Part dimensional inaccuracies serve as a barrier from adopting Additive Manufacturing (AM) processes in mass production. Fused Deposition Modeling (FDM) is a thermoplastic based low cost AM process which can create conceptual models, prototypes and end user industrial parts. The current study involves predicting the optimal parameter settings and significant parameter for reduced geometric deviations in printed part using Nylon filament reinforced with 20% carbon fiber. Five input factors such as build orientation, layer thickness, infill density, raster angle and infill pattern have been considered for preparing the experimental layout through taguchi�s mixed fractional factorial design. The changes in length, width and thickness of the printed part from CAD value have been evaluated individually through ANOVA and Signal to Noise Ratio method (Smaller the better). Layer thickness is significant only for variations in length, but build orientation affects both width and thickness dimensions. The geometric deviations are further analyzed using combined multi criteria decision making (MCDM) approaches such as Entropy-CoCoSo and PCA-TOPSIS. The optimal parameter settings obtained for reduced geometric deviations is found to be Flat orientation, 0.1mm layer thickness, 50% infill density, 0� raster angle and cubic infill pattern. Layer thickness is found to be highly significant parameter influencing the geometric deviations subsequently followed by build orientation from both the MCDM methods. The multi response performance index values obtained from Entropy-CoCoSo has been trained using classification algorithms such as decision tree, random forest and Naive Bayes. Naive Bayes algorithm outperformed other methods with highest classification accuracy of 99.4% in a training-testing split ratio of 75:25.
{"title":"Prediction of Optimal Parameter Settings and Significant Parameter for Reduced Geometric Deviations Through Multi Criteria Decision Making and Machine Learning Algorithms","authors":"Subhash Selvaraj, Rajesh P.k.","doi":"10.37358/mp.24.1.5702","DOIUrl":"https://doi.org/10.37358/mp.24.1.5702","url":null,"abstract":"\u0000Part dimensional inaccuracies serve as a barrier from adopting Additive Manufacturing (AM) processes in mass production. Fused Deposition Modeling (FDM) is a thermoplastic based low cost AM process which can create conceptual models, prototypes and end user industrial parts. The current study involves predicting the optimal parameter settings and significant parameter for reduced geometric deviations in printed part using Nylon filament reinforced with 20% carbon fiber. Five input factors such as build orientation, layer thickness, infill density, raster angle and infill pattern have been considered for preparing the experimental layout through taguchi�s mixed fractional factorial design. The changes in length, width and thickness of the printed part from CAD value have been evaluated individually through ANOVA and Signal to Noise Ratio method (Smaller the better). Layer thickness is significant only for variations in length, but build orientation affects both width and thickness dimensions. The geometric deviations are further analyzed using combined multi criteria decision making (MCDM) approaches such as Entropy-CoCoSo and PCA-TOPSIS. The optimal parameter settings obtained for reduced geometric deviations is found to be Flat orientation, 0.1mm layer thickness, 50% infill density, 0� raster angle and cubic infill pattern. Layer thickness is found to be highly significant parameter influencing the geometric deviations subsequently followed by build orientation from both the MCDM methods. The multi response performance index values obtained from Entropy-CoCoSo has been trained using classification algorithms such as decision tree, random forest and Naive Bayes. Naive Bayes algorithm outperformed other methods with highest classification accuracy of 99.4% in a training-testing split ratio of 75:25.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140788877","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zuzana Mitaľová, J. Duplák, Dariana Duplakova, D. Mital, J. Litecká
The biomaterials applicable in dental implantology, or implantology generally, are subject to specific requirements, namely biocompatibility, osseointegration, resistance to fracture/ oxidative degradation/ long-term compressive stress/ hydrolisis in boiling water, suitable morphology, suitable physical properties (including mechanical properties), aesthetics, etc. When selecting a suitable material for dental implants, it is also necessary to consider the patient s current health condition and possible complications when placing titanium implants and alloys. If there is a risk of an allergic reaction or hypersensitivity to any of the components of the metal prosthesis, the placement of a semi-crystalline thermoplastic implant - called polyetheretherketone, abbreviated PEEK - is a possible option. Such a wide range of stiffness means that PEEK formulations can be produced with modulus values similar to cortical bone. PEEK is classified as a High Performance Polymer of polymer pyramide (such as Polysulfones polybutylene terephthalate). PEEK can be applied for dental abutment and dental body. This article summarises basic information on the structure and properties of PEEK polymer, advantages/ disadvantages (compared to metal - titanium restorations), application and general information from the examined field.
