首页 > 最新文献

Materiale Plastice最新文献

英文 中文
Mechanical Properties of Polymer-Infiltrated Fluorapatite Glass Ceramics Fabricated from Clam Shell and Soda Lime Silicate Glass 蛤壳与钠钙硅酸盐玻璃聚合物渗透氟磷灰石玻璃陶瓷的力学性能
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5652
E. Kul, K. Matori, Şükran Karadeniz, E. Arslan, M. Ertuğrul
Can polymer-infiltrated florapatite glass ceramic produced from waste materials, such as clam shell and soda lime silicate glass, be used in prosthetic rehabilitation? The purpose of this study is to investigate the effect of Si/Ca ratio on the mechanical properties of Nb-Bi-Ce doped polymer-infiltrated fluorapatite ceramic networks (PICNs) produced from clam shell (CS) and soda lime silicate (SLS) glass by conventional melt-quench technique, used as a dental ceramic. PICNs comprising Si/Ca at four different weight percentage ratios: 1.27% (PICN-1), 2.15% (PICN-2), 4.12% (PICN-3) and 12.6% (PICN-4) were prepared (n=10). The powder mixtures in four different ratios were compressed in a rectangular prism shaped mold and subjected to equal pressure from all sides in a cold isostatic press, followed by heat treatment at 750C for 3 h. Then complete vacuum infiltration was done with a polymer mixture then low temperature firing was applied leading to the formation of the PICNs. Wear behavior and 3-point bending properties were evaluated and specimens were analyzed using scanning electron microscopy (SEM). The friction and wear properties were determined by means of a pin-on-disk tribotester. Since the flexural strength test did not show normal distribution, Kruskal Wallis test was performed in independent groups, p[0.05. There is a significant difference of flexural strength values between the groups (p=0.032), it was determined that the difference was between the PICN-1 and PICN-4 groups (p=0.037). In the analysis of wear scar, abrasion grooves were also observed. The results of this study showed that high Ca and Si content in CS and SLS glass, respectively, encourages the use of waste materials in the production of PICNs intended to be used in prosthetic rehabilitation. The composition of PICNs produced from waste materials affected flexural strength and wear behavior. Increasing the Si/Ca ratio was found to support the mechanical properties of experimental PICN and that experimental PICNs can be considered as high potential candidates for dental applications.
利用蛤壳和钠钙硅酸盐玻璃等废弃材料生产的聚合物渗透型氟磷灰石玻璃陶瓷可以用于假肢康复吗?本研究的目的是研究Si/Ca比例对由蛤壳(CS)和钠钙硅酸盐(SLS)玻璃通过常规熔融淬火技术制备的掺杂Nb-Bi-Ce的聚合物渗透氟磷灰石陶瓷网络(PICNs)的力学性能的影响。制备了包含四种不同重量百分比比的Si/Ca的PICN:1.27%(PICN-1)、2.15%(PICN-2)、4.12%(PICN-3)和12.6%(PICN-4)(n=10)。将四种不同比例的粉末混合物在矩形棱柱形模具中压缩,并在冷等静压机中从各个侧面承受相等的压力,然后在750下进行热处理持续3小时。然后用聚合物混合物进行完全的真空渗透,然后施加低温烧制以形成PICN。对磨损行为和三点弯曲性能进行了评估,并使用扫描电子显微镜(SEM)对试样进行了分析。采用销盘式摩擦试验机测定了摩擦磨损性能。由于弯曲强度试验未显示出正态分布,因此Kruskal-Wallis试验在独立组中进行,p[0.05。两组之间的抗弯强度值存在显著差异(p=0.032),确定PICN-1和PICN-4组之间的差异(p=0.037)。在磨痕分析中,还观察到磨损凹槽。这项研究的结果表明,CS和SLS玻璃中的高Ca和Si含量分别鼓励在生产用于假肢康复的PICN时使用废弃材料。由废料生产的PICN的组成影响弯曲强度和磨损行为。发现增加Si/Ca比可以支持实验性PICN的机械性能,并且实验性PICN可以被认为是牙科应用的高潜力候选者。
