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The Diurnal Variations of Ozone at Different Altitudes on a Rural Mountain in the Eastern United States 美国东部农村山区不同高度臭氧的日变化
Pub Date : 1987-01-01 DOI: 10.1080/08940630.1987.10466199
G. Wolff, P. Lioy, R. Taylor
Because O/sub 3/ has been mentioned as a possible contributor to the decline of forests at high altitudes in Europe and in the U.S., it is important to understand the diurnal behavior of ozone at higher altitudes. The data collected in this study, conducted on a 550-m mountain near the common border of New Jersey, New York, and Pennsylvania, show that daily maximum ozone concentrations and mid-day concentrations are similar at different altitudes but the ozone dosages increase with height. The lower the site, the more time the site is below the nocturnal inversion layer where the ozone is rapidly depleted. A site located at 500 m received an average ozone dose 32 percent greater than at the 300-m level and 72 percent greater than at the 140-m level.
由于在欧洲和美国的高海拔地区,臭氧的昼夜变化可能是造成森林减少的原因之一,因此了解高海拔地区臭氧的昼夜变化是很重要的。在新泽西州、纽约州和宾夕法尼亚州共同边界附近一座550米高的山上进行的这项研究收集的数据表明,不同海拔高度的日最大臭氧浓度和正午浓度相似,但臭氧剂量随着高度的增加而增加。地点越低,在夜间逆温层以下的时间就越长,在逆温层下,臭氧迅速消耗。位于500米的场址的平均臭氧剂量比300米水平高32%,比140米水平高72%。
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引用次数: 25
On the occurrence of transient puffs in a rotary kiln incinerator simulator I. Prototype solid plastic wastes 回转窑焚烧炉模拟装置中瞬态泡烟的发生研究I.固体塑料废弃物的原型
Pub Date : 1987-01-01 DOI: 10.1080/08940630.1987.10466202
W. Linak, J. Kilgroe, J. McSorley, J. Wendt, J. Dunn
In the operation of practical rotary kiln incinerators, the hazardous waste charge is often introduced in drums or containers in a batch mode. The ensuing transient condition, caused by the rapid devolatilization of waste materials, can momentarily deplete or displace local levels of excess oxygen in the kiln, resulting in heavy transient loadings of unburned gaseous and particulate hydrocarbons (here denoted as "puffs") leaving the kUn. This system upset must then be handled by an afterburner and subsequent air pollution control devices downstream. Such an overcharging or transient condition may even result in unacceptably low destruction of principal organic hazardous constituents (POHC) and the formation of products of incomplete combustion (PIC). A 73-kW (250,000-Btu/h) rotary kiln simulator was designed and constructed to provide engineering insight into the chemical and physical parameters associated with failure mode conditions. To this end, a statistically designed parametric investigation was und...
在实际的回转窑焚烧炉的运行中,危险废物的装料往往采用桶装或容器分批方式引入。随后的瞬态状态,由废料的快速脱挥发引起,可以暂时耗尽或取代窑内局部过量的氧气水平,导致未燃烧的气态和颗粒碳氢化合物(这里表示为“泡”)的大量瞬态负荷离开kUn。这种系统扰动必须由加力燃烧器和随后的下游空气污染控制装置来处理。这种过度充电或瞬态状态甚至可能导致主要有机有害成分(POHC)的低破坏和不完全燃烧产物(PIC)的形成。设计并建造了一个73 kw (250,000 btu /h)的回转窑模拟器,以提供与失效模式条件相关的化学和物理参数的工程洞察力。为此,进行了统计设计的参数调查。
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引用次数: 47
Physicochemical Fate of Sulfate in Soils 硫酸盐在土壤中的物理化学命运
Pub Date : 1987-01-01 DOI: 10.1080/08940630.1987.10466197
M. Tabatabai
Sulfur occurs in soils in organic and inorganic forms, with the inorganic S accounting for < 5 percent of the total S in most soils from humid and semihumid regions. Sulfate in soils may occur as water-soluble salts, adsorbed by soil colloids, or as insoluble forms. Considerable seasonal fluctuations in the concentration of soluble SO4 2− in surface soils occur as a result of interaction of seasonal conditions on the mineralization of organic S, leaching, and uptake by plants. Soils vary widely in their capacity to adsorb SO4 2− . Sulfate adsorption is readily reversible and the amount of SO4 2− adsorbed is concentration and temperature dependent. The capacity of soil to adsorb SO4 2− depends upon clay content, nature of clay minerals, pH, associated cation, and the amount of hydrous Al and Fe oxides. The mechanisms of SO4 2− retention by soils involve coordination with hydrous oxides, exchange on edges of silicate clays, incorporation in mineral structures, and molecular adsorption. For acid soils, SO4 2...
