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In situ formation of PE-EPR core-shell rubber particles in polypropylene matrix by melt blending: Effect of PE chain structure and viscosity 通过熔融混合在聚丙烯基体中原位形成 PE-EPR 芯壳橡胶颗粒:聚乙烯链结构和粘度的影响
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-10 DOI: 10.1002/app.56245
Wei Bao, Yunbao Gao, Jianing Zhang, Jing Jin, Baijun Liu, Mingyao Zhang, Xiangling Ji, Wei Jiang

Twenty types of polyethylene (PE) including high density polyethylene (HDPE) and linear low-density polyethylene (LLDPE) with various viscosity were used to study the in-situ formation of PE- ethylene propylene rubber (EPR) core-shell rubber particles (CSRP) in polypropylene (PP) matrix by melt blending. The results show that PE and EPR cannot form CSRP if PE melt flow index (MFI) is lower than about 0.3 g/10 min. As a result, the impact fracture of PP/PE/EPR composite is brittle. If PE MFI is higher than 0.3 g/10 min, PE and EPR can form CSRP, leading to the ductile impact fracture of PP/PE/EPR composite. Interestingly, upper limit content of PE for the formation of CSRP depends on the type and viscosity of PE. For HDPE, upper limit content of PE tends to increase with the increase of its MFI, whereas it drops considerably for LLDPE. Understanding these relationships provides insights into optimizing the selection of core types and viscosity for enhancing the mechanical properties of polymer composites with core-shell structure. This may potentially guide the development of cost-effective and high-performance polymer composites.

采用 20 种不同粘度的聚乙烯(PE),包括高密度聚乙烯(HDPE)和线型低密度聚乙烯(LLDPE),研究了聚乙烯-乙丙橡胶(EPR)在聚丙烯(PP)基体中通过熔融共混原位形成芯壳橡胶颗粒(CSRP)的情况。结果表明,如果聚乙烯熔体流动指数(MFI)低于约 0.3 克/10 分钟,聚乙烯和乙丙橡胶就不能形成 CSRP。因此,PP/PE/EPR 复合材料的冲击断裂是脆性的。如果 PE 熔体流动指数(MFI)高于 0.3 克/10 分钟,PE 和 EPR 就会形成 CSRP,从而导致 PP/PE/EPR 复合材料发生韧性冲击断裂。有趣的是,形成 CSRP 的 PE 上限含量取决于 PE 的类型和粘度。对于高密度聚乙烯,聚乙烯的上限含量往往会随着其 MFI 的增加而增加,而对于低密度聚乙烯,上限含量则会大幅下降。了解这些关系有助于优化芯材类型和粘度的选择,从而提高具有芯壳结构的聚合物复合材料的机械性能。这有可能为开发具有成本效益和高性能的聚合物复合材料提供指导。
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引用次数: 0
Functionalization of poly(butylene adipate-co-terephthalate) and its compatibilizing effect on PBAT/thermoplastic starch blends 聚(己二酸丁二醇酯-共对苯二甲酸酯)的功能化及其对 PBAT/热塑性淀粉混合物的相容效果
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-09 DOI: 10.1002/app.56246
Guangxiang Zhang, Ke Yang, Songqi Zheng, Xiangyan Han, Yuexin Hu, Yuanyuan Han, Guiyan Zhao, Yulin Feng

Poly(butylene adipate-co-butylene terephthalate) (PBAT)/thermoplastic starch (TPS) blends were prepared by melt blending. However, the processability and practical application of PBAT/TPS blends are limited by their poor compatibility. To enhance the compatibility between PBAT and TPS, PBAT was functionalized by maleic anhydride (MA) to prepare PBAT-MA, and then it was employed as a compatibilizer for PBAT/PBAT-MA/TPS blends. The effects of PBAT-MA on the tensile properties, rheological properties, morphology, and dynamic mechanics of PBAT/PBAT-MA/TPS blends were studied in detail. Rheological results revealed that the interaction between PBAT-MA and TPS enhanced the segment entanglement ability and improved the compatibility of the blends, which enhanced the tensile properties of the blends. Compared with the PBAT/PBAT-MA/TPS (50/0/50) blend, the tensile strength of the PBAT/PBAT-MA/TPS (40/10/50) blend increased from 9.2 to 15.8 MPa, and the elongation at break increased from 326.9% to 1017.6%. The dynamic mechanical results showed that the Tg of PBAT and TPS were close to each other after the addition of PBAT-MA, which confirmed that the compatibility of the blend was improved. This study provides a feasible approach to preparing high-performance and cost-effective PBAT/PBAT-MA/TPS blends while expanding the application prospects of PBAT in the packaging industry and agricultural film.

