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The influence of viscosity buildup on the foaming dynamics of rigid polyurethane foams 粘度积累对硬质聚氨酯泡沫发泡动力学的影响
IF 3 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-19 DOI: 10.1002/app.56302
Paula Cimavilla-Román, Pablo Álvarez-Zapatero, Suset Barroso-Solares, Anja Vananroye, Paula Moldenaers, Miguel Ángel Rodriguez-Pérez
The viscoelastic properties development during the reactive foaming of four standard polyurethane formulations was monitored using a flooded parallel plate rheometer. The measurements in situ demonstrated how foams of low catalyst content took longer than 10 min to increase their viscosity from 1 to 103 Pa s, while foams with higher catalysts reached this modulus in less than 4 min. This polymerization speed deeply impacted the evolution of the cellular structure during foaming, which was demonstrated through in situ x-ray imaging and computer simulation. Foams with high catalyst stabilized in their final cell size in 4–5 min, concurring with the stage of largest viscosity buildup. In contrast, the foams of low catalyst content underwent strong degeneration as a result of the slow gelification and stiffening of the matrix. Simulation results also revealed that stabilization of the cellular structure happens faster when the catalyst and blowing agent contents are increased.
使用浸没式平行板流变仪监测了四种标准聚氨酯配方在反应发泡过程中粘弹性能的变化。现场测量结果表明,催化剂含量低的泡沫需要 10 分钟以上的时间才能将粘度从 1 Pa s 提高到 103 Pa s,而催化剂含量高的泡沫在不到 4 分钟的时间内就能达到这一模量。这种聚合速度对发泡过程中蜂窝结构的演变产生了深刻影响,这一点已通过现场 X 射线成像和计算机模拟得到证实。使用高催化剂的泡沫在 4-5 分钟内就稳定了最终的细胞大小,这与粘度积累最大的阶段相吻合。相反,催化剂含量低的泡沫则由于基质凝胶化和硬化缓慢而发生强烈退化。模拟结果还显示,当催化剂和发泡剂含量增加时,蜂窝结构的稳定速度更快。
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引用次数: 0
Incorporations of 2,2′-benzidinedisulfonic acid and forward osmotic extraction-favored nanoparticles in polyethersulfone nanofiltration membrane for the simultaneous enhancements in nitrate rejection and water permeation 在聚醚砜纳滤膜中加入 2,2′-苯二磺酸和有利于正向渗透萃取的纳米颗粒,同时提高硝酸盐去除率和透水性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-19 DOI: 10.1002/app.56296
Zeya Li, Mingyu Zhai, Xin Wu, Zeying Chen, Lifen Liang, Xiuli Wang, Laizhou Song

The nanofiltration (NF) membrane has not been extensively competent for rejection of monovalent ions (such as Cl and NO3), and the strategy for enhancing monovalent ion rejection and permeation flux still faces a significant challenge. Herein, based on our previous polyethersulfone (PES)-type NF membrane (NF-0), two novel NF membranes were fabricated with additional incorporations of 2,2′-benzidinedisulfonic acid (BDSA) and forward osmotic extraction solution-functioned nanoparticles (MNPs) to remove nitrate from the aqueous solution. The fabricated NF-BDSA membrane with introduction of BDSA in ultrathin layer displays a significant nitrate rejection of 92.2% and an acceptable permeation flux of 21 L m−1 h−1 at 0.6 MPa. As anticipated, the obtained NF-MNPs1.0 membrane with additional incorporation of MNPs (1.0 wt% addition) in the substrate layer of NF-BDSA membrane achieves further improvements in nitrate rejection (95%) and water permeability (32.3 L m−1 h−1); encouragingly, this membrane exhibits comparable monovalent ion rejection and permeation flux to reverse osmosis membrane under relatively low pressure. Compared with those of NF-0 membrane, the permeation flux and nitrate rejection of NF-MNPs1.0 membrane increase by 111.1% and 6.1%, respectively. Moreover, the superior performances of endurance, antifouling and chlorine resistance of NF-MNPs1.0 membrane demonstrate its expectable perspective of potential engineering applications.

