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Electrical and magnetic response of a phosphate glass - NiFe2O4 composite. A novel magnetic sensor design 磷酸玻璃- NiFe2O4复合材料的电、磁响应。一种新型磁传感器设计
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00082
M. Frechero, PE di Pratula, Pistonesi Ca, A. Ma, HR di Pratula, E. Guillermo
NiFe 2 O 4 spinel – phosphate (Bi-Ba-Li) glass composite was synthesized by solid-state reaction. New crystalline magnetic phases was developed inside the glassy matrix through a controlled heat treatment. New NF-LBPB4 magnetic nanocomposite material was study. Complex impedance analysis has shown that mobile ions inside the matrix induce the development of complementary crystalline phases resulting in a composite material with excellent magnetic response. An innovative homemade device was designed to test the nanocomposite magnetic response.
采用固相法合成了nife2o4尖晶石-磷酸(Bi-Ba-Li)玻璃复合材料。通过控制热处理,在玻璃基体内部形成了新的磁性晶相。研究了新型NF-LBPB4磁性纳米复合材料。复阻抗分析表明,基体内部的移动离子诱导互补晶相的发展,从而形成具有优异磁响应的复合材料。设计了一种创新的自制装置来测试纳米复合材料的磁响应。
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引用次数: 5
Silver recovery from dental amalgam wastes 从牙科汞合金废料中回收银
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00109
E. Yılmaz, Selim Ertürk, C. Arslan, F. Arslan
Alloys made with mercury and other metals are known as amalgam. Dental amalgams are important alloys having mercury (Hg≈40-50%) as a main component and include silver (≈22-39%), tin (≈12-18%) and copper (≈2-18%). Considering the content of dental amalgams, due to the combination of silver, tin and copper in the structure, they have high economic value.1,2 The mixing of silver and other elements and mercury is known as amalgamation. During this process, metallic powders are dissolved in the mercury along the surfaces, and this process leads to the formation of new phases in the structure. These new solid phases result in the plastic state of amalgam. At the end of amalgamation, resulting phases are rigid. The metallurgical phases that are occurred as a result of these reactions are shown in detail in Table 1.3 The metallurgical properties belonging to these phases are complex and the final phase varies according to the content of the starting alloy. In case of Ag-Sn alloy containing copper below 4%, amalgam become harder and stronger but more brittle. In contrast, if the alloy contains copper about 4-5%, separate Cu3Sn phases form in the structure. These phases increase the workability of amalgam and decrease the fragility.3 Basic reactions which occur during amalgamation are as follows:
用汞和其他金属制成的合金被称为汞合金。牙用汞合金是以汞(Hg≈40-50%)为主要成分,包括银(≈22-39%)、锡(≈12-18%)和铜(≈2-18%)的重要合金。考虑到牙科汞合金的含量,由于结构中银、锡、铜的结合,具有很高的经济价值。银和其他元素与汞的混合称为汞齐。在这个过程中,金属粉末沿着表面溶解在汞中,这个过程导致结构中新相的形成。这些新的固相导致了汞合金的塑性状态。在合并结束时,所产生的相是刚性的。表1.3详细列出了这些反应所产生的冶金相。属于这些相的冶金性能是复杂的,最终相根据起始合金的含量而变化。在含铜量低于4%的银锡合金中,银汞合金变得更硬、更强,但更脆。相反,当合金含铜量约为4-5%时,在组织中形成单独的Cu3Sn相。这些相增加了汞合金的和易性,降低了脆性在合并过程中发生的基本反应如下:
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引用次数: 1
Histological characteristics of periprosthetic tissue around metal on metal hip prostheses 金属髋关节假体金属周围假体组织的组织学特征
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00085
A. Cőr
