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The Guajira contourite depositional system along the northern Colombian Caribbean convergent margin 哥伦比亚加勒比海北部辐合边缘的瓜希拉等长岩沉积体系
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-14 DOI: 10.1016/j.marpetgeo.2025.107556
J. Naranjo-Vesga , O. Mantilla , D. Rincón-Martínez , E. Rodriguez-Rubio , A. Ortiz-Karpf , C. Winter , Y. Rojas-Agramonte
Bottom currents have a significant role in the transport, erosion and deposition of sediments. They also have the power to modify the seabed morphology. Contourite depositional systems have been reported worldwide, mainly in passive margins; with few examples reported at convergent margins. This study uses regional multibeam bathymetry and seismic data, to document for the first time a∼20,000 km2 slope contourite depositional system along the upper continental slope of the northern Colombian Caribbean convergent margin. We compare the characteristics of the slope geomorphology with hydrodynamic modeling of the bottom currents. We identified on the upper slope, close to the shelf edge, the presence of erosional terraces and moats over an area of∼2,700 km2. Near this sector, the modelled ocean currents can reach speeds of up to∼10 cm/s. However, the bottom currents have a high degree of variability, and low values of∼1 cm/s are also identified over the terraces; this may suggest that erosion can occur when the currents reach their highest speeds of circulation. Therefore, the erosion is neither homogeneous nor continuous along the slope. On the other hand, the plastered drift and sediment wave fields related to sediment accumulation have low current velocities between∼1 - 5 cm/s, and they cover a large area of the upper slope (∼17,600 km2), suggesting that sediment accumulation may occur in areas where bottom currents have low velocities. The plastered drift thickness also shows high variability in the study area. The major thicknesses of∼785 ms (or ± 800 m) are related to a gentle slope topography (<2°). In contrast, the lowest thicknesses of∼300 ms (or ± 300 m) are identified in areas with steep slope topography (>2–5°), indicating that in gently slope topography (<2°) plastered drift deposits have a greater thickness. This work allows us to characterize for the first time a regional slope contourite depositional system along the northern Colombian Caribbean margin and highlights the influence of bottom current strength and slope gradient topography in controlling the erosion and preferential accumulation of sediments in an active margin with low sediment supply. This mode of occurrence may be characteristic of contourite depositional system development on convergent margins with low fluvial sediment discharge worldwide.
海底流在沉积物的运输、侵蚀和沉积中起着重要的作用。它们也有能力改变海底的形态。轮廓岩沉积体系在世界范围内已被报道,主要分布在被动边缘;在收敛边缘有几个例子报告。本研究利用区域多波束测深和地震数据,首次在哥伦比亚加勒比海北部辐合边缘的上大陆斜坡上记录了一个~ 20,000 km2的斜坡等高线沉积体系。我们将坡面地貌特征与底流的水动力模拟进行了比较。我们在靠近陆架边缘的上斜坡上发现了面积约2700平方公里的侵蚀阶地和护城河。在这个区域附近,模拟洋流的速度可以达到~ 10厘米/秒。然而,底部洋流具有高度的可变性,在阶地上也发现了~ 1 cm/s的低值;这可能表明,当水流达到其最高循环速度时,侵蚀就会发生。因此,沿坡的侵蚀既不是均匀的,也不是连续的。另一方面,与泥沙堆积相关的灰泥漂移和泥沙波场流速较低,在~ 1 ~ 5 cm/s之间,覆盖了较大的上坡面积(~ 17,600 km2),表明泥沙堆积可能发生在底流流速较低的地区。灰泥漂移厚度在研究区内也表现出较高的变异性。~ 785 ms(或±800 m)的主要厚度与缓坡地形(<2°)有关。相比之下,陡坡地形(>2 - 5°)地区的最低厚度为~ 300 ms(或±300 m),这表明在缓坡地形(<2°),灰泥漂移沉积物具有更大的厚度。这项工作使我们能够首次描述哥伦比亚北部加勒比海边缘的区域斜坡等高线沉积体系,并强调了底流强度和斜坡梯度地形在控制低沉积物供应的活动边缘的侵蚀和沉积物优先堆积方面的影响。这种产状模式可能是世界范围内河流输沙量较低的辐合边缘的等长岩沉积体系发育的特征。
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引用次数: 0
The sedimentary provenance of Upper Miocene Dongfang submarine fan, Yinggehai Basin: source-to-sink system unravelled through new detrital zircon U-Pb ages and heavy mineral analysis 莺歌海盆地上中新统东方海底扇沉积物源:通过碎屑锆石U-Pb年龄和重矿物分析揭示源-汇体系
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-14 DOI: 10.1016/j.marpetgeo.2025.107557
Xingzong Yao , Congjun Feng , Wei Zhou , Pengfei Wu , Hongjun Qu , Jiahao Lei , Zhiqiang Chen , Yanlong Ge , Mengsi Sun
The Upper Miocene Dongfang submarine fan, developed in the Yinggehai Basin, is considered one of the most valuable reservoirs in the northern South China Sea. However, the provenance of the fan remains a controversy between the Red River drainage area and Central Vietnam, hindering hydrocarbon exploration in the basin. In this study, heavy mineral analysis and detrital zircon geochronology of samples from the Upper Miocene intervals in four boreholes were conducted for provenance analysis of the fan. The occurrence of Cr-spinel and high leucoxene contents (34.3 %–85.9 %) in heavy mineral assemblages from these wells suggest sediment contributions from the Red River drainage area and Central Vietnam. Detrital zircon grains from the