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Adsorption and desorption of Hg(II) from aqueous solution using magnetic Fe3O4@PPy composite microspheres 磁性Fe3O4@PPy复合微球对水溶液中汞的吸附与解吸
IF 2.3 Q2 Environmental Science Pub Date : 2021-01-25 DOI: 10.2166/WRD.2021.080
Xiao-qiang Cao, Fei Xiao, Xiao-yu Xie, Xuan-ke Li, Guang Li, Lin Li, Qing-jian Zhang, Wei Zhang, Xiao-fang You, Y. Gai, X. Lyu
Functional magnetic Fe3O4@PPy microspheres were prepared and characterized by XRD, FTIR, SEM, TEM, and magnetometer, and the adsorption of Hg(II) onto Fe3O4@PPy was investigated. The results showed that the adsorption of Hg(II) onto Fe3O4@PPy dramatically increases within 5 min and reaches adsorption equilibrium at 200 min. The adsorption of Hg(II) increases with pH increased, and a removal efficiency (RE) of 90.5% was obtained at pH 7.2. The isotherm studies revealed that the adsorption of Hg(II) onto the Fe3O4@PPy fits well with the Langmuir isotherm model, and the calculated qm value of 232.56 mg/g. The adsorption process of Hg(II) onto the Fe3O4@PPy is well-fitted by the pseudo-second-order model with a high correlation coefficient (R2) of 0.999. The thermodynamic coefficients (ΔH°, ΔS°, and ΔG°) were calculated from the temperature-dependent adsorption isotherms and illustrated that the adsorption of Hg(II) on the Fe3O4@PPy was spontaneous and endothermic. Different desorption agents were used to recover Hg(II) adsorbed onto Fe3O4@PPy, and a satisfactory recovery percentage of 93.0% was obtained by using 0.1 M HCl and 0.05 M NaCl.
制备了功能磁性Fe3O4@PPy微球,并用XRD、FTIR、SEM、TEM和磁强计对其进行了表征,并研究了Fe3O4@PPy对Hg(II)的吸附。结果表明:Fe3O4@PPy对Hg(II)的吸附在5 min内急剧增加,在200 min时达到吸附平衡。随着pH的增加,Hg(II)的吸附量增加,在pH 7.2时,Hg(II)的去除率达到90.5%。等温线研究表明,Fe3O4@PPy吸附Hg(II)符合Langmuir等温线模型,计算得到的qm值为232.56 mg/g。Fe3O4@PPy吸附Hg(II)的拟二阶模型拟合良好,相关系数(R2)为0.999。热力学系数(ΔH°,ΔS°和ΔG°)由温度依赖的吸附等温线计算得到,表明Hg(II)在Fe3O4@PPy上的吸附是自发的、吸热的。采用不同的解吸剂对Fe3O4@PPy吸附的Hg(II)进行回收,0.1 M HCl和0.05 M NaCl的回收率为93.0%。
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引用次数: 5
Influence of light quality on Chlorella growth, photosynthetic pigments and high-valued products accumulation in coastal saline-alkali leachate 水质对滨海盐碱渗滤液小球藻生长、光合色素及高价值产物积累的影响
IF 2.3 Q2 Environmental Science Pub Date : 2021-01-25 DOI: 10.2166/WRD.2021.088
Xiao-ya Liu, Yu-Chuau Hong, W. Gu
Using saline-alkali leachate to cultivate microalgae is an effective way to realize the utilization of wastewater and alleviate the shortage of water resources. Light source is usually used as an optimized parameter to further improve the cultivation efficiency of microalgae. In this work, the influence of light qualities on the growth and high-valued substances accumulation of Chlorella sp. HQ in coastal saline-alkali leachate were investigated. The specific growth rate of Chlorella in coastal saline-alkali leachate was 0.27–0.60 d−1. At the end of cultivation, the algal density under blue light reached 8.71 ± 0.15 × 107 cells·mL−1, which was significantly higher than the other light groups. The lipid content in the biomass was 29.31–62.95%, and the highest lipid content and TAGs content were obtained under red light and blue-white mixed light, respectively. Percentages of total chlorophylls (0.81–1.70%) and carotenoids (0.08–0.25%) were obtained in the final biomass of the coastal saline-alkali leachate. In addition, the contents of photosynthetic pigments and three high-valued products under mixed light were higher than those of monochromatic light, and the protein, total sugar and starch content under blue-red mixed light was 1.52–3.76 times, 1.54–3.68 times and 1.06–3.35 times of monochromatic blue light and red light, respectively.
