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Current Status and Future Plan of the Viscosity Measurement for the Lead-Free Solder 无铅焊料粘度测量的现状与展望
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016066
Yasutaka Hashimoto, T. Nishi, H. Ohta
The viscosities of the lead–free solders are important to simulate the process of the manufacturing process. In this article, current status of the viscosity measurements for the lead–free solders are reviewed. In addition, we introduced the current work of the viscosity measurements for the lead–free solders by using the rotational viscometer with concentric cylinder spindle geometry. [doi:10.2320/jinstmet.J2016066]
无铅焊料的黏度是模拟无铅焊料制造过程的重要指标。本文综述了无铅焊料粘度测量的现状。此外,本文还介绍了利用同心圆柱主轴几何形状旋转粘度计测量无铅焊料粘度的工作现状。(doi: 10.2320 / jinstmet.J2016066)
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引用次数: 0
Description of the Thermal Vacancies in the CALPHAD Method CALPHAD方法中热空位的描述
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016061
T. Abe, K. Hashimoto, M. Shimono
Thermal vacancies in solids have not been treated explicitly in the CALPHAD-type thermodynamic assessments because it was considered that their contributions to the Gibbs energy were limited, even at the melting point. However, the vacancy fraction is necessary for dynamic simulations, such as precipitations and di ff usion processes. In this paper, a procedure is proposed to set parameters in the CALPHAD-type assessments, to reproduce the temperature dependency of thermal vacancies in pure metals and solid solutions.
在calphad型热力学评估中,固体中的热空位没有得到明确的处理,因为人们认为它们对吉布斯能的贡献是有限的,即使在熔点也是如此。然而,空位分数对于动态模拟是必要的,例如沉淀和扩散过程。本文提出了一种在calphad型评估中设置参数的方法,以重现纯金属和固溶体中热空位的温度依赖性。
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引用次数: 1
Influence of the Addition of Small Amount of Zn on the Solidification of Sn-Ag Alloys 添加少量Zn对Sn-Ag合金凝固的影响
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016060
R. Yoshimura, H. Esaka, K. Shinozuka
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引用次数: 1
Changes in Recrystallized Texture after Annealing of 5083 Aluminum Alloy Cold Rolled at Increasing Reduction Rate 5083铝合金冷轧退火后再结晶织构的变化
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2017001
M. Tsukamoto
The recrystallized textures of 5083 aluminum alloy plates were examined. These plates were cold rolled at total reduction rates of 30, 50 and 85%, followed by annealing. When reduction rate was 30%, recrystallization was not complete and recovered grains remained despite annealing the specimen at 673 K for 10.8 ks in a salt bath. Recrystallized grains were mostly formed through particle stimulated nucleation, while strain induced grain boundary migration was scarcely occurred. The orientations of recrystallized grains were similar to those of the grains obtained after cold rolling. The orientations of recovered grains were returned to those of the grains before cold rolling with annealing. When reduction rate was 50%, the lattice rotations in the grains increased slightly as compared with the specimen that was cold rolled at a reduction rate of 30%. The distribution of the orientation was close to that of a β–fiber composed of copper, brass and S orientations. Several grains with the {142} plane parallel to the rolling direction were observed. On the contrary, the grains with the {111} plane parallel to the rolling direction decreased. When reduction rate was 85%, the image of the microstructure formed after cold rolling could not be obtained using SEM–EBSD. This was because Kikuchi patterns were not clear owing to the formation of dislocation tangles close to the rolling surface. EBSD images could be obtained by annealing the specimen at 673 K for 3 s. It can be considered that dislocation tangles were rearranged and changed into subgrains. The orientations of recrystallized grains close to precipitations were considerably irregular. However, these grains were difficult to grow. The grains with the {142} plane parallel to the rolling direction were more in the specimen cold rolled at a reduction rate of 85% than in the specimen cold rolled at a reduction rate of 50%. It was concluded that the <142>//ND texture was gradually constructed by increasing the total reduction rate for the cold rolling of 5083 aluminum alloy. [doi:10.2320/jinstmet.J2017001]