聚(己二酸丁二醇酯-对苯二甲酸丁二醇酯)(PBAT)/热塑性淀粉(TPS)混合物是通过熔融混合制备的。然而,由于 PBAT/TPS 混合物的相容性较差,其加工性和实际应用受到了限制。为了提高 PBAT 与 TPS 的相容性,用马来酸酐(MA)对 PBAT 进行官能化,制备出 PBAT-MA,并将其用作 PBAT/PBAT-MA/TPS 共混物的相容剂。详细研究了 PBAT-MA 对 PBAT/PBAT-MA/TPS 共混物拉伸性能、流变性能、形态和动态力学的影响。流变学结果表明,PBAT-MA 与 TPS 之间的相互作用增强了段缠结能力,改善了共混物的相容性,从而提高了共混物的拉伸性能。与PBAT/PBAT-MA/TPS(50/0/50)共混物相比,PBAT/PBAT-MA/TPS(40/10/50)共混物的拉伸强度从9.2兆帕提高到15.8兆帕,断裂伸长率从326.9%提高到1017.6%。动态力学结果表明,添加 PBAT-MA 后,PBAT 和 TPS 的 Tg 相互接近,这证实了共混物的相容性得到了改善。这项研究为制备高性能、高性价比的 PBAT/PBAT-MA/TPS 共混物提供了一种可行的方法,同时也拓展了 PBAT 在包装行业和农用薄膜领域的应用前景。
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引用次数: 0
Preparation and characterization of cardanol based vinyl ester resins as cross-linker units 制备和表征作为交联剂单元的贲醇基乙烯基酯树脂
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-09 DOI: 10.1002/app.56129
Emre Kinaci, John J. La Scala, Erde Can, Giuseppe R. Palmese

In this study, two cardanol based epoxidized resins, NC514 with less than two epoxies per molecule and side chain epoxidized cardanol glycidyl ether (SCECGE) with approximately 2.45 epoxies (1.0 phenolic+1.45 aliphatic epoxies) per molecule were methacrylated. The methacrylated versions of cardanol based NC514 (NC514VE) and SCECGE (SCECGEVE) epoxy resins were used as cross-linker units in vinyl ester formulations with methacrylated lauric acid (MFA) and styrene (ST) as bio-based and synthetic based reactive diluents respectively, at various concentrations (10–40 wt%). The curing reactions of the resins were studied via FTIR and the extent of polymerization was determined for different cross-linker units in the presence of ST and MFA. Our mechanical and thermomechanical characterizations showed that VER formulations prepared with cardanol based SCECGEVE cross-linker unit have significantly improved properties than the samples prepared with commercially available counterpart NC514VE using either reactive diluent. These properties of SCECGEVE were also comparable with to that of methacrylated petroleum-based diglycidyl ether of bisphenol A vinyl ester (DGEBAVE) formulations unlike NC514VE formulations due to more effective side chain functionalization and cross-linking.

