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Errors in grab sample measurements of N2O from combustion sources 从燃烧源抓取N2O样品测量误差
Pub Date : 1989-03-01 DOI: 10.1080/08940630.1989.10466528
L. Muzio, M. Teague, J. Kramlich, J. A. Cole, J. Mccarthy, R. Lyon
An artifact in the use of grab sampling techniques for the measurement of N2O emissions from fossil fuel combustion has been identified. Storing combustion products containing SO2, NOX and water for periods as short as two hours can lead to the formation of several hundred parts per million of N2O where none originally existed. The amount of N2O formed depends both on the amount of NOX and SO2 originally in the container. The experimental results are supported by a proposed chemical mechanism and kinetic calculations. An investigation of sampling protocols indicate that drying the gas to a 0°C dewpoint before introduction in the container reduces, but does not eliminate, N2O formation. More complete drying may yield a valid sample although this approach has, as yet, not been evaluated. Valid grab samples can be obtained by either 1) removing the SO2 before introducing the gas into the container; or 2) increasing the pH of the aqueous phase in the container with NaOH. The findings of this work have importa...
已经确定了使用抓取采样技术测量化石燃料燃烧产生的N2O排放的人工制品。将含有二氧化硫、氮氧化物和水的燃烧产物储存短短两小时,就能在原本不存在的地方形成百万分之几百的二氧化氮。形成的N2O的数量取决于容器中最初的NOX和SO2的数量。实验结果得到了化学机理和动力学计算的支持。对采样方案的调查表明,在将气体引入容器之前将其干燥到0°C露点可以减少,但不能消除N2O的形成。更完全的干燥可能产生有效的样品,尽管这种方法尚未得到评价。有效的抓取样品可以通过以下两种方式获得:1)在将气体引入容器之前先除去SO2;或2)用NaOH增加容器中水相的pH值。这项工作的发现具有重要意义。
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引用次数: 54
GLOBAL EMISSIONS OF NITROGEN AND SULFUR OXIDES FROM 1860 TO 1980 1860年至1980年全球氮氧化物和硫氧化物排放量
Pub Date : 1989-02-01 DOI: 10.1080/08940630.1989.10466519
J. Dignon, S. Hameed
Statistical models have been developed that relate the rate of emissions of a pollutant to the rate of fuel consumption. These relations may be used to estimate emissions in other regions, or at other times, if fuel consumption data are available. This approach has been used to estimate global emissions of nitrogen and sulfur oxides in fossil fuel combustion at ten year intervals from 1860 to 1980. Emissions from each of the populated continents, i.e., North America, South America, Asia, Europe, Africa and Oceania from 1930 to 1980 are also presented. When averaged globally over the 1860 to 1980 period, sulfur emissions increased at the rate of 2.9 percent per year and the nitrogen emissions at the rate of 3.4 percent per year. The ratio of global sulfur emissions to nitrogen emissions has declined steadily; it was nearly 5 in the 19th century and became 3 by 1980. After the second world war, the most rapid increases in emissions have been registered in Asia, South America, and Africa.
已经开发出统计模型,将污染物的排放率与燃料消耗率联系起来。如果有燃料消耗数据,这些关系可用于估计其他地区或其他时间的排放量。这种方法已被用来估计从1860年到1980年每十年一次的化石燃料燃烧中氮和硫氧化物的全球排放量。还列出了1930年至1980年每个人口稠密的大陆,即北美洲、南美洲、亚洲、欧洲、非洲和大洋洲的排放量。从1860年到1980年的全球平均来看,硫排放量以每年2.9%的速度增长,氮排放量以每年3.4%的速度增长。全球硫排放与氮排放的比例稳步下降;19世纪接近5个,到1980年变成3个。第二次世界大战后,亚洲、南美洲和非洲的排放量增长最快。
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引用次数: 135
Rotary Kiln Injection I. An Indepth Study—Liquid Injection 回转窑注射1 .液体注射的深入研究
Pub Date : 1989-01-01 DOI: 10.1080/08940630.1989.10466510
V. Cundy, T. Lester, A. Sterling, J. S. Morse, Alfred N. Montestruc, C. B. Leger, S. Acharya, D. W. Pershing
A multlfaceted experimental and theoretical program directed toward the understanding of rotary kiln performance is underway. University, Industry and government participation is involved. This paper, the first In a series, presents a general discussion of the overall programmatic goals, followed by a brief description of the sub-programs Including: in-situ measurements from an industrial-scale rotary kiln located at the Louisiana Division of Dow Chemical USA in Plaquemine, Louisiana; laboratory-scale desorption characterization and klln-slmulator studies; and incinerator modeling efforts. Water-cooled probes have been used to obtain gas samples from the kiln and the afterburner of an Industrial-scale facility. The samples were analyzed using GC and GC/MS techniques. We include in this communication a report on these preliminary measurements.