fan exhibit a wide U-Pb age range, including Luliangian, Jinningian, Caledonian, Indosinian, Yanshanian, and Himalayan populations. Multidimensional scaling (MDS) robustly supports a dual-provenance model consisting of the Red River drainage area and Central Vietnam. Furthermore, we propose that the Red, Ma, Lam, Gianh, and Ben Hai rivers served as sediment pathways owing to the similarities in zircon age distributions between the fan and modern drainage systems. Unmixing models employing the Kolmogorov-Smirnov (K-S) test D statistic quantify the relative source contributions, indicating a potential internal evolution of the fan. Among these, the Red River drainage area dominated the samples D132h and D1310h, accounting for 94.3 % and 86 % of detritus, respectively. Central Vietnam predominantly contributed 99.5 % of sediments to the sample D134h. For the sample D136h, 45.7 % of sediments were derived from the Red River drainage area and 54.3 % from Central Vietnam. The reconstruction of the source-to-sink system reveals that the global forcings (the uplift of the Tibetan Plateau, the expansion of Antarctic ice sheets) and regional adjustments (the intensification of East Asian monsoon, the reversal of Red River Shear Zone) collectively controlled the formation and development of Dongfang submarine fan. Specifically, the activity on the Red River Shear Zone destabilized the deltaic sediments along the western margin of Yinggehai Basin, generating sediment gravity flows that accumulated in the depocenter and formed the Dongfang submarine fan. The source-to-sink system model may provide valuable insights into the prediction of Upper Miocene reservoirs and guides the future hydrocarbon exploration in the basin.
莺歌海盆地发育上中新统东方海底扇,是南海北部最有价值的储层之一。然而,在红河流域与越南中部地区之间,扇的物源仍存在争议,阻碍了盆地的油气勘探。通过对4个钻孔上中新世段样品进行重矿物分析和碎屑锆石年代学研究,对扇体进行物源分析。这些井重矿物组合中铬尖晶石含量高(34.3% ~ 85.9%),亮绿世含量高(34.3% ~ 85.9%),表明红河流域和越南中部的沉积物贡献。扇体碎屑锆石的U-Pb年龄范围较广,包括陆梁期、金宁期、加里东期、印支期、燕山期和喜马拉雅期。多维尺度(MDS)强有力地支持由红河流域和越南中部组成的双物源模型。此外,由于扇河与现代水系锆石年龄分布相似,我们认为红河、马河、林河、吉安河和Ben Hai河可能是沉积路径。采用Kolmogorov-Smirnov (K-S)检验D统计量的解混模型量化了相对源贡献,表明扇的潜在内部演化。其中,D132h和D1310h样品以红河流域为主,分别占94.3%和86%。越南中部主要贡献了99.5%的沉积物到样品D134h。样品D136h中,45.7%的沉积物来自红河流域,54.3%来自越南中部。源-汇系统重建表明,全球强迫(青藏高原隆升、南极冰盖扩张)和区域调整(东亚季风增强、红河切变带反转)共同控制了东方海底扇的形成和发展。具体而言,红河剪切带活动使莺歌海盆地西缘三角洲沉积失稳,形成沉积重力流,在沉积中心积聚,形成东方海底扇。源-汇系统模型可为上中新统储层预测提供有价值的指导,为今后盆地油气勘探提供指导。
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引用次数: 0
Isotopic equilibrium constraints on CO2 dissolution and carbon isotopic reversal in a thermogenic coalbed gas system associated with the Zhuzang syncline, Guizhou, China 贵州竹藏向斜热成因煤层气系统CO2溶解和碳同位素逆转的同位素平衡约束
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-11 DOI: 10.1016/j.marpetgeo.2025.107554
Xiangrui Chen , Yunpeng Wang , Mingxin Tao , Zheng Zhou , Meng Wei
Natural gas is a vital energy resource. The isotopic composition of natural gas plays a critical role in understanding its origin, thermal maturity, and secondary alteration. Both kinetic and equilibrium isotopic fractionations have been observed in various natural gas systems. However, the dominant mechanism (either equilibrium or kinetic) that controls the isotopic compositions of the primary natural gas is still unclear. Coalbed gas (CBG), formed and stored in situ coalbeds, is an ideal natural gas for studying this key issue. We collected CBG and coproduced water samples from the Zhuzang syncline in China. This study shows that the CBG is an over-mature thermogenic gas formed during the Yanshanian orogeny. The CH4-C2H6-CO2 system was likely near carbon isotope equilibrium during the CBG formation. However, later alterations, such as meteoric water recharge, CO2 dissolution, and CBG recovery led to obvious isotopic disequilibrium of the CH4-C2H6-CO2-DIC (dissolved inorganic carbon) system. Carbon isotope reversals (δ13CCH4 > δ13CC2H6) were observed in the CBG samples, resulting from decreasing δ13CC2H6 values after CBG formation. Based on isotopic equilibrium, the δ13C values of the primary ethane were estimated. Some hypotheses often used to explain isotope reversals in natural gas cannot explain the isotope reversals of the CBG samples. We propose that the CBG recovery process led to more negative δ13CC2H6 and thus δ13CCH4 > δ13CC2H6. Model-estimated 53–99 % CO2 generated during thermogenic or microbial CBG formation has dissolved into coalbed water to become DIC. Hence, dissolution trapping is an important mechanism for CO2 storage in coalbeds over geological timescales. This study implies that isotopic equilibrium fractionation plays a vital role in understanding the primary geochemical composition and secondary alteration of CBG.