在这项研究中,对两种基于卡旦醇的环氧树脂进行了甲基丙烯酸化处理,一种是 NC514,其每个分子中的环氧化合物少于两个;另一种是侧链环氧化卡旦醇缩水甘油醚(SCECGE),其每个分子中的环氧化合物约为 2.45 个(1.0 个酚类环氧化合物+1.45 个脂肪族环氧化合物)。甲基丙烯酸化的卡旦醇基 NC514(NC514VE)和 SCECGE(SCECGEVE)环氧树脂在乙烯基酯配方中用作交联剂单元,甲基丙烯酸化月桂酸(MFA)和苯乙烯(ST)分别作为生物基和合成基活性稀释剂,浓度各异(10-40 wt%)。通过傅立叶变换红外光谱研究了树脂的固化反应,并确定了不同交联剂单元在 ST 和 MFA 存在下的聚合程度。我们的机械和热力学特性分析表明,与使用市售同类产品 NC514VE 制备的样品相比,使用卡旦醇基 SCECGEVE 交联剂单元制备的 VER 配方在性能上有明显改善。由于侧链官能化和交联效果更好,SCECGEVE 的这些性能也可与甲基丙烯酸石油基双酚 A 乙烯基酯二缩水甘油醚(DGEBAVE)配方媲美,而 NC514VE 配方则不同。
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引用次数: 0
Exploring of novel reverse thermally induced phase separation process based on preparation and characterization of polysulfate ultrafiltration membranes with bicontinuous structure 基于双连续结构聚硫酸盐超滤膜的制备和表征的新型反向热诱导相分离过程探索
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-08 DOI: 10.1002/app.56082
Wei Wang, Linghao Sun, Jiaqi Wang, Fanfu Zeng, Baiyu Xu

Contaminated water sources from various industries pose severe environmental challenges due to their complex compositions, high toxicity, and fluctuating qualities. This study introduces a groundbreaking strategy for fabricating advanced polysulfate (PSE) ultrafiltration membranes using a novel reverse thermally induced phase separation (RTIPS) process. By manipulating the cloud point through the DMAc/DEG solvent/nonsolvent system, our work innovatively controls membrane microstructure, overcoming limitations of conventional nonsolvent-induced phase separation (NIPS). Our findings reveal that RTIPS, when employed above the cloud point, yields PSE membranes with a unique bicontinuous sponge-like structure, significantly improving upon conventional NIPS products. Specifically, the optimized RTIPS membranes exhibit enhanced pure water flux (916.23 vs. 336.23 LMH), larger pore sizes (0.083 vs. 0.054 μm), increased tensile strength (1.32 vs. 0.84 MPa), and improved fouling resistance (FRR 65.5% vs. 55.2%). This research pioneers a facile yet potent method for tailoring membrane properties, achieving a balance between permeability, mechanical stability, and filtration efficacy. The demonstrated success of RTIPS in enhancing PSE membrane performance not only contributes to the development of high-performance water treatment technologies but also charts a new course in membrane science, offering a promising avenue for sustainable wastewater management solutions.

来自各行各业的污染水源因其成分复杂、毒性大、水质波动大而对环境构成了严峻的挑战。本研究介绍了一种利用新型反向热诱导相分离(RTIPS)工艺制造高级聚硫酸盐(PSE)超滤膜的突破性策略。通过操纵 DMAc/DEG 溶剂/非溶剂系统的浊点,我们的工作创新性地控制了膜的微观结构,克服了传统非溶剂诱导相分离(NIPS)的局限性。我们的研究结果表明,当 RTIPS 在浊点以上使用时,可产生具有独特双连续海绵状结构的 PSE 膜,大大改进了传统的非溶剂诱导相分离产品。具体来说,经过优化的 RTIPS 膜提高了纯水通量(916.23 LMH 对 336.23 LMH),增大了孔径(0.083 μm 对 0.054 μm),增加了抗拉强度(1.32 MPa 对 0.84 MPa),并改善了抗污垢性能(FRR 65.5% 对 55.2%)。这项研究开创了一种简便而有效的方法来定制膜特性,实现了渗透性、机械稳定性和过滤效果之间的平衡。RTIPS 在提高 PSE 膜性能方面所取得的成功不仅有助于开发高性能水处理技术,还为膜科学开辟了一条新的道路,为可持续废水管理解决方案提供了一条前景广阔的途径。
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引用次数: 0
Polydopamine-coated iron-nickel alloy and epoxy composites for electromagnetic interference shielding 用于电磁干扰屏蔽的聚多巴胺涂层铁镍合金和环氧树脂复合材料
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-07 DOI: 10.1002/app.56187
Hakjeong Kim, Sera Jeon, Yun Seong Cho, Chenyao Huang, Seongmin Na, Jihun Lee, Youngwook Chung, Joohoon Kang, Sang-Woo Kim, Dukhyun Choi

