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Factors Influencing Deformation Behavior and Electrical Conductivity of Pure Copper Castings Fabricated by Industrial Process 影响工业纯铜铸件变形行为和电导率的因素
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016052
I. Goto, S. Aso, K. Ohguchi, Hayato Oguri, K. Kurosawa, Hiroyuki Y. Suzuki, H. Hayashi, J. Shionoya
The factors influencing the tensile deformation behavior and the electrical conductivity of pure copper castings fabricated by an industrial process were investigated. The pure copper castings had sufficient deformation characteristics and electrical conductiv ity on the practical side. However, the deformation characteristics and the electrical conductivity of the castings were slightly inferior to those of the castings fabricated by laboratory experiments. The oxygen content in the castings fabricated by the industrial process was less than 0 . 01 mass % , which resulted in the absence of Cu ︲ Cu 2 O eutectic phase that exhibits the brittle behavior. On the other hand, observations of the fracture surface and the cross ︲ section of the castings showed the existences of microporosity and two types of inclusions. These may be the factors influencing the decrease in the both tensile strength and uniform elongation. The microporosity were suggested to be caused by higher hydrogen content in the melt and / or by slower cooling rate during solidifica -tion. EDX analyses suggested that the inclusions are a kind of slag and straw ashes. Furthermore, phosphorus and iron content in the castings fabricated by the industrial process were higher than those in the castings fabricated by the laboratory experiments. These may be the factors influencing the decrease in electrical conductivity. The above findings indicated the several methods to improve the properties of the castings fabricated by the industrial process. [ doi:10 . 2320 / jinstmet.J2016052 ]
研究了影响工业生产纯铜铸件拉伸变形性能和电导率的因素。纯铜铸件具有良好的变形特性和导电性。然而,铸件的变形特性和电导率略低于室内试验制造的铸件。用工业工艺制造的铸件氧含量小于0。0.01质量%,导致Cu不存在︲Cu 2o共晶相,表现出脆性行为。另一方面,对断口表面和︲横截面的观察表明,铸件存在微孔隙和两种类型的夹杂物。这些可能是影响拉伸强度和均匀伸长率下降的因素。微孔隙是由于熔体中氢含量较高和/或凝固过程中冷却速度较慢造成的。EDX分析表明夹杂物为矿渣和秸秆灰的一种。此外,工业工艺铸造的铸件中磷和铁的含量高于实验室工艺铸造的铸件。这些可能是影响电导率下降的因素。以上研究结果表明了提高工业工艺铸件性能的几种方法。[doi:10]2320 / jinstmet。J2016052]
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引用次数: 3
Development of Room Temperature Formability of Rolled Magnesium Alloy Sheets by Texture Control 织构控制轧制镁合金板材室温成形性能的研究
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016059
Y. Chino, Xinsheng Huang, Kazutaka Suzuki
Magnesium (Mg) alloys are suitable materials for weight reduction in vehicles because of their low densities and high specific strengths. However, rolled Mg alloy sheets generally exhibit a poor formability at room temperature and thus their applications are restricted. This poor formability is originated from basal slip dominated deformation as well as strong basal texture. It is known that the formability can be improved by suppression of basal texture formation. Thus, large efforts have been devoted to texture control for the purpose of enhancing the room temperature formability. In this paper, recent researches for texture control of rolled Mg alloy sheets are reviewed. [doi:10.2320/jinstmet.J2016059]
