Pub Date : 2021-01-01DOI: 10.15294/jbat.v10i1.25323
A. Sugiharto, Adilla Syarifa, Nindita Handayani, R. Mahendra
Bioplactic from banana corm and glycerol has been studied in this research. In addition, the physical chemical properties of it has been improved by adding chitosan, clay and CMC as filler and glycerol as plasticizer. Plastic that produced form organic material such as starch usually has poor properties in physical and mechanical. Composition variation of chitosan, clay and CMC as filler then combined by variation of glycerol as plasticizer have produced significant improve of the bioplastic physical properties. Properties of the bioplastic that studied in this research was focused to biodegradation, elongation, and tensile strength. The addition of fillers and plasticizers is carried out to produce a better bioplastics. This study used 3 variations of the filler composition : 4, 5, and 6 grams and 2 variations of the plasticizer composition: 1 ml and 2 ml. The bioplastics that produced were tested for tensile strength, elongation, and biodegradation of the soil for 7 days. The best tensile strength results is 8.43 MPa for bioplastic that using CMC fillers. On the other side, the best elongation percentage is 9.87% for bioplastic which using CMC fillers. The bioplastic that added Clay as filler can be degraded up to 100% in 7 days.
{"title":"Effect of Chitosan, Clay, and CMC on Physicochemical Properties of Bioplastic from Banana Corm with Glycerol.","authors":"A. Sugiharto, Adilla Syarifa, Nindita Handayani, R. Mahendra","doi":"10.15294/jbat.v10i1.25323","DOIUrl":"https://doi.org/10.15294/jbat.v10i1.25323","url":null,"abstract":"Bioplactic from banana corm and glycerol has been studied in this research. In addition, the physical chemical properties of it has been improved by adding chitosan, clay and CMC as filler and glycerol as plasticizer. Plastic that produced form organic material such as starch usually has poor properties in physical and mechanical. Composition variation of chitosan, clay and CMC as filler then combined by variation of glycerol as plasticizer have produced significant improve of the bioplastic physical properties. Properties of the bioplastic that studied in this research was focused to biodegradation, elongation, and tensile strength. The addition of fillers and plasticizers is carried out to produce a better bioplastics. This study used 3 variations of the filler composition : 4, 5, and 6 grams and 2 variations of the plasticizer composition: 1 ml and 2 ml. The bioplastics that produced were tested for tensile strength, elongation, and biodegradation of the soil for 7 days. The best tensile strength results is 8.43 MPa for bioplastic that using CMC fillers. On the other side, the best elongation percentage is 9.87% for bioplastic which using CMC fillers. The bioplastic that added Clay as filler can be degraded up to 100% in 7 days.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66989401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.15294/jbat.v10i1.28636
Endang Su Hendi, R. Rusdi, Bagja Nur Alam, S. Nurbaeti
Cooking oil that is used repeatedly at high temperatures will reduce the quality of cooking oil. This will trigger the hydrolysis and oxidation processes that will change the characteristics of the oil, such as an increase in free fatty acid levels and peroxide numbers. Purification of used cooking oil can be carried out physically and chemically. The physical purification of oil is carried out by using adsorbents, while chemically purification process is carried out with an alkaline solution. Physically, natural materials such as zeolite can be used, where zeolite is a natural rock or mineral which chemically has a large surface area to be used in the adsorption process. Chemically with alkaline solution you can use sodium hydroxide (NaOH). In this study, used cooking oil is purified by three stages of the process, namely despicing, neutralization and bleaching to comply with the SNI quality standards. The purpose of this study was to determine the optimum operating conditions for the purification of used cooking oil in accordance with the quality standards for cooking oil. based on the results obtained by adding a NaOH concentration of 19% in the neutralization process and a zeolite concentration of 90% can reduce the acid number value of 2.4 mg NaOH/gr, the peroxide number is 7 mekO2/kg, the color degradation of used cooking oil is 51.83%.
