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Developmental model and filling response characteristics of paleokarst conduits in the Middle-Lower Ordovician strata of Well 094 area, Tahe Oilfield 塔河油田094井区中下奥陶统古岩溶管道发育模式及充填响应特征
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-09-07 DOI: 10.1016/j.marpetgeo.2025.107596
Jiyuan Gao , Nuoyu Wang , Heng Zhang , Zhongxian Cai
The Ordovician strata in the Tahe Oilfield of the Akekule Low Uplift, Tarim Basin, host diverse palaeokarst fracture–cavity reservoirs. Among these reservoirs, the large-scale epignic karst conduit system that formed during the early Hercynian represents one of the most significant reservoir spaces. The Well 094 well block, located in the Carboniferous-covered western slope area of the Tahe Oilfield, contains typical Ordovician palaeokarst conduit-type reservoirs. On the basis of 3D seismic and well logging data, in this study, the palaeokarst hydrogeomorphic conditions of the Ordovician strata in this area are reconstructed; the spatial distribution, developmental conditions, and filling characteristics of large-scale branchwork karst conduits are analysed; and their controlling factors are investigated. The results indicate that the Ordovician strata in the Well 094 well block were situated in the early Hercynian karstification zone, characterized by a typical binary flow field structure of a karst watershed. The karst landform exhibits medium-to-high relief, with well-developed asymmetrical branchwork surface drainage systems converging from north to south into a karst canyon. The karst conduits are predominantly developed approximately 120 ms below the top of the Lower-Middle Ordovician series. The development of these conduits was jointly controlled by the steep topographic gradient of the Ordovician strata, the syncline-confined groundwater convergence zone between secondary anticlines, and the water-conducting effects of NNE- and NNW-trending strike-slip faults. The karst conduits display distinct east‒west differential evolution. The eastern conduits experienced intense vertical erosion and roof collapse, forming a subsurface fluvial window geomorphology with severe clastic infilling, whereas the western conduits maintained relatively stable configurations. This finding suggests that conduit evolution is influenced by tectonic uplift and the hydraulic gradient, with the degree of infilling closely related to the watershed area, fault activity, and evolutionary stage. Highly evolved conduit segments tend to exhibit more severe infilling.The complete filling of the cave not only reduces porosity but also significantly compromises the reservoir's effective storage capacity. These findings provide a theoretical basis for evaluating the effectiveness of similar karst fracture–cavity reservoirs worldwide.
塔里木盆地阿克库勒低隆起塔河油田奥陶系地层赋存多种古岩溶缝洞型储层。其中,海西期早期形成的大型外闪岩溶管道系统是最重要的储集空间之一。094井区块位于塔河油田石炭系西斜坡区,具有典型的奥陶系古岩溶导管型储层。在三维地震和测井资料的基础上,重建了本区奥陶系古岩溶水文地貌条件;分析了大型枝状岩溶管道的空间分布、发育条件及充填特征;并对其控制因素进行了探讨。结果表明,094井区奥陶系地层处于早海西期岩溶作用带,具有典型的岩溶流域二元流场结构。喀斯特地貌呈中高起伏,地表水系发育,不对称,由北向南汇聚成喀斯特峡谷。岩溶管道主要发育在中—下奥陶统顶部下方约120ms处。这些输水管道的发育受奥陶系地层陡峭的地形坡度、次级背斜间向斜承压地下水汇合带以及北北东向和北西向走滑断裂的导水作用共同控制。岩溶导管具有明显的东西差异演化特征。东部河道垂直侵蚀剧烈,顶板坍塌,形成碎屑充填严重的地下河窗地貌,而西部河道则保持相对稳定的形态。研究结果表明,导管演化受构造隆升和水力梯度的影响,充填程度与流域面积、断层活动性和演化阶段密切相关。高度进化的导管段往往表现出更严重的填充。溶洞的完全充填不仅降低了孔隙度,而且严重影响了储层的有效存储量。研究结果为评价国内外同类岩溶缝洞型储层的有效性提供了理论依据。
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引用次数: 0
The Guajira contourite depositional system along the northern Colombian Caribbean convergent margin 哥伦比亚加勒比海北部辐合边缘的瓜希拉等长岩沉积体系
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-07-14 DOI: 10.1016/j.marpetgeo.2025.107556
J. Naranjo-Vesga , O. Mantilla , D. Rincón-Martínez , E. Rodriguez-Rubio , A. Ortiz-Karpf , C. Winter , Y. Rojas-Agramonte
Bottom currents have a significant role in the transport, erosion and deposition of sediments. They also have the power to modify the seabed morphology. Contourite depositional systems have been reported worldwide, mainly in passive margins; with few examples reported at convergent margins. This study uses regional multibeam bathymetry and seismic data, to document for the first time a∼20,000 km2 slope contourite depositional system along the upper continental slope of the northern Colombian Caribbean convergent margin. We compare the characteristics of the slope geomorphology with hydrodynamic modeling of the bottom currents. We identified on the upper slope, close to the shelf edge, the presence of erosional terraces and moats over an area of∼2,700 km2. Near this sector, the modelled ocean currents can reach speeds of up to∼10 cm/s. However, the bottom currents have a high degree of variability, and low values of∼1 cm/s are also identified over the terraces; this may suggest that erosion can occur when the currents reach their highest speeds of circulation. Therefore, the erosion is neither homogeneous nor continuous along the slope. On the other hand, the plastered drift and sediment wave fields related to sediment accumulation have low current velocities between∼1 - 5 cm/s, and they cover a large area of the upper slope (∼17,600 km2), suggesting that sediment accumulation may occur in areas where bottom currents have low velocities. The plastered drift thickness also shows high variability in the study area. The major thicknesses of∼785 ms (or ± 800 m) are related to a gentle slope topography (<2°). In contrast, the lowest thicknesses of∼300 ms (or ± 300 m) are identified in areas with steep slope topography (>2–5°), indicating that in gently slope topography (<2°) plastered drift deposits have a greater thickness. This work allows us to characterize for the first time a regional slope contourite depositional system along the northern Colombian Caribbean margin and highlights the influence of bottom current strength and slope gradient topography in controlling the erosion and preferential accumulation of sediments in an active margin with low sediment supply. This mode of occurrence may be characteristic of contourite depositional system development on convergent margins with low fluvial sediment discharge worldwide.
