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High-Strength Solidification of Fly Ash/Carbide Slag and Its Fixing Ability for Heavy Metals 粉煤灰/电石渣高强度凝固及其对重金属的固结能力
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/19
Huiping Song, Y. Wei, F. Cheng
Hydrothermal hot-pressing will occur between silica in fly ash and calcium in carbide slag and give rise to high-strength hydrates. High-strength solidified specimens were prepared with fly ash and carbide slag via hydrothermal hot-pressing at 200°C and 7 MPa. The effect of concentration of activator and content of carbide slag on compressive strength of the specimens was analyzed. It was found that when the mass ratio of fly ash to carbide slag was 1:1 and 20% 5 mol/L NaOH solution was added, the solidified specimens contained a large amount of cross-linked fibrous tobermorite with compressive strength of 70.93 MPa. The solidified specimens had a good fixation effect on such heavy metals as Cu, Zn, Cd and Pb. Hydrothermal hot-pressing, featured by simple procedures, easy automation and low cost, is an ideal potential way of utilizing fly ash and carbide slag and fixation of heavy metals.
粉煤灰中的二氧化硅与电石渣中的钙发生水热热压反应,生成高强度水合物。以粉煤灰和电石渣为原料,在200℃、7 MPa条件下进行水热压,制备了高强固化试样。分析了活化剂浓度和电石渣含量对试样抗压强度的影响。研究发现,当粉煤灰与电石渣的质量比为1:1,并添加20%的5 mol/L NaOH溶液时,固化试样中含有大量交联纤维状托贝莫来石,抗压强度为70.93 MPa。固化试样对Cu、Zn、Cd、Pb等重金属具有良好的固定效果。水热热压具有操作简单、自动化程度高、成本低等特点,是一种理想的、有潜力的粉煤灰、电石渣资源化和重金属固溶方法。
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引用次数: 2
Multiple Solution and Aging Treatment Technology Improves Microstructures and Properties of Ti53 Alloy 多次固溶时效处理技术改善了Ti53合金的组织和性能
Pub Date : 2017-01-01 DOI: 10.12783/issn.1544-8053/14/1/42
Wang Huigai, Zhang Keke, Z. Jianxin
The effect of multiple solution and aging treatment on microstructures and room-mechanical properties of Ti-53 alloy is studied by OM, SEM and universal material testing machine. The results show that the quantity of secondary α lamella, hardness, strength, and plasticity of Ti-53 alloy decrease after the peak value with the cycling times of multiple solution and aging treatment increasing. In the process of double solid solution aging treatment, the numerical values of room-mechanical properties reached the highest level. Multiple solution and aging treatment modulates morphology effectively, which can make martensite lamellas with different Berlese’s vectors merge or decompose. Therefore, the excellent match of strength and plasticity can be obtained.
采用OM、SEM和万能材料试验机研究了多次固溶和时效处理对Ti-53合金组织和室内力学性能的影响。结果表明:随着多次固溶和时效处理次数的增加,Ti-53合金的次生α片层数量、硬度、强度和塑性均在峰值后下降;在双固溶时效处理过程中,室内力学性能数值达到最高水平。多次固溶和时效处理能有效调节马氏体的形态,使具有不同Berlese矢量的马氏体片层合并或分解。因此,可以获得强度和塑性的良好匹配。
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引用次数: 0
Comprehensive Characterization of Grounded Bottom Ash from Indian Thermal Power Plant 印度火电厂底灰接地的综合表征
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/1
G. Singh, S. Kumar, Kaushal Kumar
In present work, an attempt has been made to improve the quality of bottom ash for utilization as a pozzolanic material. All samples were crushed and passed through 250 µm sieve to prepare grounded bottom ash. The physio-chemical, mineral and leaching characteristics of original and grounded bottom ash were studied. Results show that specific gravity and bulk density of all sample increases whereas porosity, water holding capacity and loss of ignition decreases after the grounding the bottom ash. Pozzolanic properties of bottom ash also improved after grounding the ash samples which helps to commercialize its utilization and reduce environmental impact.
