组分之间的关系。聚类分析表明,Pb、Cu和Cd具有相似的来源,与人为来源有关,并得到化学形态分析的证实。研究结果为相关地区的地方当局监测沿海沉积物中微量金属的长期贡献,进而制定解决污染沉积物的策略提供了基础。
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引用次数: 1
Mechanical Behaviors of High Performance Concrete Beams Prestressed with CFRP Strands 碳纤维布预应力高性能混凝土梁的力学性能
Pub Date : 2016-01-01 DOI: 10.12783/ISSN.1544-8053/13/4/S16
W. Xue, X. H. Wang, R. Zheng
The merits of high performance concrete (HPC) and fiber reinforced polymer (FRP) could be combined for using in the concrete structures to improve the structural mechanical behavior. Six beams cast with HPC and prestressed with Carbon FRP (CFRP) strands were tested and discussed in this paper. Test variables included partial prestressing ratio (PPR) of CFRP strands and material of reinforcements (steel and Glass FRP). Test results indicated that all the beams failed in two modes, i.e., compression failure mode and tension failure mode. The ultimate deflection of all the beams reached 1/70-1/41 of the spans and the ductility coefficients of the steel reinforced beams were higher than 3.5 (except the one with the highest steel reinforcement ratio), indicating good deformability and ductility. An increase in partial prestressing ratio (PPR) had a positive effect on ductility. The ductility of Glass FRP reinforced beam was much lower than that of steel reinforced beams while the deformability was quite similar.
高性能混凝土(HPC)和纤维增强聚合物(FRP)的优点可以结合在混凝土结构中,以改善结构的力学性能。本文对6根高性能混凝土浇筑梁和碳纤维布预应力梁进行了试验和讨论。试验变量包括CFRP股的局部预应力比(PPR)和增强材料(钢和玻璃钢)。试验结果表明,所有梁均以受压破坏和受拉破坏两种破坏模式破坏。所有梁的极限挠度均达到跨度的1/70 ~ 1/41,钢配筋梁的延性系数均大于3.5(除配筋率最高的梁外),具有良好的变形性和延性。局部预应力比(PPR)的增加对延性有积极的影响。玻璃钢加固梁的延性远低于钢加固梁,但其变形能力相当。
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引用次数: 0
Addition of Calcium Compounds Improve the Yield of Hydrogen and Retention of Chromium Metal during the Gasification of Simulated Waste 在模拟废物气化过程中,钙化合物的加入提高了氢的产率和金属铬的保留率
Pub Date : 2016-01-01 DOI: 10.12783/ISSN.1544-8053/13/2/S9
Lin Chiou-Liang, Wu Min-Hao, Hsu Tzu-Pin
This study explored the constituents of syngas and the distribution of chromium metal when different calcium compounds (Ca(NO3)2, CaCO3 and CaO) were used as additives. In this experiment, artificially simulated waste was taken as the biomass for gasification and chromium metal was used as the heavy metal in the simulated waste. The syngas composition, the yield of H2 and the retention of chromium metal were analyzed. Results showed that all the three calcium compounds could increase the proportion of H2, but that there was no significant difference between them. The contents of chromium in the bed materials with different particle size were measured and displayed that the concentrations of chromium were higher in the bed materials with particle diameters above 1.00 mm and below 0.35 mm. Under the operation temperature of 700°C, the calcium compounds retained the highest content of chromium metal, for it evaporated only a little under this low temperature. Therefore, adding calcium compounds into the fluidized bed during the gasification of the waste could enhance the yield of H2 in the syngases and increase the content of retained chromium metal in the sand bed.
本研究考察了不同钙化合物(Ca(NO3)2、CaCO3和CaO)作为添加剂时合成气的组成和金属铬的分布。本实验以人工模拟废弃物为生物质进行气化,以金属铬为模拟废弃物中的重金属。分析了合成气的组成、H2的产率和金属铬的保留率。结果表明,3种钙化合物均能提高H2的比例,但差异不显著。测定了不同粒径床料中铬的含量,结果表明,粒径在1.00 mm以上和0.35 mm以下的床料中铬的含量较高。在700℃的操作温度下,钙化合物中金属铬的含量最高,因为在这个低温下金属铬的蒸发很少。因此,在废物气化过程中,在流化床中添加钙化合物可以提高合成气中H2的产率,增加砂床中金属铬的残留含量。
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引用次数: 0
Optimized Preparation of Directional Modified Attapulgiteand its Application to Adsorbance of Humic Acidin Polluted Raw Water Effluent 定向改性凹凸棒石的优化制备及其对腐植酸污染原水出水的吸附研究
Pub Date : 2016-01-01 DOI: 10.12783/issn.1544-8053/13/1/2
Xian Zou, H. Wang
Natural attapulgite modified using acid activation, heat treatment, and organicmodification was investigated as a humic acid adsorbent and an optimal modificationmethod was confirmed. Results suggest that acid activation should be performedfirst and followed by organic modification. Optimum dosage of modified attapulgite was0.7 g/L and the humic acid removal rate reached 97%. Optimum modification conditionswere as follows: acid concentration at 3 mol/L, sodium chloride concentration at 0.5mol/L, sodium treatment duration was 2 h, modifier amount was 3%, and microwavemodification time was 9 min. Modified attapulgite prepared as such may be beneficial forwater treatment processes.