{"title":"Mechanical Properties of Polymer-Infiltrated Fluorapatite Glass Ceramics Fabricated from Clam Shell and Soda Lime Silicate Glass","authors":"E. Kul, K. Matori, Şükran Karadeniz, E. Arslan, M. Ertuğrul","doi":"10.37358/mp.23.1.5652","DOIUrl":"https://doi.org/10.37358/mp.23.1.5652","url":null,"abstract":"\u0000Can polymer-infiltrated florapatite glass ceramic produced from waste materials, such as clam shell and soda lime silicate glass, be used in prosthetic rehabilitation? The purpose of this study is to investigate the effect of Si/Ca ratio on the mechanical properties of Nb-Bi-Ce doped polymer-infiltrated fluorapatite ceramic networks (PICNs) produced from clam shell (CS) and soda lime silicate (SLS) glass by conventional melt-quench technique, used as a dental ceramic. PICNs comprising Si/Ca at four different weight percentage ratios: 1.27% (PICN-1), 2.15% (PICN-2), 4.12% (PICN-3) and 12.6% (PICN-4) were prepared (n=10). The powder mixtures in four different ratios were compressed in a rectangular prism shaped mold and subjected to equal pressure from all sides in a cold isostatic press, followed by heat treatment at 750C for 3 h. Then complete vacuum infiltration was done with a polymer mixture then low temperature firing was applied leading to the formation of the PICNs. Wear behavior and 3-point bending properties were evaluated and specimens were analyzed using scanning electron microscopy (SEM). The friction and wear properties were determined by means of a pin-on-disk tribotester. Since the flexural strength test did not show normal distribution, Kruskal Wallis test was performed in independent groups, p[0.05. There is a significant difference of flexural strength values between the groups (p=0.032), it was determined that the difference was between the PICN-1 and PICN-4 groups (p=0.037). In the analysis of wear scar, abrasion grooves were also observed. The results of this study showed that high Ca and Si content in CS and SLS glass, respectively, encourages the use of waste materials in the production of PICNs intended to be used in prosthetic rehabilitation. The composition of PICNs produced from waste materials affected flexural strength and wear behavior. Increasing the Si/Ca ratio was found to support the mechanical properties of experimental PICN and that experimental PICNs can be considered as high potential candidates for dental applications.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42527323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CONTENTS 1 / 2023 内容1/2023
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5638
{"title":"CONTENTS 1 / 2023","authors":"","doi":"10.37358/mp.23.1.5638","DOIUrl":"https://doi.org/10.37358/mp.23.1.5638","url":null,"abstract":"","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48381127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical and Mechanical Properties for Rosin-based Hybrid Resins 松香基杂化树脂的化学和机械性能
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5646
A. Bolcu, N. Cioateră, D. Bolcu, M. Stănescu, I. Ciuca, A. Diniță, I. Constantin
The increasing concern for the protection of the environment, through the use of renewable natural resources, has led in the last decades to the realization of a number of natural polymers or hybrids to be able to replace petroleum-based polymeric materials. Rosin is a low-cost wood resin extracted from conifers. In this paper, based on FTIR and Raman analyses, the spectra of natural Rosin resin and some hybrid resins with volume proportions of 45, 55 and 65% Rosin were studied. Some mechanical properties such as modulus of elasticity, elongation at break, tensile strength were determined from stress-strain diagrams obtained from tensile stress. Increasing the volume proportion of Rosin leads to a decrease in stiffness and strength properties and obtaining a visco-elastic behavior.