The ultimate challenge for orthopedic surgeons who implant hip prosthesis is providing long-term function of the joint without pain. The most common cause of total hip arthroplasty failure is aseptic loosening mostly initiated by wear particles.1 The current paradigm explains aseptic loosening as an inflammatory response to the wear debris particles produced by prosthetic implants. Wear particles are phagocytosed by macrophages and induce a variety of cytokines that mediate inflammatory response leading to the recruitment and activation of osteoclasts, and eventual implant loosening.2 For over 40 years, the metal-on-polyethylene (MoPE) bearing has dominated the field of total hip replacement (THR). The second generation of metal on metal (MoM) THRs made of CoCrMo alloy was introduced into the market in early 1990s with the aim to eliminate the wear of polyethylene (PE) and therefore, to achieve better long-term clinical results compared to conventional MoPE THRs. MoM artificial hip prostheses showed an extremely low rate of wear of the articulation surfaces. In addition, metal particles that are produced are smaller than PE particles and hence, they may induce less tissue reaction.3–5 However, patients with M-M articulations have increased levels of Co and Cr in the serum and urine, and this has raised concerns about toxicity, mutagenesis and hypersensitivity.6 There are reports from orthopedic registers about increase complications and potential problems of early failure of MoM, often require revision surgery.7,8 Several studies reported soft tissue damages with adverse reaction to metal debris.9
对于植入髋关节假体的整形外科医生来说,最大的挑战是在没有疼痛的情况下提供关节的长期功能。全髋关节置换术失败的最常见原因是无菌性松动,主要由磨损颗粒引起目前的研究范式将无菌性松动解释为假体植入物产生的磨损碎片颗粒的炎症反应。磨损颗粒被巨噬细胞吞噬,并诱导多种细胞因子介导炎症反应,导致破骨细胞的募集和激活,最终导致植入物松动40多年来,金属对聚乙烯(MoPE)轴承在全髋关节置换术(THR)领域占据主导地位。由CoCrMo合金制成的第二代金属对金属(MoM) THRs于20世纪90年代初进入市场,旨在消除聚乙烯(PE)的磨损,因此与传统的MoPE THRs相比,可以获得更好的长期临床效果。MoM人工髋关节假体显示关节面磨损率极低。此外,产生的金属颗粒比PE颗粒小,因此它们可能引起较少的组织反应。3-5然而,患有M-M关节的患者血清和尿液中的Co和Cr水平升高,这引起了对毒性、诱变和超敏反应的关注骨科登记的报告显示,早期MoM失败的并发症和潜在问题增加,通常需要翻修手术。一些研究报道了金属碎片对软组织的不良反应
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引用次数: 1
Dimples and heat transfer efficiency 酒窝与传热效率
Pub Date : 2018-10-31 DOI: 10.15406/MSEIJ.2018.02.00051
J. Ghani, Mohd Naqib Bin Derani, W. M. Mahmood
Dimple surface is one of the surface textures that are widely studied today. In general, dimples are already well known from golf ball aerodynamics. In the case of golf balls, the application of dimples is a special form of surface roughness, which shifts the typical dropdown of the flow resistance for blunt bodies into the low Reynolds number range. Initially, the idea was to use dimples for drag reduction.
酒窝表面是目前研究较多的表面结构之一。一般来说,酒窝已经从高尔夫球空气动力学中众所周知。以高尔夫球为例,韧窝的应用是一种特殊形式的表面粗糙度,它将钝体流动阻力的典型下降转移到低雷诺数范围内。最初的想法是使用酒窝来减少阻力。
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引用次数: 1
Nanowires in magnetic drug targeting 纳米线在磁性药物靶向中的应用
Pub Date : 2018-10-12 DOI: 10.20944/PREPRINTS201711.0054.V4
Behzad Heidarshenas, Hongyu Wei, Zfar Ali Moghimi Moghimi, G. Hussain, F. Baniasadi, Gholamreza Naghieh
Magnetic drug targeting can be used for locoregional cancer therapy, although the limitation is minuteness of the induced force. A new and simple procedure to enhance the magnetic force is changing the shape of carrier particles. It has been mathematically proved that exerting much stronger magnetic dipoles to nanowires are more possible than to spheres with the same volume. The magnetic dipole of wires having aspect quotient (ratio of length to diameter) of 3 is higher than the spheres of the same volume. Nanowires with α = 5 have magnetic dipoles 1.95 times greater than the spheres with the same volume. At a fixed radius, the magnetic dipole increases with the volume of the drug carrier. Magnetic targeting depth is an important parameter depending on the aspect quotient α of particles. Calculations show that the depth of targeting can exceed 8.5 cm if a nanowire with 15 nm radius and length larger than 150 nm is used as the drug carrier. This depth is 1.7 times more than that reported by previous authors for spherical particles with the same-volume.
