Pub Date : 2019-07-24DOI: 10.15294/JBAT.V8I1.14028
Dzikri Hamzah, T. Rinaldi, M. Marwan, W. Rinaldi
Esterification of glycerol with acetic acid under microwave irradiation in the presence of activated natural zeolite was investigated. Natural zeolite was collected from Ujung Pancu (Aceh Besar) and chemically activated with hydrochloric acid. The reaction was carried out in a stirred glass flask reactor placed inside microwave oven. Experimental variables include microwave transmission time, molar ratio of glycerol to acetic acid, and catalyst loading. XRD profile of activated zeolite showed an increase of Si/Al ratio to 6.042 and the crystallinity decreased slightly by 12.23%, mainly due to dealumination during chemical treatment. Qualitative analysis by FTIR shows that the reaction product obtained by microwave heating contains ester group (triacetin) at wavelength 1706.669 cm-1, while the quantitative analysis by acidi-alkalimetry titration indicates the highest glycerol conversion of 93.033% at the reaction condition of the molar ratio of 1:9, catalyst loading of 3%, and microwave transmission of 10 minutes. The present work suggests that microwave can be utilized as efficient heating technique in esterification of glycerol to triacetin.
{"title":"Synthesis of Triacetin Catalyzed by Activated Natural Zeolite Under Microwave Irradiation","authors":"Dzikri Hamzah, T. Rinaldi, M. Marwan, W. Rinaldi","doi":"10.15294/JBAT.V8I1.14028","DOIUrl":"https://doi.org/10.15294/JBAT.V8I1.14028","url":null,"abstract":"Esterification of glycerol with acetic acid under microwave irradiation in the presence of activated natural zeolite was investigated. Natural zeolite was collected from Ujung Pancu (Aceh Besar) and chemically activated with hydrochloric acid. The reaction was carried out in a stirred glass flask reactor placed inside microwave oven. Experimental variables include microwave transmission time, molar ratio of glycerol to acetic acid, and catalyst loading. XRD profile of activated zeolite showed an increase of Si/Al ratio to 6.042 and the crystallinity decreased slightly by 12.23%, mainly due to dealumination during chemical treatment. Qualitative analysis by FTIR shows that the reaction product obtained by microwave heating contains ester group (triacetin) at wavelength 1706.669 cm-1, while the quantitative analysis by acidi-alkalimetry titration indicates the highest glycerol conversion of 93.033% at the reaction condition of the molar ratio of 1:9, catalyst loading of 3%, and microwave transmission of 10 minutes. The present work suggests that microwave can be utilized as efficient heating technique in esterification of glycerol to triacetin.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43928909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-07-24DOI: 10.15294/JBAT.V8I1.20162
A. Kusumastuti, S. Anis, Gunawan Muhammad Najibulloh
Study on the application of Taylor-Couette column for emulsion liquid membrane system has been done. To optimise extraction process under TCC, a research to investigate effect of viscosity and cylinders rotation is of important. Fluid viscosity was examined by varying volume ratio of kerosene to water. TCC was characterised to determine flow regimes, shear stress, and energy loss distribution. Volume ratio of oil to water was varied at 1:1, 1:3, 1:5, and 1:6 while inner and outer cylinders speed were maintained constant at 300 and 200 rpm, respectively. Investigation on the effect of volume ratio of oil to water towards flow regime ended to same flow regime of Featureless Turbulent. There was degradation of wall shear stress from 8.57x10-2 Pa to 7.42x10-2 Pa.