天然气是一种重要的能源。天然气的同位素组成对认识天然气的成因、热成熟度和次生蚀变具有重要意义。在不同的天然气系统中都观察到动力学和平衡同位素分馏。然而,控制原生天然气同位素组成的主要机制(平衡机制或动力学机制)仍不清楚。煤层中形成并储存的煤层气是研究这一关键问题的理想天然气。我们收集了中国Zhuzang向斜的CBG和产水样品。研究表明,煤层气是燕山期造山期形成的过成熟热成气。在CBG形成过程中,CH4-C2H6-CO2体系可能接近碳同位素平衡。然而,后来的变化,如大气水分补给、CO2溶解和CBG恢复,导致CH4-C2H6-CO2-DIC(溶解无机碳)体系的同位素不平衡明显。碳同位素倒转(δ13CCH4 >;δ13CC2H6),这是由于CBG形成后δ13CC2H6值减小所致。根据同位素平衡,估算了原乙烷的δ13C值。一些常用于解释天然气同位素逆转的假设不能解释CBG样品的同位素逆转。我们认为CBG开采过程导致δ13CC2H6负增加,δ13CCH4 >;δ13 cc2h6。模型估计,在热成因或微生物成因煤层气形成过程中产生的53 - 99%的二氧化碳已经溶解到煤层气水中成为DIC。因此,在地质时间尺度上,溶蚀圈闭是煤层中二氧化碳储存的重要机制。研究表明,同位素平衡分馏对了解煤层气的原生地球化学组成和次生蚀变具有重要意义。
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引用次数: 0
Sequence stratigraphic and reservoir modeling of KOC Field onshore Niger Delta Basin: implication for mature oilfield revitalization 尼日尔三角洲盆地陆上KOC油田层序地层与储层模拟:对成熟油田振兴的启示
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-11 DOI: 10.1016/j.marpetgeo.2025.107553
Amoke Aniebonam Ignatius , Ayonma Wilfred Mode , Ikechukwu Onyema Njoku , Eze Martins Okoro
Recently, the exploration focus in the onshore areas of the Niger Delta Basin has been targeted towards extending the economic viability of “shallow hanging” producing reservoir units whilst searching wider and deeper for new oil and gas pools beyond known depths. The need therefore arises to deploy improved technologies for accurate mapping of prospect opportunities located at intermediate and deeper intervals within the basin. In this study, integrated sequence stratigraphic and reservoir modeling of the KOC Field onshore Niger Delta Basin was carried out using well logs, 3D seismic, and biostratigraphic data to assess the hydrocarbon potentials and also uncover the reservoir geometry, stratigraphic configuration, and structural framework of the study area. Logging and biofacies information from seven (7) wells, as well as key stratal surfaces including three (3) sequence boundaries (SB) and three (3) maximum flooding surfaces (MFS) provided in Well 001 and Well 039, formed the basis for chronostratigraphic correlation across the field. Two genetic sequences bounded at the top and base by maximum flooding surfaces were mapped and designated as Genetic Sequence 1 (G_SEQ1) and Genetic Sequence 2 (G_SEQ2). Three main stacking patterns (progradational, retrogradational and aggradational) interpreted as Lowstand Systems Tract (LST), Highstand Systems Tract (HST) and Transgressive Systems Tract (TST) were delineated from each of the identified genetic sequences. Lithological correlation of the wells revealed two hydrocarbon-bearing sand units with good reservoir quality characteristics. These reservoirs designated as R12 Sand and R15 Sand belonged to the LST and TST of G_SEQ2, and were interpreted to be basin floor fans and channel fill complexes, deposited within the neritic to bathyal environments. 3D geological modelling of the reservoirs showed good structural closures with thick sedimentary packages, suggesting that they are good locations for hydrocarbon accumulation. The major faults constitute good reservoir seals due to stratigraphic juxtapositions that may have prevailed in the cause of the dip slip movement.
