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The Study of the Glass Fiber Surface Treatment Effect on the Base Strength Characteristics of the Composite Material 玻璃纤维表面处理对复合材料基本强度特性影响的研究
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-05 DOI: 10.37358/mp.23.4.5695
Imad Rezakalla Antypas, A. Dyachenko
This article examines the impact of surface treatment of glass fibers on the strength of a composite material with an unsaturated polyester polymer matrix reinforced with glass fibers. The strength tests conducted include tensile, bending, and impact strength tests, as well as weight loss measurements. The research was conducted in two stages: in the first stage, the time was kept constant while the fibers were treated with varying concentrations of an alkaline NaOH solution; in the second stage, the concentration was fixed and the variable parameter was the treatment time. The results of the study indicate that surface treatment of glass fibers significantly improves their adhesion to the matrix materials, resulting in improved strength test results for the composite samples. The impact resistance, bending resistance, and tensile strength values all increased compared to the reference samples. However, certain changes in the individual parameters of fiber processing led to a slight decrease in tensile strength when it fell below the reference values. Additionally, it was observed that as the concentration of the solution and treatment time increased, the weight of the fibers decreased.
本文研究了玻璃纤维表面处理对玻璃纤维增强不饱和聚酯聚合物基体复合材料强度的影响。所进行的强度测试包括拉伸、弯曲和冲击强度测试以及失重测量。研究分两个阶段进行:在第一阶段,用不同浓度的碱性 NaOH 溶液处理纤维时,时间保持不变;在第二阶段,浓度固定,可变参数是处理时间。研究结果表明,玻璃纤维的表面处理可显著提高其与基体材料的粘附性,从而改善复合材料样品的强度测试结果。与参考样品相比,抗冲击性、抗弯强度和拉伸强度值均有所提高。然而,纤维加工过程中个别参数的某些变化导致拉伸强度在低于参考值时略有下降。此外,还观察到随着溶液浓度和处理时间的增加,纤维的重量也在减少。
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引用次数: 0
Surface-modified Polyurethane Structures Used as a Carrier for Simvastatin for the Possible Treatment of Atherosclerosis in Patients with Hepatic Arterial Variations 表面改性聚氨酯结构用作辛伐他汀的载体,可用于治疗肝动脉变异患者的动脉粥样硬化症
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-05 DOI: 10.37358/mp.23.4.5690
Laura Andreea Ghenciu (Bolintineanu), Sorin Lucian Bolintineanu, F. Borcan, D. Zăhoi
Simvastatin, a lipid-lowering drug from the statins group, is used in various dyslipidemias. It appears like a very useful medication to decrease the level of total cholesterol, of the low-density-lipids and triglycerides from blood, but it is well-known that the administration of statins have serious side effects, like muscle pain and weakness that can lead to kidney damage, rash on the skin and inflammation of the joints and of the blood vessels, shortness of breath, inflammation of the liver, dark urine, anemia, memory and sleep disorders, and problems in performing the sexual act. The main aims of this research were to obtain and to characterize a polymer carrier used for the transmembrane transfer of simvastatin. Hepatic arterial variations are common knowledge and it has been studied that these types of arteries have a narrower endoluminal diameter, therefore the patients may be prone to develop atherosclerosis more rapid that the ones with standard hepatic arterial patterns. The samples based on polyurethane structures with and respectively without the active agent were synthesized and characterized by measurements of pH, encapsulation efficacy, cumulative drug release in a simulated body fluid, scanning electron microscopy, Zetasizer measurements, thermal stability, cytotoxicity assay, and non-invasive skin irritation assessment. The results indicate the obtaining of heterogenous polyurethane structures with mean sizes between 80-440 nm and neutral pH, that have a good stability against the agglomeration tendency and a prolonged release rate. The results on structures cytotoxicity and their non-irritative potential are important clues that can be used in further clinical investigations.