利用盐碱渗滤液培养微藻是实现废水利用、缓解水资源短缺的有效途径。光源通常被用作优化参数,以进一步提高微藻的培养效率。研究了光照条件对滨海盐碱渗滤液中小球藻生长和高价值物质积累的影响。小球藻在滨海盐碱渗滤液中的比生长速率为0.27–0.60 d−1。培养结束时,蓝光下的藻类密度达到8.71±0.15×107个细胞·mL−1,显著高于其他光照组。生物质中的脂质含量为29.31–62.95%,在红光和蓝白混合光下分别获得最高的脂质含量和TAGs含量。海岸盐碱渗滤液的最终生物量中总叶绿素(0.81–1.70%)和类胡萝卜素(0.08–0.25%)的百分比。此外,在混合光下,光合色素和三种高价值产物的含量高于单色光,在蓝-红混合光下蛋白质、总糖和淀粉的含量分别是单色蓝光和红光的1.52–3.76倍、1.54–3.68倍和1.06–3.35倍。
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引用次数: 18
Microcoagulation improved the performance of the UF–RO system treating the effluent from a coastal municipal wastewater treatment plant: a pilot-scale study 微混凝改善了UF-RO系统处理沿海城市污水处理厂出水的性能:中试研究
IF 2.3 Q2 Environmental Science Pub Date : 2021-01-25 DOI: 10.2166/WRD.2021.099
Tong Yu, Chenlu Xu, F. Chen, Haoshuai Yin, Hao Sun, Lihua Cheng, X. Bi
Microcoagulation has recently been considered as a promising pretreatment for an ultrafiltration (UF) process from numerous studies. To investigate the effects of microcoagulation on the performance of the UF–reverse osmosis (RO) system treating wastewater with high and fluctuant salinity, different dosages of coagulant (poly-aluminum chloride) were added prior to the UF unit in a pilot-scale UF–RO system for a 10-week period operation. Microcoagulation obviously improved the contaminant removal and cleaning efficiencies, including water backwash, chemical enhanced backwash and cleaning in place processes. Organic fouling was dominated during the initial stage of the RO membrane fouling. The microbial communities of water samples and foulant on the RO membrane were similar to those of seawater and foulant on the RO membranes from seawater RO plants. The microbial community of the foulant on the membrane was similar to that of UF permeate and RO concentrate. These results demonstrated that microcoagulation could improve the performance of the UF–RO system treating the effluent with high and fluctuant salinity from a coastal municipal wastewater treatment plant.