纳滤膜尚未广泛用于排斥单价离子(如 Cl- 和 NO3-),提高单价离子排斥和渗透通量的策略仍面临重大挑战。在此,我们在之前的聚醚砜(PES)型无负压膜(NF-0)的基础上,制作了两种新型无负压膜,并在其中添加了 2,2′-苯二磺酸(BDSA)和正向渗透萃取液功能纳米粒子(MNPs),以去除水溶液中的硝酸盐。在超薄层中引入 BDSA 的 NF-BDSA 膜的硝酸盐去除率高达 92.2%,在 0.6 兆帕的压力下,渗透通量为 21 L m-1 h-1。正如预期的那样,在 NF-BDSA 膜的基质层中额外加入 MNPs(添加量为 1.0 wt%)后得到的 NF-MNPs1.0 膜进一步提高了硝酸盐去除率(95%)和透水性(32.3 L m-1 h-1);令人鼓舞的是,这种膜在相对较低的压力下表现出与反渗透膜相当的单价离子去除率和渗透通量。与 NF-0 膜相比,NF-MNPs1.0 膜的渗透通量和硝酸盐去除率分别提高了 111.1%和 6.1%。此外,NF-MNPs1.0 膜在耐久性、防污性和耐氯性方面的优异表现也表明其潜在的工程应用前景值得期待。
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引用次数: 0
Synthesis and characterization of epoxy resin-polydicyclopentadiene interpenetrating polymer networks by UV-initiated simultaneously frontal polymerization 通过紫外线引发的同时正面聚合法合成环氧树脂-聚二环戊二烯互穿聚合物网络并确定其特性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-19 DOI: 10.1002/app.56268
Zhenjie Yuan, Siqi Huang, Wenduo Chen, Dazhi Jiang

By combination of UV curing and frontal polymerization, interpenetrating polymer networks (IPNs) based on diglycidyl ether of bisphenol-A (DGEBA) epoxy resin and polydicyclopentadiene (PDCPD) were prepared by UV-induced simultaneously frontal polymerization in this paper. Compared with the net DGEBA cured polymer, the tensile strength, elongation at break and impact strength of the IPNs were simultaneously improved. The maximum tensile strength and elongation at break of the IPNs reached 100 MPa and 4.64%, respectively, and the maximum impact strength reached 7.34KJ/m2 with an improvement of 115.2% over that of the net DGEBA cured polymer. Thermogravimetric analysis (TGA) results revealed that the IPNs could enhance the thermal stability. Data of the differential scanning calorimetry (DSC) and TGA testing shows that the IPN shows a single glass transition temperature (Tg) which is between the Tg of DGEBA and DCPD, indicating homogeneous phase and highly cross-linked IPN formed. Morphologies and molecular structure of the IPNs polymer were observed by scanning electron microscope (SEM) and characterized by Fourier transform infrared spectroscopy (FTIR), respectively, whose results also proved the formation of ideal IPNs structures.

通过紫外固化和正面聚合相结合的方法,本文利用紫外同时正面聚合法制备了基于双酚 A 的二缩水甘油醚(DGEBA)环氧树脂和聚双环戊二烯(PDCPD)的互穿聚合物网络(IPNs)。与净 DGEBA 固化聚合物相比,IPNs 的拉伸强度、断裂伸长率和冲击强度同时得到提高。IPNs 的最大拉伸强度和断裂伸长率分别达到了 100 MPa 和 4.64%,最大冲击强度达到了 7.34KJ/m2,比净 DGEBA 固化聚合物提高了 115.2%。热重分析(TGA)结果表明,IPNs 可以提高热稳定性。差示扫描量热法(DSC)和热重分析(TGA)测试的数据显示,IPN 显示出单一的玻璃化转变温度(Tg),介于 DGEBA 和 DCPD 的 Tg 之间,表明形成了均相和高度交联的 IPN。扫描电子显微镜(SEM)和傅立叶变换红外光谱(FTIR)分别观察了 IPN 聚合物的形态和分子结构,其结果也证明形成了理想的 IPN 结构。
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引用次数: 0
Recyclability of take-back glass fiber-reinforced blends of polyphenylene oxide with high-impact polystyrene for high-performance engineering applications 用于高性能工程应用的玻璃纤维增强型聚苯氧化物与高抗冲聚苯乙烯混合物的可回收性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-19 DOI: 10.1002/app.56294
Kyriaki Gkaliou, Tanmay Mogre, Michael Lei, Anders E. Daugaard

Increased recycling of plastics is an essential step toward a more sustainable use of materials, where some of the most challenging fractions are engineering materials and composites. Used pump houses prepared from glass fiber (GF)-reinforced blends of polyphenylene oxide (PPO) and high-impact polystyrene (HIPS) obtained through a take-back scheme (take-back, TB) were characterized and shredded for use in the preparation of new composites by injection molding. Initial degradation was observed on the surface of the TB parts; however, the core of the material was unaffected. Mechanical reprocessing of regrind and virgin material showed a reduction of tensile strength already at 10% regrind, which was attributed to fiber length reduction during reprocessing. At the same time, Young's modulus and extension at break were largely unaffected, confirming that 25% of TB could be included without any additional loss of properties. As a worst-case scenario, tests with extensively degraded material showed that Young's modulus and tensile strength would ultimately be reduced with an increasing amount of heavily degraded material and that a balance would have to be found between loss of properties and recycled content for heavily degraded material.