With the development of electronic devices and wireless communication technology, the quality of human life has improved. However, shielding from electromagnetic interference (EMI) is required due to device malfunctions and harmful effects on human health. Polymer-based shielding materials getting much attention due to their light weight, flexibility, good processability, and other desirable traits. However, achieving consistent dispersion of conductive fillers and optimizing the balance between electrical, mechanical, and thermal properties remain challenges despite the advantages of polymer-based materials. Especially, epoxy resins are promising polymer materials for EMI shielding applications due to their excellent mechanical strength, chemical resistance, and excellent adhesive properties. Additionally, epoxy resin exhibits remarkable processability allowing for various fabrication techniques such as casting, molding, and three-dimensional printing. However, one of the significant drawbacks of epoxy resin is the difficulty in achieving uniform dispersion of conductive fillers within the epoxy matrix. In this study, we propose an iron-nickel alloy (FeNi) embedded in an epoxy matrix (FeNi/Epoxy) for EMI shielding material. It is manufactured by facile fabrication process due to the advantages of epoxy, which has excellent processability. EMI shielding effectiveness at 12 GHz is enhanced from 9.12 to 17.86 dB by the increase of FeNi concentrations. Furthermore, thermal and mechanical properties were improved by the increase of FeNi concentration. Thermal conductivity for efficient heat dissipation is increased from 0.63 to 1.49 Wm−1 K−1. Moreover, polydopamine (PDA) was employed as a surface coating material for FeNi to overcome the non-uniform dispersion of FeNi particles in the epoxy matrix. Surface coating by PDA significantly enhanced the dispersion uniformity and strengthened the adhesion between the filler and matrix. Elastic modulus is greatly increased from 83.03 MPa to 1.29 GPa by the surface coating. The enhancement of mechanical properties is derived from the chemical bonds between the filler and matrix.

随着电子设备和无线通信技术的发展,人类的生活质量得到了提高。然而,由于设备故障和对人体健康的有害影响,需要屏蔽电磁干扰(EMI)。聚合物屏蔽材料因其重量轻、柔韧性好、可加工性强等优点而备受关注。然而,尽管聚合物基材料具有诸多优势,但要实现导电填料的稳定分散以及优化电气、机械和热性能之间的平衡仍是一项挑战。特别是环氧树脂,由于其优异的机械强度、耐化学性和出色的粘合性,是 EMI 屏蔽应用中很有前途的聚合物材料。此外,环氧树脂还具有出色的可加工性,可用于各种制造技术,如铸造、模塑和三维打印。然而,环氧树脂的一个显著缺点是难以在环氧基质中实现导电填料的均匀分散。在本研究中,我们提出了一种嵌入环氧树脂基体(FeNi/Epoxy)的铁镍合金(FeNi)作为 EMI 屏蔽材料。由于环氧树脂具有良好的可加工性,因此可以通过简便的制造工艺进行生产。随着铁镍浓度的增加,12 GHz 的 EMI 屏蔽效果从 9.12 dB 提高到 17.86 dB。此外,随着镍铁浓度的增加,热性能和机械性能也得到了改善。有效散热的热导率从 0.63 Wm-1 K-1 提高到 1.49 Wm-1 K-1。此外,还采用了聚多巴胺(PDA)作为镍铁的表面涂层材料,以克服镍铁颗粒在环氧基体中分散不均匀的问题。PDA 表面涂层大大提高了分散均匀性,并增强了填料与基体之间的粘附力。通过表面涂层,弹性模量从 83.03 MPa 大幅提高到 1.29 GPa。机械性能的提高源于填料与基体之间的化学键。
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引用次数: 0
Structure–property correlation assessment of LLDPE-based biocomposites with Azadirachta Indica wood flour 用 Azadirachta Indica 木粉对基于 LLDPE 的生物复合材料进行结构-性能相关性评估
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-07 DOI: 10.1002/app.56237
Jitender Yadav, PL Ramkumar, Ajit Kumar Parwani

This research explores the development of new composite material by integrating Azadirachta Indica (AI) with LLDPE to create wood-plastic composites using the rotational molding process. By examining various proportions of AI wood flour blended with LLDPE, we investigated their impact on mechanical and physical properties. Our tests elucidate a clear correlation between mechanical properties and composite morphologies. Despite identical molding conditions, higher wood particle concentrations reduced mechanical properties compared to lower concentrations. Remarkably, a 12% wood content emerges as optimal, yielding a tensile modulus of 3.69 MPa and a flexural modulus of 468.5 MPa, with an acceptable reduction of 11% density and 13% porosity versus pure LLDPE. Additionally, we observed declines in tensile strength, impact strength, and hardness by up to 23%, 62%, and 11%, respectively, compared to neat LLDPE. Natural fillers enhance aesthetics, making these materials ideal for consumer products like garden equipment and furniture accessories.