磁性药物靶向可以用于局部肿瘤的治疗,但其局限性在于诱导力的微小。一种新的、简单的增强磁力的方法是改变载体粒子的形状。数学上已经证明,对纳米线施加更强的磁偶极子比对同样体积的球体施加更强的磁偶极子更有可能。长商(长径比)为3的金属丝的磁偶极子比相同体积的球体高。α = 5的纳米线的磁偶极子比相同体积的球的磁偶极子大1.95倍。在固定半径下,磁偶极子随药物载体体积的增大而增大。磁瞄准深度是与粒子的向商α有关的重要参数。计算表明,如果使用半径为15nm、长度大于150nm的纳米线作为药物载体,靶向深度可超过8.5 cm。这个深度是先前作者报道的相同体积的球形粒子的1.7倍。
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引用次数: 14
Treatment of Water Effluents Using Silver Nanoparticles 纳米银处理污水的研究
Pub Date : 2018-10-12 DOI: 10.15406/mseij.2018.02.00050
Mamatha Susan Punnoose, B. Mathew
Water pollution is an environmental issue which is gaining global attention in the recent years. The major source of water pollution are the effluents from textile dyeing and finishing industries. Because of drastic changes in customer’s demands, the textile industry is a challenge to use high quantity of dyes and auxiliaries that are necessary for modern textile processing. The used water contains various constituents such as dyes and chemicals which are directly released into the sources of water which gets contaminated and thus resulting in water pollution. The discharge of untreated waste into the water bodies has raised much concern because of potential health hazards associated with the entry of toxic components into the food chains of humans and animals. In our day to day demand for potable water is increasing, which is placing an increasing burden on nature’s availability of water resource, has forced for new and efficient methods for water treatment.
水污染是近年来引起全球关注的环境问题。水污染的主要来源是纺织染整工业的废水。由于客户需求的急剧变化,纺织工业对现代纺织加工所需的大量染料和助剂的使用是一个挑战。用过的水含有各种成分,如染料和化学物质,这些成分直接释放到水源中,被污染,从而导致水污染。向水体排放未经处理的废物引起了极大关注,因为有毒成分进入人类和动物的食物链可能对健康造成危害。在我们的日常生活中,对饮用水的需求正在增加,这对自然界的水资源供应造成了越来越大的负担,迫使人们采用新的和有效的水处理方法。
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引用次数: 7
Using hydrogel-biochar composites for enhanced cadmium removal from aqueous media 使用水凝胶-生物炭复合材料增强水介质中镉的去除
Pub Date : 2018-10-03 DOI: 10.15406/MOJMM.2018.1.00012
Simeng Li, G. Chena
Mining activities and metallurgical processes often introduce considerable amounts of heavy metals to the surrounding environment; especially the nearby water bodies as well as groundwater system.1 High concentrations of most heavy metals are highly toxic to living organisms including humans. Moreover, many heavy metals can accumulate in organisms (i.e., bioaccumulation) and be consumed by other organisms along the food chain.2 among the common heavy metals, cadmium (Cd), which is mostly sourced from zinc refinery, has the highest toxicity to most organisms.3 Inhalation of high levels of Cd in a short period of time can lead to acute flu-like symptoms and lung damages, while long-term exposure to Cd can result in serious kidney, bone and lung diseases.4 In addition, cadmium and its compounds are also known to be carcinogenic.5 Therefore, removing heavy metals, particularly Cd from the contaminated aquatic environment has long been an important challenge.