海底流在沉积物的运输、侵蚀和沉积中起着重要的作用。它们也有能力改变海底的形态。轮廓岩沉积体系在世界范围内已被报道,主要分布在被动边缘;在收敛边缘有几个例子报告。本研究利用区域多波束测深和地震数据,首次在哥伦比亚加勒比海北部辐合边缘的上大陆斜坡上记录了一个~ 20,000 km2的斜坡等高线沉积体系。我们将坡面地貌特征与底流的水动力模拟进行了比较。我们在靠近陆架边缘的上斜坡上发现了面积约2700平方公里的侵蚀阶地和护城河。在这个区域附近,模拟洋流的速度可以达到~ 10厘米/秒。然而,底部洋流具有高度的可变性,在阶地上也发现了~ 1 cm/s的低值;这可能表明,当水流达到其最高循环速度时,侵蚀就会发生。因此,沿坡的侵蚀既不是均匀的,也不是连续的。另一方面,与泥沙堆积相关的灰泥漂移和泥沙波场流速较低,在~ 1 ~ 5 cm/s之间,覆盖了较大的上坡面积(~ 17,600 km2),表明泥沙堆积可能发生在底流流速较低的地区。灰泥漂移厚度在研究区内也表现出较高的变异性。~ 785 ms(或±800 m)的主要厚度与缓坡地形(<2°)有关。相比之下,陡坡地形(>2 - 5°)地区的最低厚度为~ 300 ms(或±300 m),这表明在缓坡地形(<2°),灰泥漂移沉积物具有更大的厚度。这项工作使我们能够首次描述哥伦比亚北部加勒比海边缘的区域斜坡等高线沉积体系,并强调了底流强度和斜坡梯度地形在控制低沉积物供应的活动边缘的侵蚀和沉积物优先堆积方面的影响。这种产状模式可能是世界范围内河流输沙量较低的辐合边缘的等长岩沉积体系发育的特征。
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引用次数: 0
Cenomanian channel system evolution of Mundaú Sub-basin deepwater, Brazilian Equatorial Margin: Reservoir characterization using machine learning techniques 巴西赤道边缘Mundaú次盆地深水塞诺曼期河道体系演化:利用机器学习技术表征储层
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-07-10 DOI: 10.1016/j.marpetgeo.2025.107540
Ian de Oliveira Souza Cerdeira , Karen Maria Leopoldino Oliveira , Jorge de Jesus Picanço Figueiredo , Heather Bedle , Narelle Maia de Almeida , Ana Clara Braga Souza
Submarine channel systems have garnered significant attention in recent years due to their importance in petroleum exploration and favorable reservoir characteristics. Specifically, the Brazilian Equatorial Margin basins have attracted considerable interest from various sectors because of substantial hydrocarbon discoveries in adjacent basins. In the Mundaú Sub-basin (Ceará Basin, NE Brazil), recent studies have identified a series of sand-rich structures associated with a Cenomanian submarine channel system. However, despite these advancements, the depositional elements, sedimentary architecture, and stratigraphic sequences remain poorly understood. This paper aims to integrate robust quantitative geophysical techniques, including unsupervised machine learning methods, multi-attribute analysis, and RGB blending, to clarify the main evolutionary stages of the Cenomanian submarine channel-lobo system in the central portion of the aforementioned Sub-basin and their controlling factors. We utilized data from four exploration wells drilled in the deep waters of the Mundaú Sub-basin, along with a 2200 km2 seismic volume covering the study area. Our integrated approach identified three main evolutionary stages. The first stage is characterized by straight to low-sinuosity confined channels on the upper to middle slope, alongside poorly confined channels and splays on the lower slope to basin floor, primarily comprising sand-prone layers developed during a Falling Stage System Tract. The second stage exhibits low to moderate sinuosity confined channels in the upper to middle slope, with significantly poorly confined channels and splays on the lower slope to basin floor, also dominated by sand-prone layers developed in a Lowstand Tract System. The final stage features a high-sinuosity confined channel with dominant sand-prone and sand/mud-prone layers developed in a Transgressive System Tract. all stages and across almost the whole region, sand-prone and sand/mud-prone facies were identified and associated with various depositional elements at different scales. the presence of sand-prone layers in all stages is thought to result from high-density turbidity currents driven by a narrow shelf and stepped slope. The mapped features and predicted facies indicate an unexplored area with sand-rich layers likely possessing good lateral and vertical connectivity. Important structures that may facilitate oil migration were identified, highlighting the high exploration potential of the Cenomanian submarine channel system in the Mundaú Sub-basin.
