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Biodiesel production by microalgae Nannochloropsis sp. grown in palm oil mill effluent 棕榈油厂废水中生长的微藻纳米绿藻生产生物柴油
Pub Date : 2020-10-07 DOI: 10.54279/mijeec.v2i3.245036
Karthiani Kanagesan, Karthick Murugan Palanisamy, Gaanty Pragas Maniam, Mohd Hasbi Ab. Rahim, Natanamurugaraj Govindan
A marine microalga, Nannochloropsis sp., was discovered in a water body in Teluk Cempedak, Kuantan, Pahang. In Nannochloropsis sp., for biomass and lipid synthesis, POME was used as a substitute medium. The isolated monoculture was grown in various concentrations of POME (5%, 10%, 15%, and 20%), as well as a standard control medium. Nannochloropsis sp. showed greater cell growth at 10% POME, with a maximum dry biomass of 1.504 g L-1 and extracted 35.9% lipid after 14 days of flask cultivation. Fatty acids namely oleic acid, linoleic acid, palmitic acid, and stearic acid were shown to be prominent in GC-MS analysis. The fatty acid oleic acid has been discovered to be the most abundant (73.40%). POME has the prospective to be used as a growth media for the cultivation of microalgae Nannochloropsis sp.
在彭杭州关丹省的铁鹿山佩扎一水体中发现了一种海洋微藻——纳米绿藻。在Nannochloropsis sp.中,POME被用作生物质和脂质合成的替代培养基。在不同浓度的POME(5%, 10%, 15%和20%)以及标准对照培养基中培养分离的单株。在10% POME条件下,纳米叶绿体的细胞生长速度更快,干燥生物量最大达1.504 g L-1,培养14天后,其脂质提取率为35.9%。脂肪酸即油酸、亚油酸、棕榈酸和硬脂酸在GC-MS分析中被证明是突出的。其中脂肪酸油酸含量最高(73.40%)。POME是一种极具发展前景的微藻生长培养基。
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引用次数: 0
Synthesis and characterization of TiO2 and palm oil fiber ash hybrid photocatalysts for seawater pretreatment 海水预处理用TiO2与棕榈油纤维灰杂化光催化剂的合成与表征
Pub Date : 2020-09-16 DOI: 10.54279/mijeec.v2i3.245035
Abdulkarim Abdulrahman Mohamed Suliman, Ruzinah Isha, Mazrul Nizam Abu Seman, Abdul Latif Ahmad
Titanium dioxide (TiO2) has been used in various applications such as air purification, water purification, and photoelectrochemical conversion systems. However, developing advanced materials with enhanced performance for catalytic applications, especially water treatment, is highly required. This work aims to study the effect of (TiO2) photocatalyst in pretreatment seawater desalination. The catalyst with a mass ratio of TiO2: palm oil fibre ash (POFA) at 0:100, 40:60, 60:40, and 100:0 was synthesized via wet impregnation. The catalyst was calcined at 500 ℃ for four hours. The mixture of artificial seawater and catalyst at a mass ratio of photocatalyst: artificial seawater at 1:300 was put in a one-litre borosilicate photo-reactor fixed with mercury light of 350 nm for two hours with stirring at 1000 rpm. In this investigation, an evaporator was used to collect the freshwater. The fresh and spent catalysts were characterized via X-Ray Diffractogram (XRD), Nitrogen physisorption analysis, Diffuse Reflectance Spectrometer (DRS), Scanning Electron Microscopy (SEM), and Energy Dispersive X-Ray Spectroscopy (EDX). The catalyst with Ti: palm oil fibre ash (POFA) at 40:60 and 60:40 can reduce the COD at 45 % and 41%, respectively. As more OPFA was added into the hybrid TiO2 catalyst, there has been a change in the properties of seawater due to the use of special evaporators, especially EC and TDS. It can be deduced that the hybrid TiO2 photocatalyst synthesized with OPFA has vast potential to treat seawater.