最近,尼日尔三角洲盆地陆上区域的勘探重点是扩大“浅挂”生产储层单元的经济可行性,同时在已知深度之外寻找更广泛、更深的新油气藏。因此,有必要部署改进的技术,以便在盆地内的中深层段精确绘制勘探机会。在本研究中,利用测井、三维地震和生物地层数据,对尼日尔三角洲盆地KOC油田进行了综合层序地层和储层建模,以评估油气潜力,并揭示了研究区域的储层几何形状、地层构型和构造格架。7口井的测井和生物相信息,以及001井和039井提供的3个层序边界(SB)和3个最大淹水面(MFS)等关键地层面,构成了整个油田年代地层对比的基础。绘制以最大泛洪面为界的两个基因序列,分别命名为基因序列1 (G_SEQ1)和基因序列2 (G_SEQ2)。根据所鉴定的基因序列,划分出了低水位系统域(LST)、高水位系统域(HST)和海侵系统域(TST) 3种主要的叠加模式(进积、退积和堆积)。通过井间岩性对比,发现2个含油气砂单元具有良好的储层物性特征。R12砂和R15砂属于G_SEQ2的LST和TST,被解释为盆地底扇和河道充填复合体,沉积于浅海-深海环境。三维地质模拟结果显示,该区构造闭包较厚,是油气聚集的有利位置。由于地层并置,主要断裂构成了良好的储层封印,这可能是导致倾斜滑动运动的主要原因。
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引用次数: 0
Genesis and developmental pattern of Middle Permian dolomite in Northwestern Sichuan, China 川西北地区中二叠统白云岩成因及发育模式
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-11 DOI: 10.1016/j.marpetgeo.2025.107555
Zhidian Xi , Fei Huo , Huachuan Jiang , Xingzhi Wang , Huiwen Huang , Yuhan Huang , Yi Hu , Xueyan Wu , Yang Li , Wenli Xu , Anqing Chen
The formation of large-scale dolomite reservoirs in the Middle Permian of Northwest Sichuan shares a good temporal correlation with the occurrence of major events in the Emeishan Large Igneous Province (ELIP). However, because the dolomitized fluids, the timing of dolomitization and the genesis mechanism of the dolomites are not comprehensively understood, its developmental pattern requires further analysis. This paper identified the diagenetic fluids of different types of dolomites via petrological characteristics of dolomites, carbon and oxygen isotopes, strontium isotopes, and other geochemical data, as well as fluid inclusions and laser U-Pb isotope dating. The dolomite genesis model related to the dynamical formation mechanism of the ELIP was also reconstructed. The Middle Permian dolomites in Northwest Sichuan are divided into matrix dolomite (Md) and cement dolomites (Cd). Importantly, the matrix dolomites include very finely to finely crystalline matrix dolomite (Md1), finely to medium crystalline matrix dolomite (Md2), and medium to coarsely crystalline matrix dolomite (Md3). The dolomites were primarily modified by three phases of dolomitizing fluids. The Md1 phase yields a U-Pb age of 262 ± 9.2 Ma, consistent with the host stratigraphic age, and exhibits 87Sr/86Sr ratios matching Permian seawater values. These features indicate Md1 formed dominantly through penecontemporaneous seawater reflux dolomitization. In contrast, the Md2 phase shows a U-Pb age of 261.3 ± 7.4 Ma—also stratigraphically consistent—but contains later-stage subsurface cements with a distinct U-Pb age of 245.7 ± 1.9 Ma. This significant age offset demonstrates that Md2 resulted from overprinting by multiple dolomitizing fluid phases. These fluids were mainly formed owing to the temperature difference between the warming stratigraphic water and the cold seawater in the ELIP under the geothermal warming effect. The cold seawater on the slope creates a fluid potential energy difference, generating lateral open circulation and causing thermal convection. Furthermore, Md3 and Cd have negatively skewed δ18O values, along with higher Th and Eu/Eu∗ values, suggesting that the diagenetic fluids were substantially shallow buried strata water, which resembled Permian seawater. They were mostly produced under the higher geothermal temperatures during the ELIP active period, which generated a substantial fluid potential energy difference, and were driven by a more rapid thermal convection cycle. This study quantitatively constrains the timing of dolomitization using laser U-Pb isotope dating, aiming to give a reliable and valuable reference for the impact of tectonic activities on dolomite genesis caused by the Large Igneous Province.
川西北中二叠统大型白云岩储层的形成与峨眉山大火成岩省(ELIP)重大事件的发生具有良好的时间相关性。但由于白云化流体、白云化时间及白云岩成因机制尚不全面,其发育模式有待进一步分析。本文通过白云岩岩石学特征、碳氧同位素、锶同位素等地球化学资料,以及流体包裹体和激光U-Pb同位素定年,对不同类型白云岩的成岩流体进行了识别。重建了与ELIP动力形成机制相关的白云岩成因模式。川西北地区中二叠统白云岩分为基质白云岩(Md)和胶结白云岩(Cd)。重要的是,基质白云岩包括极细至细晶基质白云岩(Md1),细至中晶基质白云岩(Md2)和中至粗晶基质白云岩(Md3)。白云岩主要经过3期白云化流体的改性。Md1相U-Pb年龄为262±9.2 Ma,与寄主地层年龄一致,87Sr/86Sr比值与二叠纪海水值吻合。这些特征表明Md1主要通过准同生海水回流白云化作用形成。相比之下,Md2相的U-Pb年龄为261.3±7.4 Ma,与地层一致,但含有后期地下胶结物,U-Pb年龄明显为245.7±1.9 Ma。这种明显的年龄偏移表明,Md2是由多个白云化流体相叠加形成的。这些流体主要是由于地热增温作用下的暖地层水与ELIP内的冷海水之间的温差而形成的。斜坡上的冷海水产生流体位能差,产生横向开放环流,引起热对流。Md3和Cd δ18O值呈负偏态,Th和Eu/Eu *值较高,表明成岩流体基本为浅埋地层水,与二叠纪海水相似。它们主要是在ELIP活动期地热温度较高的条件下产生的,产生了较大的流体位能差,并且受更快速的热对流循环驱动。本研究利用激光U-Pb同位素定年技术对白云化时间进行定量约束,旨在为构造活动对大火成岩省白云岩成因的影响提供可靠而有价值的参考。
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引用次数: 0
Inconsistencies in organosulfur compounds during natural and artificial maturation 有机硫化合物在自然和人工成熟过程中的不一致性
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-11 DOI: 10.1016/j.marpetgeo.2025.107541
Poorna Srinivasan , Constantin Sandu , Estefania M. Endara Arguello , Ibrahim Atwah
