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Cr-Mo-N被膜の硬度および摩擦摩耗特性に及ぼすCu添加の影響 Cu添加对Cr-Mo-N被膜的硬度和摩擦磨损特性的影响
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-03-27 DOI: 10.2320/JINSTMET.JBW201613
優 鈴木, 祐司 須藤, 大輔 安藤, 淳一 小池
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引用次数: 0
Effect of Ti and Al Contents on γ′ Morphology in Wrought Ni-based Superalloys Ti和Al含量对变形镍基高温合金γ′形貌的影响
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-02-24 DOI: 10.2320/jinstmet.j2016062
Hiromu Hisazawa, Y. Terada
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引用次数: 0
Effects of Two-Phase Microstructure Morphology on Mechanical Properties in Co-Base Heat Resistant Alloys Strengthened by E2 1 -(Co, Ni) 3 AlC Phase E2 1 -(Co, Ni) 3alc相强化Co基耐热合金力学性能的影响
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-02-17 DOI: 10.2320/jinstmet.jbw201611
Mami Kasakura, Y. Kimura
Two-phase microstructure consisting of the E21 type (Co, Ni)3 AlC, κ phase, and (Co, Ni) primary solid solution, α phase, forms having three different characteristic morphologies in the same alloy according to their thermal history. Two of them are observed in the as-cast microstructure; the primary α phase dendrite with fi ne cuboidal κ precipitates, and the eutectic lamellar consisting of α and κ phases. During heat treatments of the alloys at high temperatures, the nodular type discontinuous precipitation (DCP) lamellar, consisting of α and κ phases, forms locally in the primary α dendrite regions as the third morphology. The interlamellar spacing and nodule size of the DCP lamellar becomes larger with increasing heat treatment temperature. Micro-Vickers hardness numbers of the α primary dendrites having κ precipitates and the eutectic lamellar are comparable, and higher than those of the DCP lamellar. The alloy annealed at 1173 K for 96 h exhibits high yield strength, the 0.2% proof stress, exceeding about 800 MPa in compression, and the excellent ductility of 13.6% plastic strain at room temperature in tension. On the other hand, the DCP lamellar formation lowers the strength of the alloys, however high strength about 750 MPa can be maintained in the alloy heat treated at the highest temperature of 1373 K as the lowest yield stress of all. Elevated temperature strength measured at 1123 K for the alloy heat treated at 1173 K is 486 MPa of yield stress in compression. The DCP lamellar formation can be suppressed by the two-step heat treatments and by the unidirectional solidifi cation. The former has more homogeneous distribution of fi ne DCP lamellar than single-step heat treated alloys. The latter is very effective to improve the homogeneity and thermal stability of α and κ twophase aligned microstructure and to maintain high temperature strength of 452 MPa at 1123 K. [doi:10.2320/jinstmet.JBW201611]
两相组织由E21型(Co, Ni) 3alc κ相和(Co, Ni)初生固溶体α相组成,在同一合金中具有三种不同的特征形貌。在铸态组织中观察到其中的两种;初生α相枝晶为细小的立方体κ相,共晶片层由α相和κ相组成。高温热处理过程中,在初生α枝晶区局部形成由α相和κ相组成的球状不连续析出(DCP)片层。随着热处理温度的升高,DCP片层间间距和晶粒尺寸增大。具有κ相的α初生枝晶和共晶片层的显微维氏硬度值相当,且高于DCP片层。该合金在1173 K下退火96 h,表现出较高的屈服强度,抗应力为0.2%,压缩时超过约800 MPa,室温拉伸时塑性应变为13.6%的优异延展性。另一方面,DCP片层的形成降低了合金的强度,但在1373 K的最高温度下,合金的屈服应力最低,可以保持750 MPa左右的高强度。经1173 K热处理的合金在1123 K时的高温强度为486 MPa。两步热处理和单向凝固可以抑制DCP片层的形成。前者比单步热处理合金具有更均匀的DCP片层分布。后者对于改善α和κ两相取向组织的均匀性和热稳定性非常有效,并在1123 k下保持452 MPa的高温强度[doi:10.2320/jinstmet.JBW201611]