二氧化钛(TiO2)在空气净化、水净化、光电化学转化系统等领域有着广泛的应用。然而,开发具有增强催化应用性能的先进材料,特别是水处理,是迫切需要的。本文旨在研究(TiO2)光催化剂在海水淡化预处理中的作用。通过湿浸渍法合成了TiO2与棕榈油纤维灰分(POFA)质量比为0:100、40:60、60:40和100:0的催化剂。催化剂在500℃下煅烧4小时。将光催化剂与人工海水质量比为1:300的人造海水与催化剂的混合物置于350 nm汞光固定的1升硼硅光反应器中,以1000 rpm搅拌2小时。在本次调查中,使用蒸发器收集淡水。通过x射线衍射(XRD)、氮物理吸附分析、漫反射光谱仪(DRS)、扫描电镜(SEM)和能量色散x射线能谱(EDX)对新鲜催化剂和废催化剂进行了表征。钛与棕榈油纤维灰分(POFA)比例为40:60和60:40的催化剂,COD分别降低45%和41%。随着在杂化TiO2催化剂中加入更多的OPFA,由于使用了特殊的蒸发器,特别是EC和TDS,海水的性质发生了变化。由此可以推断,用OPFA合成的杂化TiO2光催化剂在处理海水方面具有巨大的潜力。
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引用次数: 2
Treatment of Chromium in Wastewater by using Loquat Leaves as Biosorbent 枇杷叶作为生物吸附剂处理废水中的铬
Pub Date : 2020-08-28 DOI: 10.54279/mijeec.v2i3.244961
Ching-Hua Liao, Jer-Yuan Shiu, Chi-En Hung, Chih-Hung Wu, Ming-Zhong Liu
Heavy metal pollution generating from industries is a serious issue in China as it causes severe environmental pollution and health problems. Chromium is one of the common heavy metal appeared in wastewater of metal plating and processing industries and has to reduce its concentration to permissible levels before discharge by law. This study focused on removing chromium ion present in wastewater by using bioresource material loquat leaves as an adsorbent. The extent of adsorption of chromium ion was studied and found to be dependent on solution contact time with the adsorbent, particle size and dosage of the loquat leaves and chromium concentration. The result showed that the loquat leaves have a 70% efficiency in removing chromium ions. The experimental equilibrium biosorption data were analyzed by two widely used isotherms namely Langmuir, and Freundlich. The Langmuir isotherm model better fits the experimental data than the Freundlich isotherm model by high correlation coefficients R2. The maximum monolayer capacity of loquat leaves was found to be 0.0201 mg/g for Chromium ions.
工业产生的重金属污染在中国是一个严重的问题,因为它会造成严重的环境污染和健康问题。铬是金属电镀和加工工业废水中常见的重金属之一,必须将其浓度降低到法律允许的水平才能排放。研究了利用生物资源枇杷叶作为吸附剂去除废水中的铬离子。研究了吸附剂对铬离子的吸附程度,发现吸附剂与溶液接触时间、枇杷叶的粒径和用量以及铬浓度对铬离子的吸附程度有一定的影响。结果表明,枇杷叶对铬离子的去除率达70%。采用Langmuir等温线和Freundlich等温线对实验平衡吸附数据进行了分析。Langmuir等温线模型比Freundlich等温线模型具有较高的相关系数R2,能更好地拟合实验数据。枇杷叶片对铬离子的最大单层容量为0.0201 mg/g。
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引用次数: 0
Application of edible coating and active packaging to extend shelf life of mango under atmosphere temperature 常温下可食用涂层和活性包装延长芒果货架期的应用
Pub Date : 2020-08-17 DOI: 10.54279/mijeec.v2i3.244960
Heryoki Yohanes, Chen-Yeon Chu, Hardaning Pranamuda, Mei-Feng Lai, Harianto, Wiwik Handayani
Two types of edible fruit coating and an active packaging were tested for their effect during 15 days of storage at atmosphere condition (24-25oC) with 60-70 % RH. One coating was alginate-based, while the other hand had palm oil-based as the main ingredient. These two coatings exhibit weight loss reduction and appearance change compared to uncoated, but only the palm-based coating delay ripening can extend 10 days of shelf life during storage. On the other side, Active packaging can effectively delay ripening during 15 days of storage. Moreover, these results show that active packaging might be a viable alternative to extend mango's shelf life because it can maintain weight loss below 3% during storage at atmospheric conditions.