一个多方面的实验和理论方案,旨在了解回转窑的性能正在进行中。涉及到大学、工业和政府的参与。本文是该系列的第一篇,对总体规划目标进行了一般性讨论,随后对子计划进行了简要描述,包括:位于路易斯安那州普拉克明的陶氏化学美国路易斯安那分部的工业规模回转窑的现场测量;实验室尺度解吸表征和klln-模拟剂研究;还有焚化炉的建模工作。水冷探头已用于从工业规模设施的窑炉和加力燃烧器中获取气体样本。采用GC和GC/MS技术对样品进行分析。我们在本函件中附上一份关于这些初步测量的报告。
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引用次数: 7
SARA Title III: Pitfalls and Practicalities 第三章:陷阱和实用性
Pub Date : 1989-01-01 DOI: 10.1080/08940630.1989.10466503
M. Levin, D. Spence
Direct regulation mandating control, cleanup and other requirements for what used to be known as "industrial waste" imposes heavy enough burdens. But the limitations of such chemical-by-chemical or wastestream by waste-stream approaches—cumbersome rulemaking, lack of knowledge of feasible control technologies, and the resources required to regulate hundreds of individual substances or production processes— are becoming increasingly obvious to citizens and regulatory agencies. Through public referenda, results like Proposition 65 in California, and statutory worker- protection or right-to-know provisions, the toxics world is shifting toward public disclosure of hazardous substances or releases as a way to address whole clusters of perceived environmental risks at once. SARA Title III is a prime example of such a "nonregulatory" approach to third-generation environmental problems. It illustrates the trend toward this kind of approach, as well as its impact and the issues that are raised. It also illustrates...
对过去被称为“工业废物”的直接管制、清理和其他要求施加了足够沉重的负担。但是,这种逐个化学品或逐个废物处理方法的局限性——繁琐的规则制定、缺乏对可行控制技术的了解以及管理数百种单独物质或生产过程所需的资源——对公民和管理机构来说正变得越来越明显。通过公众投票,加州65号提案的结果,以及法定的工人保护或知情权条款,有毒物质世界正在转向公开披露有害物质或排放,以此作为一种立即解决所有已知环境风险的方法。SARA第三章是这种“非管制”方法解决第三代环境问题的一个主要例子。它说明了这种方法的趋势,以及它的影响和提出的问题。这也说明了……
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引用次数: 2
Characterization of Emissions from a Methanol Fueled Motor Vehicle 甲醇燃料汽车排放特性分析
Pub Date : 1989-01-01 DOI: 10.1080/08940630.1989.10466507
R. Snow, Linnie Baker, W. Crews, C. O. Davis, J. Duncan, N. Perry, Paula Siudak, F. D. Stump, W. Ray, J. N. Braddock
Exhaust, evaporative, and refueling emissions were examined from a methanol fueled Ford Escort operated with M85 (85 percent methanol-15 percent gasoline) and M100 (100 percent methanol) fuels. Exhaust and evaporative emissions were examined for vehicle operation at summer and winter ambient temperatures, while refueling emissions were examined at typical summer temperatures. Regulated emissions (total hydrocarbons, carbon monoxide, nitrogen oxides) as well as formaldehyde, methanol, and detailed hydrocarbon emissions were examined. Results indicated that carbon monoxide, methanol, hydrocarbon, and formaldehyde exhaust emissions increased substantially when the vehicle was operated at reduced temperatures. Formaldehyde emissions were more fuel sensitive than hydrocarbon, carbon monoxide and methanol emissions. A significant portion of the total organic evaporative and refueling emissions with M85 fuel was comprised of hydrocarbons. Both hydrocarbon and methanol evaporative emissions were dependent on test...