采矿活动和冶金过程往往向周围环境排放大量重金属;特别是附近的水体以及地下水系统高浓度的重金属对包括人类在内的生物都是剧毒的。此外,许多重金属可以在生物体中积累(即生物积累),并被食物链上的其他生物体消耗。在常见的重金属中,镉(Cd)对大多数生物的毒性最高,主要来自锌精炼厂短时间内吸入高水平的Cd可导致急性流感样症状和肺部损伤,而长期接触Cd可导致严重的肾脏、骨骼和肺部疾病此外,镉及其化合物也被认为具有致癌性因此,从污染的水生环境中去除重金属,特别是镉一直是一个重要的挑战。
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引用次数: 18
Utilization of steel plants waste 钢铁废料的利用
Pub Date : 2018-09-25 DOI: 10.15406/MSEIJ.2018.2.00048
Yakshil B. Chokshi, Neelam Sompura, S. K. Dutta
World produced 1,689 million tonne (Mt) of crude steel in 2017, is increased about 3.8% production with respect to 2016 (1627 Mt). India is a third largest producer of steel in the world which is preceded by China and Japan. Iron and steel industry’s growth in India has been exceptional since last 10 years. India’s crude steel production of year 2017 is 101.4Mt which was 53.5Mt in year of 2007. Correspondingly, the per capita steel consumption in the country was 43kg in the year of 2007 which increased to 65 kg in the year of 2017.1 As per National steel policy 2017 (NSP), estimated domestic steel production of 300Mt will be achieved by 2030–31. Reaching out to this visionary aim, Indian steel plants must have to discontinue outdated technologies, increase their production capacities, uplift the efficiency of operations, implement latest technologies, utilize low–grade raw materials as well as minimize waste generation. Considering all waste materials as an economic asset, Ministry of Steel, Government of India2 will encourage the steel companies to develop a Waste Management Plan for additional impetus on zero–waste or complete waste recycling.
2017年,全球粗钢产量为16.89亿吨,比2016年(16.27亿吨)增加了约3.8%。印度是世界第三大钢铁生产国,排在中国和日本之前。在过去的10年里,印度的钢铁工业一直在飞速发展。2017年印度粗钢产量为1.014亿吨,而2007年为5350万吨。相应地,2007年该国人均钢铁消费量为43公斤,2017年增加到65公斤。根据2017年国家钢铁政策(NSP),预计到2030-31年,国内钢铁产量将达到3亿吨。为了实现这一富有远见的目标,印度钢铁厂必须淘汰过时的技术,提高生产能力,提高运营效率,采用最新技术,利用低品位的原材料,并尽量减少废物的产生。考虑到所有废物都是经济资产,印度政府钢铁部将鼓励钢铁公司制定废物管理计划,以进一步推动零废物或完全废物回收。
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引用次数: 7
The effect of ultrasonic treatment on the microstructure of Sn-58Bi alloy 超声处理对Sn-58Bi合金显微组织的影响
Pub Date : 2018-07-13 DOI: 10.15406/mseij.2018.02.00041
K. J.
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引用次数: 1
Ascorbic acid assisted synthesis, characterization and catalytic application of copper nanoparticles 抗坏血酸辅助铜纳米颗粒的合成、表征及催化应用
Pub Date : 2018-07-11 DOI: 10.15406/MSEIJ.2018.02.00040
Ruby Phul, Chanmeet Kaur, Umer Farooq, Tokeer Ahmad
The fabrication, designing and manipulation of materials within the dimensions of 1–100 nm could be termed as nanomaterials. Nowadays nanomaterials are being used in various fields of physics, chemistry, biology, engineering etc.1,2 The major advantage of nanomaterials is that their properties changes drastically from bulk material of the same composition. The properties of nanoparticles could be easily altered by varying their size, shape, and chemical environment.3 The earth–abundant and inexpensive metal and metal oxide nanomaterials have acquired significant attention of research community due to their potential applications in catalysis,4–6 sensors,7 antimicrobial activity,7–11 contrast agents etc.12 Among the inexpensive metal nanoparticles, copper nanoparticles have attained attentions because of their interesting and high ultraviolet–visible sensitivity, thermal and electrical conductivity, and catalytic properties as compared to metallic gold and silver nanoparticles.
制造、设计和操作尺寸在1-100纳米之间的材料可以被称为纳米材料。目前,纳米材料被广泛应用于物理、化学、生物、工程等各个领域。1,2纳米材料的主要优点是其性质与相同成分的块状材料相比发生了巨大的变化。纳米粒子的性质很容易通过改变它们的大小、形状和化学环境而改变金属和金属氧化物纳米材料储量丰富,价格低廉,因其在催化、4-6传感器、7抗微生物活性、7 - 11造影剂等方面的潜在应用而受到了研究界的广泛关注。在价格低廉的金属纳米颗粒中,铜纳米颗粒因其独特的高紫外-可见灵敏度、导热性和导电性而备受关注。以及与金属金和银纳米粒子相比的催化性能。
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引用次数: 25
期刊
Material Science & Engineering International Journal
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