辛伐他汀是他汀类药物中的一种降脂药物,可用于各种血脂异常。它似乎是一种非常有用的药物,可以降低血液中的总胆固醇、低密度脂蛋白和甘油三酯的水平,但众所周知,服用他汀类药物会产生严重的副作用,如肌肉疼痛和无力,可能导致肾脏损伤、皮肤出疹、关节和血管发炎、呼吸急促、肝脏发炎、深色尿液、贫血、记忆力和睡眠障碍以及性行为问题。这项研究的主要目的是获得一种用于辛伐他汀跨膜转移的聚合物载体并确定其特性。肝动脉变异是常识,研究表明,这类动脉的内腔直径较窄,因此患者可能比标准肝动脉模式的患者更容易迅速发生动脉粥样硬化。我们合成了含活性剂和不含活性剂的聚氨酯结构样品,并通过测量 pH 值、封装功效、模拟体液中的累积药物释放量、扫描电子显微镜、Zetasizer 测量、热稳定性、细胞毒性检测和无创皮肤刺激性评估对样品进行了表征。结果表明,获得的异质聚氨酯结构平均尺寸在 80-440 纳米之间,pH 值为中性,具有良好的稳定性,不会出现团聚趋势,且释放速率较长。该结构的细胞毒性及其无刺激潜力是重要的线索,可用于进一步的临床研究。
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引用次数: 0
Effect of Process Parameters on the Hardness of 3D-printed Thermoplastic Polyurethane that Includes Foaming Agent 工艺参数对含发泡剂的 3D 打印热塑性聚氨酯硬度的影响
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-05 DOI: 10.37358/mp.23.4.5694
Mariana Cristiana Iacob, Diana Popescu, F. Baciu
Recent progress in Material Extrusion-based Additive Manufacturing (MEX) has introduced active foaming agents in filaments composition, thus allowing for the tuning, by various process parameters, the hardness and the mechanical behavior of 3D-printed parts. In case of thermoplastic polyurethane (TPU) filaments, these advances significantly broaden the range of applications, particularly in the domains of comfort and orthotics (wrist-hand orthoses, insoles), offering the dual benefits of design flexibility inherent in MEX and the comfort of lightweight and customizable structures. However, the field is still in its early stages, with only a limited number of research efforts dedicated to characterizing these novel materials. In this context, this study is focused on determining the influence of printing temperature (190�C, 220�C, 240�C), infill density (25%, 35%, 45%) and infill pattern (honeycomb, gyroid) over the hardness of cylindrical specimens made of Colorfabb varioShore TPU. A comprehensive methodology of calibration is also presented as mandatory for obtaining good quality and accurate products by establishing correlations between flow rate and printing temperatures. The findings showed that the printing temperature is the most relevant factor impacting the hardness of varioShore TPU prints. At a printing temperature of 190�C, which corresponds to less foamed prints, the honeycomb infill yielded higher hardness compared to the gyroid infill, but the difference was not significant. Also, at 220�C and 240�C, the mean values of hardness remain relatively consistent, regardless of infill density and pattern.
基于材料挤压的增材制造(MEX)技术的最新进展在长丝成分中引入了活性发泡剂,从而可以通过各种工艺参数调整 3D 打印部件的硬度和机械性能。就热塑性聚氨酯(TPU)长丝而言,这些进步大大拓宽了其应用范围,特别是在舒适性和矫形领域(腕部矫形器、鞋垫),提供了 MEX 固有的设计灵活性以及轻质和可定制结构的舒适性的双重优势。然而,该领域仍处于早期阶段,只有有限的研究工作致力于表征这些新型材料。在此背景下,本研究的重点是确定打印温度(190℃、220℃、240℃)、填充密度(25%、35%、45%)和填充模式(蜂窝状、陀螺状)对由 Colorfabb varioShore TPU 制成的圆柱形试样硬度的影响。此外,还介绍了一套全面的校准方法,通过建立流速与印刷温度之间的相关性,获得优质、精确的产品。研究结果表明,印刷温度是影响 varioShore 热塑性聚氨酯印刷品硬度的最重要因素。在 190 摄氏度的印刷温度下(相当于较少发泡的印刷品),蜂窝状填充物的硬度高于陀螺状填充物,但差异并不显著。此外,在 220C 和 240C 温度下,无论填充密度和图案如何,硬度的平均值都保持相对一致。
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引用次数: 0
The Development of New Nanoplatforms Based on Albumin and Graphene Oxide for Aticancer Therapy 开发基于白蛋白和氧化石墨烯的新型癌症治疗纳米平台
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-05 DOI: 10.37358/mp.23.4.5682
Elena Iuliana Bîru, Andrei Sarbu, H. Iovu
This study focuses on the covalent functionalization of the carboxylated graphene oxide layers with human serum albumin for developing new nanoplatforms capable of efficient drug loading and release for antitumor therapy. Thus, new GO-HSA conjugates have been developed and their interactions with methotrexate (MTX) molecules were evidenced through FT-IR, UV-Vis and Raman spectroscopy. The cumulative in vitro release profiles of MTX drug from GO-HSA-MTX nanoplatforms were analyzed through UV-Vis spectroscopy showing a more controlled release behavior of MTX drug under acidic conditions that simulate the tumor microenvironment demonstrating the potential use of GO-HSA-MTX as antitumoral nanocarriers.