{"title":"Purification of Used Cooking Oil by Alkali Neutralization and Bleaching of Bayah Natural Zeolite","authors":"Endang Su Hendi, R. Rusdi, Bagja Nur Alam, S. Nurbaeti","doi":"10.15294/jbat.v10i1.28636","DOIUrl":"https://doi.org/10.15294/jbat.v10i1.28636","url":null,"abstract":"Cooking oil that is used repeatedly at high temperatures will reduce the quality of cooking oil. This will trigger the hydrolysis and oxidation processes that will change the characteristics of the oil, such as an increase in free fatty acid levels and peroxide numbers. Purification of used cooking oil can be carried out physically and chemically. The physical purification of oil is carried out by using adsorbents, while chemically purification process is carried out with an alkaline solution. Physically, natural materials such as zeolite can be used, where zeolite is a natural rock or mineral which chemically has a large surface area to be used in the adsorption process. Chemically with alkaline solution you can use sodium hydroxide (NaOH). In this study, used cooking oil is purified by three stages of the process, namely despicing, neutralization and bleaching to comply with the SNI quality standards. The purpose of this study was to determine the optimum operating conditions for the purification of used cooking oil in accordance with the quality standards for cooking oil. based on the results obtained by adding a NaOH concentration of 19% in the neutralization process and a zeolite concentration of 90% can reduce the acid number value of 2.4 mg NaOH/gr, the peroxide number is 7 mekO2/kg, the color degradation of used cooking oil is 51.83%.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66989509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.15294/jbat.v10i1.28829
N. Qudus, R. D. Kusumaningtyas, Zakky Syamrizal, Z. Zakaria, D. Hartanto
Controlling the release rate of the nitrogen-phosphorus-potassium (NPK) for the soil fertilized can enhance the fertilizer efficiency and reduce the drawback for the environmental. In this work, a novel slow-release organo-mineral fertilizer was produced from the vinasse, which was blended with the NPK and the chitosan-bentonite matrix. The NPK used as additional nutrients source and the chitosan-bentonite matrix was performed as a barrier to prevent the nitrogen, phosphorus, and potassium from a rapid dissolving. The NPK release rate was measured and analyzed after 3, 6, 9, and 12 days using the incubation method and leaching test. The most efficient release rate was obtained when a dry vinasse mixed with 9% NPK and 5% chitosan-bentonite matrix with the ratio of 8:2. The vinasse-based slow-release of organo-mineral fertilizer (SR-OMF) was compared to the vinasse organo-mineral fertilizer (OMF). The result indicated that the NPK release rate in the vinasse-based SR-OMF was lower compared to that in the vinasse OMF.
{"title":"Vinasse-Based Slow-Release Organo-Mineral Fertilizer with Chitosan-Bentonite Matrix","authors":"N. Qudus, R. D. Kusumaningtyas, Zakky Syamrizal, Z. Zakaria, D. Hartanto","doi":"10.15294/jbat.v10i1.28829","DOIUrl":"https://doi.org/10.15294/jbat.v10i1.28829","url":null,"abstract":"Controlling the release rate of the nitrogen-phosphorus-potassium (NPK) for the soil fertilized can enhance the fertilizer efficiency and reduce the drawback for the environmental. In this work, a novel slow-release organo-mineral fertilizer was produced from the vinasse, which was blended with the NPK and the chitosan-bentonite matrix. The NPK used as additional nutrients source and the chitosan-bentonite matrix was performed as a barrier to prevent the nitrogen, phosphorus, and potassium from a rapid dissolving. The NPK release rate was measured and analyzed after 3, 6, 9, and 12 days using the incubation method and leaching test. The most efficient release rate was obtained when a dry vinasse mixed with 9% NPK and 5% chitosan-bentonite matrix with the ratio of 8:2. The vinasse-based slow-release of organo-mineral fertilizer (SR-OMF) was compared to the vinasse organo-mineral fertilizer (OMF). The result indicated that the NPK release rate in the vinasse-based SR-OMF was lower compared to that in the vinasse OMF.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66989576","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.15294/JBAT.V9I02.21991
Erna Astuti, Z. Mufrodi, G. Budiarti, Ayu Citra Dewi, Mar'atul Husna
Palm kernel shells are one of the main wastes for processing of palm oil. Palm kernel shells are waste that can be used as a catalyst in the biodiesel production. Besides many natural ingredients, the price of catalyst prepared from these materials is also relatively cheap compared to other catalysts, make the biodiesel production more sustainable, and environmentally friendly. This study aims to make activated carbon from palm shell through the process of carbonization and chemical activation. The carbonization process was carried out at 550oC for 3 hours until charcoal was formed. While the activation process was carried out using ZnCl2 activators with concentrations of 0.1 M, 0.25 M, 0.5 M and 1 M which were activated for 4 hours at 90oC. Â Based on the results of the FTIR analysis the presence of O-H and C-O bonds indicates that the carbon produced from the palm kernel shell tends to be polar (volatile). Thus the charcoal produced can be used as catalyst in the biodiesel production. For the SEM test results, it can be seen morphologically that more pore crystals are added and are still brittle at a ZnCl2 concentration of 0.1 M. Based on FTIR and SEM analysis, the best activated charcoal was activated charcoal with a concentration of 0.25 M ZnCl2.