{"title":"Taylor-Couette Column for Emulsion Liquid Membrane System: Characterisation Study","authors":"A. Kusumastuti, S. Anis, Gunawan Muhammad Najibulloh","doi":"10.15294/JBAT.V8I1.20162","DOIUrl":"https://doi.org/10.15294/JBAT.V8I1.20162","url":null,"abstract":"Study on the application of Taylor-Couette column for emulsion liquid membrane system has been done. To optimise extraction process under TCC, a research to investigate effect of viscosity and cylinders rotation is of important. Fluid viscosity was examined by varying volume ratio of kerosene to water. TCC was characterised to determine flow regimes, shear stress, and energy loss distribution. Volume ratio of oil to water was varied at 1:1, 1:3, 1:5, and 1:6 while inner and outer cylinders speed were maintained constant at 300 and 200 rpm, respectively. Investigation on the effect of volume ratio of oil to water towards flow regime ended to same flow regime of Featureless Turbulent. There was degradation of wall shear stress from 8.57x10-2 Pa to 7.42x10-2 Pa.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46636336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-07-24DOI: 10.15294/JBAT.V8I1.17685
A. K. Sugih, Jordi Loanda, S. Prasetyo
Sugar palm or aren (Arenga pinnata) is a traditional source of starch widely cultivated throughout Indonesia. Despite its potentiality to be used as feedstock for food industries, there has been very little research reported on sugar palm starch characterization and modification. This paper describes a preliminary experimental study on the chemical modification, i.e. phosphorylation of sago palm starch using low level of Sodium tripolyphosphate (STPP), and characterization of some important physicochemical and functional properties of the modified products. Starch phosphate synthesis was conducted at an initial pH of 9, reaction temperatures of 120-140 oC, and STPP intakes of 0.5-1.5%-weight based on dry starch. The experimental result shows that Degree of Substitution (DS) of the obtained products is accessible in the range of 0.0013 – 0.0068. An increase in reaction temperature as well as STPP intake leads to products with higher DS values. The modified starch products exhibit higher swelling power (16.57-24.81 g/g) and solubility (9.12-22.79 %-w/w) compared to native sugar palm starch (swelling power and solubility of 14.50 g/g and 7.91 %-w/w, respectively). Phosphorylated starch products also have significantly improved paste clarity clarity and water/ oil absorption capacity compared to native sugar palm starch. The result suggests that phosphorylation is a promising method to enhance the properties of sugar palm starch.
{"title":"Synthesis of Phosphorylated Sugar Palm (Aren) Starch Using Low Level Sodium Tripolyphosphate (STPP)","authors":"A. K. Sugih, Jordi Loanda, S. Prasetyo","doi":"10.15294/JBAT.V8I1.17685","DOIUrl":"https://doi.org/10.15294/JBAT.V8I1.17685","url":null,"abstract":"Sugar palm or aren (Arenga pinnata) is a traditional source of starch widely cultivated throughout Indonesia. Despite its potentiality to be used as feedstock for food industries, there has been very little research reported on sugar palm starch characterization and modification. This paper describes a preliminary experimental study on the chemical modification, i.e. phosphorylation of sago palm starch using low level of Sodium tripolyphosphate (STPP), and characterization of some important physicochemical and functional properties of the modified products. Starch phosphate synthesis was conducted at an initial pH of 9, reaction temperatures of 120-140 oC, and STPP intakes of 0.5-1.5%-weight based on dry starch. The experimental result shows that Degree of Substitution (DS) of the obtained products is accessible in the range of 0.0013 – 0.0068. An increase in reaction temperature as well as STPP intake leads to products with higher DS values. The modified starch products exhibit higher swelling power (16.57-24.81 g/g) and solubility (9.12-22.79 %-w/w) compared to native sugar palm starch (swelling power and solubility of 14.50 g/g and 7.91 %-w/w, respectively). Phosphorylated starch products also have significantly improved paste clarity clarity and water/ oil absorption capacity compared to native sugar palm starch. The result suggests that phosphorylation is a promising method to enhance the properties of sugar palm starch.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41722238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-07-24DOI: 10.15294/JBAT.V8I1.15289
W. D. P. Rengga, M. A. Mubarok, N. S. Cahyarini
Indonesia has a high fertilizer demand because its use is easily dissolved during watering, so the fertilization process is inefficient. On the other hand, crab shells accumulate every year because the waste is almost 50% of the initial weight. One way to overcome this problem is to make a modified fertilizer into a slow release fertilizer by adding a bio-gel layer from chitosan and potato flour. The hydrophobic properties of chitosan and potato powder were chosen in addition to the amylopectin content of potato flour more than other types of starch. Then chitosan was dissolved using acetic acid, while potato starch was dissolved by distilled water by heating 76oC. Both mixtures are added to the fertilizer then stirred until the compost is coated. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) were used to characterize the morphology and composition of the products. Addition of thickness to the outer layer of manure reached 35.56 µm. The O-H function group is found in the spectrum of potassium and phosphorus which shows that there is a hydrogen bond in chitosan and potato flour. The most substantial swelling is obtained at the K (chitosan): P (potato flour) ratio of 3:7. The wet retention test showed that the addition of chitosan and potato flour was able to withstand soil retention. In the release test for Phosphorus shows good results at a value of 0.923 mg/L.