{"title":"PEEK-Polymer for Dental Implants: A Concise Review","authors":"Zuzana Mitaľová, J. Duplák, Dariana Duplakova, D. Mital, J. Litecká","doi":"10.37358/mp.24.1.5713","DOIUrl":"https://doi.org/10.37358/mp.24.1.5713","url":null,"abstract":"\u0000The biomaterials applicable in dental implantology, or implantology generally, are subject to specific requirements, namely biocompatibility, osseointegration, resistance to fracture/ oxidative degradation/ long-term compressive stress/ hydrolisis in boiling water, suitable morphology, suitable physical properties (including mechanical properties), aesthetics, etc. When selecting a suitable material for dental implants, it is also necessary to consider the patient s current health condition and possible complications when placing titanium implants and alloys. If there is a risk of an allergic reaction or hypersensitivity to any of the components of the metal prosthesis, the placement of a semi-crystalline thermoplastic implant - called polyetheretherketone, abbreviated PEEK - is a possible option. Such a wide range of stiffness means that PEEK formulations can be produced with modulus values similar to cortical bone. PEEK is classified as a High Performance Polymer of polymer pyramide (such as Polysulfones polybutylene terephthalate). PEEK can be applied for dental abutment and dental body. This article summarises basic information on the structure and properties of PEEK polymer, advantages/ disadvantages (compared to metal - titanium restorations), application and general information from the examined field.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140765620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. Enache, Ioana-Madalina Cristina, O. Chivu, Ileana Mates, Elena Ionita, Gabriel Geambasu
Additive technologies are continually evolving and are crucial in numerous industries, including medical, aerospace, and automotive, but they can also play an important role in the prototyping phase. Due to additive manufacturing, amateurs and enthusiasts can construct simple projects as well as large projects with specialized usage in specific applications. When it comes to complex pieces, traditional manufacturing technologies such as milling, chipping, drilling, and so on have specific constraints, often need even additional production processes to complete the item. All of these constraints can be solved with additive technologies. This work investigates Fused Deposit Modeling (FDM) printing of many specimens with varying properties in order to analyze PLA (Poly Lactic Acid) material behavior following tensile testing. The collected findings will be analyzed in order to determine the specimens with the most significant behavior according on the modified parameters.
{"title":"The Influence of 3D Printing Parameters on the Mechanical Behavior of PLA","authors":"I. Enache, Ioana-Madalina Cristina, O. Chivu, Ileana Mates, Elena Ionita, Gabriel Geambasu","doi":"10.37358/mp.24.1.5704","DOIUrl":"https://doi.org/10.37358/mp.24.1.5704","url":null,"abstract":"\u0000Additive technologies are continually evolving and are crucial in numerous industries, including medical, aerospace, and automotive, but they can also play an important role in the prototyping phase. Due to additive manufacturing, amateurs and enthusiasts can construct simple projects as well as large projects with specialized usage in specific applications. When it comes to complex pieces, traditional manufacturing technologies such as milling, chipping, drilling, and so on have specific constraints, often need even additional production processes to complete the item. All of these constraints can be solved with additive technologies. This work investigates Fused Deposit Modeling (FDM) printing of many specimens with varying properties in order to analyze PLA (Poly Lactic Acid) material behavior following tensile testing. The collected findings will be analyzed in order to determine the specimens with the most significant behavior according on the modified parameters.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140791921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This paper describes the use of video and digital image processing in investigation of the impact between a rigid hemispherical shape impactor and Hybrid Polyurea-Polyurethane-MWCNTs Nanocomposite Coatings. An experimental study was performed for six sample configurations: single aluminum plates (reference test), multilayer plates with 4 types of coatings and double aluminum plates. The impact phenomenon was recorded with a high-speed video camera and the variation of the projectile s velocity during the impact was obtained through digital analysis. Additionally, the test was instrumented using a force sensor specially designed and mounted on the impactor. The video processing was used to draw the velocity curves and to estimate the evolution of the contact forces between the impactor and the multilayer structures, the results obtained being compared with the force sensor data. Some differences between these two types of measurements are observed, so in order to analyze the configurations behavior, a numerical study of the phenomena was performed in LS-DYNA software using a 2D axial symmetric model. The simulations showed that the profile of the force evolution measured with the sensor is affected by the chosen constructive solution and the data obtained based on the video images are more accurate. The deformations were analyzed, the maximum deformation based on image processing and the residual deformation based on 3D Scan post-test. The video technique combined with 3D Scan are precise enough to study the impact at low velocities and the numerical simulations provide results according to reality. The hyperelastic coatings contribute to a better resistance of the aluminum plates.