本研究探讨了将 Azadirachta Indica(AI)与 LLDPE 相结合,利用旋转成型工艺制造木塑复合材料的新方法。通过研究 AI 木粉与 LLDPE 混合的不同比例,我们调查了它们对机械和物理特性的影响。我们的测试阐明了机械性能与复合材料形态之间的明显相关性。尽管成型条件相同,但与较低浓度的木粉相比,较高浓度的木粉会降低机械性能。值得注意的是,12% 的木材含量是最佳的,可产生 3.69 兆帕的拉伸模量和 468.5 兆帕的弯曲模量,与纯 LLDPE 相比,密度降低了 11%,孔隙率降低了 13%,这是可以接受的。此外,与纯 LLDPE 相比,我们观察到拉伸强度、冲击强度和硬度分别降低了 23%、62% 和 11%。天然填料提高了美观度,使这些材料成为花园设备和家具配件等消费品的理想选择。
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引用次数: 0
On the suitability of the α-relaxation as novel trigger for a shape memory polymer α松弛作为形状记忆聚合物的新型触发器的适用性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-07 DOI: 10.1002/app.56241
Michail Maricanov, Roman Becker, Robert David Ludwig Jerusalem, Joerg Christian Tiller, Frank Katzenberg

Shape memory polymers typically utilize the glass transition or melting temperature to switch from one shape to another. The goal of this work is to check if the α-relaxation, which is attributed to the migration of chains through lamellar crystals, can be utilized as novel switch for any crosslinkable semi-crystalline thermoplastic. Using cross-linked low-density polyethylene (x-LDPE) as an example, it is shown that the α-relaxation is indeed suitable as switch, when the polymer is crystallized under strain to an intermediate shape. It is demonstrated that post-stretching at a temperature between the α-relaxation and the melting temperature, followed by subsequent cooling to room-temperature switches x-LDPE from the intermediate to a temporary shape and that reheating to this temperature initiates the retraction back to the intermediate shape. Switching between intermediate and temporary shapes is shown to be accompanied by a reversible change in morphology.

形状记忆聚合物通常利用玻璃化转变或熔融温度从一种形状转换到另一种形状。这项工作的目的是检查α-松弛是否可用作任何可交联半结晶热塑性塑料的新型开关。以交联低密度聚乙烯(x-LDPE)为例,当聚合物在应变作用下结晶成中间形状时,α-松弛确实适合用作开关。实验证明,在介于 α-松弛温度和熔化温度之间的温度下进行后拉伸,随后冷却至室温,可将 x-LDPE 从中间形状转换为临时形状,而重新加热至该温度又可使其缩回至中间形状。事实证明,中间形状和临时形状之间的转换伴随着形态的可逆变化。
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引用次数: 0
Enhancing impact resistance in E-glass fabric composites through shear thickening fluids and functionalized polyethylene glycol 通过剪切增稠液和功能化聚乙二醇增强 E 玻璃纤维复合材料的抗冲击性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-06 DOI: 10.1002/app.56131
Tao Hai, Fahad Mohammed Alhomayani, Pradeep Kumar Singh, N. Soliman, W. El-Shafay, H. Fuad