{"title":"Active Charcoal from Palm Kernel Shells as a Catalyst in The Production of Biodiesel","authors":"Erna Astuti, Z. Mufrodi, G. Budiarti, Ayu Citra Dewi, Mar'atul Husna","doi":"10.15294/JBAT.V9I02.21991","DOIUrl":"https://doi.org/10.15294/JBAT.V9I02.21991","url":null,"abstract":"Palm kernel shells are one of the main wastes for processing of palm oil. Palm kernel shells are waste that can be used as a catalyst in the biodiesel production. Besides many natural ingredients, the price of catalyst prepared from these materials is also relatively cheap compared to other catalysts, make the biodiesel production more sustainable, and environmentally friendly. This study aims to make activated carbon from palm shell through the process of carbonization and chemical activation. The carbonization process was carried out at 550oC for 3 hours until charcoal was formed. While the activation process was carried out using ZnCl2 activators with concentrations of 0.1 M, 0.25 M, 0.5 M and 1 M which were activated for 4 hours at 90oC. Â Based on the results of the FTIR analysis the presence of O-H and C-O bonds indicates that the carbon produced from the palm kernel shell tends to be polar (volatile). Thus the charcoal produced can be used as catalyst in the biodiesel production. For the SEM test results, it can be seen morphologically that more pore crystals are added and are still brittle at a ZnCl2 concentration of 0.1 M. Based on FTIR and SEM analysis, the best activated charcoal was activated charcoal with a concentration of 0.25 M ZnCl2.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43289256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.15294/JBAT.V9I02.27136
A. Y. D. Lestari, A. Chafidz, Anindita Ratih Hapsari, Wildan Denly Elnaufal, S. Indri, M. Alatas, Sarwono Mulyono
Wastewater containing heavy metals can potentially harm the human and living organisms and also damage the environment and ecosystem. Wastewater containing total copper (Cu) and zinc (Zn) over the normal threshold will result in Wilson's disease and digestive health, respectively. One of the most widely used methods to remove heavy metals from wastewater is adsorption. One type of adsorbent that has gained interest among researchers was biomass-based adsorbent or biosorbent. In this work, magnetic modification was used to increase the adsorption capacity of the biosorbent. Therefore, the aim of this study was to determine the effect of magnetic modification of corncobs as biosorbent on the adsorption of Cu(II) and Zn(II) heavy metals from an aqueous solution. Magnetic modification with FeCl3.7H2O on corncobs has successfully increased the adsorption capability of Zn(II) and Cu(II) from aqueous solution. The optimum modification ratios for the adsorption of Zn(II) and Cu(II) were 1:2 and 2:1. The adsorption of these both heavy metals took place at temperature of 50°C with the adsorbent doses of 1 g and 1.5 g for Cu(II) and Zn(II), respectively. The highest adsorption percentages for the adsorption of Zn(II) and Cu(II) were 89.3% and 89.2%, respectively. Whereas, the maximum adsorption capacities of Cu(II) and Zn(II) were 75.76 mg/g and 63.93 mg/g, respectively. The adsorption mechanism of Zn(II) and Cu(II) has followed the Freundlich isothermal adsorption model.
