Materials最新文献

Concrete 3D printing (3DCP) combines materials science with material processing technologies to enable automated, additive construction. This review summarizes findings from the literature and industrial practice on 3DCP mortar formulation with emphasis on the material processing chain. The workflow is examined from raw material storage through handling, mixing, and deposition. The roles of binders, aggregates, dispersed reinforcement, and chemical admixtures are discussed in relation to rheological behavior, buildability, and early-age mechanical performance. The analysis covers storage, dosing, and mixing strategies with respect to mix consistency and overall process reliability, while mortar pumping and extrusion are addressed alongside nozzle-injected additives and automation. Finally, limitations and scalability challenges are outlined with research directions such as continuous mixing, in-line monitoring, and adaptive mix formulation for on-site applications.

Amid growing environmental concerns, resource depletion, and the pressing challenges of industrial waste management, this study investigates the potential of magnesium slag (MS) as a sustainable alternative binder in the production of one-part geopolymer concretes (OPGCs). The objective is to reduce reliance on conventional cementitious materials while promoting the valorization of industrial by-products in construction practices. For this purpose, ten different mixtures were designed by replacing ground granulated blast furnace slag (GGBS), the conventional aluminosilicate precursor, with MS, an innovative aluminosilicate precursor, at replacement levels of 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90%, and 100% by weight, using a solid activator. The fresh and hardened properties of these mixtures were systematically evaluated through slump, setting time, density, ultrasonic pulse velocity (UPV), and strength tests, while microstructural characterization was also conducted using scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDX) to further investigate the geopolymerization process, elemental distribution, and the role of MS in binder formation in OPGC. The results revealed that MS incorporation significantly influenced both workability and mechanical performance, and it was confirmed that MS actively participates in geopolymerization and can be effectively utilized up to a certain threshold. Replacement levels up to 30% were found to maintain acceptable mechanical performance, providing evidence that MS is a promising precursor for developing sustainable OPGC.

Owing to certain inherent deficiencies in their properties, fine reclaimed asphalt pavement (RAP) particles have not yet been widely reused worldwide, resulting in significant environmental pollution and economic waste. Currently, a diverse array of design methods for asphalt mixes has been proposed. These methods can exert a varying influence on the degree of blending (DoB) and the performance of recycled hot-mix asphalt containing fine RAP particles, and some methods may be better suited for recycling fine RAP particles. However, the specific effects and differences among these various methods have yet to be fully revealed. Therefore, this research comprehensively explored these behaviors. Four distinct mix design formulations were investigated: the dense-graded Asphalt Concrete Group (Group AC), the Stone Mastic Asphalt Group (Group SMA), the High-modulus Asphalt Concrete Group (Group HMAC), and the rejuvenator-modified Asphalt Concrete Group (Group AC+Re). It can be found that the DoB and performance varied across different groups. The DoB spanned from 69% to 82%, with Group SMA showing the highest and Group HMAC exhibiting the lowest. The tensile strength ratio (TSR) of Group AC performed only 73.7%, failing to meet the specification threshold; nevertheless, this shortfall can be compensated by employing alternative methods or adding rejuvenator. Group HMAC exhibited the highest splitting-tensile strength and fracture energy. In addition, the incorporation of rejuvenator can enhance most performance of mixes. Some findings may provide a new perspective for the application of fine RAP particles.

Transcutaneous electrical nerve stimulation techniques (TENS) are rapidly gaining attention for their potential in various clinical applications. One such technique is transcutaneous auricular vagus nerve stimulation (taVNS), and it involves delivering nerve stimulation through the skin of the external ear. However, taVNS relies on electrodes that must conform to the complex anatomy of the ear while maintaining stable electrical performance. Conventional taVNS electrodes, typically rigid metal or adhesive pads, are uncomfortable, difficult to position, prone to drying, and costly to produce. Here, we present and evaluate two complementary fabrication approaches for soft dry electrodes suitable for taVNS, which are compliant with curved anatomical features and can be operated without gel. The first employs wet spinning of a conductive elastomer into fibers, while the second extends this method to create hollow cylindrical geometries. The resulting spongy polymer composite electrodes exhibit tunable geometry, high conductivity, mechanical resilience under strain and compression, and low material impedance confirmed through bench and human testing, even under dry conditions. These properties are critical for in-ear and broader transcutaneous stimulation applications, highlighting the potential of these fabrication methods for next-generation soft bioelectronic interfaces.

This paper investigates the tensile behavior of cotton ring-spun yarn through experimental testing, numerical simulation, and theoretical calculation. Firstly, scanning electron microscope testing of the microscopic geometric morphologies of yarns was performed for the development of basic finite element (FE) models. Then, the influences of tensile speed and yarn length on the tensile properties of yarn were studied using tensile experiments. Numerical simulations were further performed to investigate the effects of yarn diameter, twist angle, and friction between fibers on the tensile modulus of yarn. Finally, a modified 'rule-of-mixtures' equation was proposed to effectively calculate the tensile modulus of yarn through incorporating the friction correction factor. The experimental results show that the tensile modulus and strength of tested yarn are significantly affected by the yarn structure and are not sensitive to the yarn length and tensile speed. Furthermore, the tensile moduli of yarns obtained from the numerical simulations show a good fitting accuracy with those obtained from experimental tests when the friction coefficient is set to 0.5 in the FE models. The simulation results show that the twist angle and friction coefficient are two key factors affecting the tensile modulus of yarn. The modified 'rule-of-mixtures' equation presents better accuracy for the calculation of the tensile modulus of yarn compared with the traditional 'rule-of-mixtures' equation, which can be used to replace the FE modeling and simulation and reduce the computational cost. This work will provide a deeper understanding of the mechanical properties of cotton ring-spun yarns and enhance their application in the textile industry.

