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Synthesis and Crystallization Kinetics of Y 2CaA1 4SiO 12 Garnet-Type Glass-Ceramic y2caa1 - 4sio12石榴石型玻璃陶瓷的合成及结晶动力学
Pub Date : 2020-06-11 DOI: 10.2139/ssrn.3618732
Liyuan Wang, Jiaxi Liu, N. Lu, Zeng-chao Yang, G. He, Xiaoyu Li, Jianqiang Li, Jiangtao Li
Y2CaA14SiO12 garnet-type glass-ceramic was obtained by heat-treatment of the bulk glass with corresponding composition, which fabricated by aerodynamic levitation coupled with a laser heating system. The crystallization kinetics of the glass was investigated via Differential Scanning Calorimetry (DSC). The effects of heat-treatment temperature on the phase, microstructure, mechanical and optical properties of the Y2CaA14SiO12 garnet-type glass-ceramic were also systemically studied. The crystallization mechanism of this Y2CaA14SiO12 glass is three-dimensional growth followed with surface and inner nucleation. With the increasing of heat-treatment temperature, the density and hardness increased, while transparency declined as a result of rapid grain growth.
采用气动悬浮耦合激光加热系统,对含有相应成分的块状玻璃进行热处理,得到了Y2CaA14SiO12石榴石型玻璃陶瓷。用差示扫描量热法(DSC)研究了玻璃的结晶动力学。系统研究了热处理温度对Y2CaA14SiO12石榴石型微晶玻璃的物相、显微组织、力学性能和光学性能的影响。Y2CaA14SiO12玻璃的结晶机制是三维生长,然后是表面成核和内部成核。随着热处理温度的升高,合金的密度和硬度增加,晶粒生长迅速,透明度下降。
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引用次数: 0
Kinetics of the Surface-Nucleated Transformation of Spherical Particles and New Model for Grain-Boundary Nucleated Transformations 球形颗粒表面成核转变动力学及晶界成核转变新模型
Pub Date : 2020-06-04 DOI: 10.2139/ssrn.3628017
N. V. Alekseechkin
Equations for the transformed volume fraction of a spherical particle with nucleation on its surface, both nonisothermal and isothermal, are derived in the framework of Kolmogorov method adapted for this problem. Characteristic parameters governing the transformation kinetics are determined; the latter is studied with particular emphasis on the Avrami exponent temporal behavior. It is shown that the surface-nucleated transformation qualitatively differs from the bulk-nucleated one at large values of the characteristic parameters due to the one-dimensional radial growth of the new phase occurring after the complete transformation of the surface itself at the early stage of the process. This effect also manifests itself in the considered ensemble of size-distributed particles and in the grain-boundary nucleated transformations. The logarithmic normal distribution inherent for the particles obtained by grinding is employed for numerical calculations and shown to stretch temporally the volume-fraction and Avrami-exponent dependences for the ensemble of identical particles. A new model for grain-boundary nucleated transformations alternative to the Cahn model of random planes is offered; it is based on the ensemble of size-distributed spherical particles with the possibility for a growing nucleus to cross grain boundaries. The kinetics of this process is shown to be governed by the same characteristic parameter, as for a single particle, and qualitatively differs from the Cahn-model one. In particular, the logarithmic volume-fraction plot at large values of the governing parameter ends by a characteristic bend observed on experimental curves for the crystallization of bulk metallic glasses. This peculiarity together with the form of the plot as a whole directly indicates to the grain (polycluster) structure of metallic glasses and nucleation at intercluster boundaries.