加强塑料的回收利用是实现材料的可持续利用的重要一步,其中最具挑战性的部分是工程材料和复合材料。我们对通过回收计划(回收,TB)获得的由玻璃纤维(GF)增强的聚苯氧化物(PPO)和高抗冲聚苯乙烯(HIPS)混合物制备的废旧泵房进行了表征,并将其粉碎,用于通过注塑成型制备新的复合材料。在 TB 部件的表面观察到了初步降解现象,但材料的核心部分未受影响。对再研磨材料和原始材料进行机械再加工的结果表明,再研磨材料的拉伸强度降低了 10%,这归因于再加工过程中纤维长度的减少。与此同时,杨氏模量和断裂伸长率基本不受影响,这证明可以加入 25% 的 TB 而不会造成任何额外的性能损失。在最坏的情况下,对大量降解材料进行的测试表明,杨氏模量和拉伸强度最终会随着大量降解材料的增加而降低,因此必须在性能损失和大量降解材料的回收成分之间找到平衡。
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引用次数: 0
Preparation and study on electrical/thermal properties of epoxy/polyacrylate rubber composite dielectric 环氧树脂/聚丙烯酸酯橡胶复合电介质的制备及其电热性能研究
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-19 DOI: 10.1002/app.56289
Wenchao Zhang, Ming Wen, Qingguo Chen, Dong Yue, Yu Feng

With the development of power systems and electronic devices, epoxy resin (EP) is facing increasingly severe operating environments, and its performance may not meet expectations. In order to broaden the application of EP, the DE/EP composite films were prepared with EP as matrix, polyacrylic rubber dielectric elastomer (DE) as reinforcement materials. The structure of DE/EP composite films was characterized by XRD, SEM, and other methods, and the electrical and thermal properties of the materials were tested and studied. The study found that with appropriate dissolution and stirring treatment, DE can be evenly dispersed in the EP matrix, and the introduction of DE does not significantly affect the structure of the EP molecular chain, also found the introduction of DE improve the electrical and thermal properties of EP. The breakdown strength of the 4% DE/EP composite film surpasses that of the pure EP film by 15.58%. Additionally, the thermal conductivity of the 8% DE/EP composite film is elevated by 41.6% compared to the pure EP film, while its dielectric constant is also enhanced by 8.2%. This work may provide a theoretical basis for studying the application of EP modified system in electrical engineering, integrated circuit packaging and other fields.

随着电力系统和电子设备的发展,环氧树脂(EP)面临着越来越严酷的工作环境,其性能可能无法达到预期。为了拓宽环氧树脂的应用领域,本文以环氧树脂为基体,聚丙烯酸橡胶介电弹性体(DE)为增强材料,制备了 DE/EP 复合薄膜。通过 XRD、SEM 等方法对 DE/EP 复合薄膜的结构进行了表征,并对材料的电性能和热性能进行了测试和研究。研究发现,经过适当的溶解和搅拌处理,DE 可以均匀地分散在 EP 基体中,且 DE 的引入不会明显影响 EP 分子链的结构,还发现 DE 的引入改善了 EP 的电学和热学性能。4% DE/EP 复合薄膜的击穿强度比纯 EP 薄膜高出 15.58%。此外,与纯 EP 薄膜相比,8% DE/EP 复合薄膜的热导率提高了 41.6%,介电常数也提高了 8.2%。这项工作可为研究 EP 改性系统在电气工程、集成电路封装等领域的应用提供理论依据。
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引用次数: 0
Impact of titanium dioxide/graphene in polyvinylidene fluoride nanocomposite membrane to intensify methylene blue dye removal, antifouling performance, and reusability 聚偏二氟乙烯纳米复合膜中的二氧化钛/石墨烯对提高亚甲基蓝染料去除率、防污性能和重复使用性的影响
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-18 DOI: 10.1002/app.56257
Ain Zaienah Sueraya, Md Rezaur Rahman, Khairul Anwar Bin Mohamad Said, Murtala Namakka, Devagi Kanakaraju, Jehan Y. Al-Humaidi, Saad M. Al-Baqami, Mohammed Muzibur Rahman, Mayeen Uddin Khandaker

