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Effect of ultraviolet light on the degradation of Low-Density and High-Density Polyethylene characterized by the weight loss and FTIR 紫外光对低密度和高密度聚乙烯降解失重和红外光谱的影响
Pub Date : 2019-07-24 DOI: 10.54279/mijeec.v1i2.244915
Prakash Bhuyar, Nurul Aqilah Binti Mohd Tamizi, Mohd Hasbi Ab. Rahim, Gaanty Pragas Maniam, Natanamurugaraj Govindan
In this study, the research was made to understand the knowledge widely related to the degradation process of polyethylene polymer. The mode of treatment that involves in the degradation process of polyethylene is physical treatment while the method of degradation used is photo-degradation of UV light. By using the physical treatment of UV irradiation light, it helps by affecting the bonding that holds the polymer together to break and weakens the plastic. From the result obtained in FTIR and SEM analysis, in FTIR spectrum of LDPE shows higher transmittance compared to FTIR spectrum of HDPE both UV-treated for 30 days. This indicates the high transmittance have few bonds to absorb light in the LDPE sample, low transmittance in HDPE sample means has high population of bonds which have vibrational energies corresponding to the incident light. For SEM result, the polyethylene for LDPE plastic sheet shows the best results for degradation and managed to reduce the weight loss at 87.5% compared to HDPE plastic which at 21.6%.
本研究旨在了解聚乙烯聚合物降解过程中广泛存在的相关知识。聚乙烯降解过程中涉及的处理方式为物理处理,降解方法为紫外光光降解。通过使用紫外线照射光的物理处理,它可以通过影响将聚合物结合在一起的键来破坏和削弱塑料。从FTIR和SEM分析得到的结果来看,经过30天的紫外处理,LDPE的FTIR光谱比HDPE的FTIR光谱显示出更高的透过率。这说明高透射率的LDPE样品中吸收光的键数较少,而低透射率的HDPE样品中吸收光的键数较多,其振动能量与入射光相对应。SEM结果显示,用于LDPE塑料片材的聚乙烯表现出最好的降解效果,与HDPE塑料片材的21.6%相比,聚乙烯片材的重量损失减少了87.5%。
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引用次数: 2
Membrane fouling issues in anaerobic membrane bioreactors (AnMBRs) for biogas production 厌氧膜生物反应器(anmbr)的膜污染问题
Pub Date : 2019-07-03 DOI: 10.54279/mijeec.v1i2.244911
Prattakorn Sittisom, Obey Gotore, Rameshprabu Ramaraj, Giang Tran Van, Yuwalee Unpaprom, Tomoaki Itayama
Anaerobic Membrane Bioreactor (AnMBR) technology in recent years has been actively used for municipal and industrial wastewater treatment. Also, AnMBR technology has been considered as an alternative wastewater treatment application over conventional activated sludge system. AnMBRs are best possible operated with flat sheet, hollow fiber, or tubular membranes both in the microfiltration or in the ultrafiltration, but on ceramic membrane use has not been reported widely. AnMBRs are a desirable technology that needs additional research efforts and development. However, membrane fouling, which continues a major problem for all membrane bioreactors, seems much more serious under anaerobic than aerobic conditions. In this review, membrane fouling issues (including membrane fouling mechanism, classification, influent parameters, and mitigation) were discussed and summarized. Moreover, in fouling control, biogas sparging and recirculation (i.e. methane production) were addressed. Lastly, future research perspectives relating to its application and membrane fouling research are planned.
厌氧膜生物反应器(AnMBR)技术近年来在城市和工业废水处理中得到了积极的应用。此外,AnMBR技术已被认为是替代传统活性污泥系统的污水处理应用。在微滤或超滤中,anmbr最好使用平板膜、中空纤维膜或管状膜,但陶瓷膜的使用尚未广泛报道。anmbr是一项需要额外研究和开发的理想技术。然而,膜污染是所有膜生物反应器的主要问题,在厌氧条件下似乎比好氧条件下更为严重。本文就膜污染的机理、分类、进水参数及防治等方面进行了综述。此外,在污染控制方面,解决了沼气喷射和再循环(即甲烷生产)问题。最后,对其应用和膜污染研究的未来研究方向进行了展望。
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引用次数: 4
Experimental study on liquid spray and small droplet formation in ethanol-oil system in a DC electric field 直流电场作用下乙醇-油系统液体喷射及小液滴形成的实验研究
Pub Date : 2019-06-05 DOI: 10.54279/mijeec.v1i2.244909
Dongbao Wang, Junfeng Wang, Piyaphong Yongphet
A detailed experimental study on the evolution process of charged liquid deformation and breakup in another immiscible liquid from a capillary channel was conducted at micro-scale. By means of high-speed microscopy technique, various liquid spray modes and droplet formation processes were illustrated in detail at different flow rates and voltages. The effects of Reynolds (Re) and electric Bond (BoE) number on droplet size distribution were analyzed. It was found that droplet sizes rose with increasing Re while declined with increasing BoE. The experimental results show that electric field could promote interfacial area through decreasing interfacial tension to augment mass transfer between immiscible liquids at low flow rates. Besides, liquid spray experienced drip, deformation, breakup and jet modes with the increase of flow rate and electric potential. A critical Re of 170 was obtained beyond which electric field had little effect on liquid dynamic behaviors.