本文介绍了利用视频和数字图像处理技术研究刚性半球形冲击器与混合聚脲-聚氨酯-MWCNTs 纳米复合涂层之间的撞击。对六种样品配置进行了实验研究：单层铝板（参考试验）、带有四种涂层的多层板和双层铝板。用高速摄像机记录了撞击现象，并通过数字分析获得了弹丸在撞击过程中的速度变化。此外，试验还使用了专门设计并安装在冲击器上的力传感器。视频处理用于绘制速度曲线和估算冲击器与多层结构之间接触力的变化，并将获得的结果与力传感器的数据进行比较。观察到这两种测量结果之间存在一些差异，因此为了分析配置行为，使用二维轴对称模型在 LS-DYNA 软件中对这些现象进行了数值研究。模拟结果表明，传感器测得的力的变化曲线受所选构造方案的影响，而根据视频图像获得的数据更为精确。对变形进行了分析，最大变形基于图像处理，残余变形基于 3D 扫描后测试。视频技术与三维扫描相结合，足以精确地研究低速冲击，而数值模拟提供的结果与实际情况相符。超弹性涂层有助于提高铝板的抗冲击性。
{"title":"Assessment of Multilayered Plates with Hyperelastic Coatings Subjected to Dynamic Loadings by Impact at Low Velocities","authors":"Florina Bucur, L. Matache","doi":"10.37358/mp.24.1.5712","DOIUrl":"https://doi.org/10.37358/mp.24.1.5712","url":null,"abstract":"\u0000This paper describes the use of video and digital image processing in investigation of the impact between a rigid hemispherical shape impactor and Hybrid Polyurea-Polyurethane-MWCNTs Nanocomposite Coatings. An experimental study was performed for six sample configurations: single aluminum plates (reference test), multilayer plates with 4 types of coatings and double aluminum plates. The impact phenomenon was recorded with a high-speed video camera and the variation of the projectile s velocity during the impact was obtained through digital analysis. Additionally, the test was instrumented using a force sensor specially designed and mounted on the impactor. The video processing was used to draw the velocity curves and to estimate the evolution of the contact forces between the impactor and the multilayer structures, the results obtained being compared with the force sensor data. Some differences between these two types of measurements are observed, so in order to analyze the configurations behavior, a numerical study of the phenomena was performed in LS-DYNA software using a 2D axial symmetric model. The simulations showed that the profile of the force evolution measured with the sensor is affected by the chosen constructive solution and the data obtained based on the video images are more accurate. The deformations were analyzed, the maximum deformation based on image processing and the residual deformation based on 3D Scan post-test. The video technique combined with 3D Scan are precise enough to study the impact at low velocities and the numerical simulations provide results according to reality. The hyperelastic coatings contribute to a better resistance of the aluminum plates.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140775504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Alrakabi, Z. Rasheed, Mayyadah Hasan Rhaif Al-sahlanee, Ibraheem Musa Mohammed
Polymers are commonly utilized sophisticated materials that may be found in nearly every item we use daily. Polymers relevance has recently been highlighted due to their applications in several fields of science, technology, and industry, ranging from fundamental usage to biopolymers and medicinal polymers. The research aims to study the effect of annealing with irradiation on the optical properties of PMMA films used in many industrial and medical applications. Where UV-Vis spectroscopy was used to study the absorption and emission spectra in calculating the optical parameters, it was found that the optical energy gap of the indirect transmission type decreases with the increase in the thickness of the thin films. Also, the optical parameters such as the absorption coefficient, refractive index, attenuation coefficient, and dielectric constants increase with increasing thickness. The character of FTIR spectra and the locations of the bands have been demonstrated to change with different time annealing temperatures with irradiation. Irradiation has been demonstrated to change the shape of FTIR Spectra and the placement of the peaks.