Hydrous pyrolysis techniques are valuable for understanding and quantifying petroleum yield, thermal maturity, compositional variations, and kinetics across different kerogen types. Such data is essential for basin modeling and well planning. Previous studies have shown that sulfur-rich Type II-S kerogen generates hydrocarbons at lower temperatures due to its lower activation energy, resulting in early cracking. Consequently, organosulfur presents a challenge in numerous basins worldwide, as sulfur-rich source rocks from various regions must be examined closely to accurately predict hydrocarbon generation in each basin. Additional factors, such as total organic carbon content and mineralogy, also influence the timing and yield of oil generation. Methyldibenzothiophene isomers have proven to be reliable maturity indicators in sulfur-rich source rocks, often providing more accurate maturity predictions than biomarkers at higher maturity levels. However, few studies have closely examined the compositional and isomeric changes of alkylated methyldibenzothiophene compounds under hydrous pyrolysis conditions. In this study, hydrous pyrolysis experiments were conducted on three sulfur-rich source rocks and one sulfur-rich crude oil at temperatures between 275 and 360 °C to monitor and quantify changes in alkylated MDBT compounds as well as other aromatic hydrocarbons. The results were compared to four naturally matured Type II-S source rocks, spanning the immature to condensate windows, to evaluate the effects of hydrous pyrolysis on aromatic compounds. Significant differences in thermal maturity parameters were observed in the kerogen, bitumen, and expelled oil. While the increase in the 4-MDBT/1-MDBT ('MDR') ratio provided consistent thermal maturity estimates in natural samples, the hydrous pyrolysis experiments revealed that these geochemical markers are inconsistent under artificial thermal conditions, potentially due to additional sulfur species forming in the reactor, buffering reactions in the closed system reactor, the limited temperature range of the experiments, or other matrix-controlled interactions that are found in nature but are not occurring in the reactor. In contrast, aromatic biomarkers such as triaromatic steroids showed a positive increase in their isomer ratios relative to the experimental run temperature. The chemical differences between these organosulfur-rich samples (e.g., TOC, hydrogen index, mineralogy) suggest that the original source material—not solely the sulfur content—plays a critical role in the kinetics of alkylated dibenzothiophene compounds.
含水热解技术对于理解和量化不同干酪根类型的石油产量、热成熟度、成分变化和动力学具有重要意义。这些数据对于盆地建模和井规划至关重要。前人研究表明,富硫II-S型干酪根由于活化能较低,在较低温度下生成烃,导致早期裂解。因此,有机硫在世界范围内的许多盆地中都是一个挑战,因为必须仔细检查来自不同地区的富硫烃源岩,才能准确预测每个盆地的生烃情况。其他因素,如总有机碳含量和矿物学,也会影响生油的时间和产量。甲基二苯并噻吩异构体已被证明是富硫烃源岩的可靠成熟度指标,通常比高成熟度水平的生物标志物提供更准确的成熟度预测。然而,很少有研究仔细研究烷基化甲基二苯并噻吩化合物在加水热解条件下的组成和异构体变化。本研究对3种富硫烃源岩和1种富硫原油在275 ~ 360℃的温度下进行了加水热解实验,以监测和量化烷基化MDBT化合物以及其他芳香烃的变化。研究结果与4种自然成熟II-S型烃源岩进行了对比,跨越了未成熟到凝析油窗口,以评价加氢热解对芳烃化合物的影响。干酪根、沥青和排油的热成熟度参数存在显著差异。虽然4-MDBT/1-MDBT ('MDR')比值的增加为自然样品提供了一致的热成熟度估计,但含水热解实验表明,这些地球化学标志在人工热条件下不一致,可能是由于反应器中形成了额外的硫种,封闭系统反应器中的缓冲反应,实验温度范围有限。或者其他在自然界中发现但不在反应器中发生的基质控制的相互作用。相比之下,芳香族生物标志物,如三芳香族类固醇,其异构体比例相对于实验运行温度呈正增加。这些富硫有机样品之间的化学差异(如TOC、氢指数、矿物学)表明,原始原料——而不仅仅是硫含量——在烷基化二苯并噻吩化合物的动力学中起着关键作用。
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引用次数: 0
Cenomanian channel system evolution of Mundaú Sub-basin deepwater, Brazilian Equatorial Margin: Reservoir characterization using machine learning techniques 巴西赤道边缘Mundaú次盆地深水塞诺曼期河道体系演化:利用机器学习技术表征储层
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-10 DOI: 10.1016/j.marpetgeo.2025.107540
Ian de Oliveira Souza Cerdeira , Karen Maria Leopoldino Oliveira , Jorge de Jesus Picanço Figueiredo , Heather Bedle , Narelle Maia de Almeida , Ana Clara Braga Souza
Submarine channel systems have garnered significant attention in recent years due to their importance in petroleum exploration and favorable reservoir characteristics. Specifically, the Brazilian Equatorial Margin basins have attracted considerable interest from various sectors because of substantial hydrocarbon discoveries in adjacent basins. In the Mundaú Sub-basin (Ceará Basin, NE Brazil), recent studies have identified a series of sand-rich structures associated with a Cenomanian submarine channel system. However, despite these advancements, the depositional elements, sedimentary architecture, and stratigraphic sequences remain poorly understood. This paper aims to integrate robust quantitative geophysical techniques, including unsupervised machine learning methods, multi-attribute analysis, and RGB blending, to clarify the main evolutionary stages of the Cenomanian submarine channel-lobo system in the central portion of the aforementioned Sub-basin and their controlling factors. We utilized data from four exploration wells drilled in the deep waters of the Mundaú