{"title":"Magnetically modified corn cob as a new low-cost biosorbent for removal of Cu (II) and Zn (II) from wastewater","authors":"A. Y. D. Lestari, A. Chafidz, Anindita Ratih Hapsari, Wildan Denly Elnaufal, S. Indri, M. Alatas, Sarwono Mulyono","doi":"10.15294/JBAT.V9I02.27136","DOIUrl":"https://doi.org/10.15294/JBAT.V9I02.27136","url":null,"abstract":"Wastewater containing heavy metals can potentially harm the human and living organisms and also damage the environment and ecosystem. Wastewater containing total copper (Cu) and zinc (Zn) over the normal threshold will result in Wilson's disease and digestive health, respectively. One of the most widely used methods to remove heavy metals from wastewater is adsorption. One type of adsorbent that has gained interest among researchers was biomass-based adsorbent or biosorbent. In this work, magnetic modification was used to increase the adsorption capacity of the biosorbent. Therefore, the aim of this study was to determine the effect of magnetic modification of corncobs as biosorbent on the adsorption of Cu(II) and Zn(II) heavy metals from an aqueous solution. Magnetic modification with FeCl3.7H2O on corncobs has successfully increased the adsorption capability of Zn(II) and Cu(II) from aqueous solution. The optimum modification ratios for the adsorption of Zn(II) and Cu(II) were 1:2 and 2:1. The adsorption of these both heavy metals took place at temperature of 50°C with the adsorbent doses of 1 g and 1.5 g for Cu(II) and Zn(II), respectively. The highest adsorption percentages for the adsorption of Zn(II) and Cu(II) were 89.3% and 89.2%, respectively. Whereas, the maximum adsorption capacities of Cu(II) and Zn(II) were 75.76 mg/g and 63.93 mg/g, respectively. The adsorption mechanism of Zn(II) and Cu(II) has followed the Freundlich isothermal adsorption model.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42676933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.15294/JBAT.V9I02.26146
Baiq Amelia Riyandari
Preparation of PEC chitosan-alginate films incorporated by eugenol has been investigated. Incorporation of eugenol in chitosan-alginate films was conducted by using the different concentration of eugenol including 0.25% 0.5%, and 1% (% w/v). The effect of eugenol incorporation in chitosan-alginate films was investigated through some properties of the films such as tensile strength, elongation at break, transparency value, and water vapor permeability. Meanwhile, the effectiveness of eugenol incorporation as an active compound of the films was investigated from antioxidant activity of chitosan-alginate films incorporated eugenol. Polyelectrolyte complex (PEC) films of chitosan-alginate was occurred through molecular interaction between polycationic groups of chitosan and polyanionic groups of alginate. The formation of chitosan-alginate PEC films was synthesized at pH ± 4.0. Based on FTIR analysis, the ionic interaction between amine groups (–NH3+) and carboxylate groups (–COO¬) formed strongly. Characterization of films also indicated that PEC films of chitosan-alginate incorporated of eugenol was formed. Study showed that PEC chitosan-alginate films had good mechanical properties. Antioxidant activity assay through fixed reaction time method using DPPH radical (α,α-difenil-β- pikrilhidrazil) resulted in good percentage of radical scavenging activity (%RSA) from the films. The E3 films which contain 1% eugenol has 55.99% of RSA value in 96 hours.