近年来,海底水道系统因其在石油勘探中的重要作用和有利的储层特征而受到广泛关注。具体来说,由于在邻近盆地发现了大量的油气,巴西赤道边缘盆地吸引了各个部门的极大兴趣。在Mundaú次盆地(巴西东北部ceear盆地),最近的研究已经确定了一系列与塞诺曼尼亚海底水道系统相关的富砂构造。然而,尽管取得了这些进展,沉积元素、沉积结构和地层层序仍然知之甚少。本文旨在整合鲁棒定量地球物理技术,包括无监督机器学习方法、多属性分析和RGB混合,以阐明上述子盆地中部塞诺曼尼亚海底通道-lobo系统的主要演化阶段及其控制因素。我们利用了在Mundaú子盆地深水钻探的四口勘探井的数据,以及覆盖研究区域的2200平方公里的地震体积。我们的综合方法确定了三个主要的进化阶段。第一阶段的特征是在上斜坡到中斜坡上有直到低弯曲度的封闭河道,在下斜坡到盆地底部有较差的封闭河道和带状河道,主要由在下降阶段体系域发育的易砂层组成。第二阶段在上斜坡至中斜坡发育低至中等曲度的封闭性河道,下斜坡至盆地底部发育明显的弱封闭性河道和带状河道,也以低洼地域体系发育的易砂层为主。最后阶段为高弯曲度封闭河道,主要发育海侵体系域的倾向砂层和倾向砂/泥层。在几乎整个地区的所有阶段,都确定了倾向于砂和倾向于砂/泥的相,并将其与不同尺度的各种沉积元素联系起来。所有阶段的易沙层的存在被认为是由狭窄的陆架和阶梯式斜坡驱动的高密度浊流造成的。图上的特征和预测相表明,这是一个尚未勘探的地区,富砂层可能具有良好的横向和纵向连通性。发现了可能有利于石油运移的重要构造,突出了Mundaú次盆地Cenomanian海底通道系统的高勘探潜力。
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引用次数: 0
Temporal and spatial variations of redox conditions in the middle Triassic Chang 7 member of the Yanchang formation, Ordos Basin, North China 鄂尔多斯盆地中三叠统延长组长7段氧化还原条件时空变化
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-07-24 DOI: 10.1016/j.marpetgeo.2025.107565
Hanlin Liu , Yuangeng Huang , Xiangdong Zhao , Wei Wang , Xincheng Qiu , Zhen Qiu , Juan Han , Zhen Shen , Yujie Li , Ganlin Hua , Zhong-Qiang Chen , Caineng Zou
The Chang 7 member of the lower Yanchang Formation, situated within the Ordos Basin, dates back to the Ladinian stage of the late Middle Triassic. These strata, notable for their organic-rich black shales, serve as a key lacustrine hydrocarbon-bearing unit in China. The Chang 7 shales encompass a wide array of vertebrate, invertebrate, and plant fossils, offering valuable perspectives on the ecological recovery of lacustrine systems following the end-Permian mass extinction (EPME). Redox conditions within the water column play a critical role in influencing organic matter deposition and shaping lacustrine biodiversity. Nonetheless, prior investigations into redox dynamics during the formation of the Chang 7 shales have predominantly relied on single redox proxies or isolated sampling locations, which restrict a comprehensive understanding of the redox evolution across the entire Ordos Basin. For these reasons, this study employs framboidal pyrite size statistics, pyrite sulfur isotopes, major and trace element concentrations, and lipid biomarkers of five Ladinian-age wells from both deep and shallow sedimentary facies to rebuilt up evolutional patterns of redox conditions in the Basin. Our results reveal remarkable difference of redox conditions amongst deposition periods of three submembers. Notably during the formation of the Chang 73 submember (lower Chang 7 member), the Ordos paleo-lake exhibited progressively declining oxygen levels, transitioning from dysoxic to anoxic conditions in deeper facies. Dysoxic conditions prevailed in the deep facies, with transient anoxic conditions emerged. By contrast, evidence indicates that the Chang 72 submember (middle Chang 7 member) was primarily deposited under fluctuating dysoxic-oxic conditions, while the Chang 71 submember (upper Chang 7 member) was formed in predominantly oxic environments. Collectively, the Chang 7 member shows remarkable organic matter preservation, with an average total organic carbon (TOC) content of 11.02 wt%, and peak TOC levels reaching 35.8 wt% in the Chang 73 submember. These findings indicate that by the Ladinian, the Ordos paleo-lake had already achieved a high level of productivity, capable of sustaining a fully developed, trophically complex lacustrine ecosystem in the aftermath of the EPME. The relatively oxygen-depleted bottom waters during deposition of the Chang 73 submember provided favorable conditions for the preservation of the abundant and diverse biota. This comprehensive analysis offers valuable insights into the lacustrine paleoenvironmental conditions and biotic recovery following the EPME, and provides important clues for the formation environment of source rocks.