{"title":"Phosphate Release from Slow Release fertilizer using a mixture of Chitosan and Potato Flour as a coating","authors":"W. D. P. Rengga, M. A. Mubarok, N. S. Cahyarini","doi":"10.15294/JBAT.V8I1.15289","DOIUrl":"https://doi.org/10.15294/JBAT.V8I1.15289","url":null,"abstract":"Indonesia has a high fertilizer demand because its use is easily dissolved during watering, so the fertilization process is inefficient. On the other hand, crab shells accumulate every year because the waste is almost 50% of the initial weight. One way to overcome this problem is to make a modified fertilizer into a slow release fertilizer by adding a bio-gel layer from chitosan and potato flour. The hydrophobic properties of chitosan and potato powder were chosen in addition to the amylopectin content of potato flour more than other types of starch. Then chitosan was dissolved using acetic acid, while potato starch was dissolved by distilled water by heating 76oC. Both mixtures are added to the fertilizer then stirred until the compost is coated. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) were used to characterize the morphology and composition of the products. Addition of thickness to the outer layer of manure reached 35.56 µm. The O-H function group is found in the spectrum of potassium and phosphorus which shows that there is a hydrogen bond in chitosan and potato flour. The most substantial swelling is obtained at the K (chitosan): P (potato flour) ratio of 3:7. The wet retention test showed that the addition of chitosan and potato flour was able to withstand soil retention. In the release test for Phosphorus shows good results at a value of 0.923 mg/L.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47518963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-07-24DOI: 10.15294/JBAT.V8I1.16318
S. I. Damayanti, Dian Fitriani Astiti, C. Purnomo, S. Sarto, W. Budhijanto
Two-stage anaerobic fluidized bed is an innovation in anaerobic digestion technology intended to handle liquid waste with high organic loading and complex substrate. The process is based on separation between acidogenic/acetogenic and methanogenic processes. The first stage is anaerobic process to convert substrate (represented as soluble chemical oxygen demand/sCOD) into volatile fatty acids (VFA). The second stage is methanogenic process to convert VFA into biogas. This study aimed to separate acidogenic/acetogenic and methanogenic processes by means of limited injection of air (micro-aeration) and inoculum selection. Micro-aeration was introduced in acidogenic/acetogenic stage because the relevant microbes were facultative so that the obligate anaerobic methanogens will be suppressed. On the other hand, the methanogenic reactor was kept completely anaerobic to ensure methanogenic dominance over acidogenic/acetogenic ones. Two sources of inoculums were used in this study, i.e. anaerobically digested biodiesel waste and anaerobically digested cow manure. Both inoculums were taken from active biogas reactor treating biodiesel waste and cow manure, respectively. Experiments were run in batch reactors treating palm oil mill effluent (POME) as the substrate for the acidogenic/acetogenic reactor. After the reaction in the first stage reached the minimum substrate concentration, the content of the reactor was used as the substrate for the methanogenic reactor as the second stage. Routine measurements were taken for sCOD and VFA concentrations, biogas production, and methane concentration in the biogas. Results confirmed that micro-aeration maintained good performance of acidogenic/acetogenic process, which was indicated by peaks in VFA accumulation, while suppressing methanogenic activities as no methane produced in this stage. Digested biodiesel waste was superior inoculum to be compared to digested cow manure with respect to sCOD removal. In the methanogenic stage, digested biodiesel waste also performed better as inoculum as it led to higher VFA conversion, higher biogas production rate, and higher methane content in the biogas.