{"title":"Preparation of Polyelectrolyte Complex Films of Chitosan-Alginate Incorporated by Eugenol and its Potency as an Antioxidant Packaging","authors":"Baiq Amelia Riyandari","doi":"10.15294/JBAT.V9I02.26146","DOIUrl":"https://doi.org/10.15294/JBAT.V9I02.26146","url":null,"abstract":"Preparation of PEC chitosan-alginate films incorporated by eugenol has been investigated. Incorporation of eugenol in chitosan-alginate films was conducted by using the different concentration of eugenol including 0.25% 0.5%, and 1% (% w/v). The effect of eugenol incorporation in chitosan-alginate films was investigated through some properties of the films such as tensile strength, elongation at break, transparency value, and water vapor permeability. Meanwhile, the effectiveness of eugenol incorporation as an active compound of the films was investigated from antioxidant activity of chitosan-alginate films incorporated eugenol. Polyelectrolyte complex (PEC) films of chitosan-alginate was occurred through molecular interaction between polycationic groups of chitosan and polyanionic groups of alginate. The formation of chitosan-alginate PEC films was synthesized at pH ± 4.0. Based on FTIR analysis, the ionic interaction between amine groups (–NH3+) and carboxylate groups (–COO¬) formed strongly. Characterization of films also indicated that PEC films of chitosan-alginate incorporated of eugenol was formed. Study showed that PEC chitosan-alginate films had good mechanical properties. Antioxidant activity assay through fixed reaction time method using DPPH radical (α,α-difenil-β- pikrilhidrazil) resulted in good percentage of radical scavenging activity (%RSA) from the films. The E3 films which contain 1% eugenol has 55.99% of RSA value in 96 hours.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48503519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.15294/JBAT.V9I02.27304
H. Hendriyana, Lulu Nurdini, Rizqi Ajeng Khusnul Khotimah, Nur Refianti Sukandi, Tika Dwi Ainun, Evi Ojo Nurjanah, Yuyun Yunengsih, F. Khoerunnisa
Jatropha oil which is non-edible oil were hydro-crack at atmospheric pressure using an activated wood char catalyst in a fixed bed reactor. The hydro-cracking process was carried out at three temperature variations of 400, 450 and 500oC, and three variations of the oil feed injection rate of 2/2, 2/5 and 2 mL/10 minutes. The catalysts were characterized using SEM and BET. The composition of the liquid product obtained from the hydro-cracking process was analyzed using GC-MS. The effects of operating temperature and oil feed injection rate on oil recovery and conversion have been discussed. The results showed that the feed injection temperature and rate had an effect on the yield and conversion. The highest yield of 59.8% oil liquid products was achieved at a temperature of 450oC with injection rate of 2 mL/10 min. The composition of the oil-liquid product was dominated by heptanal at 32.9% -mass. Alkanes group contain C5 to C20 and alkene compounds consist of C8 until C18.
{"title":"Athmospheric Hydrocracking of Jatropha Oil Using Woodchar Catalyst","authors":"H. Hendriyana, Lulu Nurdini, Rizqi Ajeng Khusnul Khotimah, Nur Refianti Sukandi, Tika Dwi Ainun, Evi Ojo Nurjanah, Yuyun Yunengsih, F. Khoerunnisa","doi":"10.15294/JBAT.V9I02.27304","DOIUrl":"https://doi.org/10.15294/JBAT.V9I02.27304","url":null,"abstract":"Jatropha oil which is non-edible oil were hydro-crack at atmospheric pressure using an activated wood char catalyst in a fixed bed reactor. The hydro-cracking process was carried out at three temperature variations of 400, 450 and 500oC, and three variations of the oil feed injection rate of 2/2, 2/5 and 2 mL/10 minutes. The catalysts were characterized using SEM and BET. The composition of the liquid product obtained from the hydro-cracking process was analyzed using GC-MS. The effects of operating temperature and oil feed injection rate on oil recovery and conversion have been discussed. The results showed that the feed injection temperature and rate had an effect on the yield and conversion. The highest yield of 59.8% oil liquid products was achieved at a temperature of 450oC with injection rate of 2 mL/10 min. The composition of the oil-liquid product was dominated by heptanal at 32.9% -mass. Alkanes group contain C5 to C20 and alkene compounds consist of C8 until C18.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46392103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.15294/JBAT.V9I02.26812
Daisy A Sriwedari, Edwin K Sijabat