The development of efficient water purification technologies is a critical research focus driven by the crucial role of clean water sources for ecological sustainability. This study explores the strategic incorporation of nanoparticles within polyvinylidene fluoride (PVDF) membranes as a promising approach to enhance membrane performance for wastewater remediation. PVDF membranes containing varying ratios of graphene (GR) and titanium dioxide (TiO2) nanocomposites were fabricated via phase inversion method. Characterization techniques including XRD, FTIR, and FESEM-EDX revealed that the 80% GR nanocomposite membrane exhibited desirable structural and functional properties with pronounced sponge-like morphology and homogenous nanoparticle distribution. Fourier-transform infrared spectroscopy and x-ray diffraction analysis confirmed the 80% GR membrane retained PVDF crystallinity while uniquely eliminating TiO2 crystallinity. Subsequently, performance testing demonstrated the 80% GR nanocomposite membrane had the highest water flux and methylene blue dye rejection rates compared to other ratios and the pristine PVDF membrane. Both fabricated membranes exhibited sufficient reusability and antifouling properties. However, 80% GR ratio exhibited superior antifouling properties, indicating its potential as an optimal material for improving membrane hydrophilicity and overall water purification technologies. These findings underscore the strategic utility of GR-TiO2 nanocomposites for enhancing PVDF membrane performance in sustainable wastewater treatment applications.

由于清洁水源对生态可持续性的关键作用,开发高效的水净化技术成为一项重要的研究重点。本研究探讨了在聚偏二氟乙烯(PVDF)膜中策略性地加入纳米粒子,作为提高废水修复膜性能的一种可行方法。通过相反转法制造了含有不同比例石墨烯(GR)和二氧化钛(TiO2)纳米复合材料的聚偏二氟乙烯(PVDF)膜。XRD、FTIR 和 FESEM-EDX 等表征技术表明,80% 的 GR 纳米复合膜具有理想的结构和功能特性,具有明显的海绵状形态和均匀的纳米粒子分布。傅立叶变换红外光谱和 X 射线衍射分析证实,80% GR 膜保留了 PVDF 结晶性,同时独特地消除了 TiO2 结晶性。随后的性能测试表明,与其他比率和原始 PVDF 膜相比,80% GR 纳米复合膜具有最高的水通量和亚甲基蓝染料去除率。两种膜都具有足够的重复使用性和防污性能。然而,80% 的 GR 比率显示出更优越的防污性能,表明它有潜力成为改善膜亲水性和整体水净化技术的最佳材料。这些发现强调了 GR-TiO2 纳米复合材料在可持续废水处理应用中提高 PVDF 膜性能的战略用途。
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引用次数: 0
Sustainable poly(imide-imide) vitrimer based on multiple dynamic covalent bonds 基于多重动态共价键的可持续聚(亚胺-酰亚胺)三聚体
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-18 DOI: 10.1002/app.56281
Yanna Zhao, Yingying Zhang, Xiaowei Bai, Yuqi Wang, Yiqing Li, Shuai Yang

Polyimide materials with high mechanical strength are widely used in various fields, but pose certain challenges in achieving sustainable material utilization. A poly(imide-imide) vitrimer material (ADTA) based on multiple dynamic covalent bonds (imide, imine, and disulfide bonds) was constructed by preparing vanillin difunctionalized derivatives (DVA) for aldolamine condensation reactions with bis-amine monomers (ATFA) and tris(2-aminoethyl) amines (TAEA) with imide structures. The ADTA material has good 5% thermal stability Td5% (278.87°C), high energy storage modulus E (2421.26 MPa), and fast relaxation time (36.39 s). The thermal stability and mechanical properties of the material are enhanced by the more stable alicyclic structure of the imide structure. The material also demonstrated excellent solvent resistance and self-healing properties. This study provides a new option for the development of sustainable utilization of polyimide materials.