{"title":"Study Effect Alpha Irradiation with Annealing on Chemical - Optical Properties of Poly (methyl methacrylate) Films","authors":"M. Alrakabi, Z. Rasheed, Mayyadah Hasan Rhaif Al-sahlanee, Ibraheem Musa Mohammed","doi":"10.37358/mp.24.1.5705","DOIUrl":"https://doi.org/10.37358/mp.24.1.5705","url":null,"abstract":"\u0000Polymers are commonly utilized sophisticated materials that may be found in nearly every item we use daily. Polymers relevance has recently been highlighted due to their applications in several fields of science, technology, and industry, ranging from fundamental usage to biopolymers and medicinal polymers. The research aims to study the effect of annealing with irradiation on the optical properties of PMMA films used in many industrial and medical applications. Where UV-Vis spectroscopy was used to study the absorption and emission spectra in calculating the optical parameters, it was found that the optical energy gap of the indirect transmission type decreases with the increase in the thickness of the thin films. Also, the optical parameters such as the absorption coefficient, refractive index, attenuation coefficient, and dielectric constants increase with increasing thickness. The character of FTIR spectra and the locations of the bands have been demonstrated to change with different time annealing temperatures with irradiation. Irradiation has been demonstrated to change the shape of FTIR Spectra and the placement of the peaks.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140779289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Acrylonitrile-butadiene-styrene (ABS) material is widely used as a protective rigid shell and impact absorber in bike helmets, providing vital protection against head injuries under specific working conditions. However, ABS aging in helmets could affect the safety factor of helmets and shorten the service life. Exploring the transformation during aging process for real assembled helmets made of ABS out shells is crucial for the investigation and fabrication of high performance helmets. Herein, the effect of long-term aging on the physical properties of practical helmets made of ABS outer shells has been discussed systematically. Four different types of helmets were subjected to different aging conditions, i.e., outdoor environment, ultraviolet exposure, hot air, and humid-heat conditions. The impact property and stiffness tests were carried out as a function of aging time and aging conditions. The measured helmets were capable of meeting engineering tolerances when aged under outdoor, ultraviolet, and hot air conditions, and could deliver competitive mechanical performance to their pristine helmets. Yet, after aging under humid-heat for 800 h, the helmets showed an obvious decrease in impact strength, gloss, and stiffness. The influence of different aging conditions was further investigated by thermal and spectral characterizations. The study might provide some valuable advice for helmet performance evaluation.
{"title":"Mechanical and Thermal Properties of Aged Helmet Outer Shells Made of Acrylonitrile-Butadiene-Styrene","authors":"Jingfei Li, Xiaolei Feng, Zhen Shen, Zheng Zhang, Shengwei Xiao, Zhicai He, Zhijun Hu","doi":"10.37358/mp.24.1.5699","DOIUrl":"https://doi.org/10.37358/mp.24.1.5699","url":null,"abstract":"\u0000Acrylonitrile-butadiene-styrene (ABS) material is widely used as a protective rigid shell and impact absorber in bike helmets, providing vital protection against head injuries under specific working conditions. However, ABS aging in helmets could affect the safety factor of helmets and shorten the service life. Exploring the transformation during aging process for real assembled helmets made of ABS out shells is crucial for the investigation and fabrication of high performance helmets. Herein, the effect of long-term aging on the physical properties of practical helmets made of ABS outer shells has been discussed systematically. Four different types of helmets were subjected to different aging conditions, i.e., outdoor environment, ultraviolet exposure, hot air, and humid-heat conditions. The impact property and stiffness tests were carried out as a function of aging time and aging conditions. The measured helmets were capable of meeting engineering tolerances when aged under outdoor, ultraviolet, and hot air conditions, and could deliver competitive mechanical performance to their pristine helmets. Yet, after aging under humid-heat for 800 h, the helmets showed an obvious decrease in impact strength, gloss, and stiffness. The influence of different aging conditions was further investigated by thermal and spectral characterizations. The study might provide some valuable advice for helmet performance evaluation.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140777109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. Deleanu, Laura Maftei, G. Ojoc, Alina Ceoromila, L. C. Titire, C. Georgescu