研究了5083铝合金板的再结晶织构。这些板分别以30%、50%和85%的总还原率进行冷轧,然后进行退火。当还原率为30%时,在673 K盐浴中退火10.8 ks,再结晶不完全,恢复晶粒仍然存在。再结晶晶粒主要通过颗粒激发形核形成,应变诱导晶界迁移极少发生。再结晶晶粒的取向与冷轧后晶粒的取向相似。退火后,恢复晶粒的取向恢复到冷轧前晶粒的取向。当压下率为50%时,晶粒中的晶格旋转比压下率为30%的冷轧试样略有增加。取向分布接近于铜、黄铜和S取向组成的β纤维的取向分布。观察到若干平行于轧制方向的{142}面晶粒。相反,平行于滚动方向的{111}面晶粒数量减少。当还原率为85%时,SEM-EBSD无法获得冷轧后组织的图像。这是因为在靠近轧制表面处形成位错缠结,导致菊池纹不清晰。在673 K下退火3 s即可获得EBSD图像。可以认为位错缠结被重新排列并转变为亚晶粒。靠近析出点的再结晶晶粒取向相当不规则。然而,这些谷物很难种植。在还原率为85%的冷轧试样中,{142}面平行于轧制方向的晶粒多于还原率为50%的冷轧试样。结果表明:5083铝合金在冷轧过程中,随着总压下率的增加,逐渐形成//ND织构。(doi: 10.2320 / jinstmet.J2017001)
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引用次数: 2
Interface Precipitation and Application to Practical Steels 界面析出及其在实用钢中的应用
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016047
Y. Funakawa
The interface–precipitation has been observed as row carbide arrange since 1960's. Whereas the interface–precipitated carbides in steels were NbC, TiC, VC and Cr23C6 in the early stage, composite TiC containing Mo and W has been also become to observe recently. Several kinds of the mechanism of the interface–precipitation have been suggested and ledge mechanism and bowing mechanism which combined interface barging and carbide precipitation are widely accepted since the mechanisms successfully explained a large amount of the experimental results. Fine interface–precipitates in low carbon steel realize high strength steel sheets, plates, bars and rods which are non–quenched and tempered. Especially, in sheet products, in which fine carbides can be easily generated, ferritic steel of 1180 MPa in tensile strength is successfully obtained by dispersing fine carbides with the diameter of several nano–meters. [doi:10.2320/jinstmet.J2016047]
自20世纪60年代以来,观察到界面析出为行碳化物排列。早期钢中界面析出的碳化物主要为NbC、TiC、VC和Cr23C6,近年来出现了含有Mo和W的复合TiC。人们提出了几种界面析出机理,其中结合界面碰撞和碳化物析出的壁架机制和弯曲机制被广泛接受,因为它们成功地解释了大量的实验结果。低碳钢中细小的界面析出物实现了非调质、高强度的钢板、棒材和棒材。特别是在易产生细小碳化物的片状产品中,通过分散直径为几纳米的细小碳化物,成功地获得了抗拉强度为1180 MPa的铁素体钢。(doi: 10.2320 / jinstmet.J2016047)
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引用次数: 1
Association between Intraosseous Vasculature and Bone Matrix Anisotropy Analyzed with a Novel Visualization Method 一种新的可视化方法分析骨内血管系统与骨基质各向异性之间的关系
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2017005
A. Sekita, Aira Matsugaki, Ryosuke Ozasa, T. Nakano
Bone tissue has a highly anisotropic microstructure derived from collagen matrix alignment and the crystallographic orientation of apatite. Bone is also a highly vascularized tissue; intraosseous vascularization and bone formation are intimately coupled. Mean -while, the structural relations between intraosseous vascular networks and bone microstructure are as yet unknown, partially due to technical difficulties in visualizing precise intraosseous vasculatures. The aim of this study is to develop a visualization method suitable for the structural analysis of intraosseous vascular networks and to reveal the relations between bone microstructure and the arrangement patterns of intraosseous vasculatures both in intact and metastasized bones. Three - dimensional vascular networks were successfully visualized, and region - dependent arrangement patterns of blood vessels were clarified using fluorescent dye - conjugated lectin. Interestingly, the anisotropic structural correlation between bone matrix and the vascular system in a region specific manner was clarified. In addition, the impaired anisotropic vascular networks in metastasized bone was clarified. The obtained results indicate the molecular interactions between the vascular system and bone tissue as a novel contributor for realiza tion of anisotropic bone matrix construct. ] ( )