在适用于该问题的Kolmogorov方法框架下,推导了非等温和等温表面有成核的球形粒子的转换体积分数方程。确定了控制转化动力学的特征参数;后者的研究特别强调了Avrami指数的时间行为。结果表明,在特征参数较大时,表面成核相变与体形成核相变在性质上存在差异,这是由于在相变的早期,在表面本身完全转变之后出现了一维径向生长的新相。这种效应也表现在粒径分布的粒子系综和晶界成核转变中。数值计算采用研磨获得的颗粒固有的对数正态分布,并显示在时间上拉伸相同颗粒系综的体积分数和avrami指数依赖关系。提出了一种新的晶界成核变换模型,用以替代随机平面的Cahn模型;它是基于大小分布的球形粒子的集合,具有生长的核跨越晶界的可能性。这一过程的动力学与单个粒子的动力学一样,是由相同的特征参数控制的,并且在质量上不同于卡恩模型。特别是,在大块金属玻璃结晶的实验曲线上观察到,在较大的控制参数值处,对数体积分数图以特征弯曲结束。这一特性连同图的整体形式直接表明了金属玻璃的晶粒(多团簇)结构和团簇间边界的成核。
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引用次数: 3
Influence of Hydrogen at the Interface on Tensile Properties of Equiatomic FeCrNiMnCo High-Entropy Alloy 界面处氢对等原子FeCrNiMnCo高熵合金拉伸性能的影响
Pub Date : 2020-06-03 DOI: 10.2139/ssrn.3606820
T. Zhu, Z. Zhong, M. Tokitani, X. Ren, B.Y. Wang, X. Cao, Q. Xu
This study reports the effect of the hydrogen's position in the lattice on the tensile properties of FeCrNiMnCo high-entropy alloy. We reveal that the hydrogen at the interface is the main factor affecting the mechanical properties of the material. We found that hydrogen alloying with a proper concentration makes the alloy resistant to hydrogen embrittlement and improves the strength and ductility of the material. This beneficial effect is positively correlated with the hydrogen concentration at the interface of the alloy, with hydrogen promoting the formation of nanotwins, which are excessively compensatory to the surface cracks introduced by the hydrogen.
本研究报道了氢在晶格中的位置对FeCrNiMnCo高熵合金拉伸性能的影响。结果表明,界面处的氢是影响材料力学性能的主要因素。结果表明,适当浓度的氢合金化可以使合金抗氢脆,提高材料的强度和延展性。这种有利效应与合金界面处的氢浓度呈正相关,氢促进纳米孪晶的形成,而纳米孪晶对氢引入的表面裂纹有过度的补偿作用。
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引用次数: 0
Smart Data Glasses For Multimeter 万用表智能数据眼镜
Pub Date : 2020-05-26 DOI: 10.2139/ssrn.3645375
Anup V. Deshmukh, Akshay Chavan, Rohit Marathe, Prof. Mrs. Pooja Shinde
Smart glasses demonstrated to be one of the advanced processing gadgets that unit the people and machines. As of late, it is seen that smart glasses have been utilized in the medical and gaming applications. Nonetheless, the highlights of smart glasses can contribute to its administrations in different fields as well. In this paper, a study is carried out to investigate the conceivable use of smart glasses in estimating readings inside a live electrical board, the thing that is inconvenient, and even risky on occasion, is turning away from your hands to peruse your multimeter. Since estimating high AC voltage utilizing conventional digital multimeter is very dangerous as it could prompt genuine mishaps. This paper represents a wearable wireless device so that the user can see readings and this wearable device is the smart glasses. While utilizing these glasses users don’t need to take a gander at DMM show since readings will be shown on smart glasses. Here we have utilized the LiPo battery for power supply to microcontroller. OLED show is utilized for showing the voltage value we estimated. This OLED show is interfaced to the controller utilizing SPI. With the assistance of Bluetooth, we have made this glass wireless so the measured voltage will show up on OLED display.
智能眼镜被证明是将人和机器结合在一起的先进处理设备之一。最近,智能眼镜已经被用于医疗和游戏应用。尽管如此,智能眼镜的亮点也可以为它在不同领域的管理做出贡献。在本文中,进行了一项研究,以调查智能眼镜在估计带电电路板内读数时的可能用途,这是不方便的,有时甚至有风险的事情,就是离开你的手去仔细阅读你的万用表。由于使用传统的数字万用表估计高交流电压是非常危险的,因为它可能会引发真正的事故。本文提出了一种可以让用户看到读数的可穿戴无线设备,这种可穿戴设备就是智能眼镜。在使用这些眼镜时,用户不需要看DMM显示,因为读数将显示在智能眼镜上。在这里,我们利用LiPo电池为微控制器供电。OLED显示器用于显示我们估计的电压值。该OLED显示器利用SPI与控制器接口。在蓝牙的帮助下,我们使这种玻璃无线化,因此测量的电压将显示在OLED显示屏上。
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引用次数: 0
Analysis of the Reaction Runaway in Al/Ni Multilayers with Combined Nanocalorimetry and Time-Resolved X-Ray Diffraction 纳米量热法和时间分辨x射线衍射联合分析Al/Ni多层膜反应失控
Pub Date : 2020-05-22 DOI: 10.2139/ssrn.3581342
T. Neuhauser, G. Tinti, H. Leiste, Nicola Casati, Michael Stüber, K. Woll
Abstract Self-sustaining runaway reactions in reactive multilayers exhibit heat-up with over 106 K/s to temperatures of higher than 1000 °C, which defines unprecedented kinetic regimes for metallurgical phase transformations. The latter allows for developing alternative concepts for microstructure design. In order to explore the phase transformations in these kinetic regimes, we combine nanocalorimetry with time-resolved synchrotron X-ray diffraction. Nanocalorimetry allows us to perform thermal analysis of ignition as well as the reaction runaway and to develop necessary and mandatory quantitative criterions for ignition. In order to trace the temporal phase evolution, we use time-resolved synchrotron X-ray diffraction. We heat the Al/Ni multilayers with 5000 K/s and find that Ni starts to diffuse into the Al layer at 271 °C. Ignition occurs, dependent on the bilayer thickness, at about 400 °C in the solid state and atomic diffusion is revealed as the dominating mechanism. During the runaway, samples heat up in four stages with maximal 106 K/s to 1100 °C. Ni2Al3 is the first phase to form which starts to nucleate once Al melts. The majority of the intermetallic phase grows after the runaway reaction in the fourth stage and reaches its maximum during cooling. This trend of the temporal phase evolution eventually enables us to propose a mechanism exhibiting conceptual similarities with the exothermic dissolution mechanism recently suggested for self-sustaining reaction fronts in Al/Ni multilayers.