{"title":"Inoculum Selection and Micro-Aeration for Biogas Production in Two-Stage Anaerobic Digestion of Palm Oil Mill Effluent (POME)","authors":"S. I. Damayanti, Dian Fitriani Astiti, C. Purnomo, S. Sarto, W. Budhijanto","doi":"10.15294/JBAT.V8I1.16318","DOIUrl":"https://doi.org/10.15294/JBAT.V8I1.16318","url":null,"abstract":"Two-stage anaerobic fluidized bed is an innovation in anaerobic digestion technology intended to handle liquid waste with high organic loading and complex substrate. The process is based on separation between acidogenic/acetogenic and methanogenic processes. The first stage is anaerobic process to convert substrate (represented as soluble chemical oxygen demand/sCOD) into volatile fatty acids (VFA). The second stage is methanogenic process to convert VFA into biogas. This study aimed to separate acidogenic/acetogenic and methanogenic processes by means of limited injection of air (micro-aeration) and inoculum selection. Micro-aeration was introduced in acidogenic/acetogenic stage because the relevant microbes were facultative so that the obligate anaerobic methanogens will be suppressed. On the other hand, the methanogenic reactor was kept completely anaerobic to ensure methanogenic dominance over acidogenic/acetogenic ones. Two sources of inoculums were used in this study, i.e. anaerobically digested biodiesel waste and anaerobically digested cow manure. Both inoculums were taken from active biogas reactor treating biodiesel waste and cow manure, respectively. Experiments were run in batch reactors treating palm oil mill effluent (POME) as the substrate for the acidogenic/acetogenic reactor. After the reaction in the first stage reached the minimum substrate concentration, the content of the reactor was used as the substrate for the methanogenic reactor as the second stage. Routine measurements were taken for sCOD and VFA concentrations, biogas production, and methane concentration in the biogas. Results confirmed that micro-aeration maintained good performance of acidogenic/acetogenic process, which was indicated by peaks in VFA accumulation, while suppressing methanogenic activities as no methane produced in this stage. Digested biodiesel waste was superior inoculum to be compared to digested cow manure with respect to sCOD removal. In the methanogenic stage, digested biodiesel waste also performed better as inoculum as it led to higher VFA conversion, higher biogas production rate, and higher methane content in the biogas. ","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43953469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-01-09DOI: 10.15294/JBAT.V7I2.17174
Shinta Amelia, W. B. Sediawan, Z. Mufrodi, T. Ariyanto
Methylene blue is one of the dyes in textile industries which has a negative impact on the environment. This compound is very stable, so it is difficult to degrade naturally. Methylene blue can be harmful to the environment if it is in a very large concentration, because it can increase the value of Chemical Oxygen Demand (COD) which can damage the balance of environment ecosystem. Adsorption method by using activated carbon as the adsorbent is one of the most efficient and effective techniques in dye removal due to its large adsorption capacity. However, the adsorption method using activated carbon only removes the pollutant compounds to other media or phases. Other method that can be used includes Advanced Oxidation Processes (AOPs). This method has the advantage of being able to degrade harmful compounds in the waste through oxidation (oxidative degradation) processes. One method of AOPs is the process by using Fenton reagents. This study was aimed to prepare and characterize iron oxide/porous activated carbon catalyst. The type of porous activated carbon used was carbon from biomass derived carbon with microporous character. This biomass carbon is obtained from renewable natural products, namely coconut shell.The kinetics and adsorption models in the material will be derived and evaluated from the research data. Based on the research, it can be concluded that catalytic degradation is very effective for degradation of dye wastewater. Methylene blue degradation increases with the use of Fe2O3/activated carbon catalyst and the addition of hydrogen peroxide as the Fenton reagent. In addition, the pore structure difference in the catalyst also had a significant effect on the methylene blue degradation reaction resulting in increased capacity of methylene blue degradation reactions.