在使用M85(85%甲醇- 15%汽油)和M100(100%甲醇)燃料的情况下,测试了以甲醇为燃料的福特Escort的尾气、蒸发和加油排放。在夏季和冬季环境温度下检查车辆运行的排气和蒸发排放,而在典型的夏季温度下检查加油排放。管制排放(总碳氢化合物、一氧化碳、氮氧化物)以及甲醛、甲醇和详细的碳氢化合物排放进行了检查。结果表明,当车辆在低温下运行时,一氧化碳、甲醇、碳氢化合物和甲醛的废气排放量大幅增加。甲醛排放比碳氢化合物、一氧化碳和甲醇排放对燃料更敏感。在M85燃料的有机蒸发和加油排放总量中,很大一部分是由碳氢化合物组成的。碳氢化合物和甲醇的蒸发排放量都取决于测试结果。
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引用次数: 9
The Role of Atmospheric Chemistry in Climate Change 大气化学在气候变化中的作用
Pub Date : 1989-01-01 DOI: 10.1080/08940630.1989.10466502
D. Wuebbles, K. Grant, P. Connell, J. Penner
Surface emissions and concentrations of globally important trace gases are increasing. Climate models indicate significant temperature increases could occur in the next century due to increasing CO...
地表排放和全球重要微量气体的浓度正在增加。气候模式表明,由于CO的增加,下个世纪可能会出现显著的温度升高。
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引用次数: 75
Low NOx, high-efficiency multistaged burner: fuel-oil results 低氮氧化物,高效多级燃烧器:燃油效果
Pub Date : 1988-09-01 DOI: 10.1080/08940630.1988.10466466
J. Mulholland, R. Srivastava
This paper discusses the fuel-oil portion of an evaluation, utilizing a multistaged combustion burner designed for in-furnace NOx control and high combustion efficiency, for high nitrogen-content fuel and waste-incineration application in a 0.6-MW package boiler simulator. A low-NOx precombustion chamber burner was reduced in size by about a factor of two (from 600 to 250 ms first-stage residence time) and coupled with (1) air staging, resulting in a three-stage configuration, and (2) natural gas fuel staging, yielding up to four stoichiometric zones. Natural gas, doped with ammonia to yield a 5.8% fuel nitrogen content, and distillate fuel oil, doped with pyridine to yield a 2% fuel nitrogen content, were used to simulate high nitrogen content fuel/waste mixtures. The multistaged burner reduced NO emissions by 85% from emission levels from a conventional unstaged burner mounted on a commercial package boiler. A minimum NO emission level of 110 ppm was achieved in the fuel-oil tests, from a level of 765 ppm for conventional firing.
本文讨论了燃油部分的评价,利用多级燃烧燃烧器设计的炉内NOx控制和高燃烧效率,高含氮燃料和垃圾焚烧应用在0.6 mw包式锅炉模拟器。低氮氧化物预燃室燃烧器的尺寸减少了大约两倍(第一级停留时间从600毫秒减少到250毫秒),并加上(1)空气分级,形成三级配置,(2)天然气燃料分级,产生多达四个化学计量区。用掺氨的天然气和掺吡啶的馏分燃料油来模拟高氮含量的燃料/废物混合物,天然气的燃料氮含量为5.8%,馏分燃料油的燃料氮含量为2%。多级燃烧器比安装在商业锅炉上的传统无级燃烧器的排放水平减少了85%的NO排放。在燃油测试中达到了110 ppm的最低NO排放水平,而传统燃烧的水平为765 ppm。
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引用次数: 4
Evidence of Growth Reduction in Ozone-Injured Jeffrey Pine (Pinus Jeffreyi Grev. and Balf.) in Sequoia and Kings Canyon National Parks 臭氧损伤的杰弗里松(Pinus Jeffreyi Grev)生长减少的证据。红杉和国王峡谷国家公园
Pub Date : 1987-08-01 DOI: 10.1080/08940630.1987.10466283
D. Peterson, M. Arbaugh, Victoria A. Wakefield, P. R. Miller
Evidence is presented for a reduction in radial growth of Jeffrey pine in the mixed conifer forest of Sequoia and Kings Canyon National Parks, California. Mean annual radial increment of trees with symptoms of ozone injury was 11 percent less than trees at sites without ozone injury. Larger diameter trees (>40 cm) and older trees (>100 yr) had greater decreases in growth than smaller and younger trees. Differences in radial growth patterns of injured and uninjured trees were prominent after 1965. Winter precipitation accounted for a large proportion of the variance in growth of all trees, although ozone-stressed trees were more sensitive to interannual variation in precipitation and temperature during recent years. These results corroborate surveys of visible ozone injury to foliage and are the first evidence of forest growth reduction associated with ozone injury in North America outside the Los Angeles basin.