鄂尔多斯盆地下延长组长7段可追溯到中三叠世晚期拉底期。这些地层以富有机质黑色页岩为主,是中国重要的湖相含油气单元。长7页岩包含了大量的脊椎动物、无脊椎动物和植物化石,为二叠纪末大灭绝(EPME)后湖泊系统的生态恢复提供了有价值的视角。水柱内的氧化还原条件在影响有机质沉积和形成湖泊生物多样性方面起着关键作用。然而,以往对长7页岩形成过程中氧化还原动力学的研究主要依赖于单一的氧化还原指标或孤立的采样点,这限制了对整个鄂尔多斯盆地氧化还原演化的全面理解。基于此,本研究利用5口拉底期深、浅沉积相井的树状黄铁矿粒度统计、黄铁矿硫同位素、主微量元素浓度、脂质生物标志物等数据,重建了盆地氧化还原条件的演化模式。结果表明,三个亚段沉积时期的氧化还原条件存在显著差异。特别是在长73亚段(长7下段)形成期间,鄂尔多斯古湖泊氧含量逐渐下降,在较深的相中由缺氧过渡到缺氧。深相以欠氧条件为主,出现短暂缺氧条件。有证据表明,长72亚段(长7中段)主要是在波动的缺氧环境下沉积的,而长71亚段(长7上段)则主要是在缺氧环境下形成的。总体而言,长7段有机质保存较好,总有机碳(TOC)含量平均为11.02 wt%,长73亚段TOC含量最高达35.8 wt%。这些结果表明,到拉丁纪,鄂尔多斯古湖泊已经达到了较高的生产力水平,能够在EPME之后维持一个充分发展的、营养复杂的湖泊生态系统。长73亚段沉积时底水相对缺氧,为其丰富多样的生物群保存提供了有利条件。这一综合分析为研究EPME后的湖相古环境条件和生物恢复提供了有价值的认识,为烃源岩形成环境提供了重要线索。
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引用次数: 0
Investigating key pressure loss factors in the Wufeng-Longmaxi formation shale gas reservoirs, Southern Sichuan: A quantitative approach 川南五峰组—龙马溪组页岩气储层压力损失关键因素定量分析
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-07-21 DOI: 10.1016/j.marpetgeo.2025.107560
Nengwu Zhou , Guangshun Xiao , Shuangfang Lu , Bo Song , Jun Wang , Zhong Chu , Xinyu Jiang , Yang Liu , Wenbiao Li , Pengfei Zhang , Guohui Chen , Min Wang
Pressure loss in the Wufeng-Longmaxi Formation shale gas reservoirs of the southern Sichuan Basin is a complex issue. This occurrence is influenced by several critical factors: faults, stratigraphic properties, fold structures, and the timing and magnitude of uplift events. While we know these factors are significant, their quantitative impact and individual contributions to pressure loss remain poorly understood. In this study, we integrate the burial and thermal history of the basin to reconstruct the evolution of key reservoir parameters, including formation temperature, hydrostatic pressure, overburden pressure, total porosity, water-filled porosity, and gas adsorption porosity. Using this framework, we simulate the effects of different preservation conditions on pressure loss within shale gas reservoirs and evaluate the relative contributions of these controlling factors. Simulation results revealed that the location of fault development, particularly its penetration through the caprock, is the predominant factor governing pressure loss in local shale gas reservoirs. In contrast, the scale of fault development has a relatively minor impact. Additionally, the thickness and vertical diffusion coefficient of the caprock, along with the time, emerged as secondary controlling factors that substantially influence the rate of pressure loss across the shale gas reservoirs. Furthermore, the dip angle of synclinal folds and the lateral diffusion coefficient act as accelerators of pressure loss, potentially leading to rapid depletion of reservoir pressure. Conversely, the properties of anticlines exhibit minimal influence on pressure loss. These findings provide valuable insights for the management and optimization of shale gas reservoirs in the Wufeng-Longmaxi Formation.
川南五峰组—龙马溪组页岩气储层压力损失是一个复杂的问题。这种产状受几个关键因素的影响:断层、地层性质、褶皱结构以及隆升事件的时间和幅度。虽然我们知道这些因素很重要,但它们对压力损失的定量影响和个人贡献仍然知之甚少。结合盆地埋藏史和热史,重建了地层温度、静水压力、覆盖层压力、总孔隙度、充水孔隙度和气体吸附孔隙度等关键储层参数的演化。在此框架下,模拟了不同保存条件对页岩气储层压力损失的影响,并评价了这些控制因素的相对贡献。模拟结果表明,断层发育的位置,特别是断层穿过盖层的位置,是控制局部页岩气储层压力损失的主要因素。相比之下,断层发育规模的影响相对较小。此外,盖层厚度和垂向扩散系数以及时间成为影响页岩气储层压力损失速率的次要控制因素。此外,向斜褶皱倾角和侧向扩散系数是压力损失的加速因素,可能导致储层压力快速衰竭。相反,背斜的性质对压力损失的影响最小。这些发现为五峰组—龙马溪组页岩气储层的管理与优化提供了有价值的参考。
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引用次数: 0
On the limitations of spot permeability measurements to quantify bulk permeability of bioturbated reservoirs: Insights from digital rock physics modeling 关于现场渗透率测量在量化生物扰动储层整体渗透率方面的局限性:来自数字岩石物理建模的见解
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-08-08 DOI: 10.1016/j.marpetgeo.2025.107577
Ahmed Refaat , Hassan A. Eltom , Ammar El-Husseiny
Substantial permeability contrasts between the fine-grained host rock matrix (HRM) and the coarse-grained burrow fillings (BF) are observed in bioturbated reservoirs, which are characterized by burrows that create a dual-porosity system. Consequently, assessing bulk permeability becomes particularly challenging, as these reservoirs often exhibit permeability contrast between HRM and BF spanning several orders of magnitude. To address this issue, the present study utilizes insights from digital rock physics modeling to critically examine the limitations of spot permeability measurements in accurately estimating bulk permeability in bioturbated systems. Specifically, we applied an integrated workflow to examine samples from a bioturbated interval in the upper Hanifa Formation in Saudi Arabia, incorporating spot permeability measurements, petrographic analysis, micro-CT scanning, pore network modeling, and permeability simulations to evaluate the effectiveness of spot permeability data in capturing bulk flow behavior. Our findings revealed that although spot permeability data are valuable for identifying localized permeability trends, they can be misleading when used to infer true bulk permeability, as they may fail to account for isolated or poorly connected pore systems. In particular, our results showed a significant discrepancy emerged between the CT scan data and spot measurements: while the CT imaging showed isolated and poorly connected pores within the burrow fillings—resulting in negligible flow during simulations—the spot measurements indicated substantially higher permeability values, ranging from 2.65 mD to 796.30 mD. This contrast underscores the complexity of relying on localized measurements to characterize bulk reservoir properties. Therefore, achieving more accurate permeability estimations in bioturbated reservoirs necessitates a comprehensive approach that integrates spot permeability data with high-resolution imaging and digital simulation techniques.