In this study, we delved into innovative strategies to make neat E-glass fabrics (NGFs) more impact- and tensile-resistant by using shear-thickening fluids (STFs). To achieve this goal, the polyethylene glycol (PEG) in STFs has been modified. Subsequently, the STF-impregnated fabric composites were prepared from unmodified PEG and functionally modified PEGs using malonic and tartaric acids, V/S/GF, M/S/GF, and T/S/GF composites, respectively. Fourier-transform infrared spectroscopy (FTIR) analysis was conducted to confirm the chemical modification of PEGs. The rheological tests showed a significant improvement in the peak viscosity of modified STFs compared with virgin STF. Dynamic rheological analysis also studied media-particle interaction, revealing improved media-particle interaction in STFs due to abundant H-bonding. In addition, a series of experimental tests, namely compressive impact resistance and strip tensile strength tests, have been conducted to investigate the effect of STF modification on the NGF. The results revealed notable improvements in tensile strength and energy dissipation in the T/S/GF and M/S/GF composites compared with V/S/GF and NGF. Importantly, this improvement extended to the impact performance of single, triple, and quintuple layers. Notably, we found that the peak load of 5 T/S/GF was 37.71%, 18.57%, and 11.87% lower than that of 5NGF, 5 V/S/GF, and 5 M/S/GF, respectively. The idea that made these improvements possible came from PEG functionalization, which helps hydrogen bonds form between the dispersed phase and the dispersion medium, leading to higher viscosity. This, in turn, increases inter-yarn friction, effectively enhancing the spring-like properties of T/S/GF and M/S/GF compared with V/S/GF. A two-step artificial intelligence regression analysis underpinned these findings, elucidating the interplay of molecular mechanisms in high-performance fabric composites.

在这项研究中,我们采用创新策略,通过使用剪切增稠流体(STFs)使整齐的电子玻璃纤维织物(NGFs)具有更强的抗冲击和抗拉伸性能。为了实现这一目标,我们对 STFs 中的聚乙二醇 (PEG) 进行了改性。随后,用未改性的 PEG 和使用丙二酸和酒石酸对 PEG 进行功能改性的 V/S/GF、M/S/GF 和 T/S/GF 复合材料分别制备了 STF 浸渍织物复合材料。傅立叶变换红外光谱(FTIR)分析证实了 PEG 的化学改性。流变测试表明,与原始 STF 相比,改性 STF 的峰值粘度明显提高。动态流变分析还研究了介质与颗粒之间的相互作用,结果表明 STF 中介质与颗粒之间的相互作用因丰富的 H 键而得到改善。此外,为了研究 STF 改性对 NGF 的影响,还进行了一系列实验测试,即抗压冲击和带材拉伸强度测试。结果表明,与 V/S/GF 和 NGF 相比,T/S/GF 和 M/S/GF 复合材料的拉伸强度和能量耗散都有明显改善。重要的是,这种改善延伸到了单层、三层和五层的冲击性能。值得注意的是,我们发现 5 T/S/GF 的峰值负载分别比 5NGF、5 V/S/GF 和 5 M/S/GF 低 37.71%、18.57% 和 11.87%。使这些改进成为可能的想法来自 PEG 功能化,它有助于在分散相和分散介质之间形成氢键,从而提高粘度。这反过来又增加了纱线间的摩擦,与 V/S/GF 相比,有效增强了 T/S/GF 和 M/S/GF 的弹簧特性。两步人工智能回归分析巩固了这些发现,阐明了高性能织物复合材料中分子机制的相互作用。
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引用次数: 0
Chitosan-based self-healing hydrogel mediated by poly(acrylic-methacrylic acid) exhibiting high biocompatibility and anti-tumor activity 聚丙烯酸-甲基丙烯酸介导的壳聚糖基自愈合水凝胶具有高生物相容性和抗肿瘤活性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-06 DOI: 10.1002/app.56231
Krishtan Pal, Sandeep Kumar, Paramjeet Yadav, Sheetal Jaiswal, Rajesh Kumar, Arbind Acharya

Multi-responsive, self-healing hydrogels were developed utilizing positively charged polysaccharides, chitosan, and water-soluble chitosan. This fabrication employed free-radical synthesized polyacrylic acid and polymethacrylic acid along with the cross-linker FeCl3, resulting in the generation of polyelectrolyte metal complexes, which enhances the properties of the chitosan-based hydrogels, particularly their mechanical strength, self-healing ability, thermal stability, swelling behavior, porous structure, cell viability, and even anticancer activity. Characterization and stability assessment of the hydrogels were performed using FT-IR, nuclear magnetic resonance, gel permeation chromatography, scanning electron microscopy, rheometer, x-ray diffraction, thermogravimetric analysis, DSC, and UV spectroscopy. FT-IR measurements indicated that the facile complexation of the cross-linker's metal ions (Fe3+) with the carboxylate (COO), amino (NH), and hydroxyl (OH) groups of the polymers and chitosan chains facilitated rapid gelation. Furthermore, the sustained release of the drug levofloxacin (up to 80%) was observed to increase with increasing pH due to the hydrogels' anionic nature. Biocompatibility and cytotoxicity tests were conducted using the MTT assay on splenocytes and Dalton Lymphoma cancer cell lines. These tests demonstrated the promising potential of these hydrogels for drug delivery applications.