在60- 70%相对湿度、24-25℃的常压条件下,对两种可食性水果包衣和活性包装在15天内的保鲜效果进行了试验。一种涂层以海藻酸盐为基础,而另一种涂层以棕榈油为主要成分。与未涂覆的涂层相比,这两种涂层表现出重量减轻和外观变化,但只有棕榈基涂层延迟成熟才能在储存过程中延长10天的保质期。另一方面,活性包装可以在15天的储存期间有效地延缓成熟。此外,这些结果表明,活性包装可能是延长芒果保质期的可行选择,因为它可以在大气条件下储存期间将重量损失保持在3%以下。
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引用次数: 0
Development of wound healing spray from keratin protein 角蛋白创面愈合喷雾的研制
Pub Date : 2020-06-10 DOI: 10.54279/mijeec.v2i2.245032
Mohamed Saad Bala, Kan Weng Chin, Basma Yahya Alashwal, Arun Gupta
Wound healing spray was developed from keratin protein extracted from a chicken feather in the study. Keratin is the most abundant protein in epithelial cells. Keratin was proven for wound healing ability because it can activate the keratinocyte in the skin responsible for wound healing. However, keratin wound healing spray is new to the market and has the potential to heal the wound gentle and pain-free. This study synthesized the keratin wound healing spray from chicken feathers and determined the character of the keratin wound healing spray. Keratin protein was extracted from chicken feathers. The extracted keratin solution was concentrated to the desired concentration by a rotary evaporator. The wound healing spray was synthesized by mixing the desired antimicrobial agent with keratin solutions like manuka honey, Garcinia Mangostana L., caprylyl glycol, ethylhexylglycerin and propylene glycol at a concentration of 13.0 w/w%, 0.5 w/w%, 1.0 w/w%, 2.0 w/w% and 2.0 w/w%, respectively, and the characteristic was determined. The result has shown that the keratin protein is maintained in the wound healing spray after mixing with an antimicrobial agent according to the formulation from the FTIR result. The wound healing spray does not contain heavy metals like cadmium and lead. Still, copper, iron and zinc were present within the maximum daily level of vitamins and minerals for adults allowed in health supplements by the National Pharmaceutical Regulatory Division of Malaysia. The pH of the keratin wound healing spray was maintained at a pH of around 5.5. The density and the viscosity of the keratin wound healing spray were higher than the deionized water. In conclusion, the Keratin wound healing spray was synthesized, and it is safe for the consumer. The wound healing ability of the keratin wound healing spray needs to carry out the in vivo clinical test for future study.
本研究以鸡毛中提取的角蛋白为原料研制了伤口愈合喷雾。角蛋白是上皮细胞中含量最多的蛋白。角蛋白被证明具有伤口愈合能力,因为它可以激活皮肤中负责伤口愈合的角化细胞。然而,角蛋白伤口愈合喷雾是市场上的新产品,具有温和无痛愈合伤口的潜力。本研究以鸡毛为原料合成了角蛋白创面喷雾剂,并测定了该喷雾剂的性质。从鸡毛中提取角蛋白。提取的角蛋白溶液通过旋转蒸发器浓缩到所需的浓度。将抗菌药物与角蛋白溶液麦卢卡蜂蜜、山竹果、丙二醇、乙基己基甘油和丙二醇分别以13.0 w/w%、0.5 w/w%、1.0 w/w%、2.0 w/w%和2.0 w/w%的浓度混合,合成创面愈合喷雾,并测定其特性。结果表明,根据FTIR结果得出的配方,将角蛋白与抗菌剂混合后,伤口愈合喷雾剂中的角蛋白得以维持。这种伤口愈合喷雾不含镉和铅等重金属。尽管如此,铜、铁和锌的含量仍在马来西亚国家药品监管局(National Pharmaceutical Regulatory Division of Malaysia)规定的成人保健品中维生素和矿物质的最大日摄入量范围内。角蛋白伤口愈合喷雾的pH值维持在5.5左右。角蛋白创面愈合喷雾的密度和黏度均高于去离子水。结果表明,合成的角蛋白创面愈合喷雾剂对消费者是安全的。角蛋白创面愈合喷雾剂的创面愈合能力需要进行体内临床试验,以供今后的研究。
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引用次数: 1
Design and fabrication of automatic classroom cleaning robot 教室自动清扫机器人的设计与制造
Pub Date : 2020-06-01 DOI: 10.54279/mijeec.v2i2.245031
M. Anil Kumar, B. Chitra Lekha
Mechanization is one of the moving subjects encompassing the assembling business in the 21st century. In addition to the fact that it helps producers stay aware of developing worldwide interest, it sets out new positions open doors just as help makers progress into the 21st century. This project requires the Arduino Uno, engine driver, and Bluetooth module. The Arduino Uno is an open-source prototyping platform with simple hardware and programming. The ATmega328 microcontroller is used in the Arduino Uno. Advanced mechanics has become increasingly important in our daily lives and the design sector, and it plays an essential role in the advancement of new technology. Arduino has replaced the traditional micro regulator, and IR sensors have been replaced by a Bluetooth module in this uncomplicated and primary type of controlling the vehicle. Any android or iOS cell can be used as the faraway. With the headway of innovation, robots are standing out enough to be noticed by scientists to make the life of humanity agreeable. Here we examine the plan of the model of Automatic Classroom cleaning Robot. The robot works self-inside a restricted space (for this situation, study hall) and require human mediation to move it from one class to the next. By utilizing fog-making measures, it cleans the encompassing. The robot is intended to supplant human endeavors with mechanization and can be a revolutionary innovation whenever made reasonable.