在目前的工作中,试图提高底灰的质量,使其成为一种火山灰材料。所有样品粉碎后通过250µm筛,得到磨碎的底灰。研究了原始底灰和磨碎底灰的理化、矿物和浸出特性。结果表明:底灰接地后,试样的比重和容重均有所增加,孔隙率、持水量和燃失量均有所降低;灰样磨后底灰的火山灰性质得到改善,有利于其商业化利用,减少对环境的影响。
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引用次数: 13
The Preparation and the Release Properties of Nanometer Titanium Dioxide 纳米二氧化钛的制备及其释放性能研究
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/41
Yong-guang Bi, Bing Liu, Xueming Liu
Nano titanium dioxide (TiO2) was synthesized by using butyl titanium as raw material with sol-gel method and assisted with ultrasound. The products were characterized by X-Ray diffraction (XRD), Fourier transform infrared spectrophotometry (FTIR). The effects of hydrothermal temperature, ultrasonic time, ultrasonic power and acetic acid dosage were all investigated, and the optimal conditions for the crystal of nano TiO2 were acid dosage 8 mL, temperature at 40°C, extration time 50 min and the ultrasonic power 240 W. A series of drug release experiments were employed in vitro, we found that the maximum drug loading rate reached 67.30%. The results reveal that nano TiO2 is a promising biomedical nanomaterial in the application of drug loading system.
以丁钛为原料,在超声辅助下,采用溶胶-凝胶法制备了纳米二氧化钛(TiO2)。采用x射线衍射(XRD)、傅里叶变换红外分光光度(FTIR)对产物进行了表征。考察了水热温度、超声时间、超声功率和乙酸用量对纳米TiO2结晶的影响,得出最佳工艺条件为酸用量8 mL、温度40℃、提取时间50 min、超声功率240 W。通过一系列体外释药实验,发现其最大载药率可达67.30%。结果表明,纳米TiO2是一种极具应用前景的生物医学纳米材料。
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引用次数: 1
Uncertainty Analysis for Evaluating CH4 Emission from Solid Waste Landfill of Hefei City Based on Monte Carlo Method 基于蒙特卡罗法评价合肥市垃圾填埋场CH4排放的不确定性分析
Pub Date : 2017-01-01 DOI: 10.12783/issn.1544-8053/14/1/7
Guang-sheng Chen, Xinhai Li Yukun Xu Lifeng Jiao, Rong Hu
It is an important content to analyze the uncertainty of emission from greenhouse gases in compiling the emission inventory. Reliable uncertainty estimates can also be used to increase the quality of emission inventories. This paper took the emission of CH4 from the solid waste landfill in Hefei City in 2014 as an example, and employed the mass balance method to compute its emission. Monte Carlo method was used to carry out the sensitivity analysis and compute uncertainty. Through computing, 95% confidence interval of CH4 emission from landfill in Hefei City was (1.89~3.40) × 104 t. The mean value was 2.61 × 104 t with uncertainty range of –27.59%~30.27%. Among all the parameters, the decomposable proportion of DOC (DOCf ) showed the greatest impact on the emission of CH4 from the landfill and its contribution to emission result was 26.33%. Followed by the degradable organic carbon (DOC) was 26.29%, the amount of solid waste (MSW) was 13.63%, methane correction factor (MCF) was 6.93% and the proportion of methane in landfill gas (F) was 6.58%. The results showed that compared with traditional error propagation method, it improved the accuracy and quality of assessment and provided a scientific basis to improve the quality of inventory as well.
