Journal of the American Oil Chemists Society最新文献

The main biofuels produced on an industrial large scale are biodiesel and ethanol, which are the most economically viable and widely implemented solutions to replace conventional fossil fuels from a greener and more sustainable perspective. In such a scenario, there is an opportunity to produce fully renewable biodiesel using ethanol instead of methanol, which is mainly derived from fossil resources. In this paper, near-infrared (NIR) spectroscopy was used to discriminate biodiesel/diesel (B7) blends regarding the synthesis route and oil feedstock of biodiesels simultaneously. Data-Driven Soft Independent Modeling of Class Analogy (DD-SIMCA) authenticated correctly all ethyl B7 (target) samples into the acceptance area, while rejected all non-target samples, implying in an efficiency of 100%. Additionally, Partial Least Squares-Discriminant Analysis coupled with interval selection by the Successive Projections Algorithm (iSPA-PLS-DA) discriminated all ethyl B7 samples correctly, considering cottonseed, sunflower, and soybean as oil feedstocks. Moreover, only one ethyl cottonseed B7 sample was incorrectly discriminated when methyl B7 samples from the same three oil feedstocks were included in the model. As advantages, the proposed analytical methodology contributes to the United Nations' Sustainable Development Goal (SDG) #7 (affordable and clean energy) as well as aligns with the principles of Green Analytical Chemistry.

Crude palm oil (CPO) is highly abundant in carotenoids. Previous findings found that dry fractionation can concentrate carotenoids from CPO but resulted in a significant loss of carotenoids. Therefore, the present study aimed to utilize solvent fractionation, which offers a better separation efficiency, to concentrate carotenoids from CPO with improved recovery. Computational study revealed a high binding affinity of phytonutrient towards unsaturated triacylglycerols (TAGs) species in olein fraction due to similar polarity. This prediction was further verified with evidence showing strong, positive correlation between the iodine value and carotenoids concentrations of fractionated oil. The difference in binding affinity of saturated and unsaturated TAG towards different solvents can be used as a guide for screening and selection of solvent suitable for recovery of phytonutrient during solvent fractionation. Subsequently, a lab-scale single- stage fractionation study disclosed that crystallization temperature of 15°C, oil to acetone ratio of 1:5 (w/v) for 4 h under agitation at 100 rpm produced olein with the highest carotenoid concentration (637 ppm) and recovery (94%). Subsequent double-stage fractionation successfully concentrated the carotenoids up to 125% with a recovery of >93%. Conclusively, solvent fractionation provides an effective way to concentrate valuable carotenoids from CPO while minimizing the lost.

Oilseeds are grown mainly for their oil content but the residues (meals) that remain after defatting are excellent sources of plant protein ingredients. However, to serve as useful ingredients, the extracted proteins must meet industry expectations in terms of functional performance. Protein functionality is influenced by structural conformation, amino acid composition, type of polypeptides, presence of non-protein materials (carbohydrates, lipids, and polyphenols), which in turn can be modified by the extraction method. Defatted oilseed meals are extracted mostly through the pH shift method, which involves alkaline solubilization followed by acid-induced protein precipitation at the isoelectric point. A less popular method is called the protein micellar mass whereby the oilseed meal proteins are extracted with a NaCl solution, which is later diluted to reduce the ionic strength to a level where the proteins are no longer soluble and hence precipitate. A third method utilizes carbohydrases and phytases to first digest non-protein materials from the oilseed meal into smaller units that are then removed by membrane ultrafiltration to leave behind a protein-rich extract. These methods produce mainly two types of isolated oilseed proteins, concentrates (60%–89% protein content) and isolates (≥90% protein content), which can differ in terms of their protein conformation, solubility, and functionality as food ingredients. Therefore, this review provides an overview of the extraction and isolation as well as structural and functional properties of soybean, peanut, canola, hemp seed, sunflower, and sesame seed proteins.