利用带正电荷的多糖、壳聚糖和水溶性壳聚糖开发了多响应自愈合水凝胶。这种制造方法采用了自由基合成的聚丙烯酸和聚甲基丙烯酸以及交联剂 FeCl3,从而生成了多电解质金属复合物,增强了壳聚糖水凝胶的性能,尤其是其机械强度、自愈合能力、热稳定性、膨胀行为、多孔结构、细胞活力,甚至抗癌活性。研究人员利用傅立叶变换红外光谱、核磁共振、凝胶渗透色谱、扫描电子显微镜、流变仪、X 射线衍射、热重分析、DSC 和紫外光谱对水凝胶进行了表征和稳定性评估。傅立叶变换红外测量结果表明,交联剂的金属离子(Fe3+)与聚合物和壳聚糖链的羧酸基(COO-)、氨基(NH)和羟基(OH)容易络合,从而促进了快速凝胶化。此外,由于水凝胶具有阴离子性质,随着 pH 值的升高,药物左氧氟沙星的持续释放率(高达 80%)也在增加。利用 MTT 法对脾细胞和道尔顿淋巴瘤癌细胞系进行了生物相容性和细胞毒性测试。这些测试表明了这些水凝胶在药物输送应用方面的巨大潜力。
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引用次数: 0
Enhanced piezoelectric and electrodeformation properties of PVDF films fabricated by roll to roll process 通过卷对卷工艺制作的 PVDF 薄膜的增强压电和电变形特性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-05 DOI: 10.1002/app.56213
Chao Zhang

β-phase poly(vinylidene fluoride) (PVDF) film boasts excellent electrical properties and can be used in sensors, micro actuation, and energy harvesting. In this paper, high β-phase PVDF films were stretched by stretch-line equipment (roll to roll) and the β-phase content can reach 60%, realizing the potential for large-scale fabrication. Moreover, the electrical and electrostrictive properties of PVDF films before and after stretching are compared. The stretched film (PVDF-R film) has better piezoelectric properties and electrostrictive properties due to the formation of high β phase in the stretched film and the directional arrangement of PVDF molecular chains in the amorphous region (the formation of directional amorphous). Under the same driving electric field intensity (180 kV/mm), the electrostrictive deformation of PVDF film is 1.5 μm, while that of PVDF-R film is 2 μm. The piezoelectric coefficient of the PVDF-R films can reach 36 pC/N. The output voltage of the PVDF-R film in finger press mode is studied and the peak position of the output voltage signal is obvious, which can be used for pulse monitoring.

β相聚偏二氟乙烯(PVDF)薄膜具有优异的电气性能,可用于传感器、微执行器和能量收集。本文利用拉伸线设备(卷对卷)拉伸了高β相聚偏氟乙烯(PVDF)薄膜,其β相含量可达 60%,实现了大规模制造的潜力。此外,还比较了拉伸前后 PVDF 薄膜的电学和电致伸缩特性。拉伸薄膜(PVDF-R 薄膜)具有更好的压电特性和电致伸缩特性,这是由于拉伸薄膜中形成了高β相,以及 PVDF 分子链在非晶区的定向排列(形成了定向非晶)。在相同的驱动电场强度(180 kV/mm)下,PVDF 薄膜的电致伸缩变形为 1.5 μm,而 PVDF-R 薄膜的电致伸缩变形为 2 μm。PVDF-R 薄膜的压电系数可达 36 pC/N。研究了 PVDF-R 薄膜在指压模式下的输出电压,其输出电压信号的峰值位置非常明显,可用于脉冲监测。
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Journal of Applied Polymer Science
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