机械化是21世纪装配行业的发展方向之一。除了帮助生产商了解世界范围内不断发展的兴趣之外,它还为生产商们打开了通往21世纪的大门。本项目需要Arduino Uno,引擎驱动,蓝牙模块。Arduino Uno是一个开源原型平台,具有简单的硬件和编程。Arduino Uno采用ATmega328微控制器。先进力学在我们的日常生活和设计领域变得越来越重要,它在新技术的进步中起着至关重要的作用。Arduino取代了传统的微调节器,红外传感器被蓝牙模块取代,这是一种简单而主要的车辆控制方式。任何android或iOS手机都可以用作遥控器。随着创新的进步,机器人已经足够引人注目,足以引起科学家的注意,使人类的生活变得愉快。在这里,我们对自动教室清洁机器人模型的方案进行了研究。机器人在一个有限的空间内(在这种情况下,是自习室)自行工作,需要人类的调解才能将它从一个班级移动到另一个班级。它利用造雾措施来清洁包裹物。机器人旨在用机械化取代人类的努力,只要合理,它就可以成为一项革命性的创新。
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引用次数: 0
Cutting tool quality improvement: a case study of electronic parts manufacturer 刀具质量改进:以电子零件制造企业为例
Pub Date : 2020-05-31 DOI: 10.54279/mijeec.v2i2.245030
Thanatorn Chuenyindee, Piyaphong Yongphet, Phongchayont Srisuwan
Electronic parts are an important part in the modern manufacturing industry. The purpose of this study was to enhance the quality of cutting tools in electronic parts manufacturing process by utilizing statistical methods. Through these approaches, it was found that the cost of precision boring blade (S2F0409R05F35R10PTD) was significantly decrease from 457 THB to 315 THB, this research can maintain the process capability value (Cpk) at the customer satisfaction level (rather than 1.5) and reduce production cost from 2,104,739 THB per year to 1,598,857 THB per year (5 months payback period). The proposed statistical methods approaches could also be applied to other electronic parts manufacturing industries worldwide.