本研究的重点是将羧基氧化石墨烯层与人血清白蛋白共价官能化,从而开发出能够高效负载和释放药物的新型纳米平台,用于抗肿瘤治疗。因此,我们开发出了新的 GO-HSA 共轭物,并通过傅立叶变换红外光谱、紫外可见光谱和拉曼光谱证实了它们与甲氨蝶呤(MTX)分子的相互作用。通过紫外可见光谱分析了MTX药物从GO-HSA-MTX纳米平台的体外累积释放曲线,结果表明在模拟肿瘤微环境的酸性条件下,MTX药物的释放行为更加可控,这表明GO-HSA-MTX具有作为抗肿瘤纳米载体的潜力。
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引用次数: 0
CONTENTS 4 / 2023 内容 4 / 2023
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-05 DOI: 10.37358/mp.23.4.5681
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引用次数: 0
Preliminary Hybrid Joint Analysis for Aircraft Structures 飞机结构的初步混合接头分析
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-05 DOI: 10.37358/mp.23.4.5687
Raul Cormoş, C. Neagoe, Miruna Ciolca
Metal-composite joints, or hybrid joints are prevalent in aerospace structures due to their high strength and low weight. Such structures are usually found in areas where because of the load configuration, the use of composite materials is possible. Thereby, the analysis of such areas needs to consider both components, the metallic and the composite part. In this paper a hybrid joint is analyzed, consisting of a metallic stiffener, a multilayered honeycomb composite material, and joining fasteners, which constitute the joint between the isotropic and orthotropic materials. The present article has two main purposes: the first is to illustrate a pre-design procedure aimed to evaluate the load-carrying capability of a hybrid joint structure, thereby giving an estimate if the structure can withstand the given loading conditions; the second purpose is to present two types of finite element modeling techniques, one that captures the real geometric structure of the composite material and another which uses a simplified equivalent model, based on the desired level of evaluation of the composite material part. A comparison between the two models is made, highlighting the advantages and disadvantages of the two forms of evaluations. For the metallic parts - stiffener and fasteners, both static and fatigue analyses were performed, as fatigue failure represents the common service failure mode for this type of structural components.
金属复合材料接头或混合接头因其强度高、重量轻而在航空航天结构中十分普遍。由于负载配置的原因,此类结构通常出现在可以使用复合材料的区域。因此,对这类区域的分析需要同时考虑金属和复合材料两个部分。本文分析了一种混合连接,它由金属加劲件、多层蜂窝复合材料和连接紧固件组成,构成了各向同性材料和正交材料之间的连接。本文有两个主要目的:第一个目的是说明一种预设计程序,旨在评估混合连接结构的承载能力,从而估计该结构能否承受给定的载荷条件;第二个目的是介绍两种有限元建模技术,一种是捕捉复合材料的真实几何结构,另一种是根据复合材料部分的预期评估水平,使用简化的等效模型。对这两种模型进行了比较,强调了两种评估形式的优缺点。对于金属部件--加强筋和紧固件--进行了静态和疲劳分析,因为疲劳失效是这类结构部件的常见失效模式。
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引用次数: 0
An Analysis of Water Sorption of Some Composites Used in Dentistry 几种牙科用复合材料的吸水性分析
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-03 DOI: 10.37358/mp.23.2.5663
Özlem Akyüz Bege�, Hakan Bege�
This study aimed to investigate the water sorption levels of 3 different condensable bulk fill composites, two flowable bulk fill composites, two microhybrid composites, one nanofilled composite, and one nanohybrid composite material polymerized with the same beam device on the 14th and 30th days.We evaluated nine different composite materials. The materials were prepared as cylindrical blocks (n=7) with a diameter of 7 mm and a thickness of 2 mm and polymerized. Each sample was kept in distilled water for specified times and measured by the ISO 4049 method.We used The Kruskal-Wallis test to compare more than two independent groups where numerical variables had no normal distribution. The Dwass-Steel-Critchlow-Fligner test evaluated differences between the groups if the non-parametric tests were applied. We used The Wilcoxon test to compare the numerical variables without normal distribution (water sorption values in the 14th and 30th-day measurements for each cement material).For water sorption, there was no statistically significant difference between the water sorption values of the resin composite materials on the 14th and 30th days. No statistically significant difference was found in comparing water sorption values between the 14th and 30th measurements for each resin composite material. There is a need for more extended studies by keeping the conditions constant for the evaluated composites and for bulk fill composites to be evaluated with 4mm samples.
