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Effect of film thickness on the structural and tribo-mechanical properties of reactive sputtered molybdenum nitride thin films 薄膜厚度对反应溅射氮化钼薄膜结构和摩擦力学性能的影响
Pub Date : 2022-07-06 DOI: 10.30544/823
A. Abboudi, L. Aissani, A. Saoudi, H. Djebaili
The current study aims to examine the impact of nitrogen content and film thickness on the structural and tribo-mechanical characteristics of reactive sputtered MoN thin films. Molybdenum nitride thin films with thicknesses ranging from 0.2 to 1.25 m have been applied to steel and silicon substrates for this purpose, with various amounts of controlled atmosphere (Ar+N2). Then, the films are characterized using XRD (X-ray diffraction), EDX (energy dispersive X-ray analysis), SEM (scanning electron microscopy), FTIR (Fourier-transform infrared spectroscopy), and nanoindentation. The residual stress was measured using Stoney formula. Results show that high compressive residual stress of -5.7 GPa is present in the film with 0.3 μm thick film and gradually decreased with increasing film thickness. Above 1 µm of film thickness, there is no change in the density of the MoN films. Also, the coating hardness and Young’s modulus vary between 9.5 and 35 GPa, 266 and 320 GPa, respectively, depending on nitrogen content and film thickness. Finally, the frictional behavior of the MoN thin films is estimated at around 0.55, confirming the gradual oxide elimination.
本研究旨在研究氮含量和薄膜厚度对反应溅射MoN薄膜结构和摩擦力学特性的影响。为了这个目的,在不同数量的可控气氛(Ar+N2)下,厚度从0.2到1.25 m的氮化钼薄膜已经应用于钢和硅衬底。然后,利用XRD (x射线衍射)、EDX(能量色散x射线分析)、SEM(扫描电子显微镜)、FTIR(傅里叶变换红外光谱)和纳米压痕对薄膜进行表征。采用Stoney公式测量残余应力。结果表明:当膜厚为0.3 μm时,残余压应力为-5.7 GPa,随膜厚的增加而逐渐减小;在薄膜厚度大于1µm时,MoN薄膜的密度没有变化。此外,涂层硬度和杨氏模量分别在9.5 ~ 35gpa和266 ~ 320gpa之间变化,这取决于氮含量和膜厚度。最后,MoN薄膜的摩擦行为估计在0.55左右,证实了氧化物的逐渐消除。
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引用次数: 0
Dry sliding wear behavior and its relation to microstructure of artificially aged Al-Si-Mg/TiB2 in situ composites 人工时效Al-Si-Mg/TiB2原位复合材料干滑动磨损性能及其与显微组织的关系
Pub Date : 2022-06-30 DOI: 10.30544/824
N. Rathod, J. Menghani
Mechanical stir casting is utilized to produce an artificially aged Al-Si-Mg alloy, whereas halide slat (K2TiF6 and KBF4) synthesis is utilized to produce Al-Si-Mg/TiB2 aluminum matrix composites. The dry sliding pin on disc wear test was conducted using a DUCOM/TR-20LE-PHM-200 machine to simulate an automobile application (Piston-Ring assembly).  Where pistons are made of aluminum alloy (for the Pin) and rings are made of grey cast iron (for the disc material). At room temperature, a wear test was conducted by altering the ageing time (3, 6, 9, 12), sliding speed (2, 2.5 m/s), and applied load (14.71, 19.62, 24.52 N) with the disc speed (500 rpm) held constant (10 min).  The results indicate that the aluminum matrix composite (AMC) wear rate is reduced by 37 percent at higher sliding speeds (2.5 m/s) and by 4 percent at lower sliding speeds (2.0 m/s) compared to the base alloy. Field emission scanning electron microscope-energy dispersive spectroscopy (FESEM-EDS) and X-ray photoelectron spectroscopy (XPS) analysis revealed that the formation of the mechanically mixed layer (MML) or oxidative layers on the worn surfaces reduces the wear rate under conditions of longer ageing time, higher sliding speed, and lower applied load. The research demonstrates that composite wear is a function of sliding velocity, aging period, and applied force. As sliding speed rose from 2 m/s to 2.5 m/s, the wear rate of composites dropped reasonably, yet composites are softer than basic alloys. It is conceivable due to the presence of a considerable amount of MML and the formation of oxidative layers between pins and their equivalents.