电子零部件是现代制造业的重要组成部分。本研究的目的是利用统计方法来提高电子零件制造过程中刀具的质量。通过这些方法,发现精密镗刀(S2F0409R05F35R10PTD)的成本从457 THB显著降低到315 THB,本研究可以将工艺能力值(Cpk)维持在客户满意水平(而不是1.5),并将生产成本从每年2,104,739 THB降低到1,598,857 THB /年(5个月的投资回收期)。所提出的统计方法方法也可应用于全球其他电子零件制造行业。
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引用次数: 3
Decomposition of gas phase benzene under different conditions in atmospheric strong ionization non–thermal plasma 气相苯在不同条件下在大气强电离非热等离子体中的分解
Pub Date : 2020-05-28 DOI: 10.54279/mijeec.v2i2.245029
Prince Junior Asilevi, Chengwu Yi, Jue Li, Huijuan Wang, Muhammad Imran Nawaz
Atmospheric volatile organic compounds (VOCs) from industry and automobiles are posing a serious threat to the environment and human health, and hence efficient control methods are indispensable. This paper presents a laboratory-scale study on the decomposition mechanism for benzene using strong ionization dielectric barrier discharge (DBD) at atmospheric pressure. The specific input energy (SIE), current density, and concentration were studied. The results show that the removal efficiency of benzene increased from 12% to 69% with the increase of SIE from 0.5 to 3.8 kJ/L. The decline in current density by 66.48% and 43.7% for an initial benzene concentration of 300 ppm, was due to increased oxygen content (from 2.4% to 20.9%) and relative humidity (from 18.9% to 90%), respectively, thus electron concentration and consequentially enhancing the removal efficiency over 93%. Further, the beta parameter of the VOC decomposition law decreased from 3.1 kJ/L at 300 ppm to 1.6 kJ/L at 100 ppm. This shows that •O and •OH radicals are key species for the decomposition of benzene and electron dissociation reactions principally control the process. The highest ozone concentration was detected at 5.5 mg/L when no benzene is present, while the main NOx species (NO and NO2) increased with increasing SIE. The Maxwell–Boltzmann electron energy distribution function was solved using the strong ionization discharge reactor (~10 eV), showing that approximately 84.8 % of high-energy electrons possess enough energy to cause the benzene ring cleavage and free radical production. Finally, GCMS and FTIR test results suggested that the byproducts mainly consisted of phenol and substitutions of phenol. The study results show that the strong ionization DBD reactor efficiently removes benzene from polluted air.
工业和汽车排放的大气挥发性有机化合物(VOCs)对环境和人类健康构成严重威胁,因此有效的控制方法必不可少。本文对常压下强电离介质阻挡放电(DBD)分解苯的机理进行了实验研究。研究了比输入能量(SIE)、电流密度和浓度。结果表明,当SIE由0.5 kJ/L提高到3.8 kJ/L时,苯的去除率由12%提高到69%。当苯的初始浓度为300 ppm时,由于氧含量(从2.4%增加到20.9%)和相对湿度(从18.9%增加到90%)的增加,电流密度分别下降了66.48%和43.7%,从而提高了电子浓度,从而使去除率提高了93%以上。此外,VOC分解规律的beta参数从300 ppm时的3.1 kJ/L下降到100 ppm时的1.6 kJ/L。这表明•O和•OH自由基是苯分解的关键基团,电子解离反应主要控制苯的分解过程。当不存在苯时,臭氧浓度在5.5 mg/L时最高,而主要NOx种类(no和NO2)随着SIE的增加而增加。利用强电离放电反应器(~10 eV)求解了麦克斯韦-玻尔兹曼电子能量分布函数,表明约84.8%的高能电子具有足够的能量引起苯环裂解和自由基的产生。最后,GCMS和FTIR测试结果表明,副产物主要由苯酚和苯酚的取代物组成。研究结果表明,强电离DBD反应器能有效去除污染空气中的苯。
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引用次数: 0
Surfactant (UMP) for emulsification and stabilization of water-in-crude oil emulsions (W/O) 表面活性剂(UMP)用于原油包水乳状液(W/O)的乳化和稳定
Pub Date : 2020-05-22 DOI: 10.54279/mijeec.v2i2.245027
N. H. Abdurahman, H. A. Magdib
The purpose of this research is to look into the formulation and evaluation of concentrated water-in-oil (W/O) emulsions stabilized by UMP NS-19-02 surfactant and their application for crude oil emulsion stabilization using gummy Malaysian crude oil. A two-petroleum oil from Malaysia oil refinery, i.e., Tapis petroleum oil and Tapis- Mesilla blend, were utilized to make water-in-oil emulsions. The various factors influencing emulsion characteristics and stability were evaluated. It was discovered that the stability of the water-in-oil emulsion improved by UMP NS-19-02 improved as the surfactant content rises, resulting in the decline of the crude oil-water interfacial tension (IFT). Nevertheless, the most optimum formulation of W/O emulsion was a 50:50 W/O ratio with 1.0% surfactant. Additionally, raising the oil content, salt concentration, duration and mixing speed, and pH of the emulsion resulted in higher emulsion stability. It also raised the temperature of the initial mixing, which significantly decreased the formulated emulsions' viscosity. The results showed that stable emulsions could be formed using the UMP NS-19-02 surfactant.