温室气体排放不确定性分析是编制温室气体排放清单的重要内容。可靠的不确定性估计也可用于提高排放清单的质量。本文以合肥市2014年固体垃圾填埋场CH4排放量为例,采用质量平衡法计算其排放量。采用蒙特卡罗方法进行灵敏度分析,计算不确定度。计算得出合肥市垃圾填埋场CH4排放量的95%置信区间为(1.89~3.40)× 104 t,平均值为2.61 × 104 t,不确定度范围为-27.59% ~30.27%。在所有参数中,DOC的可分解比例(DOCf)对填埋场CH4排放的影响最大,对排放结果的贡献率为26.33%。其次是可降解有机碳(DOC)为26.29%,固体废物(MSW)为13.63%,甲烷校正系数(MCF)为6.93%,填埋气中甲烷的比例(F)为6.58%。结果表明,与传统的误差传播法相比,该方法提高了评估的准确性和质量,为提高库存质量提供了科学依据。
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引用次数: 0
Heavy Metals in Soil and Sugarcane Accumulation in Agricultural Area along Huanjiang River in Guangxi, China 广西环江农区土壤重金属含量与甘蔗积累
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/18
Xiao-Fei Wang, G. Deng, Juan Yin
Heavy metal contaminations to farmland soil is a common threaten to crop yield and food safety, phytoremediation with economic plants with high bio-accumulation is a sustainable approach to recover polluted farmland. As a high ethanol yield crop, sugarcane has attracted increasing industrial interest as a raw material for biofuel and the risk of heavy metal in it is negligible if the sugar produced is to be fermented into ethanol rather than by consumed. This study is to do a preliminary investigation if sugarcane is a suitable crop for phytoremediation in heavy metal polluted farmland in a context of geographic conditions in southern China, thirty-eight soil and sugarcane samples were collected in five villages in a typical agricultural county called Huangjiang which is located in the Huanjiang River Basin in Guangxi province. Sugarcane is widely cultivated in Huangjiang as one of the major economic crops, meanwhile, pollutions induced by mining and ore-extraction in this area has resulted in heavy metals entering the farmland soils. Samples collected were used to assess the correlation of the level of heavy metals in the soil, and their concentrations in roots, sections of stems and leaves. Seven heavy metals were selected in this study and the results showed that most of the toxic heavy metals intake by sugarcane accumulated in the roots, while only a small portion is transferred to the stems and leaves. The study initially outlined sugarcane as a potential candidate for phytoremediation in farmland polluted by heavy metals with economic motivate in this subtropical geographical background.
农田土壤重金属污染是危害农作物产量和食品安全的常见威胁,利用具有高生物积累性的经济植物进行植物修复是恢复受污染农田的可持续途径。作为一种高乙醇产量的作物,甘蔗作为生物燃料的原料引起了越来越多的工业兴趣,如果生产的糖是发酵成乙醇而不是食用,那么其中重金属的风险可以忽略不计。为了初步探讨在中国南方地理条件下甘蔗是否适合作为重金属污染农田植物修复的作物,本研究在广西环江流域典型农业县黄江的5个村庄采集了38个土壤和甘蔗样本。甘蔗是黄江地区广泛种植的主要经济作物之一,同时该地区因采矿和采矿业的污染导致重金属进入农田土壤。收集的样本被用来评估土壤中重金属水平及其在根、茎和叶中的浓度之间的相关性。本研究选取了7种重金属,结果表明,甘蔗摄入的有毒重金属大部分在根系积累,只有一小部分转移到茎叶。该研究初步概述了在亚热带地理背景下,甘蔗作为植物修复重金属污染农田的潜在候选作物具有经济效益。
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引用次数: 5
Phytoremediation of PAHs-contaminated Sludge in a Constructed Wetland 人工湿地中多环芳烃污染污泥的植物修复研究
Pub Date : 2017-01-01 DOI: 10.12783/issn.1544-8053/14/1/14
Yubo Cui, Hongjie Sun Jinbao Zhao Shiquan Wang, Zhaobo Chen