在生物扰动储层中,细粒寄主岩石基质(HRM)和粗粒穴道充填体(BF)的渗透率存在显著差异,其特征是形成双重孔隙系统的穴道。因此,评估整体渗透率变得特别具有挑战性,因为这些储层通常表现出HRM和BF之间跨越几个数量级的渗透率差异。为了解决这个问题,本研究利用数字岩石物理建模的见解来严格检查现场渗透率测量在准确估计生物扰动系统中整体渗透率方面的局限性。具体来说,我们应用了一个集成的工作流程来检查沙特阿拉伯Hanifa组上部生物扰动层段的样品,结合现场渗透率测量、岩石学分析、微ct扫描、孔隙网络建模和渗透率模拟,以评估现场渗透率数据在捕获整体流动行为方面的有效性。我们的研究结果表明,尽管现场渗透率数据对于识别局部渗透率趋势很有价值,但当用于推断真实的整体渗透率时,它们可能会产生误导,因为它们可能无法解释孤立或连接不良的孔隙系统。特别是,我们的研究结果显示,CT扫描数据和现场测量数据之间存在显著差异:CT成像显示,在洞穴充填物中存在孤立且连接不良的孔隙,导致模拟过程中可以忽略流动,而现场测量结果显示渗透率值明显更高,范围从2.65 mD到796.30 mD。这种对比强调了依赖局部测量来表征整体储层性质的复杂性。因此,要想在生物扰动油藏中获得更准确的渗透率估计,就需要一种综合的方法,将现场渗透率数据与高分辨率成像和数字模拟技术相结合。
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引用次数: 0
Oil cracking with different water contents: New insights into the influence of water on the phase evolution and thermal stability of deep crude oil 不同含水率的原油裂解:水对深层原油相演化和热稳定性影响的新认识
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-09-10 DOI: 10.1016/j.marpetgeo.2025.107602
Aizimaiti Maimaiti , Qi Wang , Fang Hao , Jinqiang Tian , Xianzhang Yang , Haizu Zhang , Subi Abudouaini , Fuyun Cong
Water is widely distributed under geological conditions and has an significant influence on the process of oil cracking into gas. However, the mechanism of reservoir water content on the thermal stability and phase evolution of deep oil and gas reservoirs still needs further study. In this study, gold-tube pyrolysis experiments were conducted using oil, oil–water (3:2), and oil–water (1:4) mixtures, at constant heating rates of 2 °C/h and 20 °C/h. The experimental results show that water has little effect on the yield of C1-5 hydrocarbons, but increases the yields of the non-hydrocarbon gases H2 and CO2. The hydrogen isotopic composition of methane, ethane, and propane generated during pyrolysis experiments with added water became increasingly enriched in deuterium with increasing water content and maturity. Our results demonstrate that disproportionation and hydrogen isotope exchange between water and crude oil significantly affect both the evolution of product yields and the hydrogen isotopic signatures of generated hydrocarbons. Extrapolation of kinetic parameters at a constant heating rate of 2 °C/Ma based on the thermal history of the Tabei area in the Tarim Basin indicates that water reduces the thermal stability of crude oil, which ultimately leads to a decrease in the depth threshold for liquid hydrocarbon preservation by about 1000 m. The PVT phase simulation results show that the effect of water on the cracking behavior of crude oil is strongest at the stage of EasyRo = 1.33 %–2.19 %. At EasyRo = 1.47 %, the presence of water leads to a decrease in the cricondentherm of the crude oil by about 33.8 °C and an increase in the cricondenbar by about 2.46 MPa.