在微观尺度上对毛细管通道中带电液体的变形和破碎演化过程进行了详细的实验研究。利用高速显微镜技术,对不同流速和电压下的液体喷射方式和液滴形成过程进行了详细的研究。分析了雷诺数(Re)和电键数(BoE)对液滴尺寸分布的影响。液滴尺寸随Re的增大而增大,随BoE的增大而减小。实验结果表明,在低流速下,电场可以通过降低界面张力来扩大界面面积,增加非混相液体间的传质。随着流速和电势的增大,液体喷雾经历了滴注、变形、破裂和喷射等模式。在临界Re为170时,电场对液体动力学行为影响不大。
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引用次数: 0
Mixed domestic-waste catalysts for methyl ester production of soybean oil 生活垃圾混合催化剂制备大豆油甲酯
Pub Date : 2019-05-20 DOI: 10.54279/mijeec.v1i2.244908
Siti Norhafiza Mohd Khazaai, Nurul Aina Nasriqah Ma’arof, Nurul Hajar Embong, Mohd Hasbi Ab. Rahim, Gaanty Pragas Maniam
Nowadays due to the depletion of non-renewable energy resources, production of green material from domestic wastes has played an important role. The waste of banana peel impregnated with calcium oxide (CaO) from eggshell had successfully been used as a low-cost catalyst to transesterify soybean oil to produce methyl ester. The catalytic actions from potassium and calcium oxide content in calcined banana peel (700°C) and eggshell (900°C) discover through FT-IR, XRD, and SEM. Methyl ester conversion can be obtained at 76.87 wt.% with the optimal condition of 7 wt.% of catalyst amount, methanol/oil mass ratio, 9:1; and the reaction temperature, 65 °C within 2 h reaction time.
随着不可再生能源资源的日益枯竭,利用生活垃圾生产绿色材料发挥了重要作用。以蛋壳氧化钙(CaO)浸渍的香蕉皮废料为催化剂,成功地进行了大豆油酯交换制甲酯的研究。通过红外光谱(FT-IR)、x射线衍射(XRD)和扫描电镜(SEM)研究了氧化钾和氧化钙含量对香蕉皮(700℃)和蛋壳(900℃)煅烧过程的催化作用。催化剂用量为7 wt.%,甲醇/油质量比为9:1时,甲酯转化率为76.87 wt.%;反应温度为65℃,反应时间为2 h。
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引用次数: 0
Mathematical model of germinated paddy drying 发芽稻谷干燥的数学模型
Pub Date : 2019-04-10 DOI: 10.54279/mijeec.v1i1.244900
Hathaichanok Netkham, Supawan Tirawanichakul, Sirinuch Chindaruksa, Yutthana Tirawanichakul
The objective of this research was to predict the moisture content of Sang Yod germinated paddy with infrared radiation power value of 1,000 watts at 60, 80 and 100 °C and hot air temperatures of velocity 1.1 m/s at 60, 80 and 100°C using empirical model. In this research, the moisture content of the dried samples was compared with the moisture content of the drying using the empirical model. The results showed that Verma model was most suitable to describe the drying behavior of germinated paddy at 60, 80 and 100 °C drying temperature when dried with infrared and hot air.
本研究的目的是利用经验模型预测60、80和100℃下红外辐射功率为1000瓦,60、80和100℃下热风温度为1.1 m/s时桑枣发芽水稻的含水量。在本研究中,利用经验模型对干燥样品的含水率与干燥后的含水率进行了比较。结果表明,在红外和热空气干燥条件下,Verma模型最适合描述萌发水稻在60、80和100℃干燥温度下的干燥行为。
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引用次数: 0
Assessment of the biogas potential from agricultural waste in northern Thailand 泰国北部农业废弃物沼气潜力评估
Pub Date : 2019-03-20 DOI: 10.54279/mijeec.v1i1.244899
Jiraporn Kaewdiew, Rameshprabu Ramaraj, Sirichai Koonaphapdeelert, Natthawud Dussadee
In 2014-2015, there was approximately 26,823.44 x106 kg of the residue leftover from agricultural products in Northern Thailand and roughly 18,943.57x106 kg or 70.62% were left unutilized. The aim of this research was to survey and calculate the proportion of agricultural area and products as well as their corresponding waste towards potential of biogas production using biochemical methane potential (BMP) method. The results showed that rice straw was the most promising feedstock for methane production with the highest biogas yield of 363 mlN /gVSadded followed by sugarcane leaves and corn cob having 333 and 318 mlN/gVSadded, respectively. Additionally, the predicted areas for growing rice and corn decreased. Meanwhile areas for growing cassava, sugarcane and oil palm increase slightly. This study also found out that the unused agricultural waste generation was decreased due to improved waste utilization.