Wastewater sludge from metropolitan areas has become a source of polycyclic aromatic hydrocarbons (PAHs), and may result in pollution of soils and plants if applied to agricultural areas. It is important to stabilize wastewater sludge before its application to agricultural land. Constructed wetlands (CWs) have been widely applied for stabilization of sludge. In CWs, plants, especially reeds, promote degradation of pollutants in the rhizosphere and are the principal mechanisms for PAH-contaminated sludge phytoremediation. We studied PAH removal in sludge planted with Phragmites australis (common reeds) in onsite experiments over a 3-year period comprising 2 years of sludge application and 1 year of resting. The average PAH content in the feeder sludge was 5.7 mg kg–1 (DW), consisting of approximately 48% low-molecular-weight (2–3 ring) PAHs, 27% middle-molecular-weight (4 ring) PAHs and 25% high-molecular-weight (5–6 ring) PAHs. After 3 years, the average PAH content in stabilized sludge was 2.1 mg kg–1 (DW), which was lower than that of the feeder sludge. Overall, about 66% of low-molecular-weight PAHs (dominant type), 57% of middle-molecular-weight PAHs and 32% of high-molecular-weight PAHs were removed from the stabilized sludge. Additionally, there were spatial variations in PAHs in stabilized sludge, with PAHs being highest in the surface layer (12–14 cm) sludge, lower in the middle layer (6–8 cm) and lowest in the bottom layer (0–2 cm).
废水污泥从大城市已经成为一种多环芳烃(多环芳烃)的来源,并可能导致污染的土壤和植物如果应用于农业领域。污水污泥在农用地上应用前,对其进行稳定处理是十分重要的。人工湿地在污泥稳定方面得到了广泛的应用。在化粪池中,植物,特别是芦苇,促进根际污染物的降解,是多环芳烃污染污泥植物修复的主要机制。我们在为期3年的现场实验中研究了芦苇(芦苇)种植的污泥中多环芳烃的去除,其中包括2年的污泥施用和1年的休息。给料污泥中多环芳烃的平均含量为5.7 mg kg-1 (DW),其中低分子量(2-3环)多环芳烃约占48%,中等分子量(4环)多环芳烃约占27%,高分子量(5-6环)多环芳烃约占25%。3年后,稳定污泥中PAH的平均含量为2.1 mg kg-1 (DW),低于给料污泥。总的来说,大约66%的低分子量多环芳烃(主要类型)middle-molecular-weight多环芳烃的57%和32%的高分子量多环芳烃从稳定污泥被移除。稳定污泥中多环芳烃含量存在空间差异,表层(12 ~ 14 cm)污泥中多环芳烃含量最高,中层(6 ~ 8 cm)较低,底层(0 ~ 2 cm)最低。
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引用次数: 0
Preparation of the Oriented Polycrystalline BaTi2O5 Ferroelectric Ceramics 定向多晶BaTi2O5铁电陶瓷的制备
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/34
Chunyang Li, Guojun Li, R. Ren
The dense and oriented BaTi2O5 (BT2) in a single phase was successfully obtained by an arc melting process on a water-cooled copper plate using BaCO3 and TiO2 as starting materials and B2O3 as an additive. XRD pattern of BT2 showed a preferred orientation of (020). The microstructure of BT2 was examined to show a needle-like shape and the BT2 grains were 3~15 µm in diameters and 22~110 µm in lengths. Though B2O3 was effective to prepare dense BT2, it, disadvantageously, tended to decrease the permittivity of BT2. The discrepancy of the peak frequencies between Z″ and M″ could be ascribed to the existence of structural defects and occurrence of the second phase. The maximum permittivity was 863 when the frequency (f) and the Curie temperature (Tc) were 100 kHz and 465°C, respectively.