近年来,许多研究都认为微凝是一种很有前途的超滤预处理方法。为了研究微混凝对UF -反渗透(RO)系统处理高盐度和波动盐度废水性能的影响,在UF - RO中试系统中,在UF单元前添加不同剂量的混凝剂(聚合氯化铝),运行10周。微混凝明显提高了污染物去除和清洗效率,包括水反冲洗、化学强化反冲洗和就地清洗。反渗透膜污染初期以有机污染为主。水样的微生物群落和反渗透膜上的污染物与海水和海水反渗透厂反渗透膜上的污染物相似。膜上的微生物群落与超滤渗透液和反渗透浓缩液相似。结果表明,微混凝处理某沿海城市污水处理厂高盐度、波动盐度出水,可提高UF-RO系统的处理性能。
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引用次数: 15
Evaluation of the efficiency of a gray water treatment system based on aeration and filtration 曝气过滤灰水处理系统的效能评价
IF 2.3 Q2 Environmental Science Pub Date : 2021-01-22 DOI: 10.2166/WRD.2021.084
Maziar Kabiri, A. Akbarpour, M. Akbari
Gray water is a great resource for replacing fresh water to be used in standardized usages. The use of treated gray water reduces water consumption and the entry of pollutants into the environment. However, if left untreated, it can be dangerous. The present study examines the efficiency of a gray water treatment system consisting of primary filter, aeration, secondary filter and ultraviolet disinfection unit. After examining the characteristics of gray water, the efficiency of this system was analyzed to remove the pH, TSS, BOD, COD, ABS and total coliform parameters. Then, the gray water treated through this system was compared with the environmental standard of Iran. The pH of the treated gray water was 7.5–7.6. The efficiency of this system for removing the BOD and COD parameters was 98–100 and 76–100%, respectively. This system had an efficiency of 96–97% to eliminate the ABS parameter. Also, this system was able to eliminate total coliform with 100% efficiency. Results showed that in the three series of experiments performed on this system, according to the Iranian standard, the treated wastewater is suitable for irrigation and agricultural uses. However, this system could not be licensed for the COD parameter regarding the discharge to surface water and absorbent wells.
灰水是替代淡水标准化使用的重要资源。使用经过处理的灰水可以减少水的消耗和污染物进入环境。然而,如果不及时治疗,可能会很危险。本研究考察了由一级过滤器、曝气器、二级过滤器和紫外线消毒装置组成的灰水处理系统的效率。在考察了灰水的特性后,分析了该系统对pH、TSS、BOD、COD、ABS和总大肠菌群参数的去除效果。然后,将该系统处理的灰水与伊朗的环境标准进行了比较。处理后的灰水的pH值为7.5–7.6。该系统去除BOD和COD参数的效率分别为98–100和76–100%。该系统消除ABS参数的效率为96–97%。此外,该系统能够以100%的效率消除总大肠菌群。结果表明,在该系统上进行的三系列实验中,根据伊朗标准,处理后的废水适用于灌溉和农业用途。然而,该系统无法获得有关地表水和吸收井排放的COD参数的许可。
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引用次数: 5
Fate and persistence of antibiotic-resistant bacteria and genes through a multi-barrier treatment facility for direct potable reuse 抗生素耐药细菌和基因的命运和持久性通过多屏障处理设施直接饮用再利用
IF 2.3 Q2 Environmental Science Pub Date : 2021-01-05 DOI: 10.2166/WRD.2021.097
Lina Wallmann, J. Krampe, J. Lahnsteiner, E. Radu, P. Rensburg, K. Slipko, M. Wögerbauer, N. Kreuzinger
Given the availability of technological solutions and guidelines for safe drinking water, direct potable reuse of reclaimed water has become a promising option to overcome severe lack of potable water in arid regions. However, the growing awareness of the presence of antibiotic-resistant bacteria (ARB) and antibiotic resistance genes (ARG) in corresponding raw wastes has led to new safety concerns. This study investigated the fate of ARB and intracellular and extracellular ARG after each treatment step of an advanced water treatment facility in Windhoek, Namibia. The New Goreangab Water Reclamation Plant (NGWRP) produces drinking water from domestic secondary wastewater treatment plant effluent and directly provides for roughly a quarter of Windhoek's potable water demand. Procedures to study resistance determinants were based on both molecular biology and culture-based microbiological methods. TaqMan real-time PCR was employed to detect and quantify intracellular resistance genes sul1, ermB, vanA, nptII and nptIII as well as extracellular resistance gene sul1. The NGWRP reduced the amount of both culturable bacterial indicators as well as the resistance genes to levels below the limit of detection in the final product. The main ozonation and the ultrafiltration had the highest removal efficiencies on both resistance determinants.