Sub-basin, along with a 2200 km2 seismic volume covering the study area. Our integrated approach identified three main evolutionary stages. The first stage is characterized by straight to low-sinuosity confined channels on the upper to middle slope, alongside poorly confined channels and splays on the lower slope to basin floor, primarily comprising sand-prone layers developed during a Falling Stage System Tract. The second stage exhibits low to moderate sinuosity confined channels in the upper to middle slope, with significantly poorly confined channels and splays on the lower slope to basin floor, also dominated by sand-prone layers developed in a Lowstand Tract System. The final stage features a high-sinuosity confined channel with dominant sand-prone and sand/mud-prone layers developed in a Transgressive System Tract. all stages and across almost the whole region, sand-prone and sand/mud-prone facies were identified and associated with various depositional elements at different scales. the presence of sand-prone layers in all stages is thought to result from high-density turbidity currents driven by a narrow shelf and stepped slope. The mapped features and predicted facies indicate an unexplored area with sand-rich layers likely possessing good lateral and vertical connectivity. Important structures that may facilitate oil migration were identified, highlighting the high exploration potential of the Cenomanian submarine channel system in the Mundaú Sub-basin.
近年来,海底水道系统因其在石油勘探中的重要作用和有利的储层特征而受到广泛关注。具体来说,由于在邻近盆地发现了大量的油气,巴西赤道边缘盆地吸引了各个部门的极大兴趣。在Mundaú次盆地(巴西东北部ceear盆地),最近的研究已经确定了一系列与塞诺曼尼亚海底水道系统相关的富砂构造。然而,尽管取得了这些进展,沉积元素、沉积结构和地层层序仍然知之甚少。本文旨在整合鲁棒定量地球物理技术,包括无监督机器学习方法、多属性分析和RGB混合,以阐明上述子盆地中部塞诺曼尼亚海底通道-lobo系统的主要演化阶段及其控制因素。我们利用了在Mundaú子盆地深水钻探的四口勘探井的数据,以及覆盖研究区域的2200平方公里的地震体积。我们的综合方法确定了三个主要的进化阶段。第一阶段的特征是在上斜坡到中斜坡上有直到低弯曲度的封闭河道,在下斜坡到盆地底部有较差的封闭河道和带状河道,主要由在下降阶段体系域发育的易砂层组成。第二阶段在上斜坡至中斜坡发育低至中等曲度的封闭性河道,下斜坡至盆地底部发育明显的弱封闭性河道和带状河道,也以低洼地域体系发育的易砂层为主。最后阶段为高弯曲度封闭河道,主要发育海侵体系域的倾向砂层和倾向砂/泥层。在几乎整个地区的所有阶段,都确定了倾向于砂和倾向于砂/泥的相,并将其与不同尺度的各种沉积元素联系起来。所有阶段的易沙层的存在被认为是由狭窄的陆架和阶梯式斜坡驱动的高密度浊流造成的。图上的特征和预测相表明,这是一个尚未勘探的地区,富砂层可能具有良好的横向和纵向连通性。发现了可能有利于石油运移的重要构造,突出了Mundaú次盆地Cenomanian海底通道系统的高勘探潜力。
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引用次数: 0
Reconstructing hydrocarbon accumulation and burial history of Permian reservoirs in northwest Sichuan Basin, China: Integrated fluid inclusion thermometry and U-Pb dating 四川盆地西北部二叠系储层油气成藏与埋藏史重建:流体包裹体温度和U-Pb测年
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-09 DOI: 10.1016/j.marpetgeo.2025.107539
Rui Ni , Yong Chen , Yifan Song , Hui Zhang , Yanwei Feng , Fang Hao , Xuesong Lu , Xingzhi Ma
The western Sichuan basin is a typical foreland basin, and great discovery of oil and gas exploration has been done here, but the history of hydrocarbon accumulation and burial history evolution is still uncertain. Fluid inclusion thermometry and isotopic dating are employed in this study to reconstruct the burial history and hydrocarbon accumulation of the Western Sichuan Foreland Basin. Furthermore, research was conducted research on the diagenesis, reservoir-forming stages and differences of the Qixia Formation reservoirs at different tectonic locations in the northwest of Sichuan. The results show that in the Shuangyushi area (concealed front-edge belt), the upper reservoirs of the Qixia Formation are mainly composed of sparry dolomitic limestone, with a diagenesis mineral sequence of: (1) the early microcrystalline calcite, (2) recrystallized calcite, (3) quartz, albite, pore bitumen in the surrounding rock, and (4) dolomite and calcite in fractures. In the Longmen Mountain piedmont area (thrust nappe belt), the outcrop rock of the Qixia Formation is mainly dolomitic limestone, with a diagenesis mineral sequence: (1) microcrystalline calcite, (2) recrystallized calcite, (3) quartz and bitumen, and (4) calcite filled in both pores and fractures. In the Shuangyushi area, the reservoirs of the Qixia Formation underwent crude oil charging from the Middle Triassic to Middle Jurassic, subsequent natural gas charging in the Late Cretaceous, and final natural gas reservoir destruction and adjustment at Late Cretaceous (81.2 ± 8.4 Ma). While, the outcrop of the Qixia Formation in the Longmen Mountain piedmont area recorded oil charging from the Lower Cambrian source rocks at Late Triassic (217.1 ± 0.9 Ma) and the destruction of oil reservoirs during the Miocene to Pleistocene (i.e., Himalayan orogeny). By comparing the petrological characteristics, fluid inclusion development and reservoir-forming periods of the two areas, it is considered that these disparities arise from the areas’ distinct tectonic positions within the foreland basin, leading to divergent responses to the Indosinian and Himalayan orogeny, as well as the resulting hydrocarbon accumulation processes.