以BaCO3和TiO2为原料,B2O3为添加剂,在水冷铜板上采用电弧熔融法制备了致密取向的单相BaTi2O5 (BT2)。BT2的XRD谱图显示其优先取向为(020)。BT2的显微组织为针状,晶粒直径为3~15µm,长度为22~110µm。B2O3虽能有效制备致密的BT2,但不利于BT2介电常数的降低。Z″和M″之间的峰值频率差异可以归因于结构缺陷的存在和第二相的发生。当频率(f)为100 kHz,居里温度(Tc)为465℃时,其最大介电常数为863。
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引用次数: 0
Effects of C/N Ratio on Nitrate Removal from PU Synthetic Leather Wastewater Treated by Anoxic Moving Bed Bio-film Reactors C/N对缺氧移动床生物膜反应器处理PU合成革废水中硝酸盐去除的影响
Pub Date : 2017-01-01 DOI: 10.12783/issn.1544-8053/14/1/35
Yuanhong Ding, Jun Zhou Hongqiang Ren Yang Song Qing Wang, Y. Yang
One sample of PU synthetic wastewater was analyzed, its Total Nitrogen (TN) was mainly composed of about 300 mg/L nitrate, and three pieces of anoxic Moving Bed Bio-film Reactors (MBBR) were applied to treat it, one MBBR was run with raw wastewater, the second and third were with synthetic wastewater, and the results were as followings: TN could be removed off completely under the condition of relative low C/N ratio; the C/N ratio of removed pollutants was liner correlation with C/N ratio of influent, but the C/N ratio of effluent was increase violently, the above results demonstrated that, the external carbon source, necessary to the heterotrophic bacteria, was consumed more rapidly than nitrate nitrogen in initial denitrifying stage, then the nitrogen was utilized much more rapidly at later stage, and the ratio of C/N denitrification behaved as a chamfer linear.
对某PU合成废水样品进行了分析,发现其总氮(TN)主要由约300 mg/L的硝酸盐组成,采用3台缺氧移动床生物膜反应器(MBBR)进行处理,1台MBBR运行原液,2台和3台MBBR运行合成废水,结果表明:在较低的C/N比条件下,TN可以完全去除;去除污染物的C/N比与进水C/N比呈线性相关,但出水C/N比急剧增加,说明异养菌必需的外部碳源在反硝化初期消耗快于硝态氮,后期利用快于硝态氮,C/N反硝化比呈倒角线性。
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引用次数: 0
Experimental Study and Numerical Modeling of Erosion-corrosion of J55 Steel in Brine of Huanghe (Yellow) River Valley J55钢在黄河流域卤水中的冲蚀腐蚀试验研究与数值模拟
Pub Date : 2017-01-01 DOI: 10.12783/ISSN.1544-8053/14/1/28
Da-jun Zhao, Sun Zihang, Yan Zhao, Xiaoshu Lü, Xianfeng Tan
Fluid field can have significant effects on corrosion rates of steels. The objective of this paper is to investigate erosion-corrosion mechanisms of J55 steel and the effects of local hydrodynamic factors, in particular, the fluid flow velocity on J55 steel’s service life. A new experimental setup was developed to specifically simulate the actual hydrodynamic conditions of Huanghe (Yellow) River valley. Computational fluid dynamics (CFD) model was adopted to characterize the hydrodynamic factors, such as the flow rate, the turbulence kinetic energy and the shear stress, and their effects on the corrosion behavior of J55 steel. Corrosion morphology was analyzed. Results show that the erosion rate increased with the flow rate and the resulting corrosion pit became smaller and deeper. Through the research results of this paper, it could provide some technical supports for the scientific and rational exploitation of brine.
流体场对钢的腐蚀速率有显著影响。本文的目的是研究J55钢的冲蚀-腐蚀机理以及局部水动力因素,特别是流体流速对J55钢使用寿命的影响。建立了一种新的实验装置,专门模拟黄河流域的实际水动力条件。采用计算流体动力学(CFD)模型对流量、湍流动能和剪切应力等流体动力因素对J55钢腐蚀行为的影响进行了表征。分析了腐蚀形貌。结果表明:腐蚀速率随流量增大而增大,腐蚀坑越小越深;通过本文的研究成果,可以为科学合理地开采卤水提供一定的技术支持。
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引用次数: 0
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Journal of Residuals Science & Technology
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