由于有安全饮用水的技术解决办法和指导方针,再生水的直接饮用再利用已成为克服干旱地区严重缺乏饮用水的一个有希望的选择。然而,随着人们对相应原料废物中存在抗生素耐药菌(ARB)和抗生素耐药基因(ARG)的认识不断提高,引发了新的安全问题。本研究调查了纳米比亚温得和克先进水处理设施每个处理步骤后ARB和细胞内及细胞外ARG的命运。新Goreangab水回收厂(NGWRP)从国内二级污水处理厂的废水中生产饮用水,并直接提供温得和克大约四分之一的饮用水需求。研究耐药决定因素的方法是基于分子生物学和基于培养的微生物学方法。采用TaqMan real-time PCR检测并定量胞内耐药基因sul1、ermB、vanA、nptII、nptIII以及胞外耐药基因sul1。NGWRP将最终产品中可培养细菌指标和抗性基因的数量降低到低于检测极限的水平。主臭氧氧化法和超滤法对两个决定因素的去除率最高。
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引用次数: 15
Characterization of bacterial fluorescence: insight into rapid detection of bacteria in water 细菌荧光的表征:洞察水中细菌的快速检测
IF 2.3 Q2 Environmental Science Pub Date : 2021-01-01 DOI: 10.2166/wrd.2021.040
Yu-qin Mao, Xiaowen Chen, Zhuo Chen, Gen-Qiang Chen, Yun Lu, Yin-Hu Wu, Hong-Ying Hu
Microbial contamination is one of the main risks affecting water safety. Traditional microbial detection methods tend to be time-consuming and labor-intensive. Thus, this study investigated a potential rapid and simple method for bacterial detection in water by excitation–emission matrix (EEM) fluorescence spectroscopy. Particularly, bacterial intrinsic fluorophores were divided into three regions, namely Region A (amino acids), Region N (NAD(P)H) and Region F (flavins). Afterwards, fluorescence characteristics of four pure bacterial species (Bacillus subtilis, Staphylococcus aureus, Escherichia coli and Pseudomonas aeruginosa) as well as indigenous bacteria in secondary effluent from two water reclamation plants were evaluated via fluorescence regional integration (FRI). Correlation analysis between fluorescence intensity (FI) integral and bacterial concentration was conducted, and principal component analysis (PCA) was applied to distinguish the fluorescence spectra of different bacteria. The results showed that most of the bacterial autofluorescence was emitted by amino acids and the FI integral of flavins had a good linear relationship (R2 > 0.9) with bacterial concentration. PCA could distinguish varied bacterial species and bacteria from different secondary effluents. This study indicated that FRI was helpful for the characterization of bacterial fluorescence and the quantification of bacteria in water.
微生物污染是影响水体安全的主要风险之一。传统的微生物检测方法往往费时费力。因此,本研究探索了一种有潜力的快速简便的水中细菌检测方法——激发-发射矩阵荧光光谱法。特别地,细菌的固有荧光团被划分为三个区域,即A区(氨基酸),N区(NAD(P)H)和F区(黄素)。随后,利用荧光区域集成(FRI)技术对两家水厂二次出水中枯草芽孢杆菌、金黄色葡萄球菌、大肠杆菌和铜绿假单胞菌4种纯细菌及本地细菌的荧光特性进行了评价。对荧光强度(FI)积分与细菌浓度进行相关性分析,并应用主成分分析(PCA)区分不同细菌的荧光光谱。结果表明,细菌自身荧光主要由氨基酸发出,黄素的FI积分与细菌浓度呈良好的线性关系(R2 > 0.9)。PCA可以区分不同的细菌种类和不同的二次出水细菌。本研究表明,FRI有助于细菌荧光的表征和水中细菌的定量。
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引用次数: 14
Modeling granule-based completely autotrophic nitrogen removal over the nitrite (CANON) process in an SBR 模拟基于颗粒的完全自养脱氮在SBR的亚硝酸(CANON)过程
IF 2.3 Q2 Environmental Science Pub Date : 2021-01-01 DOI: 10.2166/wrd.2021.041
Qing Cai, Qiang He, Shenmin Zhang, Jiajia Ding