在过去的几十年里,人们越来越关注通过使用可再生自然资源来保护环境,从而实现了许多能够取代石油基聚合物材料的天然聚合物或混合物。松香是一种从针叶树中提取的低成本木材树脂。本文基于红外光谱和拉曼光谱分析,研究了天然松香树脂和体积比分别为45%、55%和65%的混合树脂的光谱。从拉伸应力得到的应力-应变图中确定了一些力学性能,如弹性模量、断裂伸长率、拉伸强度。增加松香的体积比例会导致刚度和强度性能的降低,并获得粘弹性行为。
{"title":"Chemical and Mechanical Properties for Rosin-based Hybrid Resins","authors":"A. Bolcu, N. Cioateră, D. Bolcu, M. Stănescu, I. Ciuca, A. Diniță, I. Constantin","doi":"10.37358/mp.23.1.5646","DOIUrl":"https://doi.org/10.37358/mp.23.1.5646","url":null,"abstract":"\u0000The increasing concern for the protection of the environment, through the use of renewable natural resources, has led in the last decades to the realization of a number of natural polymers or hybrids to be able to replace petroleum-based polymeric materials. Rosin is a low-cost wood resin extracted from conifers. In this paper, based on FTIR and Raman analyses, the spectra of natural Rosin resin and some hybrid resins with volume proportions of 45, 55 and 65% Rosin were studied. Some mechanical properties such as modulus of elasticity, elongation at break, tensile strength were determined from stress-strain diagrams obtained from tensile stress. Increasing the volume proportion of Rosin leads to a decrease in stiffness and strength properties and obtaining a visco-elastic behavior.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43625816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Polishing Systems on Translucency Parameter of the Resin Composites after Aging 抛光系统对树脂复合材料时效后透光性参数的影响
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5644
M. Fidan
The purpose of this study was to evaluate the effect of finishing/polishing systems on the translucency parameter (TP) of resin composites after accelerated artificial aging (AAA). Four composite resins (Filtek Z250, Admira, IPS Empress Direct, Clearfil Majesty Esthetic) were evaluated. Thirty samples were prepared with each resin composite and divided into three subgroups: control (Mylar strip), disc (Optidisc), and rubber (Dimanto) (n=10). The spectrophotometer was used to determine color measurements. TP was calculated the using the CIEDE 2000 formula. Data were analyzed using Generalized Lineer Model (p[0.05). The three factors (composite resin, finishing/ polishing, and AAA) had no statistically significant influence on the TP. However, composite and finishing/polishing influenced the TP. Filtek Z250 showed the lowest TP values and the IPS Empress Direct showed the highest TP values before and after AAA. Polished groups showed higher TP values than control groups before and after AAA. IPS Empress Direct with Dimanto had higher TP values than other groups (except for IPS Empress Direct with Optidisc); Filtek Z250 with finishing/polishing groups showed lower TP values than other groups. Composite type and finishing/polishing systems influenced TP values. Unfinished groups exhibited lower TP values than finished groups. There was no difference in TP values between finishing/polishing systems (Dimanto and OptiDisc).
本研究的目的是评估精加工/抛光系统对加速人工老化(AAA)后树脂复合材料半透明参数(TP)的影响。评估了四种复合树脂(Filtek Z250、Admira、IPS Empress Direct、Clearfil Majesty Esthetic)。用每种树脂复合材料制备30个样品,并将其分为三个亚组:对照组(聚酯薄膜条)、光盘组(Optidisc)和橡胶组(Dimanto)(n=10)。分光光度计用于测定颜色测量值。TP是使用CIEDE 2000公式计算的。使用广义Lineer模型分析数据(p[0.05)。三个因素(复合树脂、精加工/抛光和AAA)对TP无统计学显著影响。然而,复合材料和精加工/抛光影响TP。Filtek Z250在AAA前后显示出最低的TP值,IPS Empress Direct显示出最高的TP值。抛光组在AAA前后的TP值均高于对照组。使用Dimanto的IPS Empress Direct的TP值高于其他组(使用Optidisc的IPS Empress-Direct除外);具有精加工/抛光组的Filtek Z250显示出比其他组更低的TP值。复合材料类型和精加工/抛光系统影响TP值。未完成组的TP值低于完成组。精加工/抛光系统(Dimanto和OptiDisc)之间的TP值没有差异。
{"title":"Effect of Polishing Systems on Translucency Parameter of the Resin Composites after Aging","authors":"M. Fidan","doi":"10.37358/mp.23.1.5644","DOIUrl":"https://doi.org/10.37358/mp.23.1.5644","url":null,"abstract":"\u0000The purpose of this study was to evaluate the effect of finishing/polishing systems on the translucency parameter (TP) of resin composites after accelerated artificial aging (AAA). Four composite resins (Filtek Z250, Admira, IPS Empress Direct, Clearfil Majesty Esthetic) were evaluated. Thirty samples were prepared with each resin composite and divided into three subgroups: control (Mylar strip), disc (Optidisc), and rubber (Dimanto) (n=10). The spectrophotometer was used to determine color measurements. TP was calculated the using the CIEDE 2000 formula. Data were analyzed using Generalized Lineer Model (p[0.05). The three factors (composite resin, finishing/ polishing, and AAA) had no statistically significant influence on the TP. However, composite and finishing/polishing influenced the TP. Filtek Z250 showed the lowest TP values and the IPS Empress Direct showed the highest TP values before and after AAA. Polished groups showed higher TP values than control groups before and after AAA. IPS Empress Direct with Dimanto had higher TP values than other groups (except for IPS Empress Direct with Optidisc); Filtek Z250 with finishing/polishing groups showed lower TP values than other groups. Composite type and finishing/polishing systems influenced TP values. Unfinished groups exhibited lower TP values than finished groups. There was no difference in TP values between finishing/polishing systems (Dimanto and OptiDisc).\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46077200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Composites Based on Sustainable Biomass Fiber for Automotive Brake Pads 基于可持续生物质纤维的汽车刹车片复合材料