{"title":"MODIFICATION OF IRON OXIDE CATALYSTS SUPPORTED ON THE BIOMASS BASED ACTIVATED CARBON FOR DEGRADATION OF DYE WASTEWATER","authors":"Shinta Amelia, W. B. Sediawan, Z. Mufrodi, T. Ariyanto","doi":"10.15294/JBAT.V7I2.17174","DOIUrl":"https://doi.org/10.15294/JBAT.V7I2.17174","url":null,"abstract":"Methylene blue is one of the dyes in textile industries which has a negative impact on the environment. This compound is very stable, so it is difficult to degrade naturally. Methylene blue can be harmful to the environment if it is in a very large concentration, because it can increase the value of Chemical Oxygen Demand (COD) which can damage the balance of environment ecosystem. Adsorption method by using activated carbon as the adsorbent is one of the most efficient and effective techniques in dye removal due to its large adsorption capacity. However, the adsorption method using activated carbon only removes the pollutant compounds to other media or phases. Other method that can be used includes Advanced Oxidation Processes (AOPs). This method has the advantage of being able to degrade harmful compounds in the waste through oxidation (oxidative degradation) processes. One method of AOPs is the process by using Fenton reagents. This study was aimed to prepare and characterize iron oxide/porous activated carbon catalyst. The type of porous activated carbon used was carbon from biomass derived carbon with microporous character. This biomass carbon is obtained from renewable natural products, namely coconut shell.The kinetics and adsorption models in the material will be derived and evaluated from the research data. Based on the research, it can be concluded that catalytic degradation is very effective for degradation of dye wastewater. Methylene blue degradation increases with the use of Fe2O3/activated carbon catalyst and the addition of hydrogen peroxide as the Fenton reagent. In addition, the pore structure difference in the catalyst also had a significant effect on the methylene blue degradation reaction resulting in increased capacity of methylene blue degradation reactions.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42399949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-12-27DOI: 10.15294/JBAT.V7I2.14488
H. Hardani, A. Hidayatulloh, A. L. Maesary
The dye-sensitized solar cell (DSSC) is one of the photochemical electrical cells consisting of a photoelectrode, dye, electrolyte, and counter electrode. The purpose of using dyes in the DSSC is to extend the absorption spectrum to visible light because visible light has about 96% energy from sunlight. This article presents some experimental data on the nature of absorbance and the conductivity of natural dyes extracted from the plant as an application in the DSSC. Absorbance test using Spectrophotometer UV Visible 1601 PC and electrical properties test using Elkahfi 100 / Meter I-V. DSSC fabrication has been done using dye extract of mangosteen skin pigment (Garcinia mangostana) with a variety of coating technique of Spin Coating and Slip Casting. The results show that natural dyes from natural material extraction have an absorbance spectrum of 380-520 nm range and the greatest conductivity is owned by mangosteen fruit skin pigment (Garcinia mangostana). From the results of the test using AM Simulator 1.5G (100 mW / cm2) diesel simulator, it was found that the volume of TiO2 precursors affected the performance of DSSC solar cells and the overall conversion efficiency was 0.084% for the mangosteen skin dye by slip casting technique and 0.092% for the mangosteen skin dye by spin coating technique.