This research is about the application of Bacterial nano cellulose (BNC) as a reinforcing material in the making of liner test paper. BNC was obtained from the fermentation of banana peel extract using Gluconacetobacter xylinum bacteria obtained from the making starter of nata de coco. The reason for using banana peel waste is because it’s available in large number all across Indonesia. BNC is mixed with secondary fiber as a raw material for making liner test paper. From the experimental handsheets results, strength properties and absorption properties were then tested. Variations in the composition of the use of BNC are 0% (blank), 5%, 10%, 15%, 20%, 25%, 30% of the handsheet dry weight. The BNC is also applicated on surface sizing as a substitute for the surface sizing agent. The results of this study indicate that BNC can be used as an alternative raw material on wet end and on surface sizing, because both applications can increase the strength properties of liner test paper, and can reduce the use of chemical additive. The highest increase in strength properties of liner test paper was obtained at the composition of nano cellulose 30% and using surface sizing. Ring crush index is 14.02 Nm / g, concora index is 12.73 Nm / g, bursting index is 3.78 KPa.m² / g, ply bonding is 388.57 J / m². The absorption properties of paper increases but it has a low prosity. The highest cobb size results are obtained at 30% BNC composition, which is 45.30 g / m2 without using surface sizing and 41.83 g / m² using surface sizing. The highest porosity value is obtained at 30% BNC composition, which is 158 s / 100cc using surface sizing. This research is expected to be a reference for further research in the field of BNC, as the alternative raw materials besides wood in paper making.
{"title":"Application of Bacterial Nano Cellulose as a Reinforcing Material in The Liner Test Paper","authors":"Daisy A Sriwedari, Edwin K Sijabat","doi":"10.15294/JBAT.V9I02.26812","DOIUrl":"https://doi.org/10.15294/JBAT.V9I02.26812","url":null,"abstract":"This research is about the application of Bacterial nano cellulose (BNC) as a reinforcing material in the making of liner test paper. BNC was obtained from the fermentation of banana peel extract using Gluconacetobacter xylinum bacteria obtained from the making starter of nata de coco. The reason for using banana peel waste is because it’s available in large number all across Indonesia. BNC is mixed with secondary fiber as a raw material for making liner test paper. From the experimental handsheets results, strength properties and absorption properties were then tested. Variations in the composition of the use of BNC are 0% (blank), 5%, 10%, 15%, 20%, 25%, 30% of the handsheet dry weight. The BNC is also applicated on surface sizing as a substitute for the surface sizing agent. The results of this study indicate that BNC can be used as an alternative raw material on wet end and on surface sizing, because both applications can increase the strength properties of liner test paper, and can reduce the use of chemical additive. The highest increase in strength properties of liner test paper was obtained at the composition of nano cellulose 30% and using surface sizing. Ring crush index is 14.02 Nm / g, concora index is 12.73 Nm / g, bursting index is 3.78 KPa.m² / g, ply bonding is 388.57 J / m². The absorption properties of paper increases but it has a low prosity. The highest cobb size results are obtained at 30% BNC composition, which is 45.30 g / m2 without using surface sizing and 41.83 g / m² using surface sizing. The highest porosity value is obtained at 30% BNC composition, which is 158 s / 100cc using surface sizing. This research is expected to be a reference for further research in the field of BNC, as the alternative raw materials besides wood in paper making.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42025222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.15294/JBAT.V9I02.27345
I. Ismadi, S. S. Kusumah, Subyakto Subyakto, B. Subiyanto, L. Suryanegara, R. Marlina
The common food container product was made from plastic such as polypropylene, polystyrene, etc which has slowed to degrade hence affected to the environmental pollution and health disorder. Therefore, environmentally friendly food container composite is developed from sustainable resources such as sorghum bagasse and citric acid. The effects of sorghum species, sorghum particles and citric acid content on the composite properties were investigated. Local species of sorghum was used as raw material such as Super 2 in the manufacturing of food packaging. The size and moisture content of the particles were passthrough on 40 mesh and 10%, respectively. The content of the particle was variated such as 10, 15, and 20% wt. Furthermore, citric acid was used as a binder with difference content such as 10, 20, and 30% wt. Those raw materials were mixed with tapioca starch, polyvinyl alcohol (PVA), and glutaraldehyde. The mixing material was hot pressed at 180 ℃ for 15 minutes. The composite dimension was 12 cm x 10 cm x 3 mm. The physical and mechanical properties of the composite were carried out. Considering the properties of the composite, sorghum bagasse and citric acid are suitable as raw material of food container composite.