川西盆地是典型的前陆盆地,已取得重大油气勘探发现,但油气成藏史和埋藏史演化仍不确定。采用流体包裹体测温和同位素定年等方法重建川西前陆盆地的埋藏史和油气成藏特征。在此基础上,研究了川西北地区不同构造位置栖霞组的成岩作用、成藏期次及储层差异性。结果表明,双鱼石地区(隐伏前缘带)祁下组上储层主要由亮晶白云质灰岩组成,成岩矿物序列为:(1)早期微晶方解石,(2)重晶方解石,(3)围岩中的石英、钠长石、孔隙沥青,(4)裂缝中的白云石和方解石。龙门山前山带(逆冲推覆带)祁霞组露头岩主要为白云质灰岩,成岩矿物序列为:(1)微晶方解石,(2)重晶方解石,(3)石英和沥青,(4)孔缝充填的方解石。双鱼石地区栖霞组储层经历了中三叠统—中侏罗世原油充注、晚白垩世天然气充注、晚白垩世(81.2±8.4 Ma)天然气储层最终的破坏与调整。龙门山前地区栖霞组露头记录了晚三叠世(217.1±0.9 Ma)下寒武统烃源岩充注原油和中新世—更新世(即喜马拉雅造山运动)对油藏的破坏。通过对比两区岩石学特征、流体包裹体发育和成藏时期,认为这些差异是由于两区在前陆盆地内构造位置不同,对印支和喜马拉雅造山运动的响应不同,对油气成藏过程的响应也不同。
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引用次数: 0
Porosity estimation using deep learning and ImageJ: Implications for reservoir characterization in Central Luconia Miocene carbonates 基于深度学习和ImageJ的孔隙度估算:中陆盆统中新世碳酸盐岩储层表征的意义
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-07 DOI: 10.1016/j.marpetgeo.2025.107538
Abdulrahman Danlami Isa , Haylay Tsegab Gebretsadik , Abdulrahman Muhammad , Hassan Salisu Mohammed , Ibrahim Muhammad Kurah , Adamu Kamaliddeen Salisu
Accurate porosity prediction is essential for effective reservoir characterisation, particularly in heterogeneous carbonate systems. This study investigates applying deep learning techniques to predict porosity from petrographic thin-section images of Miocene carbonate reservoirs in Central Luconia, offshore Malaysia. Four semantic segmentation models—UNet, SegNet, PSPNet, and Fully Convolutional Network (FCN)—were trained and evaluated, with UNet achieving the highest performance across all metrics: accuracy (0.990), precision (0.849), recall (0.940), F1 score (0.892), and Intersection over Union (IoU) (0.805). These results were benchmarked against traditional image analysis using ImageJ, where UNet predictions showed strong alignment, highlighting its reliability. SegNet also performed robustly, while PSPNet and FCN demonstrated lower predictive accuracy. The study further explored the impact of data augmentation, revealing performance degradation in SegNet and PSPNet due to distortion of micropore structures. A classification scheme based on UNet output identified porosity ranges, with 71.90 % of samples exhibiting <5 % porosity, reflecting a low-porosity-dominated system. A spatial porosity distribution map was also generated using UNet to visualise heterogeneity across thin-section samples. It is important to note that this map is a conceptual representation and does not reflect the actual porosity distribution of the broader reservoir. Instead, it serves as a hypothetical visualisation to enhance understanding of porosity characteristics and heterogeneity within the analysed thin-section images. This work demonstrates the advantages of deep learning over conventional techniques for pore-scale analysis. It offers a scalable framework for integrating artificial intelligence in quantitative reservoir quality assessment.