Based on the simplified activated sludge model No. 1 (ASM1), a 1D biofilm model containing autotrophic and heterotrophic microorganisms was developed to describe the microbial population dynamics and reactor dynamics of completely autotrophic nitrogen removal over the nitrite in sequencing batch reactor (CANON SBR). After sensitivity analysis and calibration for parameters, the simulation results of NH4+-N concentration and NO2−-N concentration were consistent with the measured results, while the simulated NO3−-N concentration was slightly lower than the measured. The simulation results showed that the soluble microbial products had an extremely low concentration. The aerobic ammonia oxidation bacteria and anaerobic ammonia oxidation bacteria were the dominant microbial populations of the CANON system, while nitrite oxidization bacteria and heterotrophic bacteria were eliminated completely. The optimal ratio of air aeration load to influent NH4+-N load was about 0.18 L air/mgN. The operating condition of the reactor was optimized according to the simulation results, and the total nitrogen removal rate and the total nitrogen removal efficiency increased from 0.312 ± 0.015 to 0.485 ± 0.013 kg N/m3/d and from 71.2 ± 4.3 to 85.7 ± 1.4%, respectively.
在简化活性污泥模型1号(ASM1)的基础上,建立了包含自养和异养微生物的1D生物膜模型,描述了顺序批式反应器(CANON SBR)中亚硝酸盐完全自养脱氮的微生物种群动态和反应器动态。经过敏感性分析和参数标定,NH4+-N和NO2−-N浓度模拟结果与实测值基本一致,NO3−-N浓度模拟值略低于实测值。模拟结果表明,可溶微生物产物的浓度极低。好氧氨氧化菌和厌氧氨氧化菌是CANON系统的优势菌群,亚硝酸盐氧化菌和异养菌被完全淘汰。曝气负荷与进水NH4+-N负荷的最佳比例约为0.18 L air/mgN。根据模拟结果对反应器运行条件进行优化,总氮去除率和总氮去除率分别从0.312±0.015 kg N/m3/d提高到0.485±0.013 kg N/m3/d,总氮去除率从71.2±4.3提高到85.7±1.4%。
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引用次数: 2
Use of reclaimed water for unreinforced concrete block production for the self-construction of houses 利用再生水生产自建房屋用无钢筋混凝土砌块
IF 2.3 Q2 Environmental Science Pub Date : 2021-01-01 DOI: 10.2166/wrd.2021.031
N. Gulamussen, A. Arsénio, N. Matsinhe, R. Manjate, L. Rietveld
Experiments were conducted to evaluate the possibilities of using treated wastewater for the production of unreinforced concrete blocks. Compressive strength, water absorption and morphology tests of concrete blocks, produced from different makeups of mixing water, drinking water, drinking water spiked with ammonium and phosphate, and the effluent of the city's wastewater treatment plant, were evaluated. Results showed that the compressive strength of blocks manufactured using treated wastewater was as high as of the blocks produced using drinking water. Ammonium, phosphate and chlorine were found not to have a negative effect on the strength of the blocks. Water absorption tests confirmed the results of the compressive strength, as lower humidity was found in cases of higher strength. In the process of cement hydration, crystals of calcium silicate and calcium hydroxide were observed by morphology tests. From the variability in the results, it could be concluded that the quality of the mixing water was not the only factor that influenced the strength of the unreinforced concrete blocks. The observed differences in strength could, for example, also be attributed to the manufacturing process.