水在地质条件下分布广泛,对石油裂解成气的过程有重要影响。但储层含水率对深层油气藏热稳定性和相演化的影响机理仍需进一步研究。本研究采用油、油水(3:2)和油水(1:4)的混合物,在2°C/h和20°C/h的恒定升温速率下进行金管热解实验。实验结果表明,水对C1-5烃类的产率影响不大,但增加了非烃类气体H2和CO2的产率。在加水热解实验中生成的甲烷、乙烷和丙烷的氢同位素组成随着水含量的增加和成熟度的增加,氘的富集程度越来越高。研究结果表明,原油与水之间的歧化作用和氢同位素交换对原油产率的演化和生烃氢同位素特征均有显著影响。根据塔里木盆地塔北地区的热历史,在2°C/Ma恒定升温速率下的动力学参数外推表明,水降低了原油的热稳定性,最终导致液态烃保存深度阈值降低约1000 m。PVT相模拟结果表明,在EasyRo = 1.33% ~ 2.19%阶段,水对原油裂解行为的影响最大。在EasyRo = 1.47%时,水的存在使原油的临界温度降低了约33.8℃,临界温度升高了约2.46 MPa。
{"title":"Oil cracking with different water contents: New insights into the influence of water on the phase evolution and thermal stability of deep crude oil","authors":"Aizimaiti Maimaiti ,&nbsp;Qi Wang ,&nbsp;Fang Hao ,&nbsp;Jinqiang Tian ,&nbsp;Xianzhang Yang ,&nbsp;Haizu Zhang ,&nbsp;Subi Abudouaini ,&nbsp;Fuyun Cong","doi":"10.1016/j.marpetgeo.2025.107602","DOIUrl":"10.1016/j.marpetgeo.2025.107602","url":null,"abstract":"<div><div>Water is widely distributed under geological conditions and has an significant influence on the process of oil cracking into gas. However, the mechanism of reservoir water content on the thermal stability and phase evolution of deep oil and gas reservoirs still needs further study. In this study, gold-tube pyrolysis experiments were conducted using oil, oil–water (3:2), and oil–water (1:4) mixtures, at constant heating rates of 2 °C/h and 20 °C/h. The experimental results show that water has little effect on the yield of C<sub>1-5</sub> hydrocarbons, but increases the yields of the non-hydrocarbon gases H<sub>2</sub> and CO<sub>2</sub>. The hydrogen isotopic composition of methane, ethane, and propane generated during pyrolysis experiments with added water became increasingly enriched in deuterium with increasing water content and maturity. Our results demonstrate that disproportionation and hydrogen isotope exchange between water and crude oil significantly affect both the evolution of product yields and the hydrogen isotopic signatures of generated hydrocarbons. Extrapolation of kinetic parameters at a constant heating rate of 2 °C/Ma based on the thermal history of the Tabei area in the Tarim Basin indicates that water reduces the thermal stability of crude oil, which ultimately leads to a decrease in the depth threshold for liquid hydrocarbon preservation by about 1000 m. The PVT phase simulation results show that the effect of water on the cracking behavior of crude oil is strongest at the stage of EasyRo = 1.33 %–2.19 %. At EasyRo = 1.47 %, the presence of water leads to a decrease in the cricondentherm of the crude oil by about 33.8 °C and an increase in the cricondenbar by about 2.46 MPa.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"182 ","pages":"Article 107602"},"PeriodicalIF":3.6,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145060253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Origin of hydrogen sulfide in produced gas of Upper Permian shales from western Hubei, southern China: A preliminary study 鄂西地区上二叠统页岩产出气硫化氢成因初探
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-08-05 DOI: 10.1016/j.marpetgeo.2025.107570
Yasheng Cui , Le Li , Huan Yang , Keliang Pan , Jie Xin , Yuanqing Hu , Xiaogui Peng , Feng Yang
An unexpected moderate concentration (0.3 %–2 %) of hydrogen sulfide (H2S) was detected in the produced gas from upper Permian shales in western Hubei, southern China. This raised the hypothesis that H2S could either be a primary component of the shale gas reservoir or a secondary product generated by fracturing. This study systematically acquired data on desorbed gas composition, produced gas composition, sulfur isotopes of H2S in the produced gas, ion chemistry of flowback water, and compiled fracturing and production data, to preliminarily investigate the origin of H2S in the produced gas. The unusually low sulfur isotope composition of H2S in the produced gas (3.20 ‰–4.48 ‰, with an average of 3.66 ‰) rules out contamination from overlying (Changxing Formation) or underlying (Huanglong Formation) gas-bearing layers via natural fractures or fracturing-induced pathways. A two-order magnitude difference in H2S content between desorbed and produced gas indicates that most of the H2S in the produced gas is not supplied by the primary gas reservoir. The estimated volume of produced H2S (62,025 m3) greatly exceeds the theoretical maximum H2S yielded from acid-rock reactions (4243.5 m3), ruling out this reaction as the major source of H2S. The reservoir temperature (average 89.39 °C), coupled with a positive correlation between H2S content and sulfate and calcium ions, suggests that fracturing-induced bacterial sulfate reduction (BSR) is the main driver for secondary H2S formation. Thermochemical sulfate reduction (TSR) is unlikely due to temperature constraints.