本研究旨在研究在第14天和第30天用相同的束装置聚合的3种不同的可冷凝体填充复合材料、两种可流动体填充复合物、两种微杂化复合材料、一种纳米填充复合材料和一种纳米杂化复合材料的吸水水平。我们评估了九种不同的复合材料。将材料制备为直径为7mm、厚度为2mm的圆柱形块体(n=7)并聚合。每个样品在蒸馏水中保存指定时间,并通过ISO 4049方法进行测量。我们使用Kruskal-Wallis检验来比较两个以上数值变量没有正态分布的独立组。如果采用非参数检验,则Dwass Steel Critchlow Fligner检验评估了各组之间的差异。我们使用Wilcoxon检验来比较没有正态分布的数值变量(每种水泥材料在第14天和第30天测量的吸水值)。对于吸水性,树脂复合材料在第十四天和第三十天的吸水值之间没有统计学上的显著差异。在比较每种树脂复合材料的第14次和第30次测量之间的吸水值时,没有发现统计学上的显著差异。需要通过保持评估的复合材料和用4mm样品评估的散装填充复合材料的条件不变来进行更广泛的研究。
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引用次数: 0
Application of the Six Sigma Method to Improve Vulcanization Times in Automotive Tires 六西格玛方法在提高汽车轮胎硫化时间中的应用
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-03 DOI: 10.37358/mp.23.2.5660
Ion Durbacă, Nicoleta Sporea, G. Tomescu, A. Dumitrescu
The present paper considers the use of the results of the evaluations carried out by applying the Six Sigma statistical method to improve the vulcanization times of elastomeric composites on the external manufacturing cycle of several size types of car tires. This statistical approach aims to verify the distribution of the measured values of the external vulcanization times between the normal specification limits to optimize them and improve the performance, efficiency, and quality of the automotive tire vulcanization processes. Through the analysis carried out, the operations that caused delays and defects were identified, a program of corrective measures was carried out and after its execution, the fulfillment of the purpose was verified, namely the optimization of external vulcanization times and reducing the number of faulty tires. The new measured values of the vulcanization times were within the normal limits of the imposed specifications (LSS = 2.5). This situation corresponds to achieving a maximum level of performance and represents the successful completion of the quality improvement project.