准确的孔隙度预测对于有效的储层描述至关重要,特别是在非均质碳酸盐岩体系中。本研究旨在利用深度学习技术预测马来西亚Luconia中部中新世碳酸盐岩储层的岩石薄片图像孔隙度。四种语义分割模型——UNet、SegNet、PSPNet和全卷积网络(FCN)——进行了训练和评估,UNet在所有指标上都取得了最高的性能:准确率(0.990)、精度(0.849)、召回率(0.940)、F1分数(0.892)和交集比联合(IoU)(0.805)。这些结果与使用ImageJ的传统图像分析进行了基准测试,其中UNet预测显示出很强的一致性,突出了其可靠性。SegNet也表现稳健,而PSPNet和FCN表现出较低的预测准确性。该研究进一步探讨了数据增强的影响,揭示了SegNet和PSPNet由于微孔结构扭曲而导致的性能下降。基于UNet输出的分类方案确定了孔隙度范围,71.90%的样品孔隙度为5%,反映了低孔隙度为主的系统。利用UNet生成了空间孔隙度分布图,以可视化薄片样品的非均质性。值得注意的是,这张图是一个概念性的表示,并不能反映更广泛的储层的实际孔隙度分布。相反,它可以作为一种假设的可视化,以增强对所分析的薄片图像中的孔隙度特征和非均质性的理解。这项工作证明了深度学习相对于传统孔隙尺度分析技术的优势。它为将人工智能集成到定量储层质量评价中提供了一个可扩展的框架。
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引用次数: 0
Differential diagenetic controls on petrophysical heterogeneity of lacustrine beach-bar tight sandstones: Insights from the Boxing Sag, eastern China 湖相滩坝致密砂岩岩石物性非均质性的差异成岩控制:来自中国东部博兴凹陷的启示
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-05 DOI: 10.1016/j.marpetgeo.2025.107537
Cunfei Ma , Haowen Song , Yuqi Wu , Xiaopeng Cao , Haicheng Liu , Huafeng Zhang , Yong Fu , Wei Wang , Chao Huang , Xianxu Fang
The Bohai Bay Basin is rich in petroleum resources, and the lacustrine beach-bar tight sandstone facies in the upper part of the fourth Member of the Paleogene Shahejie Formation (Es4s) of the Boxing Sag is a key exploration target. However, the heterogeneity in petrophysical properties caused by differential diagenesis during burial impacts its development. In this study, an integrated approach is used that includes core and thin section descriptions, scanning electron microscopy (SEM), carbon and oxygen isotope analysis, fluid inclusion analysis, rock physical properties, and high-pressure mercury injection analyses to investigate the differential diagenesis of the beach-bar tight sandstone reservoirs and its effects on petrophysical heterogeneity. Key findings include: (1) The sequence of diagenetic evolution of the reservoirs is: mechanical compaction and spherical pyrite cementation → calcite and dolomite cementation → feldspar dissolution, authigenic kaolinite precipitation, and quartz overgrowth → ferro-calcite and ankerite cementation → secondary dissolution and quartz overgrowth → late agglomerate pyrite cementation, reflecting alternating alkaline and acidic diagenetic environments. (2) Mechanical compaction and cementation are the dominant factors responsible for the reduction in reservoir quality. (3) Four distinct diagenetic facies are identified: an intense compaction with intergranular dissolution diagenetic facies (DF-I), an intense compaction with residual intergranular porosity diagenetic facies (DF-II), a weak-moderate compaction with intergranular cementation diagenetic facies (DF-Ⅲ), an intense compaction with matrix occlusion diagenetic facies (DF-Ⅳ). DF-I and DF-II exhibit superior reservoir quality (porosity >10 %, permeability >0.1 mD), making them effective reservoirs. (4) The genesis and spatial distributions of these facies are controlled by the petrological structure, petrographic composition, sand-mud interface, mudstone thickness, and distance from oil-source faults. By integrating multiple factors, this study elucidates the genetic mechanisms of the four diagenetic facies and establishes their vertical distribution patterns. This provides a basis for predicting favorable reservoir distribution and guiding future exploration.
渤海湾盆地油气资源丰富,博兴凹陷古近系沙河街组四段上段湖相滩坝致密砂岩相是重点勘探对象。但埋藏过程中差异成岩作用导致的岩石物性非均质性影响了其发育。本研究采用岩心和薄片描述、扫描电镜(SEM)、碳氧同位素分析、流体包裹体分析、岩石物性和高压压汞分析等综合方法,研究滩坝致密砂岩储层的差异成岩作用及其对岩石物性非均质性的影响。主要发现:(1)储层成岩演化顺序为:机械压实和球形黄铁矿胶结作用→方解石和白云石胶结作用→长石溶蚀、自生高岭石沉淀、石英过生长→铁方解石和铁白云石胶结作用→次生溶蚀和石英过生长→晚期块状黄铁矿胶结作用,反映了碱性和酸性交替的成岩环境。(2)机械压实作用和胶结作用是导致储层质量降低的主要因素。(3)识别出4种不同的成岩相:强压实-粒间溶蚀成岩相(DF- i)、强压实-残余粒间孔隙成岩相(DF- ii)、弱-中度压实-粒间胶结成岩相(DF-Ⅲ)、强压实-基质封堵成岩相(DF-Ⅳ)。df - 1和df - 2具有较好的储层质量(孔隙度10%,渗透率0.1 mD),为有效储层。(4)这些相的成因和空间分布受岩石学构造、岩相组成、砂泥界面、泥岩厚度和离油源断裂的距离等因素的控制。综合多种因素,阐明了四种成岩相的成因机制,建立了四种成岩相的垂向分布模式。这为预测有利储层分布和指导今后勘探提供了依据。
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Marine and Petroleum Geology
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