在鄂西地区上二叠统页岩的产出气中,检测到硫化氢(H2S)的浓度出人意料地中等(0.3% - 2%)。这提出了一种假设,即H2S可能是页岩气储层的主要成分,也可能是压裂产生的二次产物。系统采集了解吸气组成、采出气组成、采出气中硫化氢硫同位素、返排水离子化学等数据,编制了压裂生产资料,初步探讨了采出气中硫化氢的成因。产出气中硫化氢硫同位素组成异常低(3.20‰~ 4.48‰,平均为3.66‰),排除了上伏(长兴组)或下伏(黄龙组)含气层通过天然裂缝或压裂诱导途径污染的可能性。解吸气和采出气中H2S含量相差2个数量级,表明采出气中的大部分H2S不是由原生气藏提供的。估计产生的H2S体积(62025 m3)大大超过了酸岩反应产生H2S的理论最大值(4243.5 m3),排除了酸岩反应是H2S主要来源的可能性。储层温度(平均89.39℃),以及H2S含量与硫酸盐和钙离子之间的正相关关系表明,压裂诱导的细菌硫酸盐还原(BSR)是次生H2S形成的主要驱动因素。由于温度的限制,热化学硫酸盐还原(TSR)是不可能的。
{"title":"Origin of hydrogen sulfide in produced gas of Upper Permian shales from western Hubei, southern China: A preliminary study","authors":"Yasheng Cui ,&nbsp;Le Li ,&nbsp;Huan Yang ,&nbsp;Keliang Pan ,&nbsp;Jie Xin ,&nbsp;Yuanqing Hu ,&nbsp;Xiaogui Peng ,&nbsp;Feng Yang","doi":"10.1016/j.marpetgeo.2025.107570","DOIUrl":"10.1016/j.marpetgeo.2025.107570","url":null,"abstract":"<div><div>An unexpected moderate concentration (0.3 %–2 %) of hydrogen sulfide (H<sub>2</sub>S) was detected in the produced gas from upper Permian shales in western Hubei, southern China. This raised the hypothesis that H<sub>2</sub>S could either be a primary component of the shale gas reservoir or a secondary product generated by fracturing. This study systematically acquired data on desorbed gas composition, produced gas composition, sulfur isotopes of H<sub>2</sub>S in the produced gas, ion chemistry of flowback water, and compiled fracturing and production data, to preliminarily investigate the origin of H<sub>2</sub>S in the produced gas. The unusually low sulfur isotope composition of H<sub>2</sub>S in the produced gas (3.20 ‰–4.48 ‰, with an average of 3.66 ‰) rules out contamination from overlying (Changxing Formation) or underlying (Huanglong Formation) gas-bearing layers via natural fractures or fracturing-induced pathways. A two-order magnitude difference in H<sub>2</sub>S content between desorbed and produced gas indicates that most of the H<sub>2</sub>S in the produced gas is not supplied by the primary gas reservoir. The estimated volume of produced H<sub>2</sub>S (62,025 m<sup>3</sup>) greatly exceeds the theoretical maximum H<sub>2</sub>S yielded from acid-rock reactions (4243.5 m<sup>3</sup>), ruling out this reaction as the major source of H<sub>2</sub>S. The reservoir temperature (average 89.39 °C), coupled with a positive correlation between H<sub>2</sub>S content and sulfate and calcium ions, suggests that fracturing-induced bacterial sulfate reduction (BSR) is the main driver for secondary H<sub>2</sub>S formation. Thermochemical sulfate reduction (TSR) is unlikely due to temperature constraints.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"182 ","pages":"Article 107570"},"PeriodicalIF":3.6,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144781623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mud volcanism and diapirism along the Japan Trench axis: evidence for a complex earthquake plumbing system on the down-going plate 沿日本海沟轴线的泥火山作用和底辟作用:下行板块上复杂地震管道系统的证据
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-09-05 DOI: 10.1016/j.marpetgeo.2025.107597
Myra Keep , Troy Rasbury , Cecilia McHugh , Michael Strasser , Ken Ikehara , Charlotte Pizer , Yasuyuki Nakamura
Mud volcanoes occur in a variety of geodynamic settings, and are common in subduction zones, usually within the accretionary prism. Although mud volcanism occurs along the Ryukyu Trench in southern Japan, no such activity has been documented along the Japan Trench. Sub-bottom profile data from International Ocean Discovery Program Expedition 386 show acoustically anomalous features in the basin-fill stratigraphy consistent with mud diapirism and mud volcanism along the Japan Trench. Unusually these features occur in basins along the trench axis itself, and not primarily as part of the accretionary complex. We present evidence for diapirism along ∼600 km of the Japan Trench and for mud volcanoes in the central and northern part of the trench. Mud diapirism and nearby igneous volcanic activity shows close spatial relationships to flexural faults on the down-going plate, which may provide the plumbing system for mobile muds to reach the surface.