硫以有机和无机形式存在于土壤中,在湿润和半湿润地区的大多数土壤中,无机硫占总硫的比例< 5%。土壤中的硫酸盐可能以水溶性盐的形式存在,被土壤胶体吸附,也可能以不溶性形式存在。由于季节条件对有机S矿化、淋溶和植物吸收的相互作用,表层土壤中可溶性SO4 - 2 -浓度出现了相当大的季节性波动。土壤吸附so4.2−的能力差别很大。硫酸盐吸附是容易可逆的,吸附的SO4 2−的量是浓度和温度依赖。土壤吸附SO4 2−的能力取决于粘土含量、粘土矿物的性质、pH值、伴生阳离子以及含水铝和铁氧化物的数量。土壤对SO4 2−的保留机制包括与含水氧化物的配位、硅酸盐粘土边缘的交换、矿物结构的掺入和分子吸附。对于酸性土壤,so42…
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引用次数: 29
An Assessment of the Long-Term Performance of Gas Continuous Emission Monitoring Systems 气体连续排放监测系统的长期性能评价
Pub Date : 1987-01-01 DOI: 10.1080/08940630.1987.10466196
R. Rollins, T. Logan, M. Midgett, J. Jernigan, J. W. Peeler
A field test program was conducted to evaluate the long-term performance of several gas continuous emission monitoring systems (CEMS).* This paper presents the results gathered on the long-term accuracy and calibration drift characteristics of ten CEMS installed at scrubber-controlled, coal-fired power plants. The program involved periodic accuracy audits and a review of available calibration drift data for selected CEMS. Accuracy audit results show that both SO2 and NOx CEMS are capable of providing accurate data on a long-term basis. However, frequent audits are necessary in order to verify the performance of an individual CEMS. The results of the calibration drift data evaluation show that despite infrequent occurrences of excessive drift, CEMS operated with a significant bias for extended time periods simply because corrective action was not taken in a timely manner.
对几种气体连续排放监测系统(CEMS)的长期性能进行了现场测试。本文介绍了安装在洗涤器控制的燃煤电厂的10个CEMS的长期精度和校准漂移特性的结果。该计划包括定期精度审核和审查选定CEMS的可用校准漂移数据。准确性审计结果表明,SO2和NOx CEMS都能够长期提供准确的数据。然而,为了验证单个CEMS的性能,频繁的审核是必要的。校准漂移数据评估的结果表明,尽管过度漂移很少发生,但CEMS在较长时间内运行时存在明显的偏差,这仅仅是因为没有及时采取纠正措施。
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引用次数: 0
A Practical Guide to Trial Burns for Hazardous Waste Incinerators 危险废物焚化炉试烧实用指引
Pub Date : 1987-01-01 DOI: 10.1080/08940630.1987.10466203
P. Gorman, R. Hathaway, D. Wallace, A. Trenholm
This guide concentrates on those aspects of a trial burn that are the most important and those that are potentially troublesome. It contains practical explanations based on experience of Midwest Research Institute (MRI) and others in conducting trial burns and related tests for EPA. Comments of several industrial plant owners and operators are included in the Guide. It is directed mainly to incinerator operators, those who may conduct the actual sampling and analysis and those who must interpret trial burn results, but it will also be useful for regulatory personnel and others who need to understand trial burns. Potential trouble spots that have been encountered are: (1) trial burns frequently take more time and effort than an operator anticipates and (2) failure to meet the trial burn requirements. This project summary was developed byEPA’s Hazardous Waste Engineering Research Laboratory, Cincinnati, OH, to announce key findings of the research project that is fully documented in a separate report of the...
本指南集中在试验烧伤的那些方面,是最重要的和那些是潜在的麻烦。它包含了基于中西部研究所(MRI)和其他机构进行EPA试验烧伤和相关试验的经验的实际解释。《指南》收录了几位工业工厂业主和经营者的意见。它主要针对焚化炉操作员,那些可能进行实际采样和分析的人,以及那些必须解释试验燃烧结果的人,但它对监管人员和其他需要了解试验燃烧的人也很有用。遇到的潜在问题有:(1)试烧花费的时间和精力往往比作业者预期的要多;(2)不能满足试烧要求。本项目摘要是由俄亥俄州辛辛那提市环保局危险废物工程研究实验室开发的,旨在宣布研究项目的主要发现,并在…
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引用次数: 1
Improved Predictions of Plume Perception with a Human Visual System Model 用人类视觉系统模型改进羽感预测
Pub Date : 1986-12-01 DOI: 10.1080/00022470.1986.10466186
R. Henry
This paper describes incorporation of a human visual system model in the widely used plume visibility model PLUVUE. The results will be of interest to all involved with siting new sources for which visibility of the plume is a concern and to visibility researchers. The human visual system model allows inclusion of size and shape effects on the perceptibility of a plume. Example calculations are given for 2250- and 1600-MW power plants which show that size and shape effects can reduce the predicted perceptibility by up to a factor three.