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5642
C. Pinca-Bretotean, A. Josan, Dr. Arun Kumar Sharma
Biomass fibers are promising materials for applications in modern vehicles. They have great economic and ecological significance, as well as a great potential in the fabrication of composite materials due to the relatively high level of strength and rigidity, low density, availability, recyclability, and biodegradability. In this context, the focus is on the development of automotive brake pad materials from sustainable sources. This work refers to the investigation of the behavior of composite materials made of biomass fibers, phenolic resin, graphite and aluminum oxide. These materials are intended to be used for brake pads on automobiles with moderate efficiency. For this purpose, three recipes of composite materials with different percentages of coconut fiber and wood powder were developed in laboratory. The physical and mechanical as well as functional properties of these composite materials with varying amounts of biomass fibers are examined in this paper. The best performances in this terms was obtained for the composite material containing the highest amount of wood powder and the lowest amount of coconut fiber.
生物质纤维是一种很有前途的现代汽车材料。由于其相对较高的强度和刚度、低密度、可用性、可回收性和生物降解性,它们具有巨大的经济和生态意义,在复合材料的制造中也具有巨大的潜力。在此背景下,重点是开发可持续来源的汽车制动片材料。本文研究了由生物质纤维、酚醛树脂、石墨和氧化铝组成的复合材料的性能。这些材料旨在用于具有中等效率的汽车制动片。为此,在实验室中开发了三种含有不同百分比椰子纤维和木粉的复合材料配方。本文研究了这些含有不同量生物质纤维的复合材料的物理、机械和功能性能。在这方面,含有最高量的木粉和最低量的椰子纤维的复合材料获得了最佳性能。
{"title":"Composites Based on Sustainable Biomass Fiber for Automotive Brake Pads","authors":"C. Pinca-Bretotean, A. Josan, Dr. Arun Kumar Sharma","doi":"10.37358/mp.23.1.5642","DOIUrl":"https://doi.org/10.37358/mp.23.1.5642","url":null,"abstract":"\u0000Biomass fibers are promising materials for applications in modern vehicles. They have great economic and ecological significance, as well as a great potential in the fabrication of composite materials due to the relatively high level of strength and rigidity, low density, availability, recyclability, and biodegradability. In this context, the focus is on the development of automotive brake pad materials from sustainable sources. This work refers to the investigation of the behavior of composite materials made of biomass fibers, phenolic resin, graphite and aluminum oxide. These materials are intended to be used for brake pads on automobiles with moderate efficiency. For this purpose, three recipes of composite materials with different percentages of coconut fiber and wood powder were developed in laboratory. The physical and mechanical as well as functional properties of these composite materials with varying amounts of biomass fibers are examined in this paper. The best performances in this terms was obtained for the composite material containing the highest amount of wood powder and the lowest amount of coconut fiber.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41882088","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on Mechanical Properties and Fracture Mechanisms of Lignin Fiber/epoxy Resin Composites 木质素纤维/环氧树脂复合材料的力学性能及断裂机理研究
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5640
Wu Zhe, Wang Qingnan, Zhao Shuai, Zhang Yang, Xue Bo
Lignin fiber/epoxy resin compositeused for energy absorbing was prepared by atmospheric stirring method. Quasi-static compressive mechanics tests were implemented by using the electronic universal mechanics tester (WDW-100KN) under ambient conditions to analyze the compressing behavior of the matrix material and composite at the strain rate of 10-2s-1 .Scanning electron microscope (SEM) was used to observe the microstructure of the composite after quasi-static compression damage. The results showed that when the ratio of epoxy resin and curing agent was 3:1, the internal structure of the matrix material was more uniform with smoother cross-section, which represented better mechanical properties. It was found that the addition of lignin fiber changed the compression characteristics of the matrix material, resulting in a strengthening stage appeared. At the same time, when the lignin fiber content was 2% or 3%, the composite could absorb more impact energy and delay crack generation, which met the performance requirement of energy absorbing materials.