泥火山发生在各种地球动力学环境中,在俯冲带中很常见,通常在增生棱镜内。虽然在日本南部的琉球海沟有泥火山活动,但在日本海沟没有记录到这样的活动。国际海洋发现计划(International Ocean Discovery Program Expedition 386)的海底剖面资料显示,日本海沟沿岸盆地充填地层的声学异常特征与泥底辟作用和泥火山作用一致。不同寻常的是,这些特征出现在沿海沟轴线本身的盆地中,而不是主要作为增生复合体的一部分。我们提供了沿日本海沟约600公里的底辟作用和海沟中部和北部泥火山的证据。泥浆底辟作用和附近火成岩火山活动与下行板块上的弯曲断裂有密切的空间关系,这可能为流动泥浆到达地表提供了管道系统。
{"title":"Mud volcanism and diapirism along the Japan Trench axis: evidence for a complex earthquake plumbing system on the down-going plate","authors":"Myra Keep ,&nbsp;Troy Rasbury ,&nbsp;Cecilia McHugh ,&nbsp;Michael Strasser ,&nbsp;Ken Ikehara ,&nbsp;Charlotte Pizer ,&nbsp;Yasuyuki Nakamura","doi":"10.1016/j.marpetgeo.2025.107597","DOIUrl":"10.1016/j.marpetgeo.2025.107597","url":null,"abstract":"<div><div>Mud volcanoes occur in a variety of geodynamic settings, and are common in subduction zones, usually within the accretionary prism. Although mud volcanism occurs along the Ryukyu Trench in southern Japan, no such activity has been documented along the Japan Trench. Sub-bottom profile data from International Ocean Discovery Program Expedition 386 show acoustically anomalous features in the basin-fill stratigraphy consistent with mud diapirism and mud volcanism along the Japan Trench. Unusually these features occur in basins along the trench axis itself, and not primarily as part of the accretionary complex. We present evidence for diapirism along ∼600 km of the Japan Trench and for mud volcanoes in the central and northern part of the trench. Mud diapirism and nearby igneous volcanic activity shows close spatial relationships to flexural faults on the down-going plate, which may provide the plumbing system for mobile muds to reach the surface.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"182 ","pages":"Article 107597"},"PeriodicalIF":3.6,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145026784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The sedimentary provenance of Upper Miocene Dongfang submarine fan, Yinggehai Basin: source-to-sink system unravelled through new detrital zircon U-Pb ages and heavy mineral analysis 莺歌海盆地上中新统东方海底扇沉积物源:通过碎屑锆石U-Pb年龄和重矿物分析揭示源-汇体系
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-07-14 DOI: 10.1016/j.marpetgeo.2025.107557
Xingzong Yao , Congjun Feng , Wei Zhou , Pengfei Wu , Hongjun Qu , Jiahao Lei , Zhiqiang Chen , Yanlong Ge , Mengsi Sun
The Upper Miocene Dongfang submarine fan, developed in the Yinggehai Basin, is considered one of the most valuable reservoirs in the northern South China Sea. However, the provenance of the fan remains a controversy between the Red River drainage area and Central Vietnam, hindering hydrocarbon exploration in the basin. In this study, heavy mineral analysis and detrital zircon geochronology of samples from the Upper Miocene intervals in four boreholes were conducted for provenance analysis of the fan. The occurrence of Cr-spinel and high leucoxene contents (34.3 %–85.9 %) in heavy mineral assemblages from these wells suggest sediment contributions from the Red River drainage area and Central Vietnam. Detrital zircon grains from the fan exhibit a wide U-Pb age range, including Luliangian, Jinningian, Caledonian, Indosinian, Yanshanian, and Himalayan populations. Multidimensional scaling (MDS) robustly supports a dual-provenance model consisting of the Red River drainage area and Central Vietnam. Furthermore, we propose that the Red, Ma, Lam, Gianh, and Ben Hai rivers served as sediment pathways owing to the similarities in zircon age distributions between the fan and modern drainage systems. Unmixing models employing the Kolmogorov-Smirnov (K-S) test D statistic quantify the relative source contributions, indicating a potential internal evolution of the fan. Among these, the Red River drainage area dominated the samples D132h and D1310h, accounting for 94.3 % and 86 % of detritus, respectively. Central Vietnam predominantly contributed 99.5 % of sediments to the sample D134h. For the sample D136h, 45.7 % of sediments were derived from the Red River drainage area and 54.3 % from Central Vietnam. The reconstruction of the source-to-sink system reveals that the global forcings (the uplift of the Tibetan Plateau, the expansion of Antarctic ice sheets) and regional adjustments (the intensification of East Asian monsoon, the reversal of Red River Shear Zone) collectively controlled the formation and development of Dongfang submarine fan. Specifically, the activity on the Red River Shear Zone destabilized the deltaic sediments along the western margin of Yinggehai Basin, generating sediment gravity flows that accumulated in the depocenter and formed the Dongfang submarine fan. The source-to-sink system model may provide valuable insights into the prediction of Upper Miocene reservoirs and guides the future hydrocarbon exploration in the basin.
莺歌海盆地发育上中新统东方海底扇,是南海北部最有价值的储层之一。然而,在红河流域与越南中部地区之间,扇的物源仍存在争议,阻碍了盆地的油气勘探。通过对4个钻孔上中新世段样品进行重矿物分析和碎屑锆石年代学研究,对扇体进行物源分析。这些井重矿物组合中铬尖晶石含量高(34.3% ~ 85.9%),亮绿世含量高(34.3% ~ 85.9%),表明红河流域和越南中部的沉积物贡献。扇体碎屑锆石的U-Pb年龄范围较广,包括陆梁期、金宁期、加里东期、印支期、燕山期和喜马拉雅期。多维尺度(MDS)强有力地支持由红河流域和越南中部组成的双物源模型。此外,由于扇河与现代水系锆石年龄分布相似,我们认为红河、马河、林河、吉安河和Ben Hai河可能是沉积路径。采用Kolmogorov-Smirnov (K-S)检验D统计量的解混模型量化了相对源贡献,表明扇的潜在内部演化。其中,D132h和D1310h样品以红河流域为主,分别占94.3%和86%。越南中部主要贡献了99.5%的沉积物到样品D134h。样品D136h中,45.7%的沉积物来自红河流域,54.3%来自越南中部。源-汇系统重建表明,全球强迫(青藏高原隆升、南极冰盖扩张)和区域调整(东亚季风增强、红河切变带反转)共同控制了东方海底扇的形成和发展。具体而言,红河剪切带活动使莺歌海盆地西缘三角洲沉积失稳,形成沉积重力流,在沉积中心积聚,形成东方海底扇。源-汇系统模型可为上中新统储层预测提供有价值的指导,为今后盆地油气勘探提供指导。
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引用次数: 0
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Marine and Petroleum Geology
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