以天然凹凸棒土为吸附剂,采用酸活化、热处理和有机改性等方法进行了改性研究,确定了最佳改性方法。结果表明,应先进行酸活化,再进行有机改性。改性凹凸棒土的最佳投加量为0.7 g/L,腐植酸去除率达97%。最佳改性条件为:酸浓度为3 mol/L,氯化钠浓度为0.5mol/L,钠处理时间为2 h,改性剂用量为3%,微波改性时间为9 min。由此制备的改性凹凸棒石可用于水处理工艺。
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引用次数: 3
Harmonic Analysis and Detection of Power System based on Double Moment Wavelet Transform 基于双矩小波变换的电力系统谐波分析与检测
Pub Date : 2016-01-01 DOI: 10.1504/ijris.2017.090048
Kangyou Liang, Ling-ling Yuan, Yuhang Tan
The influence of unbalanced installation of single-phase DG unit with harmonic compensation function in three-phase and three-wire public power grid shows that there will be risk for the unbalanced installation to increase the three-phase current of the power grid. In order to overcome this problem, balanced triple-frequency harmonic function is proposed for the purpose of avoiding the increase in three-phase power grid current. In addition, compared with the traditional method, such method is also capable of reducing the rated power of harmonic current compensation. In order to verify the effectiveness of the method proposed, the balance and unbalanced conditions are verified in experiment and the experimental circuit is a simplified system based on actual three-phase three-wire system. In order to avoid the increase in the harmonic current, a balanced third harmonic suppression method is proposed. Finally, performance of the algorithm proposed has been verified through experiment.
具有谐波补偿功能的单相DG机组不平衡安装对三相三线制公共电网的影响表明,不平衡安装会增加电网三相电流的风险。为了克服这一问题,提出了平衡三频谐波函数,以避免三相电网电流的增加。此外,与传统方法相比,该方法还能够降低谐波电流补偿的额定功率。为了验证所提出方法的有效性,在实验中验证了平衡和不平衡条件,实验电路是基于实际三相三线制系统的简化系统。为了避免谐波电流的增加,提出了一种平衡的三次谐波抑制方法。最后,通过实验验证了所提算法的性能。
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引用次数: 0
Separating and Recycling of Fe, Cu, Zn from Dumped Copper Slag by Microwave IrradiationAssisted Carbothermic Method 微波辅助碳热法从倾倒铜渣中分离、回收铁、铜、锌
Pub Date : 2016-01-01 DOI: 10.12783/ISSN.1544-8053/13/2/S22
Yalong Liao, Fei Zhou
Iron, copper and zinc were separated and recycled from dumped copper slag using a carbothermic method in the presence of microwave irradiation. Iron in the form of fayalite and magnetite in the slag was reduced to metal iron while zinc was evaporated and captured as zinc oxide powder. Results indicated that metallization rate of iron could reach 91.38~93.45 wt% and zinc recovery efficiency was 90.5 wt% when the new methodology was employed, and that reaction temperature was 100°C lower compared to that of traditional processes, reaction time of the new process was decreased by 90 min.