骨组织具有高度各向异性的微观结构,来源于胶原基质的排列和磷灰石的晶体取向。骨也是一种高度血管化的组织;骨内血管形成与骨形成密切相关。同时,骨内血管网络和骨微结构之间的结构关系尚不清楚,部分原因是在可视化精确的骨内血管系统方面存在技术困难。本研究的目的是开发一种适合于骨内血管网络结构分析的可视化方法,揭示完整骨和转移骨中骨内血管网络的排列模式与骨微结构之间的关系。利用荧光染料偶联凝集素成功地实现了三维血管网络的可视化,并阐明了血管的区域依赖性排列模式。有趣的是,骨基质和血管系统在特定区域的各向异性结构相关性得到了澄清。此外,转移骨中受损的各向异性血管网络也得到了澄清。研究结果表明,血管系统与骨组织之间的分子相互作用是实现各向异性骨基质构建的新途径。] ( )
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引用次数: 0
Thermodynamic Properties for Nd 2 (MoO 4 ) 3 Formed in the Nuclear Fuel Waste Glasses Nd 2 (moo4) 3在核燃料废料玻璃中形成的热力学性质
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.JAW201703
Y. Kinoshita, M. Morishita, A. Nozaki, Hiroaki Yamamoto
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引用次数: 3
Oxidation Behavior of Fe-Ni-Cr Alloys at 700°C in Air and Steam 700℃时Fe-Ni-Cr合金在空气和蒸汽中的氧化行为
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/jinstmet.jb201705
S. Hayashi, D. Takashima, Norifumi Kochi, Y. Nishiyama
High ︲ temperature oxidation behavior of Fe ︲ Ni ︲ Cr alloys with different Ni contents in air and steam at 700 ℃ was investigated. Oxidation mass gain in steam was higher than that in air. In both atmospheres oxidation mass gain tended to decrease with increas ing Ni content. However, the Ni concentration dependence of oxidation mass gain in air was complex, i.e., oxidation mass gain increased with increase in Ni content up to 35 % then decreased with higher Ni content. But oxidation mass gain of binary Ni ︲ 20Cr significantly increased. Such a complex oxidation behavior was not observed when alloys were oxidized in steam. The internal oxidation zone was locally formed in air, and a Cr 2 O 3 scale was found to develop on the areas without internal oxidation. The size of area, where an internal oxidation zone was developed, changed depending on Ni content. In steam, most of the surface area of alloys was covered by an internal oxidation zone. Cr content, 20 % , was considered to be insufficient but close to the critical Cr content for exclusive Cr 2 O 3 scale formation in air. The critical Cr content for exclusive Cr 2 O 3 scale formation was found to depend on alloy Ni content due to lower oxygen permeability in alloys with higher Ni content and the cross ︲ term effect for Cr outward diffu -sion. [ doi:10 . 2320 / jinstmet.JB201705 ] )
研究了不同Ni含量的Fe︲Ni︲Cr合金在700℃空气和蒸汽中的高温︲氧化行为。蒸汽中的氧化质量增益高于空气中的氧化质量增益。在两种气氛下,氧化质量增益均随Ni含量的增加而减小。而空气中氧化质量增益与Ni浓度的关系较为复杂,当Ni含量达到35%时,氧化质量增益随Ni含量的增加而增加,随着Ni含量的增加而降低。但二元Ni︲20Cr的氧化质量增益明显增加。当合金在蒸汽中氧化时,没有观察到这种复杂的氧化行为。空气中局部形成内氧化带,未发生内氧化的区域形成铬氧化垢。内部氧化区形成的区域大小随Ni含量的变化而变化。在蒸汽中,合金的大部分表面积被内部氧化区所覆盖。20%的Cr含量被认为是不够的,但接近空气中唯一形成二氧化铬结垢的临界Cr含量。由于高Ni含量合金的氧渗透性较低,以及Cr向外扩散的交叉︲项效应,发现合金Ni含量决定了形成纯cr2o3结垢的临界Cr含量。[doi:10]2320 / jinstmet。[b201705])
{"title":"Oxidation Behavior of Fe-Ni-Cr Alloys at 700°C in Air and Steam","authors":"S. Hayashi, D. Takashima, Norifumi Kochi, Y. Nishiyama","doi":"10.2320/jinstmet.jb201705","DOIUrl":"https://doi.org/10.2320/jinstmet.jb201705","url":null,"abstract":"High ︲ temperature oxidation behavior of Fe ︲ Ni ︲ Cr alloys with different Ni contents in air and steam at 700 ℃ was investigated. Oxidation mass gain in steam was higher than that in air. In both atmospheres oxidation mass gain tended to decrease with increas ing Ni content. However, the Ni concentration dependence of oxidation mass gain in air was complex, i.e., oxidation mass gain increased with increase in Ni content up to 35 % then decreased with higher Ni content. But oxidation mass gain of binary Ni ︲ 20Cr significantly increased. Such a complex oxidation behavior was not observed when alloys were oxidized in steam. The internal oxidation zone was locally formed in air, and a Cr 2 O 3 scale was found to develop on the areas without internal oxidation. The size of area, where an internal oxidation zone was developed, changed depending on Ni content. In steam, most of the surface area of alloys was covered by an internal oxidation zone. Cr content, 20 % , was considered to be insufficient but close to the critical Cr content for exclusive Cr 2 O 3 scale formation in air. The critical Cr content for exclusive Cr 2 O 3 scale formation was found to depend on alloy Ni content due to lower oxygen permeability in alloys with higher Ni content and the cross ︲ term effect for Cr outward diffu -sion. [ doi:10 . 