This paper presents an analysis of 3D amplitude and functional parameters for worn surfaces of composites with polyamide 6 as matrix and different glass bead concentrations (0%, 2.5%, 5%, 10%, 20%, 30% and 50%wt). The worn surfaces after dry sliding of a steel pin on a disk, for 10 km, at constant velocity (0.5 m/s, 1 m/s and 1.5 m/s) and under an average pressure of 1 MPa. There were done two tests under the same conditions. On each worn track, there were investigated three surfaces of 500 μm x 500 μm with a contact profilometer. The number of points on the scan line was 200 points and the step between lines was 5μm. The following amplitude parameters were measured and calculated for assessed surfaces: the arithmetic mean deviation, Sa, the root mean square deviation, Sq, the maximum height of surface prominence, Sp, the maximum surface depth, Sv, the maximum height, St, the skewness factor, Ssk and the kurtosis, Sku. The discussed functional parameters are the reduced peak height, Spk, the height of the core of the surface, Sk and the depth of the valley zone, Svk. The comparison of their values makes posible to evaluate if the worn surface could function in a new running or the replacement of the component is recommended. Considering that machine components have intermittent operation, these worn surfaces becoming initial surfaces for the following cycle of contact operation. Based on the average values of amplitude and functional parameters, it was found that a relatively good surface quality is preserved for concentrations of 10...30%wt glass beads, for v=0.5...1 m/s (Sa and Sq having similar trend); for lower concentrations and for 50% glass beads, the parameter values increase but without identifying a distinct relationship with the working regime, especially for 2.5 and 5% glass beads.
{"title":"Influence of Sliding Speed and Glass Bead Concentration on 3D Roughness Parameters","authors":"L. Deleanu, Laura Maftei, G. Ojoc, Alina Ceoromila, L. C. Titire, C. Georgescu","doi":"10.37358/mp.23.4.5691","DOIUrl":"https://doi.org/10.37358/mp.23.4.5691","url":null,"abstract":"\u0000This paper presents an analysis of 3D amplitude and functional parameters for worn surfaces of composites with polyamide 6 as matrix and different glass bead concentrations (0%, 2.5%, 5%, 10%, 20%, 30% and 50%wt). The worn surfaces after dry sliding of a steel pin on a disk, for 10 km, at constant velocity (0.5 m/s, 1 m/s and 1.5 m/s) and under an average pressure of 1 MPa. There were done two tests under the same conditions. On each worn track, there were investigated three surfaces of 500 μm x 500 μm with a contact profilometer. The number of points on the scan line was 200 points and the step between lines was 5μm. The following amplitude parameters were measured and calculated for assessed surfaces: the arithmetic mean deviation, Sa, the root mean square deviation, Sq, the maximum height of surface prominence, Sp, the maximum surface depth, Sv, the maximum height, St, the skewness factor, Ssk and the kurtosis, Sku. The discussed functional parameters are the reduced peak height, Spk, the height of the core of the surface, Sk and the depth of the valley zone, Svk. The comparison of their values makes posible to evaluate if the worn surface could function in a new running or the replacement of the component is recommended. Considering that machine components have intermittent operation, these worn surfaces becoming initial surfaces for the following cycle of contact operation. Based on the average values of amplitude and functional parameters, it was found that a relatively good surface quality is preserved for concentrations of 10...30%wt glass beads, for v=0.5...1 m/s (Sa and Sq having similar trend); for lower concentrations and for 50% glass beads, the parameter values increase but without identifying a distinct relationship with the working regime, especially for 2.5 and 5% glass beads.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139449564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. Ardelean, Adriana Popa, Ecaterina-Stela Dragan, C. Davidescu
Aromatic amines are the significant compounds used as intermediates in the organic synthesis, for obtaining such as azo dyes, antioxidants, fuel additives, corrosion inhibitors, pesticides, antiseptic agents, poultry medicine, and pharmaceutical synthesis. However, the presence of aromatic amines in water, even at very low concentrations, is extremely harmful to aquatic life and human health. Pollution of natural waters by aromatic amines is a serious environmental concern. The aim of this work was to obtain new adsorbents for use in the removal of aromatic amines from aqueous solutions. Styrene-15%divinylbenzene copolymers grafted with aminophosphonate groups (code: AP-S15%DVB) and amino acid-phosphonate groups (code: AM-S15%DVB) were used for the removal of pollutants such as: aniline, 2-methyl-aniline and 4-methyl-aniline. The adsorption capacity and the adsorption kinetic using the pseudo-first order and pseudo-second order equations were examined. From a kinetic point of view, it was established that the adsorption of the studied amino derivatives on the used adsorbents took place according to the pseudo-second order model. It was found that the adsorption rate constant increased with the increase of temperature, so the speed of the adsorption process increased. The obtained results confirm that the polymer adsorbents studied can be successfully used for the removal of aromatic amino derivatives from aqueous solutions for the purpose of wastewater treatment.