{"title":"THE EFFICIENCY OF DYE-SENSITIZED SOLAR CELL (DSSC) IMPROVEMENT AS A LIGHT PARTY TiO2-NANO PARTICLE WITH EXTRACT PIGMENT MANGOSTANA PEEL (Garcinia Mangostana) WITH VARIOUS SOLVENTS","authors":"H. Hardani, A. Hidayatulloh, A. L. Maesary","doi":"10.15294/JBAT.V7I2.14488","DOIUrl":"https://doi.org/10.15294/JBAT.V7I2.14488","url":null,"abstract":"The dye-sensitized solar cell (DSSC) is one of the photochemical electrical cells consisting of a photoelectrode, dye, electrolyte, and counter electrode. The purpose of using dyes in the DSSC is to extend the absorption spectrum to visible light because visible light has about 96% energy from sunlight. This article presents some experimental data on the nature of absorbance and the conductivity of natural dyes extracted from the plant as an application in the DSSC. Absorbance test using Spectrophotometer UV Visible 1601 PC and electrical properties test using Elkahfi 100 / Meter I-V. DSSC fabrication has been done using dye extract of mangosteen skin pigment (Garcinia mangostana) with a variety of coating technique of Spin Coating and Slip Casting. The results show that natural dyes from natural material extraction have an absorbance spectrum of 380-520 nm range and the greatest conductivity is owned by mangosteen fruit skin pigment (Garcinia mangostana). From the results of the test using AM Simulator 1.5G (100 mW / cm2) diesel simulator, it was found that the volume of TiO2 precursors affected the performance of DSSC solar cells and the overall conversion efficiency was 0.084% for the mangosteen skin dye by slip casting technique and 0.092% for the mangosteen skin dye by spin coating technique.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46258542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-12-20DOI: 10.15294/JBAT.V7I2.14925
N. Widiarti, I. Haq, F. W. Mahatmanti, Harjito Harjito, Cepi Kurniawan, S. Suprapto, D. Prasetyoko
CaO is a very good catalyst for oil transesterification reactions into biodiesel, but requires a reaction time of 2 hours to obtain equilibrium. The time of CaO catalysis reaction can be accelerated by modifying the CaO catalyst with SrO. Synthesis biodiesel of waste cooking oil has been successfully conducted by transesterification reaction that used batch reactor assisted by CaO.SrO catalyst. The aim of this study is to determine the characteristics and catalytic activity of catalyst in the transesterification reaction. Catalysts have been successfully synthesized by coprecipitation method with oil to methanol molar ratio of 1:1, and its calcined at 800oC for 3 hours. Catalyst was characterized by XRD to determine the crystallinity. The smaller catalyst crystallinity obtained as the decline in intensity and shifts diffraction angles of CaO modified SrO catalyst. Surface area of catalyst characterized by SAA, that allow surface area between CaO modified SrO by 10.217 m2/g. Transesterification reaction performed on variation time (30, 60, 90, 120, 150 minutes), and the catalysts amount (1, 2, 4, 6, 8% w/v). The optimum condition of catalytic activity in reaction for 2 hours and the catalyst amount is 1% w/v of reactants that produce yield of biodiesel is 96.4%.