Three oleogelator molecules (Triacontane (TC), Stearic acid (SA), and Behenyl Lignocerate (BL)) were studied individually, in pairs, or all together to make an oleogel using triolein as the oil. WAXS, SAXS and USAXS were used to elucidate the solid structures from angstroms to a few micrometers. A two-dimensional mapping of atomic positions for each molecule was carried out to understand the crystalline multilayer structures formed. We assumed that the molecules were rigidly extended and that they underwent no significant (hindered) rotations so that the free energy is determined by the Lennard-Jones interactions of closely packed multilayers. TC molecules were predicted to form a tilt angle of $��{\theta }_t�\approx �33�°�$, yielding a SAXS line at $��q�\approx �0.194�$ Å^─1, in acceptable agreement with the measured $��q�=�0.181��{\AA }^{�-�1�}�$. For SA crystals $��{\theta }_t�\approx �33�°�$ (predicted) yielding a SAXS line at $��q�=�0.150��{\AA }^{�-�1�}�$ compared to $��q�=�0.159��{\AA }^{�-�1�}�$ (observed). No mixed crystals were observed for any pair of molecules or when all three were used. USAXS data showed that SA forms large nanocrystals compared to TC and BL. All three combinations of molecular pairs showed basic scatterers smaller or similar to those of individual mo

Nonthermal plasma (NTP), for the first time, was integrated in glycerol dehydration reaction catalyzed by silicotungstic acid supported on mesoporous silica with argon as the carrier and discharge gas. A range of reaction temperatures (220–320°C) and NTP discharge field strengths (2.06–6.87 kV/cm) were studied for the individual and interactive effects regarding the glycerol conversion and product selectivity. Results showed that the presence of NTP always improved the glycerol conversion, and NTP increased acrolein selectivity if properly conditioned. An optimal condition of 275°C and 4.58 kV/cm NTP field strength achieved a glycerol conversion of 94.4 mol%, acrolein selectivity of 88.0 mol%, with an acrolein yield of 83.1 mol%, representing a 10% improvement in acrolein production over that conducted at the same temperature but without NTP. Results of this study will also have significant implication for other heterogeneously catalyzed dehydration reactions. Simulation of the high-voltage electric field distribution as function of NTP electrical conductivity and relative permittivity of catalyst materials also offers insight for the future design of reactors and catalysts.

Alpha-linolenic acid and antioxidant substances (such as tocopherols and polyphenols) are abundant in chia seed oil, which may prevent certain chronic diseases. This study compared the physicochemical parameters, chemical composition and antioxidant properties of black and white chia seed oil extracted by solvent extraction, pressing and supercritical CO₂ extraction. Chia seed oil contained higher levels of polyunsaturated fatty acids, including linoleic acid (18.68%–20.15%) and α-linolenic acid (60.47%–63.68%). Black and white chia seeds and processing methods had significant effects on minor components (tocopherols, total phenols, phytosterols and squalene), oxidative stability and free radical scavenging ability. Compared with other methods, the contents of tocopherols (512.72–603.04 mg/kg), total phenols (35.21–57.75 mgGAE/kg) and phytosterols (5536.69–5956.65 mg/kg) were higher in the pressing method. In addition, 17 individual polyphenols were identified and quantified, among which genistein and gallic acid had higher contents, which were significantly affected by varieties and processing methods. In general, the pressing process may be the best processing method to improve minor components and antioxidant capacity. This study can provide a valuable reference for producing functional foods supplemented with α-linolenic acid.

This paper describes the composition and quality characteristics of the “Moroccan Picholine” virgin olive oil (VOO) produced in Taza province (northern Morocco). Legal quality indices, pigments, total phenols, oxidative stability, and fatty acid composition were analyzed under the impact of three extraction systems (two phase [C2] and three phase [C3] centrifugation decanters and super-pressure [SP]) in three production sites (Bni Frassen, Bouchfaa, and Taza) during three consecutive crop seasons (2014, 2015, and 2016). All the assessed parameters were largely affected by the extraction system. Indeed, the two phase centrifugation system provided the better quality of VOO with the lowest values of free fatty acids and oxidation indices and the highest amounts of oleic acid, carotenoids, and total phenols therefore the greatest oxidative stability. Crop season and production site had only significant impacts on some parameters. VOO produced in 2015 from Bni Frassen was richer on total phenols hence presented lower values of peroxide value. Principal component analysis (PCA) showed a clear separation along PC1 (58%) between C2 with better VOO characteristics from both C3 and SP, while PC2 (11%) allowed a net distinction of VOO produced in 2014 from those in 2015 and 2016. Moreover, the oxidative stability of the assessed VOO was found strongly related to total phenol and carotenoid contents as well as oleic/linoleic ratio.