本文考虑利用应用六西格玛统计方法进行的评价结果来改善几种尺寸类型的汽车轮胎的外部制造周期中弹性复合材料的硫化时间。这种统计方法的目的是验证外硫化时间测量值在正常规格限值之间的分布,以优化外硫化时间,提高汽车轮胎硫化工艺的性能、效率和质量。通过分析,找出造成延误和缺陷的工序,制定整改措施方案,并在实施后验证了优化外硫化次数和减少故障轮胎数量的目的的实现。新的硫化时间测量值在规定规范的正常范围内(LSS = 2.5)。这种情况对应于达到最高绩效水平,并代表质量改进项目的成功完成。
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引用次数: 0
About Some Mechanical Properties Regarding Sandwich Samples Reinforced with Poplar Strips and the Core from Crushed Corn Cobs with Hybrid Dammar-Based Matrix 用混合Dammar基基质研究杨条和玉米棒芯增强夹层样品的一些力学性能
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-03 DOI: 10.37358/mp.23.2.5666
A. I. Rădoi, M. Stănescu, D. Bolcu, C. Miriţoiu, A. Rosca, M. Bogdan, C. Nicolicescu
In this research some composite materials built in sandwich type style are studied. The lower and upper layers, that reinforce the samples, are made from poplar strips. The core is made from crushed corn cob and the adhesion of all parts (layers and core) is made by using hybrid resins based on a combination from dammar resin and the synthetic acrylic one (with its hardener). The static and dynamic mechanical behaviour by testing the samples to tensile and bending were studied. Two types of hybrid resins were used: one abbreviated as type B with the percentage of 60% dammar and 40% acrylic resin with hardener and one abbreviated as type C with the percentage of 65% dammar and 35% acrylic resin with hardener. A general conclusion from this study it was: the mechanical properties decrase with the dammar percentage increase. This fact can be explained by the decreased mechanical properties of the natural dammar resin compared to the synthetic acylic on
在本研究中,研究了一些三明治式的复合材料。加固样品的下层和上层由白杨条制成。芯部由粉碎的玉米芯制成,所有零件(层和芯部)的粘合都是通过使用混合树脂制成的,该混合树脂基于达玛树脂和合成丙烯酸树脂(及其硬化剂)的组合。通过对试样的拉伸和弯曲试验,研究了试样的静态和动态力学行为。使用了两种类型的混合树脂:一种缩写为B型,具有60%的dammar和40%的丙烯酸树脂与硬化剂的百分比,另一种简写为C型,具有65%的dammar,35%的丙烯酸树脂和硬化剂的比例。本研究得出的一般结论是:力学性能随着达玛百分比的增加而下降。与合成丙烯酸树脂相比,天然达玛树脂的机械性能下降可以解释这一事实
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引用次数: 0
Effect of Abrasive Water Jet Parameters on the Drilling of Aluminum Foam Sandwiched with Glass Fiber Polymer Composites 磨料水射流参数对泡沫铝夹层玻璃纤维聚合物复合材料钻孔的影响
IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-03 DOI: 10.37358/mp.23.2.5658
Madhan Kumar Subramani, Sivakumar Krishnamurthy, Chandradass Jeyaseelan
To attain good geometric shape and size, machining of high-strength metal Fiber laminate becomes inevitable in the field of automotive industries. In this research, aluminum foam sandwiched with glass fiber reinforced polymer (GFRP) composites fabricated using a hand layup process. The glass Fiber composite was fabricated using aluminum foam with a thickness of 1 mm. The effect of abrasive water jet parameters such as pressure (P), stand-off distance (L), and nozzle diameter (D) on material removal rate (MRR) and Kerf angle (Ka) and Surface roughness were investigated. The results were compared without aluminum foam composites. Glass fiber composites with aluminum foam reduced the kerf angle by 44.18 %, and surface roughness (Ra) by 41.77 % as compared with glass fiber composites without aluminum foam. From the investigation, it was noticed that maximum pressure (220 Bar) and minimum stand-off distance (1mm) were optimum parameters for reducing the kerf angle and surface roughness. Also, Optical images of the hole were analyzed for surface quality.
为了获得良好的几何形状和尺寸,高强度金属纤维层压板的加工成为汽车工业领域的必然选择。在本研究中,泡沫铝夹在玻璃纤维增强聚合物(GFRP)复合材料采用手工叠层工艺。采用厚度为1mm的泡沫铝制备玻璃纤维复合材料。研究了磨料水射流压力(P)、分离距离(L)、喷嘴直径(D)等参数对材料去除率(MRR)、切口角(Ka)和表面粗糙度的影响。结果与不含泡沫铝的复合材料进行了比较。与不含泡沫铝的玻璃纤维复合材料相比,含泡沫铝的玻璃纤维复合材料的切口角减小44.18%,表面粗糙度(Ra)减小41.77%。从调查中可以看出,最大压力(220 Bar)和最小分离距离(1mm)是减小切口角和表面粗糙度的最佳参数。并对孔的光学图像进行了表面质量分析。
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引用次数: 0
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