{"title":"Biodiesel Synthesis From Waste Cooking Oil Using CaO.SrO Catalyst By Transesterification Reaction In Batch Reactor","authors":"N. Widiarti, I. Haq, F. W. Mahatmanti, Harjito Harjito, Cepi Kurniawan, S. Suprapto, D. Prasetyoko","doi":"10.15294/JBAT.V7I2.14925","DOIUrl":"https://doi.org/10.15294/JBAT.V7I2.14925","url":null,"abstract":"CaO is a very good catalyst for oil transesterification reactions into biodiesel, but requires a reaction time of 2 hours to obtain equilibrium. The time of CaO catalysis reaction can be accelerated by modifying the CaO catalyst with SrO. Synthesis biodiesel of waste cooking oil has been successfully conducted by transesterification reaction that used batch reactor assisted by CaO.SrO catalyst. The aim of this study is to determine the characteristics and catalytic activity of catalyst in the transesterification reaction. Catalysts have been successfully synthesized by coprecipitation method with oil to methanol molar ratio of 1:1, and its calcined at 800oC for 3 hours. Catalyst was characterized by XRD to determine the crystallinity. The smaller catalyst crystallinity obtained as the decline in intensity and shifts diffraction angles of CaO modified SrO catalyst. Surface area of catalyst characterized by SAA, that allow surface area between CaO modified SrO by 10.217 m2/g. Transesterification reaction performed on variation time (30, 60, 90, 120, 150 minutes), and the catalysts amount (1, 2, 4, 6, 8% w/v). The optimum condition of catalytic activity in reaction for 2 hours and the catalyst amount is 1% w/v of reactants that produce yield of biodiesel is 96.4%.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46905253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-12-16DOI: 10.15294/jbat.v7i2.11623
R. A. Nugrahani, T. Hendrawati, Susanty Susanty
The need for environmentally friendly chemical products in daily needs encourages the production of its. The green-chemistry concept is using the process and produces chemical products that are ecofriendly. Including ecofriendly chemical products are base oil and additives for lubricants, grease, and fuels. The production is expected to reduce the consumption of mineral and synthetic base oils, so it will be biodegradable and renewable. This study compares the results of analysis of metallic surfaces immersed in the mixture of mineral and vegetable base oil, with the addition of rice bran oil bioadditive, ie epoxidized methyl ester (EME) and hydroxyl alkylbenzene sulphonic acid ester (HASE). The research method consists of preparing HASE; analyzing the effect of HASE and EME bioadditives addition on the mixture of base oil to the changing of metallic weight immersed in the mixture; determining the inhibition efficiency of the EME and HSAE additions; analyzing the metal surface using SEM-EDX (Scanning Electron Microscope) / (Energy Dispersive X-ray Spectrometry) to find images of microstructure and chemical compounds contained in specimens, and testing the metal difractogram immersed in base oil mixtures with bioadditive using XRD (X-Ray Diffraction). SEM test results of carbon steel immersed in a mixture of base oil and bioadditives show corrosion in which the metal surface color immersed in EME bioadditive mixtures is brighter. EDX spectra of metal sample surfaces immersed in a mixture of base oil, EME and HASE contain carbon (C) and iron (Fe). The carbon content in carbon steel samples immersed in the mixtures and HASE is higher. XRD test results show Fe2O3 phases in carbon steel samples immersed in the HASE bioadditive mixture are higher than in EME. While Fe3O4 phases in carbon steel samples immersed in the EME bioadditive mixture are higher than Fe2O3 phases in samples immersed in HASE bioadditive mixture.
{"title":"AN ANALYSIS OF METAL SURFACE IMMERSED IN BASED LUBRICANT FROM MINERAL OIL CONTAINING VEGETABLE OIL WITH RICE BRAN OIL BASED BIO-INHIBITOR","authors":"R. A. Nugrahani, T. Hendrawati, Susanty Susanty","doi":"10.15294/jbat.v7i2.11623","DOIUrl":"https://doi.org/10.15294/jbat.v7i2.11623","url":null,"abstract":"The need for environmentally friendly chemical products in daily needs encourages the production of its. The green-chemistry concept is using the process and produces chemical products that are ecofriendly. Including ecofriendly chemical products are base oil and additives for lubricants, grease, and fuels. The production is expected to reduce the consumption of mineral and synthetic base oils, so it will be biodegradable and renewable. This study compares the results of analysis of metallic surfaces immersed in the mixture of mineral and vegetable base oil, with the addition of rice bran oil bioadditive, ie epoxidized methyl ester (EME) and hydroxyl alkylbenzene sulphonic acid ester (HASE). The research method consists of preparing HASE; analyzing the effect of HASE and EME bioadditives