反应性多层膜中的自维持失控反应表现出超过106 K/s的升温到高于1000°C的温度,这定义了冶金相变的前所未有的动力学机制。后者允许开发微观结构设计的替代概念。为了探索这些动力学体系中的相变,我们将纳米量热法与时间分辨同步加速器x射线衍射相结合。纳米量热法使我们能够进行点火和反应失控的热分析,并制定必要的和强制性的点火定量标准。为了跟踪时间相演化,我们使用了时间分辨同步加速器x射线衍射。对Al/Ni多层膜进行5000 K/s加热,发现Ni在271℃时开始向Al层扩散。在400℃左右的固体状态下,随双层膜厚度的不同而发生点火,原子扩散是主要的机制。在失控过程中,样品以最高106 K/s的速度加热到1100℃,分为四个阶段。Ni2Al3是第一个形成的相,在Al熔化后开始成核。大部分金属间相在第四阶段失控反应后生长,并在冷却时达到最大值。这种时间相演变的趋势最终使我们能够提出一种机制,与最近提出的Al/Ni多层膜中自维持反应前沿的放热溶解机制具有概念上的相似性。
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引用次数: 6
Synthesis and Characterization of Optically Transparent Ceramic Crystalline/Amorphous and Amorphous/Amorphous Multilayers 光学透明陶瓷晶体/非晶和非晶/非晶多层膜的合成与表征
Pub Date : 2020-05-21 DOI: 10.2139/ssrn.3603425
Chelsea D. Appleget, A. Hodge
Abstract Optical nano multilayers (NMs) are promising candidates for durable transparent multifunctional coatings, where the contributions of interfaces and high transparency configurations have yet to be explored. To address this, high transparency NMs (%T380-1100nm≈94–99%) were synthesized by magnetron sputtering, and the effects of crystalline/amorphous (AlN/SiO2, AlN/Al2O3) and amorphous/amorphous (TiO2/SiO2) interfaces were characterized by spectrophotometry, transmission electron microscopy, and nanoindentation. We demonstrate that tuning layer configurations for improved transmittance resulted in substantial variations in microstructure and multifunctional film properties. Overall, this work presents a methodology for evaluating the structure-properties relationship in optical NMs in the context of interface character and layer microstructure.