采用碳热法在微波照射下对铜渣中的铁、铜、锌进行分离和回收。铁在渣中以铁沸石和磁铁矿的形式还原为金属铁,锌则被蒸发成氧化锌粉。结果表明,新工艺的铁金属化率可达91.38~93.45 wt%,锌回收率为90.5 wt%,反应温度比传统工艺低100℃,反应时间缩短90 min。
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引用次数: 8
A Case Study on Utilization of 50-year-old Concrete in Recycled Aggregate 50年混凝土在再生骨料中的应用实例研究
Pub Date : 2016-01-01 DOI: 10.12783/ISSN.1544-8053/13/4/S19
Zongping Chen, Jinjun Xu, Yuliang Chen, Chenggui Jing
This paper investigates some mechanical properties of recycled aggregate concrete (RAC) with 50-year-old recycled coarse aggregate (RCA), and theoretically analyzes the corresponding RAC stress-strain curves relative to those of normal aggregate concrete. Concrete prism specimens, including 66 standard prisms and 33 nonstandard ones, were fabricated and tested through 11 groups of RCA replacement ratios from 0% to 100% with an interval of 10%. On this basis, the standard prism compressive strength at ages of 28 days and two years, the flexural strength of the nonstandard prism, the cube strength after flexural test and the strain at the maximum standard prism compressive stress for 28 days, as well as Poisson’s ratio of the standard prisms for two years was investigated. Finally, analytical expressions were proposed for predicting the peak strain, the stress-strain curves of RAC and the strength conversion relationships.
研究了使用50年再生粗骨料的再生骨料混凝土(RAC)的一些力学性能,并相对于普通骨料混凝土的应力-应变曲线进行了理论分析。通过11组RCA替换率为0% ~ 100%,间隔为10%的RCA替换率,制作混凝土棱镜试件66个,其中标准棱镜试件和非标准棱镜试件33个。在此基础上,研究了标准棱柱在28天和2年时的抗压强度、非标准棱柱的抗折强度、标准棱柱在28天最大压应力下的立方体抗折强度和应变,以及标准棱柱在2年时的泊松比。最后,提出了预测RAC峰值应变、应力-应变曲线及强度转换关系的解析表达式。
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引用次数: 2
Removal of Toxic Organic Pollutants from Coke Plant Wastewater by UV-Fenton UV-Fenton去除焦化废水中有毒有机污染物的研究
Pub Date : 2016-01-01 DOI: 10.12783/ISSN.1544-8053/13/2/S20
Yangyang Liang, Suqin Li, Bin Li
Coke plant wastewater containing lots of toxic organic pollutants should be treated before being discharged into the environment. It is challenging to treat toxic and refractory compounds using conventional methods. In this study, a UV-Fenton technology was investigated. When the initial COD, NH3-N concentration and SS of wastewater were 5080 mg/L, 329.9 mg/L, and 847.7 mg/L, results showed that the removal rate of COD, NH3-N and SS were 88.0%, 58.4% and 99.2% respectively under the optimal reaction conditions. Under the identified optimal condition, H2O2 concentration is 75 mmol/L, the concentration ratio of H2O2 and Fe2+ is 3:1, and original pH is 4 within 30 min. GC-MS analysis, revealed that organic substances such as indole and quinoline were degraded effectually.
焦化废水中含有大量的有毒有机污染物,在排放到环境中之前必须进行处理。使用传统方法处理有毒和难熔化合物具有挑战性。本研究对UV-Fenton技术进行了研究。当初始COD、NH3-N和SS浓度分别为5080 mg/L、329.9 mg/L和847.7 mg/L时,在最佳反应条件下,COD、NH3-N和SS的去除率分别为88.0%、58.4%和99.2%。在确定的最优条件下,H2O2浓度为75 mmol/L, H2O2与Fe2+的浓度比为3:1,初始pH为4,30 min内可有效降解吲哚和喹啉等有机物。
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引用次数: 2
Biosolids Application for Barley Production 生物固体在大麦生产中的应用
Pub Date : 2016-01-01 DOI: 10.12783/ISSN.1544-8053/13/2/9
A. Tamimi, B. Athamneh, C. Gerba, W. Suleiman
Biosolids with different loading rates were applied to soil planted with rainfedbarley to study the effects of applying biosolids on soil and on barley’s straws andgrains yield. Randomized Complete Block experimental design was employed with 5treatments. This included a control and four replicates to test the null hypothesis whichstates that there is no significant difference between treatment means on crop and soilparameters vs. the research hypothesis which states applying biosolids to land plantedwith rain-fed barley affects both soil and crop parameters. Biosolids loading rates were0 as a control, 2, 4, 6, and 8 metric tons/ha. Soil at the testing site had a high clay content in the sub-soil and relatively lower claycontent on the surface, probably due to wind erosion. The soil was slightly calcareouswith lime content increasing with depth and with a slight alkalinity. Organic matter andphosphorus contents of soil were low with colors that varied from reddish brown to yellowishbrown. At harvesting time, there was no significant differences in grain yields at different biosolidsloading rates with a p-value of 0.52. Average grain yields of 2.86, 3.37, 3.4, 3.57,and 3.20 tons/ha were measured at biosolids loading rates of 0, 2, 4, 6, and 8 tons/ha,respectively. Average grain yield of 3.00 for a recommended inorganic fertilizer rate of diammoniumphosphate and Urea traditionally applied at rates of 90 kg/ha and 20 kg/ha,respectively, showed a yield higher than the 0 biosolids loading rate. However, it waslower than all other biosolids loading rates. It was determined that applying biosolids to soils planted with rain-fed barley significantlyincreased straw yield and straw protein content. No significant increase in grainyield or in grain protein content was measured. It was also determined that a statisticalsignificant decrease in the thousand grain weight occurs as biosolids loading rates increasedwith a p-value < 0.000001. This has negative effects on barley’s grain quality.No significant increase in heavy metals in the crop or the soil was observed in thebiosolids treated plots. However, increases in soil organic carbon, total Kjeldahl nitrogenand salt concentrations were increased with increasing biosolids loading rates. The null hypothesis tested in this study showed that applying biosolids to soils plantedwith rain-fed barley had positive effects on the crop with no effects on the soil in comparisonwith no application of biosolids and the application of inorganic fertilizer.