研究了UMP NS-19-02表面活性剂稳定油包水(W/O)乳状液的配方及性能评价,并探讨了该乳状液在马来西亚原油胶状液稳定中的应用。利用马来西亚炼油厂的两种石油,即Tapis石油和Tapis- Mesilla混合油,制成油包水乳液。对影响乳化液特性和稳定性的各种因素进行了评价。研究发现,随着表面活性剂含量的增加,经UMP NS-19-02改性的油包水乳状液的稳定性提高,导致原油-水界面张力(IFT)下降。而W/O乳液的最佳配方是W/O比为50:50,表面活性剂为1.0%。此外,提高乳状液的含油量、盐浓度、搅拌时间、搅拌速度和pH值可以提高乳状液的稳定性。它还提高了初始混合的温度,这大大降低了配方乳剂的粘度。结果表明,使用UMP NS-19-02表面活性剂可以形成稳定的乳剂。
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引用次数: 0
Replacement of fish meal using pig manure as protein source for Nile tilapia culture 利用猪粪代替鱼粉作为尼罗罗非鱼养殖的蛋白质来源
Pub Date : 2020-05-20 DOI: 10.54279/mijeec.v2i2.244959
Buncha Tongmee, Niwooti Whangchai, Sudaporn Tongsiri, Yuwalee Unpaprom
The cost of fish feed is a significant constraint to freshwater fish farming in Asia. In the aquaculture value chain, feed is a responsible factor and accounts for nearly 75% of the total cost of fish production in many countries. Therefore, this study attempts to focus the feasibility of using pig manure fermentation to formulate feed pellets to culture the tilapia fish in the cement pond, along with the cultured using ready-made feed containing the residue from the manure fermentation at different ratios. Accordingly, the experimental studies were approached by two types of experiments, namely, experiment 1 (focused on the nutrients in pig manure collected from an anaerobic system farm), and experiment 2 (studied the appropriate level of pig manure to be used as a raw material for fish feeding). The five months’ fermentation of pig manure contains 17.09% protein, which is the highest amount of nutrition source. Digestate manure was estimated; other primary macronutrients, including nitrogen, phosphorus, and potassium, were 2.73, 0.55 and 1.22 %, respectively. Also, a considerable amount of essential micronutrients, for example, copper, manganese and zinc, were found in the digestate. Nile tilapia were grown at the cement ponds for 120 days. The maximum verified dry matter and protein digestibility in tilapia were attained for diets containing 10 % percent pig manure at 89.28 ± 4.09 and 56.64 ± 1.43 (p> 0.05), respectively. In this study experimental results indicated that fish meal consisting of 15% manure was found to be the most acceptable substitute source of protein for tilapia production. This implies that the cost of fish meal production using fermented pig manure can be significantly lowered, gain higher profit and provide significant economic benefits to farmers.
鱼饲料成本是亚洲淡水鱼养殖的一个重要制约因素。在水产养殖价值链中,饲料是一个负责任的因素,在许多国家占鱼类生产总成本的近75%。因此,本研究试图探讨利用猪粪发酵配制饲料颗粒在水泥池中养殖罗非鱼的可行性,以及利用含有不同比例猪粪发酵残留物的现成饲料进行养殖的可行性。因此,通过两类实验进行实验研究,即实验1(关注厌氧系统农场收集的猪粪中的营养成分)和实验2(研究猪粪作为鱼饲料原料的合适水平)。发酵5个月的猪粪蛋白质含量为17.09%,是最高的营养来源。对消化粪肥进行估算;其他主要常量营养元素氮、磷、钾含量分别为2.73%、0.55%和1.22%。此外,在消化液中还发现了相当数量的必需微量营养素,例如铜、锰和锌。尼罗罗非鱼在水泥池中养殖120天。在添加10%猪粪的条件下,罗非鱼干物质消化率和蛋白质消化率最高,分别为89.28±4.09和56.64±1.43 (p < 0.05)。本研究的实验结果表明,添加15%粪便的鱼粉是罗非鱼生产中最可接受的蛋白质替代来源。这意味着利用发酵猪粪生产鱼粉的成本可以显著降低,获得更高的利润,为养殖户提供显著的经济效益。
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引用次数: 3
期刊
Maejo International Journal of Energy and Environmental Communication
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