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引用次数: 0
大気圧走査電子顕微鏡ASEMによる液相での 金のマイクロ粒子生成のin-situ観察 通过大气压力扫描电子显微镜ASEM在液相中金微粒子生成的in-situ观察
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-02-10 DOI: 10.2320/JINSTMET.JE201605
泰也 松野, 江里 小此木, 彰大 吉村, 真理 佐藤, 主税 佐藤
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引用次数: 0
Ti-5Al-2Sn-2Zr-4Cr-4Mo(Ti-17)合金の静的熱処理過程の粒成長および静的球状化 Ti-5Al-2Sn-2Zr-4Cr-4Mo(Ti-17)合金の静的熱処理過程の粒成長および静的球状化
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-02-01 DOI: 10.2320/JINSTMET.J2016043
玄 山根, 洋明 松本
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引用次数: 1
Ti-6Al-4Vレーザー積層材の組織と機械的特性 Ti-6Al-4V激光积层材料的组织和机械特性
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-20 DOI: 10.2320/JINSTMET.J2016042
勇也 櫻井, 幸次 筧
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引用次数: 3
Recent Research in Solvent Extraction of Platinum Group Metals 溶剂萃取铂族金属的研究进展
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.JE201604
H. Narita, Tomoya Suzuki, R. Motokawa
Most of the refineries for platinum group metals (PGMs) in Japan have adopted solvent extraction methods for mutual separation of PGMs. Few effective extractants for industrial use have been found although some industrial processes were established in 1970's. Recently, some compounds have been reported as candidates for practical PGM extractants in addition to new concepts for PGM extraction mechanisms. In this review article, we present well–known PGM recovery processes based on solvent extraction, industrial extractants and their properties, and conventional extraction mechanism for PGMs. Additionally, we discuss recent interesting extraction systems (amide–type compounds and ionic liquid) and then introduce new extraction concepts based on the specific interactions at the outer–sphere of a metal complex in the organic phase. [doi:10.2320/jinstmet.JE201604]
日本大部分铂族金属精炼厂都采用溶剂萃取法对铂族金属进行相互分离。虽然在20世纪70年代建立了一些工业工艺,但很少发现有效的工业用萃取剂。近年来,一些化合物被报道为实用的PGM萃取剂,以及PGM萃取机理的新概念。本文综述了以溶剂萃取法为基础的PGM回收工艺、工业萃取剂及其性能、PGM的常规提取机理。此外,我们讨论了最近有趣的萃取系统(酰胺型化合物和离子液体),然后介绍了基于金属配合物在有机相的外球的特定相互作用的新萃取概念。(doi: 10.2320 / jinstmet.JE201604)
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引用次数: 10
Formation of Fine Protrusions by Sputter Etching of Commercially Pure Titanium 工业纯钛溅射蚀刻精细凸点的形成
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2016064
K. Nakasa, A. Yamamoto, T. Kubo, Rongguang Wang, T. Sumomogi
1High-Tech Research Center, Hiroshima Kokusai Gakuin University, Hiroshima 7390321 2Asahi Surface Tec. LLC, Higashi-Hiroshima 7390024 3Center for General Education, Hiroshima Kokusai Gakuin University, Hiroshima 7390321 4Department of Mechanical System Engineering, Faculty of Engineering, Hiroshima Institute of Technology, Hiroshima 731-5193 5Department of Manufacturing Engineering, Faculty of Engineering, Hiroshima Kokusai Gakuin University, Hiroshima 7390321
1日本广岛国学大学高新技术研究中心,日本广岛73903217390321广岛工业大学工程学院机械系统工程系,广岛731-5193广岛国新学院工程学院制造工程系,广岛7390321
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引用次数: 2
Influences of Concentration and Thickness of MgCl 2 Solution Layer on Pit Initiation of Type 304 Stainless Steel in Atmospheric Environment 大气环境下mgcl2溶液层浓度和厚度对304不锈钢起坑的影响
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.JAW201607
Youhei Hirohata, H. Ota, T. Haruna, K. Noda