This work aims to enhance the stability of the Mg/Al₃Y interface through first-principles investigations of low-cost dopants. Density functional theory calculations were employed to systematically examine the bulk properties of Mg and Al₃Y, as well as the structural stability, electronic characteristics, and alloying element effects at the Mg(0001)/Al₃Y(0001) interface. The calculated lattice parameters, elastic moduli, and phonon spectra demonstrate that both Mg and Al₃Y are dynamically stable. Owing to the similar hexagonal symmetry and a small lattice mismatch (~1.27%), a low-strain semi-coherent Mg(0001)/(2 × 2)Al₃Y(0001) interface can be constructed. Three representative interfacial stacking configurations (OT, MT, and HCP) were examined, among which the MT configuration exhibits significantly higher work of adhesion, indicating superior interfacial stability. Differential charge density and density of states analyses reveal pronounced charge transfer from Mg to Al/Y atoms and strong orbital hybridization, particularly involving Y-d states, which underpins the enhanced interfacial bonding. Furthermore, the segregation behavior and adhesion enhancement effects of typical alloying elements (Si, Ca, Ti, Mn, Cu, Zn, Zr, and Sn) were systematically evaluated. The results show that Mg-side interfacial sites, especially Mg₂ and Mg₃, are thermodynamically favored for segregation, with Zr and Ti exhibiting the strongest segregation tendency and the most significant improvement in interfacial adhesion. These findings provide fundamental insights into interfacial strengthening mechanisms and offer guidance for the alloy design of high-performance Mg-based composites.

A carbon-modified attapulgite composite (C-AATP@CTAB) was synthesized via the hydrothermal method using citric acid as the carbon source and cetyltrimethylammonium bromide (CTAB) as a surface modifier for efficient rhodamine B (Rh-B) removal. Carbon modification elevated the composite's specific surface area (212 m²/g) and negative surface charge (-38.21 mV), significantly enhancing dye adsorption capacity to 666.66 mg/g-nearly double that of unmodified ATP variants (360.4-386.8 mg/g). Kinetic studies confirmed pseudo-second-order adsorption kinetics, attributed to hydrogen bonding and van der Waals interactions between Rh-B and the composite. Under photo-Fenton conditions, C-AATP@CTAB achieved 99.8% Rh-B degradation within 20 min, demonstrating superior catalytic performance in heterogeneous Fenton/photo-Fenton systems. This work establishes a low-cost, high-efficiency adsorbent-catalyst hybrid derived from low-grade attapulgite, offering promising avenues for sustainable wastewater treatment.

Sandwich panels with trapezoidal (corrugated) cores combine low weight, high specific stiffness, and energy absorption capability. This study analyzes four configurations with different core heights by means of microstructural analyses (optical microscopy, SEM/EDS, XRD) and quasi-static compression tests. The tests yield stress-strain curves with an initial linear stage, a peak, a plateau, and a densification stage. Peak stresses range from 0.5 MPa for the thickest core (P1) to 6.2 MPa for the thinnest core (P4), while the energy absorbed density (EAD) increases with strain: at ε = 30% it varies from 0.031 to 0.670 J/cm³, and at ε = 50% the thin-core configuration reaches ≈1.113 J/cm³. The face sheets and the core are both manufactured from AA 3000 series (Al-Mn) aluminum alloy; widespread micro-porosity and Fe/Mn-rich phases are observed by SEM/EDS. XRD confirms aluminum with different peak intensities ascribable to the manufacturing texture. Increasing the core height promotes earlier local/global instabilities and reduces the peak stress; the thinnest core displays higher stiffness and peak loads. These findings support the use of trapezoidal corrugation where low weight and progressive strain are required.

In metal band sawing, higher cutting speeds increase frictional heat at sliding guide blocks. Recirculating water-miscible metalworking fluids (MWFs) often lack fine filtration and accumulate debris that can enter the guide-band interface. A 1 L coolant sample collected after 22.5 m² of cutting contained a particle load of 0.438 g/L; optical sizing yielded a number-median maximum Feret diameter of 345 µm, with particles up to 1.5 mm. Compared with typical guide clearances (~0.1 mm), these sizes imply frequent ingress/bridging and three-body interactions. The coolant viscosity follows an Andrade relation and decreases by ~2% K^-1 around 40 °C. HFRR tribometry indicates low steady-state friction (µ ≈ 0.12), comparable to cutting oil. Together, these results provide quantitative design inputs for next-generation guide clearances and targeted filtration/coolant-delivery concepts in high-speed band sawing.

Tetra-missing rib honeycombs (TMRHs), characterized by monoclinic geometry, exhibit high elastic stiffness but suffer from poor deformation stability and reduced axial load-bearing capacity, which limit their applicability in energy-absorbing and load-sensitive engineering structures. To address these inherent drawbacks, this study proposes two symmetry-enhanced tetra-missing rib honeycomb configurations through overall axisymmetric design and subunit-level symmetric optimization. A finite element model was established in Abaqus/Explicit and validated against quasi-static compression experiments, demonstrating good agreement in deformation modes and mechanical responses. Systematic numerical investigations were then conducted to compare the mechanical properties and deformation behaviors of three honeycomb layouts, including the conventional TMRH and the proposed symmetric designs. Furthermore, the effects of impact velocity on mechanical performance were examined to evaluate the dynamic response characteristics of the structures. Finally, the influence of subunit angle parameters on the stiffness, energy absorption, and deformation stability of the tetra-missing rib honeycombs was comprehensively analyzed. The results provide insight into the role of symmetry and geometric parameters in improving the mechanical performance of TMRH-based structures and offer guidance for the design of high-performance auxetic honeycombs.