{"title":"Removal of Aromatic Amino-derivatives from Aqueous Solutions Using Polymeric Supports Functionalized with Aminophosphonated/aminoacid-phosphonated Groups","authors":"R. Ardelean, Adriana Popa, Ecaterina-Stela Dragan, C. Davidescu","doi":"10.37358/mp.23.4.5685","DOIUrl":"https://doi.org/10.37358/mp.23.4.5685","url":null,"abstract":"\u0000Aromatic amines are the significant compounds used as intermediates in the organic synthesis, for obtaining such as azo dyes, antioxidants, fuel additives, corrosion inhibitors, pesticides, antiseptic agents, poultry medicine, and pharmaceutical synthesis. However, the presence of aromatic amines in water, even at very low concentrations, is extremely harmful to aquatic life and human health. Pollution of natural waters by aromatic amines is a serious environmental concern. The aim of this work was to obtain new adsorbents for use in the removal of aromatic amines from aqueous solutions. Styrene-15%divinylbenzene copolymers grafted with aminophosphonate groups (code: AP-S15%DVB) and amino acid-phosphonate groups (code: AM-S15%DVB) were used for the removal of pollutants such as: aniline, 2-methyl-aniline and 4-methyl-aniline. The adsorption capacity and the adsorption kinetic using the pseudo-first order and pseudo-second order equations were examined. From a kinetic point of view, it was established that the adsorption of the studied amino derivatives on the used adsorbents took place according to the pseudo-second order model. It was found that the adsorption rate constant increased with the increase of temperature, so the speed of the adsorption process increased. The obtained results confirm that the polymer adsorbents studied can be successfully used for the removal of aromatic amino derivatives from aqueous solutions for the purpose of wastewater treatment.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139449940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ana Miroznicenco, Gabriel Saracu, V. Bria, M. Gorovei, A. Cîrciumaru
Last years research in polymers registered an increase of interest regarding polymer mixtures aiming to obtain materials with properties of the mixed polymers. In this respect many studies are pointing the mixtures between a thermoset polymer and a thermoplastic polymer. It is known the fact that thermoplastic polymers are much more malleable than the thermoset ones and the goal is to obtain a mixture with the general properties of the thermoset polymer and with a machining ability proper to the thermoset polymer. The vitrimers are this type of polymers and, some of them, can be obtained by mixing polymers form the two categories. This study is about using solutions of two thermoset polymers to modify the basic properties of three epoxy resins. The results show that the presence of PMMA, respectively, PLA inside the epoxy resin matrix determines changes of the mechanical properties of the formed materials. Without analysing the adhesive properties of new materials is hard to decide about their value from the composites applications point of view.
{"title":"Mechanical Properties of PMMA and PLA Modified Epoxy Resins","authors":"Ana Miroznicenco, Gabriel Saracu, V. Bria, M. Gorovei, A. Cîrciumaru","doi":"10.37358/mp.23.4.5696","DOIUrl":"https://doi.org/10.37358/mp.23.4.5696","url":null,"abstract":"\u0000Last years research in polymers registered an increase of interest regarding polymer mixtures aiming to obtain materials with properties of the mixed polymers. In this respect many studies are pointing the mixtures between a thermoset polymer and a thermoplastic polymer. It is known the fact that thermoplastic polymers are much more malleable than the thermoset ones and the goal is to obtain a mixture with the general properties of the thermoset polymer and with a machining ability proper to the thermoset polymer. The vitrimers are this type of polymers and, some of them, can be obtained by mixing polymers form the two categories. This study is about using solutions of two thermoset polymers to modify the basic properties of three epoxy resins. The results show that the presence of PMMA, respectively, PLA inside the epoxy resin matrix determines changes of the mechanical properties of the formed materials. Without analysing the adhesive properties of new materials is hard to decide about their value from the composites applications point of view.\u0000","PeriodicalId":18360,"journal":{"name":"Materiale Plastice","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139450067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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