采用常压搅拌法制备了木质素纤维/环氧树脂复合吸能材料。采用电子万能力学试验机(WDW-100KN)在环境条件下进行了准静态压缩力学试验,分析了基体材料和复合材料在10-2s-1应变速率下的压缩行为。采用扫描电子显微镜(SEM)观察了复合材料准静态压缩损伤后的微观结构。结果表明,当环氧树脂与固化剂的比例为3:1时,基体材料的内部结构更加均匀,截面更光滑,力学性能更好。研究发现,木质素纤维的加入改变了基体材料的压缩特性,出现了强化阶段。同时,当木质素纤维含量为2%或3%时,复合材料可以吸收更多的冲击能量,延缓裂纹的产生,满足吸能材料的性能要求。
{"title":"Study on Mechanical Properties and Fracture Mechanisms of Lignin Fiber/epoxy Resin Composites","authors":"Wu Zhe, Wang Qingnan, Zhao Shuai, Zhang Yang, Xue Bo","doi":"10.37358/mp.23.1.5640","DOIUrl":"https://doi.org/10.37358/mp.23.1.5640","url":null,"abstract":"\u0000Lignin fiber/epoxy resin compositeused for energy absorbing was prepared by atmospheric stirring method. Quasi-static compressive mechanics tests were implemented by using the electronic universal mechanics tester (WDW-100KN) under ambient conditions to analyze the compressing behavior of the matrix material and composite at the strain rate of 10-2s-1 .Scanning electron microscope (SEM) was used to observe the microstructure of the composite after quasi-static compression damage. The results showed that when the ratio of epoxy resin and curing agent was 3:1, the internal structure of the matrix material was more uniform with smoother cross-section, which represented better mechanical properties. It was found that the addition of lignin fiber changed the compression characteristics of the matrix material, resulting in a strengthening stage appeared. At the same time, when the lignin fiber content was 2% or 3%, the composite could absorb more impact energy and delay crack generation, which met the performance requirement of energy absorbing materials.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49237495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Starch Modified Tough Biocompatible Polyurethane/acrylamide bio Composites: Physicochemical Properties and Biodegradation Studies 淀粉改性韧性生物相容性聚氨酯/丙烯酰胺生物复合材料:理化性质及生物降解研究
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5649
Jeevitha Vedaiyan, Ravichandran Kandaswamy, Lynda Merlin Dasaien
Biodegradable bio composites with potential applications in medical implants were prepared with starch content by in situ polymerization technique using polyurethane prepolymers. (PU) and acrylamide (AAM) monomers. The structure and properties of bio composites were evaluated. FT-IR spectroscopy showed bonding between N=C=O functional group terminated polyurethanes confirmed improved compatibility of prepolymers, AAM, starch and bio composites. The DSC data are the glass transition (Tg) of the bio composite and ordinary polyacrylamide (PAAM) network. By incorporating starch and polyurethane in the form of an interpenetrating network into a polyacrylamide network, mechanical and thermal properties of bio composites due to higher crosslink density given by hard segment content. We studied the swelling behavior of both bio composites and individual PAAM networks under different pH conditions to validate their biocompatibility and potential use in biomedicine setting. The hydrolytic stability of biocomposites and PAAM networks was investigated using phosphate buffer. Hydrolytic stability of biocomposites was found to be higher comparison with PAAM network. Morphological analysis of the samples showed uniform distribution and good interfacial adhesion. Improves sample biodegradability it was revealed by the soil runoff test.