进行了试验,以评估利用处理过的废水生产无钢筋混凝土砌块的可能性。对不同配比的混合水、饮用水、掺有铵和磷酸盐的饮用水以及城市污水处理厂的污水生产的混凝土块进行了抗压强度、吸水率和形貌试验。结果表明,用处理过的废水生产的砌块抗压强度与用饮用水生产的砌块相当。发现铵、磷酸盐和氯对砌块的强度没有负面影响。吸水试验证实了抗压强度的结果,因为在强度较高的情况下发现较低的湿度。在水泥水化过程中,通过形貌试验观察到硅酸钙和氢氧化钙的结晶。从结果的变异性可以看出,搅拌水的质量不是影响无筋混凝土砌块强度的唯一因素。例如,观察到的强度差异也可以归因于制造过程。
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引用次数: 4
Waterminer – a regional spatio-temporal approach to water reuse management in mining areas in Vietnam Waterminer——越南矿区水再利用管理的区域时空方法
IF 2.3 Q2 Environmental Science Pub Date : 2020-12-01 DOI: 10.2166/wrd.2020.045
S. Greassidis, V. T. Quoc, K. Brömme, H. Stolpe
Mining is usually associated with draining of large quantities of water. On the other hand, mining operations themselves are water users for purposes like coal or ore washing, dust mitigation, recultivation, etc. The normally existing water surplus can be seen as a resource for public purposes instead of discharging the water to rivers and the sea. It is typical for the mining operation that these water amounts vary spatio-temporally according to the mining process. The R&D project WaterMiner investigates the example of the Hon Gai hard coal mining area in Ha Long, Vietnam, as to how and to what extent under the variable spatio-temporal conditions the mine water can cover the water demand in the mines themselves and contribute to the public water supply in the surrounding settlement area of Hon Gai. The spatio-temporal change of mine water drainage, mine water treatment and mine-internal water use and the potential mine-external water use volumes in the project region are investigated by a material flow model and visualized by Sankey diagrams, maps, and tables. Several options for delivery of mine water for mine-external water uses as a contribution to the public water supply are shown.
采矿通常与大量排水有关。另一方面,采矿作业本身是用水户,用于煤炭或矿石洗涤、减少粉尘、再耕作等目的。通常存在的剩余水可以被视为公共资源,而不是将水排入河流和海洋。在采矿作业中,这些水量随采矿过程而发生时空变化是很典型的。研发项目WaterMiner以越南下龙Hon Gai硬煤矿区为例,研究在可变时空条件下,矿井水如何以及在多大程度上满足矿井自身的用水需求,并为Hon Gai周边居住区的公共供水做出贡献。采用物质流模型对项目区矿井排水、矿井水处理、矿井内用水和矿井外用水潜力的时空变化进行了研究,并采用Sankey图、图、表进行了可视化。列出了几种提供矿井水供矿井外部用水的备选办法,作为对公共供水的贡献。
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引用次数: 4
Future-oriented technologies and concepts to increase water availability by water reuse and desalination 面向未来的技术和概念,通过水再利用和海水淡化来增加水的可用性
IF 2.3 Q2 Environmental Science Pub Date : 2020-12-01 DOI: 10.2166/wrd.2020.000
J. Drewes
Printed by BMBF Water in sufcient quantity and quality is fundamental for human health, the sustainable development of regions and an intact environment. However, water is becoming scarce not only in arid areas, but in many regions of the world. The ability to adequately supply households, agriculture and industry with water is becoming an ever greater global challenge. Water demand will drastically increase worldwide in the coming years. Main reasons are population growth, increasing industrial and agricultural activities and the expansion of metropolitan areas. At the same time, the availability of water is already severely limited and is even declining regionally. Contaminated and over-exploited water resources, climate change and the uneven distribution of supplies are contributory factors.
BMBF Water印刷的足够数量和质量是人类健康、地区可持续发展和完整环境的基础。然而,不仅在干旱地区,而且在世界许多地区,水资源都变得稀缺。向家庭、农业和工业充分供水的能力正在成为一个越来越大的全球挑战。未来几年,全球对水的需求将急剧增加。主要原因是人口增长、工农业活动增加以及大都市地区的扩张。与此同时,水的供应已经受到严重限制,甚至在区域范围内呈下降趋势。水资源受到污染和过度开采、气候变化和供应分配不均是促成因素。
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引用次数: 0
期刊
Journal of Water Reuse and Desalination
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