镁合金具有密度低、比强度高的特点,是汽车减重的理想材料。然而,轧制镁合金板材在室温下通常表现出较差的成形性,因此限制了其应用。形成性差的主要原因是基底滑移为主的变形和较强的基底织构。可以通过抑制基底织构的形成来改善成形性。因此,为了提高室温成形性,人们对织构控制进行了大量的研究。本文综述了近年来镁合金轧制薄板织构控制的研究进展。(doi: 10.2320 / jinstmet.J2016059)
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引用次数: 5
Influence of Zn Addition on the Solid/Liquid Interfacial Energy in Sn-Ag Alloy 添加Zn对Sn-Ag合金固/液界面能的影响
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016048
R. Yoshimura, H. Esaka, K. Shinozuka
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引用次数: 1
Electronic Structure and Thermoelectric Properties of Pseudogap Intermetallic Compound Al 5 Co 2 赝隙金属间化合物al5co2的电子结构和热电性能
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016053
Masaya Kumagai, K. Kurosaki, Y. Ohishi, H. Muta, S. Yamanaka
Thermoelectric ( TE ) power generation can directly convert waste heat into electric energy. However, one of the bottlenecks for widespread use of TE power generation is toxicity of currently ︲ used TE materials. We focused on Al ︲ based materials as candidate of low ︲ toxicity TE materials. Although Al ︲ based materials have high power factor, the achievement of high TE performance is dif - ficult because of the high lattice thermal conductivity. The aims of the present study are to synthesize Al 5 Co 2 known as a pseudogap intermetallic compound, and to investigate the TE properties. We found that lattice thermal conductivity κ lat of Al 5 Co 2 is lower than those of other Al based TE materials, such as Fe 2 VAl, Al 2 Ru and Al 3 V. The κ lat of Al 5 Co 2 at room temperature was 7 . 1 Wm ︲ 1 K ︲ 1 . We also found that Fe substitution at Co sites enhances power factor ( PF ) . The maximum PF was ~ 0 . 6 mWm ︲ 1 K ︲ 2 at room temperature for Al 5 ( Co 0 . 95 Fe 0 . 05 ) 2 . [ doi:10 . 2320 / jinstmet.J2016053 ] ( 2016 )
热电发电可以直接将余热转化为电能。然而,广泛使用TE发电的瓶颈之一是目前︲使用的TE材料的毒性。我们专注于Al︲基材料作为低︲毒性TE材料的候选材料。虽然Al︲基材料具有较高的功率因数,但由于晶格热导率高,实现高TE性能是困难的。本研究的目的是合成假间隙金属间化合物al5co 2,并研究其TE性质。我们发现al5co 2的晶格导热系数κ lat低于其他Al基TE材料,如fe2val, al2ru和al3v。室温下al5co 2的κ lat为7。1 Wm︲1 K︲我们还发现Co位点的Fe取代提高了功率因数(PF)。最大PF为~ 0。6毫微米︲1 K︲2在室温下的Al 5 (Co 0)。[au:]05 ) 2 . [doi:10]2320 / jinstmet。[2016053] (2016)
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引用次数: 0
Chlorine Leaching of Nickel and Cobalt Mixed Sulfide using Iron Chloride Solution 用氯化铁溶液氯浸出镍钴混合硫化物
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016065
Hiroshi Kobayashi, Hirofumi Shoji, S. Asano, Masaki Imamura
The matte chlorine leach and electro ︲ winning ( MCLE ) process, developed by Sumitomo Metal Mining Co., Ltd. ( SMM ) is well known as a unique commercial nickel refining process with a high nickel recovery ratio. SMM has gradually increased the ratio of mixed sulfide ( MS: mixture of nickel and cobalt sulfides ) that can be used as a raw material in the MCLE process over the past decade. However, the reactivity of MS in chlorine leaching remains insufficient and further improvements are needed. We performed bench scale chlorine leaching tests with iron chloride, instead of the currently used copper chloride, as an oxi - dant medium for chlorine gas. However the reactivity of MS was not improved despite the higher oxidation ︲ reduction potential ( ORP ) of iron chloride than that of copper chloride. Though stability studies of iron chloride complexes based on an E ︲ pCl ( poten - tial, ︲ log a Cl ︲ ) diagram, the chlorine leaching potential that is suitable for copper chloride was found to be too low for iron chloride. Reactivity of MS was improved at a higher leaching potentials; however this did not represent a significant improvement over copper chloride based methods. We elucidated the reaction mechanism and showed that chlorine leaching with iron chloride is not suitable for industrial application to MS. [ doi:10 . 2320 / jinstmet.J2016065 ]