{"title":"Characteristics of Environmentally Friendly Food Container Composite Made From Sorghum Bagasse and Citric Acid","authors":"I. Ismadi, S. S. Kusumah, Subyakto Subyakto, B. Subiyanto, L. Suryanegara, R. Marlina","doi":"10.15294/JBAT.V9I02.27345","DOIUrl":"https://doi.org/10.15294/JBAT.V9I02.27345","url":null,"abstract":"The common food container product was made from plastic such as polypropylene, polystyrene, etc which has slowed to degrade hence affected to the environmental pollution and health disorder. Therefore, environmentally friendly food container composite is developed from sustainable resources such as sorghum bagasse and citric acid. The effects of sorghum species, sorghum particles and citric acid content on the composite properties were investigated. Local species of sorghum was used as raw material such as Super 2 in the manufacturing of food packaging. The size and moisture content of the particles were passthrough on 40 mesh and 10%, respectively. The content of the particle was variated such as 10, 15, and 20% wt. Furthermore, citric acid was used as a binder with difference content such as 10, 20, and 30% wt. Those raw materials were mixed with tapioca starch, polyvinyl alcohol (PVA), and glutaraldehyde. The mixing material was hot pressed at 180 ℃ for 15 minutes. The composite dimension was 12 cm x 10 cm x 3 mm. The physical and mechanical properties of the composite were carried out. Considering the properties of the composite, sorghum bagasse and citric acid are suitable as raw material of food container composite.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43409522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.15294/JBAT.V9I02.26131
Maya Rahmayanti, S. J. Santosa, S. Sutarno
Sonochemical technology is a technology that involves ultrasonic waves in chemical reactions. In this study, humic acid isolated from peat soil has been successfully modified with magnetite (HA-Fe3O4) using sonochemical technology. Characterization of the physical and chemical properties of HA-Fe3O4 was carried out using FTIR, XRD, SEM and VSM. HA-Fe3O4 was used for recovery of gold from simulated gold waste (HAuCl4). FTIR characterization showed that the interaction between HA and Fe3O4 was through hydrogen bonds. The crystal size of HA-Fe3O4 using the Debye-Scherrer equation based on the XRD diffractogram was 12.4 nm. The saturation magnetization value of HA-Fe3O4 obtained was 52.80 emu/g. Adsorption studies at various pH showed that HA-Fe3O4 has been successful in recovering of gold from simulated gold waste. The % recovery of gold was 99%. Gold recovery occurs through the adsorption process followed by reduction of Au (III) to Au(0).
{"title":"Modified Humic Acid from Peat Soils with Magnetite (Ha-Fe3O4) by Using Sonochemical Technology for Gold Recovery","authors":"Maya Rahmayanti, S. J. Santosa, S. Sutarno","doi":"10.15294/JBAT.V9I02.26131","DOIUrl":"https://doi.org/10.15294/JBAT.V9I02.26131","url":null,"abstract":"Sonochemical technology is a technology that involves ultrasonic waves in chemical reactions. In this study, humic acid isolated from peat soil has been successfully modified with magnetite (HA-Fe3O4) using sonochemical technology. Characterization of the physical and chemical properties of HA-Fe3O4 was carried out using FTIR, XRD, SEM and VSM. HA-Fe3O4 was used for recovery of gold from simulated gold waste (HAuCl4). FTIR characterization showed that the interaction between HA and Fe3O4 was through hydrogen bonds. The crystal size of HA-Fe3O4 using the Debye-Scherrer equation based on the XRD diffractogram was 12.4 nm. The saturation magnetization value of HA-Fe3O4 obtained was 52.80 emu/g. Adsorption studies at various pH showed that HA-Fe3O4 has been successful in recovering of gold from simulated gold waste. The % recovery of gold was 99%. Gold recovery occurs through the adsorption process followed by reduction of Au (III) to Au(0).","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47707795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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