addition on the mixture of base oil to the changing of metallic weight immersed in the mixture; determining the inhibition efficiency of the EME and HSAE additions; analyzing the metal surface using SEM-EDX (Scanning Electron Microscope) / (Energy Dispersive X-ray Spectrometry) to find images of microstructure and chemical compounds contained in specimens, and testing the metal difractogram immersed in base oil mixtures with bioadditive using XRD (X-Ray Diffraction). SEM test results of carbon steel immersed in a mixture of base oil and bioadditives show corrosion in which the metal surface color immersed in EME bioadditive mixtures is brighter. EDX spectra of metal sample surfaces immersed in a mixture of base oil, EME and HASE contain carbon (C) and iron (Fe). The carbon content in carbon steel samples immersed in the mixtures and HASE is higher. XRD test results show Fe2O3 phases in carbon steel samples immersed in the HASE bioadditive mixture are higher than in EME. While Fe3O4 phases in carbon steel samples immersed in the EME bioadditive mixture are higher than Fe2O3 phases in samples immersed in HASE bioadditive mixture.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49357476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-12-16DOI: 10.15294/JBAT.V7I2.13254
S. Gala, M. Mahfud, S. Sumarno, L. Qadariyah
Currently, exploration of natural dyes is increasingly being activated and developed, especially to find natural sources of dyes from different plant species and also to develop natural dyestuff extraction process technology for textile applications. During this natural dye extraction process is done by conventional methods that require a long time and a large amount of solvent. Therefore, it is a necessary alternative to the use of "green techniques" are economical in its use. In this research, extraction of Jackfruit wood waste with the microwave by studying the extraction time required to produce the optimum yield and comparing with the conventional method (heat-reflux extraction). Both of these methods use water solvent. On the microwave-assisted extraction, the optimum extraction time at 30 minutes with the acquisition yield of 3.14% (microwave power 400 watt, the ratio of material to solvent 0.02 g/mL). whereas extraction with heat-reflux method showed the optimum extraction time of 180 minutes with a yield of 3.50%. Identification of groups of pigments contained in the Jackfruit wood waste is known categories tannins, flavonoids, and quinones. Fourier Transform Infrared Spectroscopy was used to identify the major chemical groups in the extracted dye. Description of the effects of extraction with microwave and conventional, structural damage shown in a solid surface material using by Scanning Electron Microscopy. Further, to test the application on the fabric dyeing.
{"title":"THE EXTRACTION OF NATURAL DYES FROM JACKFRUIT WOOD WASTE (Artocarpus Heterophyllus Lamk) WITH WATER SOLVENT BY USING THE MICROWAVE METHOD","authors":"S. Gala, M. Mahfud, S. Sumarno, L. Qadariyah","doi":"10.15294/JBAT.V7I2.13254","DOIUrl":"https://doi.org/10.15294/JBAT.V7I2.13254","url":null,"abstract":"Currently, exploration of natural dyes is increasingly being activated and developed, especially to find natural sources of dyes from different plant species and also to develop natural dyestuff extraction process technology for textile applications. During this natural dye extraction process is done by conventional methods that require a long time and a large amount of solvent. Therefore, it is a necessary alternative to the use of \"green techniques\" are economical in its use. In this research, extraction of Jackfruit wood waste with the microwave by studying the extraction time required to produce the optimum yield and comparing with the conventional method (heat-reflux extraction). Both of these methods use water solvent. On the microwave-assisted extraction, the optimum extraction time at 30 minutes with the acquisition yield of 3.14% (microwave power 400 watt, the ratio of material to solvent 0.02 g/mL). whereas extraction with heat-reflux method showed the optimum extraction time of 180 minutes with a yield of 3.50%. Identification of groups of pigments contained in the Jackfruit wood waste is known categories tannins, flavonoids, and quinones. Fourier Transform Infrared Spectroscopy was used to identify the major chemical groups in the extracted dye. Description of the effects of extraction with microwave and conventional, structural damage shown in a solid surface material using by Scanning Electron Microscopy. Further, to test the application on the fabric dyeing.","PeriodicalId":17764,"journal":{"name":"Jurnal Bahan Alam Terbarukan","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45048895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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