2014-2015年,泰国北部约有26,823.44 x106 kg的农产品残留物,约有18,943.57x106 kg或70.62%未被利用。本研究的目的是利用生物化学甲烷势(BMP)法调查和计算农业面积和农产品及其相应的废弃物占沼气生产潜力的比例。结果表明,水稻秸秆是最有希望生产甲烷的原料,其沼气产量最高,为3.63亿n / gvsadd,其次是甘蔗叶片和玉米芯,分别为3.33和3.18亿n / gvsadd。此外,水稻和玉米的预测种植面积也有所减少。与此同时,木薯、甘蔗和油棕的种植面积略有增加。本研究还发现,由于废物利用率的提高,未使用的农业废物产生量减少了。
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引用次数: 10
Optimization of combined pre-treatments on sugarcane leaves for bioethanol production 甘蔗叶片生物乙醇复合预处理工艺优化
Pub Date : 2019-03-15 DOI: 10.54279/mijeec.v1i1.244898
Numchok Manmai, Katherine Bautista, Yuwalee Unpaprom, Rameshprabu Ramaraj
This paper reports the comparison of an optimized pretreatment model for Reducing Sugar (RS) production from Sugarcane leaf (SL) using NaOH to depolymerize of lignocellulosic biomass. The addition variables for a pretreatment model consisted of NaOH concentrations, heating temperatures and pretreatment times in the variety of 1-2% (v/v), 30-40 °C and 1-3 days individually. After pretreatment RS was estimated to transform into energy, both of RS and the energy were optimized by Respond surface methodology (RSM) on Central composite design (CCD). The models showed high determinational coefficients (R2) above 0.9876. Process optimization provided highest RS yield and energy of 5.632 g/L and 90.112 kJ/L. for NaOH pretreatment at condition 2% (v/v) NaOH, low temperature (40 °C) for 3 days. This report presented demonstrate that sugarcane leaf waste which is usually burnt after harvesting can be a part of renewable source for the biofuel production.
本文报道了一种优化的预处理模式,比较了用NaOH解聚木质纤维素生物质从甘蔗叶(SL)生产还原糖(RS)的效果。预处理模型的添加变量包括NaOH浓度、加热温度和预处理时间,分别为1-2% (v/v)、30-40°C和1-3天。在预估RS转化为能量后,采用响应面法(RSM)在中心复合设计(CCD)上对RS和能量进行优化。模型的确定系数(R2)均在0.9876以上。优化后的RS产率最高,能量为5.632 g/L和90.112 kJ/L。NaOH预处理在2% (v/v) NaOH条件下,低温(40℃)预处理3天。该报告展示了通常在收获后燃烧的甘蔗叶废料可以成为生物燃料生产的可再生资源的一部分。
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引用次数: 18
Effect of salt on growth and ethanol production of ethanologenic yeasts – A preliminary investigation 盐对产乙醇酵母生长和产乙醇影响的初步研究
Pub Date : 2019-03-10 DOI: 10.54279/mijeec.v1i1.244897
Binita Dev, Balasubramanian P, Jayabalan R
Seawater can reduce the freshwater footprint in bioethanol industries by replacing it in several bioprocessing steps in bioethanol production. However, the yeasts must be salt tolerant and be able to produce ethanol in seawater. In the present study, the salt tolerance capacity of two ethanologenic yeasts was checked in YPD and YPX media in the presence and absence of salt by comparing their growth and fermentation ability to produce ethanol. P. stiptis NCIM 3498 performed better regarding ethanol production when compared to S. cerevisiae NCIM 3570. The presence of salt did not impact the glucose and xylose fermentation by the yeasts.