采用机械搅拌铸造法制备人工时效的Al-Si-Mg合金,采用卤化物板(K2TiF6和KBF4)合成法制备Al-Si-Mg/TiB2铝基复合材料。采用DUCOM/TR-20LE-PHM-200型机床模拟某汽车应用(活塞环总成)进行干式滑动销盘面磨损试验。其中活塞由铝合金制成(销),环由灰铸铁制成(阀瓣材料)。在室温下,通过改变老化时间(3、6、9、12)、滑动速度(2、2.5 m/s)和施加载荷(14.71、19.62、24.52 N)进行磨损试验,保持圆盘速度(500 rpm)恒定(10 min)。结果表明,与基合金相比,在较高的滑动速度(2.5 m/s)下,铝基复合材料(AMC)的磨损率降低了37%,在较低的滑动速度(2.0 m/s)下,磨损率降低了4%。场发射扫描电子显微镜-能谱(FESEM-EDS)和x射线光电子能谱(XPS)分析表明,在较长的时效时间、较高的滑动速度和较低的载荷条件下,磨损表面形成机械混合层(MML)或氧化层,降低了磨损率。研究表明,复合材料的磨损是滑动速度、时效时间和受力的函数。当滑动速度从2 m/s提高到2.5 m/s时,复合材料的磨损率有所下降,但复合材料比基本合金更柔软。这是可以想象的,由于存在相当数量的MML和氧化层的形成之间的引脚和它们的等价物。
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引用次数: 3
Endothermic solvent extraction of copper (II) with furfuryl thioalcohol from sulfate medium 糠酰硫醇从硫酸盐介质中吸热萃取铜(II)
Pub Date : 2022-06-30 DOI: 10.30544/758
U. Shep, Jivan M Kondre, Pratap A Shep, B. Arbad, V. Kalalawe
A simple solvent extraction method was developed to extract copper (II) from sulfate solution. The extraction of copper (II) with furfuryl thioalcohol was investigated. The effect of variables such as aqueous phase pH, furfuryl thioalcohol concentration, temperature, stripping reagents, and diluents was investigated. The extraction data revealed that using 15% (v/v) furfuryl thioalcohol with aqueous solution containing 0.5 mol L-1 Na2SO4, equilibrium pH 5.5, and phase ratio organic phase: aqueous phase (O:A) of 1:1 resulted in 98.20 percent extraction of copper (II) without nickel coextraction (II). Extraction isotherm results show that the extraction procedure is endothermic, with ΔH = 28.542 kJ mol-1 and ΔS = 41.740 J K-1 mol-1. Using 2.0 M H2SO4, copper loaded in organic phase was stripped at a rate greater than 99 percent.
建立了一种从硫酸盐溶液中提取铜(II)的简单溶剂萃取法。研究了糠酰硫醇萃取铜(II)的工艺。考察了水相pH、糠酰巯基醇浓度、温度、溶出试剂、稀释剂等因素的影响。提取结果表明,在15% (v/v)糠酰硫醇和含0.5 mol L-1 Na2SO4的水溶液、平衡pH为5.5、有机相与水相(O:A)比为1:1的条件下,铜(II)的提取率为98.20%,无需共萃取(II)。萃取等温线结果表明,萃取过程为吸热萃取,萃取速率为ΔH = 28.542 kJ mol-1, ΔS = 41.740 J K-1 mol-1。使用2.0 M H2SO4,负载在有机相中的铜的剥离率大于99%。
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引用次数: 0
Historical overview of refractory lining in the blast furnace 高炉耐火材料衬里的历史概况
Pub Date : 2022-06-30 DOI: 10.30544/811
T. Volkov-Husović, Sanja Martinović, M. Vlahović
The majority of refractories used today are associated with the iron and steel industries. Typically, the refractory lining of a blast furnace consists of a combination of different refractory materials chosen for different portions of the furnace, as well as distinct process conditions and temperature ranges. Knowledge and requirements for the iron manufacturing system in conjunction with the physical, mechanical, and chemical qualities of the proposed refractories determine the choice of refractory combination. Inadequate understanding of the aforementioned components frequently results in refractory failure, which then becomes a difficult problem to tackle. A blast furnace's refractory liner typically fails owing to any number or combination of these variables. To facilitate comprehension, we will explain the types of refractory lining required in a blast furnace by region, as well as the observed trend in refractory lining patterns over the past few decades.
今天使用的大多数耐火材料都与钢铁工业有关。通常,高炉的耐火衬里由不同耐火材料的组合组成,这些材料是为高炉的不同部分选择的,以及不同的工艺条件和温度范围。铁制造系统的知识和要求以及所建议的耐火材料的物理、机械和化学质量决定了耐火材料组合的选择。对上述部件的不充分了解经常导致耐火材料失效,这就成为一个难以解决的问题。高炉的耐火衬里通常由于这些变量的任何数量或组合而失效。为了便于理解,我们将按地区解释高炉所需的耐火衬里类型,以及在过去几十年中观察到的耐火衬里模式的趋势。
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引用次数: 1
Simultaneous improvement of corrosion and mechanical properties of AA 5083 aluminum alloy 同时改善了AA 5083铝合金的腐蚀性能和力学性能
Pub Date : 2022-06-30 DOI: 10.30544/809
Qanita Tayyaba, Adnan Qayum Butt, M. Shahzad, Tahir Ali
In this study, the effects of cold-rolling and annealing on the structural, electrochemical, and mechanical properties of AA5083 in a simulated seawater environment are investigated. The results demonstrated that annealing temperature significantly affects the alloy's mechanical and corrosion properties. According to potentiodynamic results, the rate of corrosion decreased after annealing. Compared to the cold-rolled sample, the heat treatment doubles the electrochemical impedance, indicating that the corrosion resistance of AA5083 alloy is suitable at 50°C annealing. Approximately twice as much ductility was added to the materials as compared to the as-received materials. Additionally, the mechanical testing revealed the Portevin-Le Chatelier (PLC) Effect Type B band, which reflected the smaller grain size.