由住友金属矿业株式会社(SMM)开发的磨砂氯浸电︲浸出(MCLE)工艺是一种独特的商业镍精炼工艺,具有很高的镍回收率。在过去的十年中,SMM逐渐增加了混合硫化物(MS:镍和钴硫化物的混合物)在MCLE工艺中用作原料的比例。然而,MS在氯浸出中的反应性仍然不足,需要进一步改进。我们用氯化铁代替目前使用的氯化铜作为氯气的氧化介质,进行了实验规模的氯浸出试验。尽管氯化铁的氧化还原电位︲(ORP)高于氯化铜,但MS的反应活性并未得到改善。虽然基于E︲pCl(电位,︲log a Cl︲)图对氯化铁络合物的稳定性进行了研究,但发现适合氯化铜的氯浸出电位对于氯化铁来说太低了。在较高的浸出电位下,质谱的反应性得到改善;然而,这并不代表比基于氯化铜的方法有显著的改进。我们阐明了反应机理,并表明用氯化铁进行氯浸不适合用于ms的工业应用[doi:10]。2320 / jinstmet。J2016065]
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引用次数: 0
マイクロマグネティクス計算によるNd-Fe-B磁石磁化反転過程の解析 利用微磁控计算分析钕铁硼磁体磁化反转过程
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.JA201602
忠勝 大久保, H. Sepehri-Amin, 和博 宝野
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引用次数: 1
Growth Process of ω-precipitates in a Ti-20 mass% Mo Alloy Ti-20质量% Mo合金中ω-相的生长过程
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/jinstmet.j2016049
Y. Shimogami, T. Oyama, C. Watanabe, R. Monzen
The growth process of ω ︲ precipitates was studied for a Ti ︲ 20 mass % Mo alloy aged at 673 K. Investigations of the aging time t dependences of precipitate size, precipitate volume fraction, and precipitate number density revealed that the growth process was divided into three stages: the first stage of diffusion ︲ controlled growth, the second mixed stage of growth and coarsening, and the third stage of coarsening. In the first stage, the precipitate size d increased as d 2 ∝ t with increasing t , and then the precipitate growth became very slow after a value of d =14 nm was reached at the beginning of the second mixed stage. This is ascribed to the transi - tion from the growth stage to the mixed stage of growth and coarsening, and the collision of neighboring ω ︲ precipitates. After the neighboring ω ︲ precipitates of the same variant collided and then coalesced, the precipitate size increased as d 3 ∝ t with increasing t in the mixed stage and the coarsening stage. [ doi:10 . 2320 / jinstmet.J2016049 ]
研究了Ti︲20质量% Mo合金在673 K时效过程中ω︲析出相的生长过程。通过对析出相尺寸、析出相体积分数和析出相数量密度随时效时间的变化规律的研究表明,该合金的生长过程可分为3个阶段:扩散︲控制生长阶段、生长与粗化混合阶段和粗化阶段。在第一阶段,随着t的增大,析出相尺寸d随d2∝t的增大而增大,在第二混合阶段开始,d =14 nm后,析出相的生长变得非常缓慢。这是由于从生长阶段过渡到生长与粗化混合阶段,以及相邻ω︲相的碰撞所致。在混合阶段和粗化阶段,相邻的相同变异体ω︲相碰撞合并后,随着t的增大,相尺寸随d³∝t的增大而增大。[doi:10]2320 / jinstmet。J2016049]
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引用次数: 0
Production techniques of coin-type medal rewarding contributions manufacturing in the Momoyama -era 桃山时代硬币型奖状制造技术
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016050
F. Kirino, Naoshi Ohono, Satoko Taguchi, Akimitsu Nezu, R. Yokoyama