摘要光学纳米多层膜(NMs)是耐用透明多功能涂层的有希望的候选者,其中界面和高透明度配置的贡献尚未被探索。为了解决这一问题,采用磁控溅射法制备了高透明度纳米材料(%T380-1100nm≈94-99%),并通过分光光度法、透射电镜和纳米压痕等方法表征了晶体/非晶态(AlN/SiO2、AlN/Al2O3)和非晶态/非晶态(TiO2/SiO2)界面的影响。我们证明了为提高透光率而调整层的结构会导致微观结构和多功能薄膜性能的实质性变化。总的来说,本工作提出了一种在界面特征和层微观结构背景下评估光学NMs结构-性质关系的方法。
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引用次数: 4
Inoculation Treatment of an Additively Manufactured 2024 Aluminium Alloy with Titanium Nanoparticles 纳米钛孕育处理增材制备2024铝合金
Pub Date : 2020-05-18 DOI: 10.2139/ssrn.3592041
Qiyang Tan, Jingqi Zhang, Qiang Sun, Z. Fan, Gan Li, Yu Yin, Yingang Liu, Mingxing Zhang
Abstract Considerable studies on metal selective laser melting (SLM) have proved the necessity to refine microstructure parts fabricated by SLM in order to eliminate property anisotropy, hot-tearing and to increase the SLM-processability. In the present work, Ti nanoparticles, at the first time, were discovered to be an extremely effective inoculant for an SLMed 2024 aluminium alloy. 0.7 wt% addition of Ti nanoparticles was capable of substantially eliminating the hot-tearing cracks and columnar structure, and refining the grains in the SLMed 2024 alloy in a broad processing window. The substantial grain refinement in the Ti-inoculated 2024 alloy was attributed to the in-situ formation of Al3Ti nanoparticles with a L12 ordered structure, which formed a coherent interface with Al matrix and therefore significantly promoted the heterogeneous nucleation of the α-Al during solidification of melt pools in the SLM process. After a conventional T6 heat treatment, this SLMed alloy exhibited a superior balance of strength and ductility (tensile strength was up to 432 ± 20 MPa and elongation of 10 ± 0.8%), which was comparable to its wrought counterpart. This work can be considered as a breakthrough in research of fabricating high-strength aluminium alloys using SLM.
对金属选择性激光熔化(SLM)的大量研究表明,为了消除性能各向异性、热撕裂和提高SLM加工性能,有必要对SLM制造的微结构零件进行细化。在本研究中,Ti纳米颗粒首次被发现是一种非常有效的SLMed 2024铝合金孕育剂。掺量为0.7 wt%的Ti纳米颗粒能够在较宽的加工窗口内消除SLMed 2024合金的热撕裂裂纹和柱状组织,细化晶粒。在SLM过程中,原位形成了具有L12有序结构的Al3Ti纳米颗粒,与Al基体形成共格界面,从而显著促进了α-Al在熔池凝固过程中的非均相形核。经过常规的T6热处理后,该SLMed合金表现出良好的强度和延展性平衡(抗拉强度高达432±20 MPa,伸长率为10±0.8%),与变形后的合金相当。这一研究成果是利用SLM制备高强度铝合金研究的一个突破。
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引用次数: 186
In Situ Microstructural Evolution in Fcc and Bcc Complex Concentrated Solid-Solution Alloys Under Heavy Ion Irradiation Fcc和Bcc复合浓固溶合金在重离子辐照下的原位组织演变
Pub Date : 2020-05-18 DOI: 10.2139/ssrn.3591845
C. Parkin, M. Moorehead, M. Elbakhshwan, A. Couet, K. Sridharan, Wei-Ying Chen, Meimei Li, Lingfeng He
This study characterizes the microstructural evolution of single-phase complex concentrated solid-solution alloy (CSA) compositions under heavy ion irradiation with the goal of evaluating mechanisms for CSA radiation tolerance in advanced fission systems. Three such alloys, Cr18Fe27Mn27Ni28, Cr15Fe35Mn15Ni35, and equimolar NbTaTiV, along with reference materials (pure Ni and E90 for the CrFeMnNi family and pure V for NbTaTiV) were irradiated at 50 K and 773 K with 1 MeV Kr++ ions to various levels of dpa using in-situ TEM. Cryogenic irradiation resulted in small defect clusters and faulted dislocation loops as large as 12 nm in FCC CSAs. With thermal diffusion suppressed at cryogenic temperatures, defect densities were lower in all CSAs than in their less compositionally complex reference materials indicating that point defect accumulation is reduced during the displacement cascade stage. High temperature irradiation of the two FCC CSA resulted in the formation of interstitial dislocation loops which by 2 dpa grew to an average size of 27 nm in Cr18Fe27Mn27Ni28 and 10 nm in Cr15Fe35Mn15Ni35. This difference in loop growth kinetics was attributed to the difference in Mn-content due to its effect on the nucleation rate by increasing vacancy mobility or reducing the stacking-fault energy.