证据提出了减少径向生长的杰弗里松在红杉和国王峡谷国家公园的混交林针叶林,加州。有臭氧损伤症状的树木的年平均径向增量比没有臭氧损伤的树木少11%。直径较大的树木(40 ~ 40 cm)和年龄较大的树木(100 ~ 100年)的生长下降幅度大于较小和较年轻的树木。1965年以后,损伤树与未损伤树的径向生长模式差异显著。尽管近年来臭氧胁迫树木对降水和温度的年际变化更为敏感,但冬季降水占所有树木生长变化的很大比例。这些结果证实了对树叶可见臭氧损伤的调查,并且是洛杉矶盆地以外北美地区森林生长减少与臭氧损伤相关的第一个证据。
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引用次数: 86
Determination of the sodium carbonate-sulfur dioxide reaction rate coefficient at 450°F 450°F时碳酸钠-二氧化硫反应速率系数的测定
Pub Date : 1987-07-01 DOI: 10.1080/08940630.1987.10466276
A. W. Stelson
Various solid sorbents have been identified as potential candidates for flue gas desulfurization schemes. This research will demonstrate a theoretical and graphical technique which yields the particle size independent reaction rate coefficient from thin bed sorbent studies.
各种固体吸附剂已被确定为潜在的候选烟气脱硫方案。本研究将展示一种理论和图形技术,从薄床吸附剂研究中得出与粒径无关的反应速率系数。
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引用次数: 1
Transformations of Organic and Inorganic Sulfur: Importance to Sulfate Flux in an Adirondack Forest Soil 有机和无机硫的转化:对阿迪朗达克森林土壤中硫酸盐通量的重要性
Pub Date : 1987-01-01 DOI: 10.1080/08940630.1987.10466198
M. David, M. Mitchell
Sulfate flux from forest soils as a result of inputs from acidic deposition is thought to be a critical process in regulating acidification of surface waters. The purpose of this study was to evaluate biotic transformations of sulfur in an Adirondack Mountain forest soil by adding 35S-sulfate to the forest floor. In September 1983 to each of two 0.5 m2 plots, 2.22 × 1010 dpm of 35S-sulfate was added in 4 liters of solution. Analysis of soil horizons from the plot at the end of the six week incubation indicated that 70 and 99 percent of the added 35S was retained in the soil at plots 1 and 2, respectively. More than 70 percent of the 35S was found in Oa, Bh, and Bs1 horizons. In O horizons greater than 80 percent of the 3sS was found as organic sulfur, whereas in mineral horizons most was found as adsorbed sulfate. These findings indicated that a portion of the sulfate moving through the soil is both rapidly immobilized in the forest floor and adsorbed in the mineral horizons. On a net basis, however, the ...
由于酸性沉积的输入,森林土壤中的硫酸盐通量被认为是调节地表水酸化的一个关键过程。本研究的目的是通过向森林地面添加35s硫酸盐来评估阿迪朗达克山森林土壤中硫的生物转化。1983年9月,在2块0.5 m2的地块上,每块地块4升溶液中加入2.22 × 1010dpm的35s硫酸盐。在6周孵育结束时,地块土壤层的分析表明,添加的35S分别有70%和99%保留在地块1和地块2的土壤中。超过70%的35S是在Oa、Bh和Bs1视界发现的。在O层中,超过80%的3s被发现为有机硫,而在矿物层中,大多数被发现为吸附的硫酸盐。这些发现表明,在土壤中移动的一部分硫酸盐既迅速固定在森林地面上,又被矿物层吸收。然而,在净基础上,……
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引用次数: 33
期刊
Journal of the Air Pollution Control Association
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