Metal craft production techniques for coin ︲ type medal rewarding contributions manufactured in the Momoyama ︲ era were studied. Reward samples are separated into two types on the basis of production process. One process is casting, and the other is forging. An example of the composition of a casting sample is Ag ︲ Cu alloy, and that of a forged sample is pure Ag. Many voids in cast cultural properties, called eirakutsuho , are observed using X ︲ ray transmission imaging techniques, and indicate the production technique used during this era. Inner stress is measured by the sin 2 ψ method for identifying X ︲ ray diffraction pattern changes. The inner stress of eirakutsuho manufactured by casting is compressive. This is a solidification contraction that occurs at the time of casting. The metal morphology of cast cultural properties, such as eirakutsuho is of the branch type. A thermal flaw is manufactured at the surface of such a cultural property. A creased metal morphology is formed in production by the forging method. Eirakutsuho manufactured by the forging method is stress free. This result indicates that thermal treatment is used in this manufacture process. pure Ag is easy to process for forging. Test samples of cultural properties have been found to have been manufactured by forging methods. It is assumed that the jyotagane metal craft technique was used. The inner stress manufactured in this sample prepared by this method is compressive. After annealing, this sample becomes stress free. The result matches the results obtained by mea - suring the inner stress of cultural properties. [ doi:10 . 2320 / jinstmet.J2016050 ] ( Received 5, 20, 2017 )
对桃山︲时代制造的硬币︲型奖状的金属工艺制作技术进行了研究。奖励样品根据制作工艺分为两类。一种是铸造,另一种是锻造。例如,铸造样品的成分是银︲铜合金,锻造样品的成分是纯银。使用X︲射线透射成像技术可以观察到铸造文物中的许多空洞,这些空洞被称为eirakutsuho,并表明该时代使用的生产技术。内应力是用sin2 ψ法测量的,用于识别X︲射线衍射图样的变化。用铸造法制造的平秋穗内应力为压应力。这是浇注时发生的凝固收缩。铸造文化财产的金属形态,如eirakutsuho是分支类型。这种文化财产的表面会产生热缺陷。通过锻造方法在生产中形成一种皱褶的金属形态。用锻造法制造的平乐穗是无应力的。结果表明,该工艺采用了热处理工艺。纯银易于加工用于锻造。文物的测试样本被发现是用锻造方法制造的。推测使用的是jyotagane金属工艺技术。用这种方法制备的样品所产生的内应力为压应力。退火后,样品无应力。所得结果与测定文物内应力的方法相吻合。[doi:10]2320 / jinstmet。[J2016050](收5,20,2017)
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引用次数: 0
Magnetic Anisotropy Around Grain-Boundaries in Rare-Earth Magnets and Their Coercivity 稀土磁体晶界磁各向异性及其矫顽力
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.JA201604
T. Yoshioka, H. Tsuchiura
Recently, several experimental studies for sintered Nd-Fe-B magnets have shown that their coercivity can be decisively affected by atomic structures around the grain boundaries in the magnets. In this article, a theoretical review is given on possible coercivity reduction mechanisms in sintered Nd-Fe-B or rare-earth based permanent magnets by focusing on the anomalous local magnetic anisotropy found for Nd ions on interfacial structures, based on first-principles calculations and an effective spin model. [doi:10.2320/jinstmet.JA201604]
近年来,对Nd-Fe-B烧结磁体的实验研究表明,磁体晶界周围的原子结构对其矫顽力有决定性的影响。本文基于第一性原理计算和有效自旋模型,对烧结Nd- fe - b或稀土基永磁体中可能的矫顽力降低机制进行了理论综述,重点关注了Nd离子在界面结构上发现的异常局域磁各向异性。(doi: 10.2320 / jinstmet.JA201604)
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引用次数: 0
Formation of a TiAl 3 Layer by an AIH-FPP Treatment Using Mechanically Milled Particles and Its Wear Resistance 机械磨粒AIH-FPP处理tial3层的形成及其耐磨性
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016063
S. Saito, Shogo Takesue, J. Komotori, Kengo Fukazawa, Y. Misaka
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引用次数: 1
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Journal of The Japan Institute of Metals
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