This paper aimed to investigate conditions for pit initiation on type 304 stainless steel under MgCl2 solution layer in atmospheric environment using a CCD camera system and a surface potential measurement equipment. A droplet of dilute MgCl2 solution was put on the specimen. The specimen was set in the chamber with a relative humidity of 33% in order to make the droplet dry into the layer. The CCD camera system was employed to observe the change in the shape of the droplet and in the specimen surface during the drying process. In addition, the surface potential measurement equipment was applied for monitoring the surface potential of the specimen with the layer. When the droplet of dilute solution became thin and saturated, pitting corrosion occurred and the surface potential rapidly lowered. By contrast, thick and saturated layer did not induce pitting corrosion and the surface potential indicated the relatively low and steady. Therefore, it was revealed that the atmospheric corrosion occurred on the steel under saturated MgCl2 solution layer whose thickness less than 0.2 mm. [doi:10.2320/jinstmet.JAW201607]
利用CCD摄像系统和表面电位测量装置,研究了大气环境下MgCl2溶液层下304不锈钢的起坑条件。将稀释的MgCl2溶液滴在试样上。为了使液滴干燥进入层内,将试样置于相对湿度为33%的腔室中。利用CCD摄像系统观察干燥过程中液滴形状和试样表面的变化。另外,利用表面电位测量装置对带层试样的表面电位进行监测。当稀溶液的液滴变薄并饱和时,发生点蚀,表面电位迅速降低。相比之下,较厚和饱和层不会引起点蚀,表面电位相对较低且稳定。因此,揭示了在厚度小于0.2 mm的饱和MgCl2溶液层下,钢发生大气腐蚀。[doi:10.2320/jinstmet.JAW201607]
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引用次数: 0
Effect of Initial Grain Size Prior to ECAP-Cold Rolling Processing on the Riding and Formability of Ferritic Stainless Sheets 冷轧前初始晶粒尺寸对铁素体不锈钢板骑乘性和成形性的影响
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2017-01-01 DOI: 10.2320/JINSTMET.J2017044
Mitsuaki Adachi, M. Yuasa, H. Miyamoto, H. Fujiwara, M. Hatano
Equal–channel angular pressing (ECAP) was applied to hot–bands by one pass prior to cold–rolling and annealing in order to modify the texture, and improve the ridging and formability of ferritic stainless steel sheets. The present study focuses on the effect of initial grain size before ECAP, using the samples having extremely large grain size of 210 μm and smaller ones of 30 μm. The final grain sizes of cold–rolled and annealed sheets were about 30 μm for both processes. It was found that Rankford value (r–value) of large grain size was higher compared with that of smaller one while ridging was alleviated in the latter. The recrystallization temperature of cold–rolled sheets was about 50°C lower in the larger grain size. It is considered that higher density of grain–scale shear bands in the sample of larger grain size promotes recrystallization and reduction of <001>//ND grains and increase <111>//ND grains, resulting in higher r–value. However, coarser arrangement of <001>//ND colony parallel to the rolling direction in large grain size may causes higher ridging in spite of the lower fraction <001>//ND grains. [doi:10.2320/jinstmet.J2017044]
为了改善铁素体不锈钢板的织构,提高板的起皱性和成形性,在冷轧和退火前对热带进行一次等道角压处理。采用210 μm的超大晶粒尺寸和30 μm的小晶粒尺寸样品,研究了ECAP前初始晶粒尺寸的影响。冷轧板和退火板的最终晶粒尺寸均在30 μm左右。结果表明,大粒径的Rankford值(r值)高于小粒径的Rankford值(r值),而小粒径的垄起有所缓解。晶粒尺寸越大,冷轧薄板的再结晶温度要低50℃左右。认为在较大晶粒尺寸的试样中,较高的晶粒级剪切带密度促进了//ND晶粒的再结晶和减少,增加了//ND晶粒,从而导致较高的r值。然而,在大晶粒尺寸下,平行于轧制方向的//ND集落排列较粗,虽然//ND晶粒的分数较低,但会导致较高的脊度。(doi: 10.2320 / jinstmet.J2017044)
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Journal of The Japan Institute of Metals
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