具有高机械强度的聚酰亚胺材料被广泛应用于各个领域,但要实现材料的可持续利用却面临着一定的挑战。通过制备香兰素二官能化衍生物(DVA)与双胺单体(ATFA)和具有亚胺结构的三(2-氨基乙基)胺(TAEA)进行醛醇胺缩合反应,构建了一种基于多种动态共价键(亚胺键、亚胺键和二硫键)的聚(亚胺-亚胺)玻璃聚合物材料(ADTA)。ADTA 材料具有良好的 5%热稳定性 Td5%(278.87°C)、高储能模量 E(2421.26 兆帕)和快速弛豫时间(36.39 秒)。该材料的热稳定性和机械性能因亚胺结构中更稳定的脂环结构而得到增强。该材料还表现出优异的耐溶剂性和自愈性。这项研究为开发可持续利用的聚酰亚胺材料提供了新的选择。
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引用次数: 0
Epitaxial crystallization of polylactic acid on layered zinc phenylphosphonate: Mutual perpendicular rodlike crystals under two lattice matchings 聚乳酸在层状苯基膦酸锌上的外延结晶:两种晶格匹配下相互垂直的棒状晶体
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-18 DOI: 10.1002/app.56102
Shi-Juan Ding, Ling-Na Cui, Yue-Jun Liu

As a highly effective nucleating agent, layered zinc phenylphosphonate (PPZn) is incorporated into polylactic acid (PLA) to investigate the epitaxial crystallization of PLA on PPZn in this study. The corresponding lattice spacing change, crystalline morphology, and crystalline structure are emphasized to reveal the epitaxial crystallization mechanism. As a result, with the increase of PPZn content and the annealing time, the increasing lattice spacing of PPZn and the formation of mutually perpendicular rodlike crystals are observed through x-ray diffraction (XRD) and polarized optical micrograph (POM) measurements, implying that the interlayer spacing of PPZn crystals is expanded as the PLA α-form crystals epitaxially grow on its surface, that is, epitaxial crystallization. To be specific, “edge on” lamellae epitaxial grow on the PPZn crystals along the [010] and [100] directions under two excellent lattice matchings, which possess acceptable mismatching of 0.347% and 7.5%, respectively. With the support of the epitaxial crystallization mechanism, the occurrence of the filamentous structure observed in the fracture morphology of PLA/PPZn composites suggests strong interfacial adhesion between PLA and PPZn, which makes the impact toughness of the PLA/PPZn composites increase by 53.6% compared with pure PLA.

作为一种高效成核剂,本研究将层状苯基膦酸锌(PPZn)加入聚乳酸(PLA)中,研究聚乳酸在 PPZn 上的外延结晶。研究强调了相应的晶格间距变化、结晶形态和结晶结构,以揭示外延结晶机理。结果表明,随着 PPZn 含量的增加和退火时间的延长,通过 X 射线衍射(XRD)和偏振光学显微照片(POM)测量,观察到 PPZn 的晶格间距增大,并形成相互垂直的棒状晶体,这意味着随着聚乳酸 α 形晶体在其表面外延生长,PPZn 晶体的层间间距扩大,即外延结晶。具体来说,PPZn 晶体沿[010]和[100]方向外延生长出 "边上 "薄片,两种晶格匹配度极佳,可接受的不匹配度分别为 0.347% 和 7.5%。在外延结晶机制的支持下,聚乳酸/PPZn 复合材料断口形貌中观察到的丝状结构表明聚乳酸和 PPZn 之间具有很强的界面粘附性,这使得聚乳酸/PPZn 复合材料的冲击韧性比纯聚乳酸提高了 53.6%。
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引用次数: 0
Improving the electromechanical deformability of MWCNT/silicone composites via encapsulating MWCNT with polyphenols and multilayered structure regulation 通过多酚包裹 MWCNT 和多层结构调整改善 MWCNT/硅树脂复合材料的机电变形性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-18 DOI: 10.1002/app.56288
Yue Sun, Jiale Zhang, Tao Chen, Yanting Zhang, Chonggang Wu, Xinghou Gong, Tao Hu

Silicone rubber (SR) is an ideal dielectric elastomer substrate due to its excellent flexibility and fast response speed. However, the innate low dielectric permittivity (ε) of SR generally requires a rather high driving voltage that restricts its widespread application. Typical attempts to increase ε of SR usually deteriorate either its flexibility or electrical stability. Herein, conductive multi-walled carbon nanotube (MWCNT) were first surface modified with polyphenols (PNs) (MWCNT@PNs), aiming to facilitate its well dispersion within SR matrix, which may maintain the softness and electrical stability of SR via suppressing concentrated physical crosslinking and local leakage current flow. Then, five-layered MWCNT@PNs/SR composites were prepared with the outer two insulating layers of SR while middle three dielectric layers of MWCNT@PNs filled SR. The multilayered structure further hindered the formation of conductive pathways through the composites, promising a high breakdown strength of the composites. Therefore, the multilayered MWCNT@PNs/SR composites exhibited increased ε, maintained low Young's modulus and electrical breakdown strength compared with pure SR of the same five-layered structure. Among them, the composite with uniformly distributed MWCNT@PNs (m-1: 1: 1) showed a highest actuation strain of 11.9% (at 19.6 kV mm−1), which was 4.1 times higher than that of SR (2.9% at 19.1 kV mm−1).