以聚氨酯预聚物为原料,采用原位聚合技术以淀粉含量为原料,制备了具有潜在医用植入物应用前景的生物降解复合材料。(PU)和丙烯酰胺(AAM)单体。对生物复合材料的结构和性能进行了评价。FT-IR光谱显示,N=C=O官能团封端的聚氨酯之间的键合证实了预聚物、AAM、淀粉和生物复合材料的相容性得到改善。DSC数据是生物复合物和普通聚丙烯酰胺(PAAM)网络的玻璃化转变(Tg)。通过将淀粉和聚氨酯以互穿网络的形式结合到聚丙烯酰胺网络中,由于硬链段含量给出了更高的交联密度,生物复合材料的机械和热性能得到了改善。我们研究了生物复合材料和单个PAAM网络在不同pH条件下的溶胀行为,以验证其生物相容性和在生物医学环境中的潜在用途。用磷酸盐缓冲液研究了生物复合材料和PAAM网络的水解稳定性。与PAAM网络相比,生物复合材料的水解稳定性更高。样品的形态分析表明,样品分布均匀,界面附着力好。土壤径流试验表明,提高了样品的生物降解性。
{"title":"Starch Modified Tough Biocompatible Polyurethane/acrylamide bio Composites: Physicochemical Properties and Biodegradation Studies","authors":"Jeevitha Vedaiyan, Ravichandran Kandaswamy, Lynda Merlin Dasaien","doi":"10.37358/mp.23.1.5649","DOIUrl":"https://doi.org/10.37358/mp.23.1.5649","url":null,"abstract":"\u0000Biodegradable bio composites with potential applications in medical implants were prepared with starch content by in situ polymerization technique using polyurethane prepolymers. (PU) and acrylamide (AAM) monomers. The structure and properties of bio composites were evaluated. FT-IR spectroscopy showed bonding between N=C=O functional group terminated polyurethanes confirmed improved compatibility of prepolymers, AAM, starch and bio composites. The DSC data are the glass transition (Tg) of the bio composite and ordinary polyacrylamide (PAAM) network. By incorporating starch and polyurethane in the form of an interpenetrating network into a polyacrylamide network, mechanical and thermal properties of bio composites due to higher crosslink density given by hard segment content. We studied the swelling behavior of both bio composites and individual PAAM networks under different pH conditions to validate their biocompatibility and potential use in biomedicine setting. The hydrolytic stability of biocomposites and PAAM networks was investigated using phosphate buffer. Hydrolytic stability of biocomposites was found to be higher comparison with PAAM network. Morphological analysis of the samples showed uniform distribution and good interfacial adhesion. Improves sample biodegradability it was revealed by the soil runoff test.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42419945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Effect of Disinfection Methods on C. Albicans in Three Types of Denture Base Materials 消毒方法对三种义齿基托材料中白色念珠菌的影响
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5641
Gulsah Akyildiz, Z. Duymus, S. Karaoglu, A. Bozdeveci
This study aimed to evaluate the efficacy of disinfectant solutions on Candida albicans (C. albicans) for different types of denture materials. A total of 144 specimens (10x10x2 mm) were obtained from three different materials: autopolymerized acrylic resin, heat-cured acrylic resin, and hard relining material (n = 6). Three disinfectant solutions were used: 100% white vinegar, 2% chlorhexidine digluconate (Saver) and denture cleaning tablets (Corega). The specimens were placed on Eliza plates and 1.5 mL of Yeast Extract Peptone (YPD) was added to each well. Then, 30�L of candida culture was added to the wells. Next, the specimens were incubated at 37�C at 80 rpm for 48 h. Disinfectants were added to the Eliza plates. For all specimens, the disinfectants were replaced with 2 mL of sterile water and kept at 100 rpm for 30 min. Then, 0.1 mL of the liquid was taken and inoculated into the pads containing YPD medium. After incubation, the candida colony growth on the pads was measured. Scanning electron microscope (SEM) images were taken from randomly selected specimens from each group. Statistically significant differences (𝑃 [ 0.05) were found between the disinfectant method groups and the control group for the three types of denture materials. The 2% chlorhexidine gluconate (Saver) disinfectant was the most effective for C. Albicans ATCC 60193 and oral isolate of C. Albicans for all three of the tested denture materials. The effect of cleaning of tabs (Corega) and white vinegar was found to be similar.