本文研究了重离子辐照下单相络合浓固溶合金(CSA)组成的微观组织演变,目的是评估先进裂变系统中CSA辐射耐受机制。利用原位透射电镜,在50 K和773 K温度下,用1mev的氪离子将三种合金Cr18Fe27Mn27Ni28、Cr15Fe35Mn15Ni35和等摩尔NbTaTiV以及纯Ni和E90 (CrFeMnNi族)和纯V (NbTaTiV族)辐照至不同的dpa水平。低温辐照在FCC csa中形成了小的缺陷团簇和大12 nm的错位环。由于低温条件下的热扩散受到抑制,所有csa中的缺陷密度都低于其成分不那么复杂的对照材料,这表明在位移级联阶段,点缺陷积累减少了。两种FCC CSA在高温下形成间隙位错环,经过2 dpa的辐照后,Cr18Fe27Mn27Ni28和Cr15Fe35Mn15Ni35的平均尺寸分别达到27 nm和10 nm。这种环生长动力学的差异归因于mn含量的差异,mn含量通过增加空位迁移率或降低堆叠断层能来影响成核速率。
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引用次数: 0
Wind Turbine Power Curve Modelling using Robust Regression Techniques 基于鲁棒回归技术的风力发电功率曲线建模
Pub Date : 2020-05-09 DOI: 10.2139/ssrn.3597161
Neel Pandey
The need of accurate wind turbine power curve modelling is essential as it provides great insight on the performance of the power system and ideal estimate of generation of power by turbines. However, presence of non linear relationship between output power of turbine and its primary and secondary parameters imposes restrictions to predict exact power generated. In this work wind power curve modelling is accomplished using different robust linear techniques that reduces the effects of outliers and provides precise results in terms of power generation. Mean Absolute Error(MAE), Root Mean Square Error(RMSE), and R^2 score were used as a measure of approximation method accuracy. Since above metrics doesn't provide any information about fitted model insights like overfiiting and underfitting, so bias and variance are considered as the two important aspects that clearly assesses model complexity. By decomposing the MSE into bias and variance a clear insight about model structure is obtained with a potential way with regard to which error component is likely to contribute more degradation of model performance.
准确的风力发电机功率曲线建模是必不可少的,因为它提供了对电力系统性能的深入了解和对涡轮机发电的理想估计。然而,水轮机的输出功率与一次、二次参数之间存在非线性关系,这对准确预测发电功率造成了限制。在这项工作中,风电曲线建模使用了不同的鲁棒线性技术,减少了异常值的影响,并提供了发电方面的精确结果。使用平均绝对误差(MAE)、均方根误差(RMSE)和R^2评分来衡量近似方法的准确性。由于上述指标没有提供任何关于拟合模型洞察力的信息,如过拟合和欠拟合,因此偏差和方差被认为是清楚评估模型复杂性的两个重要方面。通过将MSE分解为偏差和方差,可以通过一种潜在的方法清楚地了解模型结构,从而了解哪些误差成分可能会导致模型性能的更大退化。
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引用次数: 0
Detecting Features via Modified Harris Corners and Matching Them through SIFT 利用改进的哈里斯角检测特征并进行SIFT匹配
Pub Date : 2020-05-02 DOI: 10.2139/ssrn.3619887
Jimut Bahan Pal
Interpreting images spatially is a daunting task which is achieved by detecting corners and features.The most important task of detecting features is achieved by Harris Corner Algorithm. The algorithmis not robust to different scale of the same image. The algorithm may detect corner but when theimage is zoomed in, the corner may appear as ridges. We use the corners detected from HarrisCorner algorithm and treat these as key points to pass into Scale Invariant Feature Transform (SIFT)algorithm. The SIFT algorithm extracts descriptor vector of dimension 128 X 1 from these cornersand can be used to find similarity between different images. This process is quite robust to noise,intensity, scale and occlusion and is used for matching images from a database of descriptors. Wehave investigated both the algorithms in this paper and made a modified version of Harris Corneralgorithm by performing different kind of thresholding, both of them gave a little different result.
图像的空间解释是一项艰巨的任务,它通过检测角点和特征来实现。最重要的特征检测任务是由Harris Corner算法完成的。该算法对同一幅图像的不同尺度具有较差的鲁棒性。该算法可以检测到角落,但当图像放大时,角落可能会出现山脊。我们利用HarrisCorner算法检测到的角点作为关键点,传递到尺度不变特征变换(SIFT)算法中。SIFT算法从这些角提取维度为128 X 1的描述子向量,用于寻找不同图像之间的相似性。这个过程对噪声、强度、尺度和遮挡都有很强的鲁棒性,并用于从描述符数据库中匹配图像。本文对这两种算法进行了研究,并通过不同的阈值分割方法对Harris corner算法进行了改进,两者的结果略有不同。
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引用次数: 0
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MatSciRN: Process & Device Modeling (Topic)
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