硅橡胶(SR)具有出色的柔韧性和快速响应速度,是一种理想的介电弹性体基材。然而,SR 固有的低介电常数(ε)通常需要相当高的驱动电压,这限制了它的广泛应用。通常情况下,试图提高 SR 的 ε 通常会降低其柔韧性或电气稳定性。在此,首先用多酚(PNs)对导电多壁碳纳米管(MWCNT)进行表面改性(MWCNT@PNs),旨在促进其在 SR 基质中的良好分散,从而通过抑制集中物理交联和局部漏电流流动来保持 SR 的柔软性和电气稳定性。然后,制备了五层 MWCNT@PNs/SR 复合材料,其中外两层为 SR 绝缘层,中间三层为填充 SR 的 MWCNT@PNs 介电层。多层结构进一步阻碍了导电通道在复合材料中的形成,从而保证了复合材料的高击穿强度。因此,与相同五层结构的纯 SR 相比,多层 MWCNT@PNs/SR 复合材料的 ε 增加,杨氏模量和电击穿强度保持较低水平。其中,MWCNT@PNs(m-1: 1:1)均匀分布的复合材料的致动应变最高,达到 11.9%(19.6 kV mm-1),是 SR(2.9%,19.1 kV mm-1)的 4.1 倍。
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引用次数: 0
A study of crashworthiness performance in thin-walled multi-cell tubes 3D-printed from different polymers 不同聚合物 3D 打印薄壁多孔管的防撞性能研究
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-18 DOI: 10.1002/app.56287
Merve Tunay, Alperen Bardakci

Multicellular, thin-walled impact tubes have been intensely studied and used in various engineering fields in recent years due to their lightweight, high performance, ease of application, superior energy absorption, and stable deformation characteristics. In this study, energy absorption, crashworthiness performances, and deformation properties of thin-walled structures manufactured from polylactic acid (PLA+) and acrylonitrile butadiene styrene (ABS) using fused deposition modeling (FDM) technology were compared under quasi-static axial compression. Thin-walled structures consist of multicellular tubes connected by concentric corner-edge connections with square and hexagonal cross-sections. Experimental testing outcomes indicate that the energy absorption capacity increases with increasing the number of corners in multicellular structures. The tubes with square wall-to-wall (S-WW) and hexagonal wall-to-wall (H-WW) cross-sections exhibit superior crashworthiness performance compared to other cross-sections. Based on the experimental results, the absorbed energy by WW patterned PLA+ square tubes are 19%, 7%, and 46% more than that of wall-to-corner (WC), corner-to-wall (CW), and corner-to-corner (CC) patterned tubes, respectively, while it is 11%, 19%, and 80% more in hexagonal cross-section tubes, respectively. This study provides an informative reference for easier applicability of multicellular energy-absorbing structures with 3D-print and the design of corner-edge connections of internal connections in multicellular structures.

近年来,多孔薄壁抗冲击管因其轻质、高性能、易于应用、优异的能量吸收和稳定的变形特性而被广泛研究和应用于各个工程领域。本研究比较了在准静态轴向压缩条件下,由聚乳酸(PLA+)和丙烯腈-丁二烯-苯乙烯(ABS)采用熔融沉积成型(FDM)技术制造的薄壁结构的能量吸收、耐撞性能和变形特性。薄壁结构由多孔管组成,管子通过同心角边连接,横截面为正方形和六边形。实验测试结果表明,多孔结构的能量吸收能力随着角的数量增加而提高。与其他横截面相比,具有方形壁到壁(S-WW)和六边形壁到壁(H-WW)横截面的管材具有更优越的防撞性能。根据实验结果,WW 图案的聚乳酸+ 方管吸收的能量分别比壁到角(WC)、角到壁(CW)和角到角(CC)图案的方管多 19%、7% 和 46%,而六边形截面方管吸收的能量分别比壁到角(WC)、角到壁(CW)和角到角(CC)图案的方管多 11%、19% 和 80%。这项研究为三维打印多孔吸能结构的简易应用以及多孔结构内部连接的角边连接设计提供了参考。
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引用次数: 0
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Journal of Applied Polymer Science
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