本研究旨在评价消毒液对不同类型义齿材料的白色念珠菌(C.白色念珠菌)的防治效果。采用自聚合丙烯酸树脂、热固化丙烯酸树脂和硬质衬里材料(n = 6),共获得144例(10x10x2 mm)标本。消毒溶液为100%白醋、2%二光酸氯己定(Saver)和Corega义齿清洁片。将标本置于elisa板上,每孔加入酵母提取物蛋白胨(YPD) 1.5 mL。然后在孔中加入30 μ L念珠菌培养液。接下来,将标本在37℃、80 rpm下孵育48 h。在elisa板上添加消毒剂。所有标本将消毒剂更换为无菌水2 mL,以100 rpm保持30 min,取0.1 mL液接种于含有YPD培养基的卫生巾中。孵育后,测定菌垫上的菌落生长情况。随机抽取各组标本进行扫描电镜(SEM)成像。三种义齿材料消毒方法组与对照组比较,差异有统计学意义(p < 0.05)。2%葡萄糖酸氯己定(Saver)消毒剂对三种义齿材料的白色念珠菌ATCC 60193和口腔分离菌最有效。研究发现,清洁标签(Corega)和白醋的效果相似。
{"title":"The Effect of Disinfection Methods on C. Albicans in Three Types of Denture Base Materials","authors":"Gulsah Akyildiz, Z. Duymus, S. Karaoglu, A. Bozdeveci","doi":"10.37358/mp.23.1.5641","DOIUrl":"https://doi.org/10.37358/mp.23.1.5641","url":null,"abstract":"\u0000This study aimed to evaluate the efficacy of disinfectant solutions on Candida albicans (C. albicans) for different types of denture materials. A total of 144 specimens (10x10x2 mm) were obtained from three different materials: autopolymerized acrylic resin, heat-cured acrylic resin, and hard relining material (n = 6). Three disinfectant solutions were used: 100% white vinegar, 2% chlorhexidine digluconate (Saver) and denture cleaning tablets (Corega). The specimens were placed on Eliza plates and 1.5 mL of Yeast Extract Peptone (YPD) was added to each well. Then, 30�L of candida culture was added to the wells. Next, the specimens were incubated at 37�C at 80 rpm for 48 h. Disinfectants were added to the Eliza plates. For all specimens, the disinfectants were replaced with 2 mL of sterile water and kept at 100 rpm for 30 min. Then, 0.1 mL of the liquid was taken and inoculated into the pads containing YPD medium. After incubation, the candida colony growth on the pads was measured. Scanning electron microscope (SEM) images were taken from randomly selected specimens from each group. Statistically significant differences (𝑃 [ 0.05) were found between the disinfectant method groups and the control group for the three types of denture materials. The 2% chlorhexidine gluconate (Saver) disinfectant was the most effective for C. Albicans ATCC 60193 and oral isolate of C. Albicans for all three of the tested denture materials. The effect of cleaning of tabs (Corega) and white vinegar was found to be similar.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44759912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Use of Panels Made from Plastic Waste in Thermal Insulation 用塑料废料制成的板作隔热材料
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5650
I. Antypas, T. Savostina
The materials of the given article are devoted to the problem solution associated with one of the processing plastic waste methods by adding various fillers in order to obtain the final product for the thermal insulation materials manufacture. The researches were conducted using the UPR (unsaturated polyester resin) samples made of EPS (expanded polystyrene) plastic waste and crushed recycled polyethylene from greenhouse film waste with various types of wood waste from carpentry workshops. The tests have revealed that when EPS is added to the unsaturated polyester mixtures, the EPS thermal conductivity coefficient decreases with a slight decrease in density, which gives the wide opportunities to use EPS waste as an additive for UPR and expands the ways of its potential industrial application, and the addition of styrene to the compositions containing 10% of styropor causes a clear decrease in thermal conductivity characteristics and a slight decrease in the density of these mixtures. The values of the thermal conductivity coefficient and the density of the low-density polyethylene material increase with the wood powder percentage raising used as an organic filler.