在生物乙醇生产的几个生物处理步骤中,海水可以替代淡水,从而减少生物乙醇工业的淡水足迹。然而,酵母必须耐盐,并能在海水中产生乙醇。本研究通过比较两种产乙醇酵母在YPD和YPX培养基中生长和发酵产乙醇的能力,考察了两种产乙醇酵母在有盐和无盐条件下的耐盐能力。与酿酒葡萄球菌NCIM 3570相比,P. stiptis NCIM 3498在乙醇生产方面表现更好。盐的存在不影响酵母对葡萄糖和木糖的发酵。
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引用次数: 1
Biodiesel production from catfish (Pangasius) fat via ultrasound- assisted method 超声波辅助鲶鱼脂肪生产生物柴油
Pub Date : 2019-02-20 DOI: 10.54279/mijeec.v1i1.244896
Intan Shafinaz Abd Manaf, Mohd Hasbi Ab. Rahim, Gaanty Pragas Maniam
This paper reports studies in ultrasound-assisted heterogeneous solid catalyzed (CaO) synthesis of biodiesel from catfish (Pangasius) fat. Ultrasonication provides a faster chemical reaction, and the rate enhancements, refereed by cavitation that causes the building- up of pressures and temperatures, as well as increased catalytic surface areas and improve mass transfer. This novel method offers significant advantages such as shorter reaction time and less energy consumption than the conventional method, efficient molar ratio of methanol to triglycerides and provides the mechanical energy for mixing. The required activation energy for initiating the transesterification reaction and so, it gives a higher yield by transesterification of oils into biodiesel. The optimized reaction conditions were as follows: methanol to oil molar ratio of 15:1; catalyst (B-CaO), 9 wt. %; reaction temperature, 65 ± 2 °C; reaction time, 1 h at a working frequency of 42 kHz and the power supply of 100W. Highest conversion of 96.4 wt. % was achieved.
本文报道了超声辅助非均相固体催化(CaO)合成鲶鱼脂肪生物柴油的研究。超声波提供了一个更快的化学反应和速度的提高,参考的空化,导致压力和温度的积累,以及增加催化表面积和改善传质。与传统方法相比,该方法具有反应时间短、能耗低、甲醇与甘油三酯的摩尔比高、为混合提供机械能等显著优点。启动酯交换反应所需的活化能,因此,将油脂酯交换成生物柴油的产率更高。优化后的反应条件为:甲醇与油的摩尔比为15:1;催化剂(B-CaO), 9 wt. %;反应温度65±2℃;反应时间为1 h,工作频率为42 kHz,电源为100W。最高转化率达到96.4 wt. %。
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引用次数: 0
A selective microalgae strain for biodiesel production in relation to higher lipid profile 与高脂质相关的生物柴油生产的选择性微藻菌株
Pub Date : 2019-02-05 DOI: 10.54279/mijeec.v1i1.244895
Prakash Bhuyar, Mohd Hasbi Ab. Rahim, Mashitah M. Yusoff, Gaanty Pragas Maniam, Natanamurugaraj Govindan
Biodiesel have become the important asset by the country especially to build up their economy. Currently, microalgae have been choosing as the source for production of biodiesel based on their advantages. Microalgae are a photosynthetic organism that use light as an energy source and able to produce their own food. These microalgae also produce a lipid that can be used to produce a biodiesel. Using microalgae that contain high lipid profile are very important to make sure the biodiesel can be produce in large quantity in short time and more cost saving. Although many microalgae species have been identified and isolated for lipid production, there is currently no consensus as to which species provide the highest productivity. Different species are expected to function best at different aquatic, geographical and climatic conditions. So, this experiment is conducted to identify which strain of microalgae contains high lipid profile that can be used to convert into the biodiesel. There are three main objectives that involve in this experiment which is to isolate and identify different strain of microalgae from Kuantan Coast, East Coast Peninsular Malaysia, to convert the lipid from microalgae into biodiesel through transesterification, and to estimate higher lipid profile of microalgae species for biodiesel production. Two species of green microalgae were isolated, which is Nannochloropsis sp and Coelastrum sp. Based on lipid extraction and lipid analysis, it shows that the Nannochloropsis sp. have more concentrated of lipid and higher lipid profile compared to Coelastrum sp. Hence, Nannochloropsis sp. are most suitable species that can be used as a biodiesel feedstock due to higher lipid profile of MUFA.
生物柴油已成为各国特别是建设经济的重要资产。目前,微藻因其自身的优势已成为生物柴油生产的首选原料。微藻是一种利用光作为能源的光合生物,能够自己生产食物。这些微藻还能产生一种脂质,可用于生产生物柴油。利用高脂微藻是保证生物柴油在短时间内大批量生产和节约成本的重要手段。虽然许多微藻物种已经被鉴定和分离用于生产脂质,但目前还没有共识,哪种物种提供最高的生产力。预计不同的物种在不同的水生、地理和气候条件下发挥最佳作用。因此,本实验旨在确定哪一株微藻含有高脂质,可用于转化为生物柴油。本实验有三个主要目的:分离和鉴定来自马来西亚东海岸关丹海岸的不同微藻菌株,通过酯交换将微藻中的脂质转化为生物柴油,以及估计用于生物柴油生产的微藻物种的更高脂质谱。通过脂质提取和脂质分析,发现纳米绿藻的脂质浓度更高,脂质谱也更高。因此,纳米绿藻具有较高的MUFA脂质谱,是最适合作为生物柴油原料的种。
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引用次数: 6
期刊
Maejo International Journal of Energy and Environmental Communication
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