在旱作大麦土壤中施用不同负荷率的生物固体,研究施用生物固体对土壤和大麦秸秆及籽粒产量的影响。采用随机完全区组试验设计,共5个处理。这包括一个对照和四个重复来检验零假设,零假设表明,在作物和土壤参数的处理方式与研究假设之间没有显著差异,研究假设表明,在种植雨养大麦的土地上施用生物固体会影响土壤和作物参数。生物固体负荷率分别为0、2、4、6和8公吨/公顷。试验场地土壤的底土粘土含量较高,地表粘土含量相对较低,可能是风蚀所致。土壤微钙化,石灰含量随深度增加而增加,呈微碱性。土壤有机质和磷含量较低,颜色从红棕色到黄褐色不等。在收获期,不同生物固体负荷速率对籽粒产量无显著影响,p值为0.52。在生物固体负荷量为0、2、4、6和8吨/公顷时,平均粮食产量分别为2.86、3.37、3.4、3.57和3.20吨/公顷。在推荐的无机肥料用量为磷酸二铵和尿素的情况下,平均产量为3.00,传统上分别施用90公斤/公顷和20公斤/公顷,产量高于0生物固体负荷率。然而,它比所有其他生物固体的装载率都要低。结果表明,在雨养大麦土壤中施用生物固形物可显著提高秸秆产量和秸秆蛋白质含量。籽粒产量和籽粒蛋白质含量没有显著增加。还确定,随着生物固体加载率的增加,千粒重出现统计学上显著的下降,p值< 0.000001。这对大麦的籽粒品质有负面影响。在生物固体处理的地块中,作物或土壤中的重金属没有显著增加。土壤有机碳、总凯氏定氮和总盐浓度随生物固体负荷率的增加而增加。本研究检验的原假设表明,与不施用生物固体和施用无机肥料相比,在雨养大麦的土壤中施用生物固体对作物有积极影响,对土壤没有影响。
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引用次数: 1
Systematic Approach to Identifying Economically Feasible and Environmentally Benign Methods of Recycling Ash on a Regional Scale 在区域范围内确定经济可行和环境友好的灰回收方法的系统方法
Pub Date : 2016-01-01 DOI: 10.12783/ISSN.1544-8053/13/3/2
I. Deviatkin, J. Havukainen, M. Horttanainen
This study systematically assessed and compared four ash recycling possibilities, namely forest fertilization, landfill construction, road construction, and road stabilization through the use of cost-benefit analysis and life cycle assessment methods. The results indicated that forest fertilization with ash was the most economically attractive method with a 60% increase in the net present value compared to ash landfilling, while reducing the environmental impact by 0.3%. On the contrary, road construction with ash resulted in a 13% reduction in the environmental impact and an increase in net present value of 25%. Landfill construction with ash was overall the least attractive proposition.
本研究采用成本效益分析和生命周期评价方法,系统评价和比较了森林施肥、填埋、筑路和筑路4种灰资源化可能性。结果表明,森林灰施肥是最具经济吸引力的方法,与灰填埋相比,净现值增加60%,同时减少0.3%的环境影响。相反,使用灰的道路建设对环境的影响减少了13%,净现值增加了25%。总的来说,用灰建造垃圾填埋场是最不吸引人的提议。
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引用次数: 4
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Journal of Residuals Science & Technology
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