本文描述了在广泛使用的羽流能见度模型PLUVUE中加入人类视觉系统模型。这些结果将对所有参与寻找新来源的人感兴趣,因为烟柱的可见性是一个问题,对能见度研究人员来说也是如此。人类视觉系统模型允许在羽状物的可感知性上包含大小和形状的影响。以2250兆瓦和1600兆瓦的电厂为例进行了计算,结果表明,尺寸和形状效应可使预测的可感知性降低三倍。
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引用次数: 4
Calculation of σZ and H for an observed vertical profile of concentration 浓度垂直剖面的σZ和H计算
Pub Date : 1986-12-01 DOI: 10.1080/00022470.1986.10466187
J. Halitsky
In extracting Gaussian plume parameters from transverse profiles of concentration measured in model or full-scale tests of dispersion from an elevated source, a common practice is to employ a statistical best-fit procedure in conjunction with the general equation. This involves 1) a calculation of x by Equation 1 for each data point (y,z) using known parameter Q and combinations of assumed parameters sigma/sub y/, sigma/sub z/, u and H; 2) a comparison of calculated and observed values of x; and 3) minimization of the discrepancy for the complete data set.
在从高源色散的模型或全尺寸试验中测量的浓度横向剖面中提取高斯羽流参数时,通常的做法是结合一般方程采用统计最佳拟合程序。这涉及1)使用已知参数Q和假设参数sigma/下标y/、sigma/下标z/、u和H的组合,通过公式1计算每个数据点(y,z)的x;2) x的计算值与实测值的比较;3)最小化完整数据集的差异。
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引用次数: 0
A new audit technique for EPA Method 25. EPA方法25的一种新的审计技术。
Pub Date : 1986-12-01 DOI: 10.1080/00022470.1986.10466184
R K Jayanty, J A Sokash, G B Howe, R G Fuerst, T J Logan, M R Midgett
A simple, inexpensive, and accurate technique for evaluating or auditing the sampling, recovery, and analytical phases of EPA Source Reference Method 25 has been developed. The technique involves spiking a U-shaped stainless steel cartridge containing Tenax® with known quantities of selected organic compounds and thermally desorbing them at temperatures from 160°C to 180°C to generate organic vapors quantitatively. The major advantages of this technique are that no other measurement methods can be used to determine the generated organic concentrations in lieu of Method 25; and that the cartridge can easily be taken to the field for evaluation. The organic compounds generated in test runs are collected and analyzed using the Method 25 procedure. The generation of organics is quantitative and recoveries were found to be 100 ± 10%. The time required for desorption of the majority of organics is generally less than forty-five minutes at a flow rate of 100 mL/min; however, based on laboratory experience the re...
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引用次数: 0
Respiratory responses of exercising asthmatic volunteers exposed to sulfuric acid aerosol. 暴露于硫酸气溶胶下运动哮喘志愿者的呼吸反应。
Pub Date : 1986-12-01 DOI: 10.1080/00022470.1986.10466181
W S Linn, E L Avol, D A Shamoo, J D Whynot, K R Anderson, J D Hackney
Young asthmatic adult volunteers (N = 27) were exposed in an environmental chamber to sulfuric acid aerosol at concentrations near 0, 122, 242, and 410 μg/m3, in purified background air at 22° C and 50 percent relative humidity. The polydisperse aerosol had a mass median aerodynamic diameter near 0.6 μm. Exposures occurred in random order at one-week intervals. Each lasted 1 h, during which subjects exercised (mean ventilation 42 L/min) and rested during alternate 10-min periods. Specific airway resistance and forced expiratory function were measured pre-exposure, after the initial exercise, and at end-exposure. Bronchial reactivity was determined by challenge with cold air immediately post-exposure. Symptoms were monitored during exposure for one week afterward. Exercise-induced bronchospasm was observed under all conditions. Physiologic and symptom changes possibly attributable to sulfuric acid exposure were small and not statistically significant. Our largely negative results contrast with positive fin...
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引用次数: 27
The characterization of ozone, sulfur dioxide, and nitrogen dioxide for selected monitoring sites in the Federal Republic of Germany. 德意志联邦共和国选定监测点的臭氧、二氧化硫和二氧化氮特征。
Pub Date : 1986-12-01 DOI: 10.1080/00022470.1986.10466182
A S Lefohn, V A Mohnen
Ambient ozone, sulfur dioxide, and nitrogen dioxide data collected at 11 rural gaseous air pollution monitoring stations located throughout the Federal Republic of Germany (FRG) were characterized to provide a basis for investigating the effect these air pollutants may have on forest decline. For any given year, with the exception of the Waldhof site, the ozone monitoring sites did not experience more than 50 occurrences of hourly mean concentrations equal to or above 0.10 ppm. In most cases, the number of occurrences equal to or above 0.10 ppm at the FRG ozone monitoring sites was below the number experienced at a rural forested site located at Whiteface Mountain, New York. Several of the FRG monitoring sites experienced a large number of occurrences of hourly mean ozone concentrations between 0.08 and 0.10 ppm. Hof, Selb, Arzberg, and Waldhof experienced several occurrences of elevated levels of sulfur dioxide concentrations. The nitrogen dioxide 24-h mean concentrations were low for all sites. Because ...
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引用次数: 32
期刊
Journal of the Air Pollution Control Association
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