本文的材料致力于通过添加各种填料来解决与处理塑料废料的方法之一相关的问题,以获得用于保温材料制造的最终产品。以发泡聚苯乙烯(EPS)塑料废弃物和大棚膜废弃物再生聚乙烯粉碎后的UPR(不饱和聚酯树脂)样品与木工车间各类木材废弃物进行了研究。试验结果表明,在不饱和聚酯混合物中加入EPS后,其导热系数随密度的轻微降低而降低,这为EPS废渣作为UPR添加剂提供了广阔的机会,扩大了其潜在的工业应用途径。在含有10%聚苯乙烯的组合物中加入苯乙烯会导致这些混合物的导热特性明显下降,密度略有下降。作为有机填料的低密度聚乙烯材料的导热系数和密度随木粉含量的增加而增大。
{"title":"Use of Panels Made from Plastic Waste in Thermal Insulation","authors":"I. Antypas, T. Savostina","doi":"10.37358/mp.23.1.5650","DOIUrl":"https://doi.org/10.37358/mp.23.1.5650","url":null,"abstract":"\u0000The materials of the given article are devoted to the problem solution associated with one of the processing plastic waste methods by adding various fillers in order to obtain the final product for the thermal insulation materials manufacture. The researches were conducted using the UPR (unsaturated polyester resin) samples made of EPS (expanded polystyrene) plastic waste and crushed recycled polyethylene from greenhouse film waste with various types of wood waste from carpentry workshops. The tests have revealed that when EPS is added to the unsaturated polyester mixtures, the EPS thermal conductivity coefficient decreases with a slight decrease in density, which gives the wide opportunities to use EPS waste as an additive for UPR and expands the ways of its potential industrial application, and the addition of styrene to the compositions containing 10% of styropor causes a clear decrease in thermal conductivity characteristics and a slight decrease in the density of these mixtures. The values of the thermal conductivity coefficient and the density of the low-density polyethylene material increase with the wood powder percentage raising used as an organic filler.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45125484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Biomaterials Used in the Prosthetics of Facial Fractures 生物材料在面部骨折修复中的应用
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-05 DOI: 10.37358/mp.23.1.5645
F. Anghelina, Alina Andreea Mitroi, E. Ciucă, Lavinia Toma Tumbar, A. Boicea, L. Anghelina, Cătălina Voiosu, A. Camen, R. Hainăroșie
The etiology of maxillofacial injuries is represented by car accidents, human aggression, and work-related trauma. Trauma to the maxillofacial area requires a complex treatment that involves functional and aesthetic rehabilitation. To restore the functionality of the damaged areas, a correct surgical technique is necessary along with the use of the ideal prostheses for a better reconstruction. Along with the development and improvement of facial fractures osteosynthesis techniques, an attempt was made to identify the right material to complete these surgical methods. We analyze in this paperwork the benefits of polyetheretherketone-based materials in the prosthetics of different facial fractures in comparison with other materials like titanium.
颌面部损伤的病因以车祸、人类攻击和工伤为代表。颌面部创伤需要复杂的治疗,包括功能和美学康复。为了恢复受损区域的功能,正确的手术技术是必要的,同时使用理想的假体进行更好的重建。随着面部骨折接骨技术的发展和改进,人们试图确定合适的材料来完成这些手术方法。在这篇论文中,我们分析了聚醚醚酮基材料在不同面部骨折修复术中与钛等其他材料相比的优势。
{"title":"Biomaterials Used in the Prosthetics of Facial Fractures","authors":"F. Anghelina, Alina Andreea Mitroi, E. Ciucă, Lavinia Toma Tumbar, A. Boicea, L. Anghelina, Cătălina Voiosu, A. Camen, R. Hainăroșie","doi":"10.37358/mp.23.1.5645","DOIUrl":"https://doi.org/10.37358/mp.23.1.5645","url":null,"abstract":"\u0000The etiology of maxillofacial injuries is represented by car accidents, human aggression, and work-related trauma. Trauma to the maxillofacial area requires a complex treatment that involves functional and aesthetic rehabilitation. To restore the functionality of the damaged areas, a correct surgical technique is necessary along with the use of the ideal prostheses for a better reconstruction. Along with the development and improvement of facial fractures osteosynthesis techniques, an attempt was made to identify the right material to complete these surgical methods. We analyze in this paperwork the benefits of polyetheretherketone-based materials in the prosthetics of different facial fractures in comparison with other materials like titanium.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":" ","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46442999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Materiale Plastice
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1