2320 / jinstmet.JB201705 ] )","PeriodicalId":17337,"journal":{"name":"Journal of The Japan Institute of Metals","volume":"140 1","pages":"417-426"},"PeriodicalIF":0.0,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73281537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preferential Arrangement of Mature Osteoblast from Juvenile Mouse Calvariae on the Oriented Collagen Substrate 幼鼠颅骨成熟成骨细胞在定向胶原基质上的优先排列
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2017027
Ryosuke Ozasa, Aira Matsugaki, Y. Isobe, Taro Saku, T. Nakano
Bone tissue has a highly anisotropic microstructure composed of biological apatite ( BAp ) and collagen fibrils, which is closely related to bone mechanical function. The formation of anisotropic bone microstructure is governed by bone - forming osteoblasts; therefore, establishment of isolation method of osteoblasts and assessment of their arrangement for generating bone tissue with optimally oriented microstructure during bone reconstruction are important. In this study, we established the isolation and culture conditions of mature osteoblasts derived from juvenile mice ( 2 - week - old ) . Osteoblasts from juvenile mice expressed significantly higher level of osteoblastic markers ( alkaline phosphatase, osterix, and osteocalcin ) than osteoblasts from neonatal mice, indicating that juvenile osteoblasts are promising materials for bone tissue engineering. Moreover, the mature osteoblasts aligned along the collagen molecule direction of substrate. This is the report that shows preferential orientation of mature osteoblasts isolated from juvenile mice. [ doi:10 . 2320 / jinstmet.J2017027 ]
骨组织具有由生物磷灰石(BAp)和胶原原纤维组成的高度各向异性的微结构,与骨力学功能密切相关。各向异性骨微观结构的形成受成骨细胞的调控;因此,在骨重建过程中,建立成骨细胞的分离方法并评估成骨细胞的排列对生成具有最佳定向微观结构的骨组织具有重要意义。本研究建立了幼鼠(2周龄)成熟成骨细胞的分离培养条件。幼龄小鼠的成骨细胞表达的成骨标志物(碱性磷酸酶、成骨酶和骨钙素)水平明显高于新生小鼠的成骨细胞,这表明幼龄小鼠成骨细胞是有前景的骨组织工程材料。成熟的成骨细胞沿基质的胶原分子方向排列。这是一份报告,显示了从幼鼠分离的成熟成骨细胞的优先取向。[doi:10]2320 / jinstmet。J2017027]
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引用次数: 0
The Present State and Problems of Precious Metals Recycling 贵金属回收利用的现状与问题
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.JE201603
Y. Kayanuma, Shoei Mizuhashi, Y. Shindo
Recycling of precious metals from scraps generated from manufacturing process have been widely done. The recycling process calls for maintenance of confidentiality of the scrap, use of isolated lots for the recycling operation, high recovery rates, short operation time and low treatment costs. In recent years, the recycling process has been facing three additional problems. The first is the reduction in the precious metal content in the scraps because of their substitution by other non ︲ ferrous metals. The second is the contamination of metals that are never contained in natural ores. They have been used for upgrading the product perfor - mance, but those contaminations make it difficult to extract and purify precious metals. The third is the enforcement of stringent environmental regulations in Japan, which prohibits the continuous use of certain chemicals such as nitric acid. This paper describes the work carried out by a precious metals recycling company to solve the aforementioned problems.
从制造过程中产生的废料中回收贵金属的工作已经广泛开展。回收过程要求保持废料的机密性,使用隔离的批次进行回收操作,回收率高,操作时间短,处理成本低。近年来,回收过程还面临着另外三个问题。首先是废料中贵金属含量的降低,因为它们被其他非︲黑色金属所取代。第二种是天然矿石中不含的金属污染。它们已被用于提高产品性能,但这些污染物使贵金属的提取和纯化变得困难。第三是在日本执行严格的环境法规,禁止持续使用某些化学品,如硝酸。本文介绍了一家贵金属回收公司为解决上述问题所做的工作。
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引用次数: 1
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Journal of The Japan Institute of Metals
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