在模拟海水环境中,研究了冷轧和退火对AA5083的结构、电化学和力学性能的影响。结果表明,退火温度对合金的力学性能和腐蚀性能有显著影响。根据动电位结果,退火后的腐蚀速率降低。与冷轧样品相比,热处理后的电化学阻抗增加了一倍,表明AA5083合金在50℃退火条件下具有良好的耐蚀性。与接收到的材料相比,材料的延展性增加了大约两倍。此外,力学测试还发现了反映较小晶粒尺寸的Portevin-Le Chatelier (PLC)效应B型带。
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引用次数: 1
Sandwich composite of aluminum alloy and magnesium alloy through accumulative roll bonding technique 采用累积辊焊技术制备铝合金与镁合金的夹心复合材料
Pub Date : 2022-06-30 DOI: 10.30544/761
J. Aishwarya, M. Nithin Kumaar, Vaira Vignesh Ramalingam, M. Govindaraju
Aluminum and magnesium alloys are lightweight materials with outstanding technical uses. Due to their combined qualities, composites built of aluminum and magnesium alloys have surpassed the utilization of these elements individually. Accumulative Roll Bonding was used to create a three-layered sandwich composite structure made of Al-alloy/Mg-alloy/Al-alloy. The composite structure's microstructure and mechanical characteristics were studied. A fine-grained AZ31 layer was formed, according to the microstructural study. At the Al-alloy/Mg-alloy contact, a diffusion layer was also seen. On the broken surface, fractography exhibited both ductile and brittle failure characteristics.
铝和镁合金是具有突出技术用途的轻质材料。由于铝和镁合金的综合性能,它们的复合材料已经超过了单独使用这些元素。采用累积辊焊技术制备了铝合金/镁合金/铝合金三层夹心复合材料结构。研究了复合材料的显微组织和力学性能。显微组织研究表明,形成了细晶AZ31层。在铝合金/镁合金接触处,也观察到扩散层。在断裂面上,断口形貌同时表现出韧性和脆性破坏特征。
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引用次数: 1
Effects of the tempering temperature on microstructure and mechanical properties of X70 dual phase steel 回火温度对X70双相钢组织和力学性能的影响
Pub Date : 2022-06-30 DOI: 10.30544/753
Zidelmel Sami, Al-Zuhairi Omar
This study uses direct quenching (DQ) heat treatment at an intercritical annealing temperature (IAT) of 800 °C to form a martensite-ferrite dual phase microstructure of X70 steel. The effects of tempering temperatures ranging from 200 to 500 °C on tensile properties in a dual-phase X70 steel are investigated. Carbon diffusion and redistribution in the microstructure are influenced by tempering. It was discovered that the amount of carbides increases with the tempered temperature, resulting in depleted carbon in martensite. Conversely, increasing the tempered temperature causes a decrease in ultimate tensile strength and yield strength while increasing elongation.
本研究采用直接淬火(DQ)热处理,在800℃的临界间退火温度(IAT)下形成X70钢的马氏体-铁素体双相组织。研究了200 ~ 500℃回火温度对双相X70钢拉伸性能的影响。回火影响了组织中碳的扩散和再分布。研究发现,随着回火温度的升高,碳化物的数量增加,导致马氏体中碳的耗尽。相反,提高回火温度会降低材料的极限抗拉强度和屈服强度,而提高延伸率。
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引用次数: 1
Effect of artificial aging treatment on microstructure, mechanical properties and fracture behavior of 2017A alloy 人工时效处理对2017A合金组织、力学性能及断裂行为的影响
Pub Date : 2022-06-30 DOI: 10.30544/744
Nassim Aguechari, A. Boudiaf, M. Ould Ouali
The effect of artificial aging treatment on 2017A aluminum alloy microstructure, mechanical properties, and fracture behavior was investigated. The samples were taken from the as-received alloy and aged at 170 °C for 5, 10, 15, 20, and 30 hours. An optical microscope, scanning electron microscope (SEM), X-ray diffraction (XRD), microhardness and tensile strength tests were used to characterize mechanical and microstructural properties. The microstructural analysis revealed that as the aging treatment duration is increased, the size and density of precipitates grow larger and more numerous. According to X-ray diffraction measurements, the microstructural evolution caused by aging treatments is primarily due to an increase in precipitation of the hardening phase -Al2Cu. According to the tensile test results, the yield stress increases with increasing aging duration. The fracture surface analysis of failed specimens subjected to tensile loading revealed that the aging treatment conditions had a significant impact on the morphology and mode of fracture: the mixed-mode (ductile-brittle) failure was established for intermediate aging durations (aging at 170 °C for 15 and 20 h), and the intergranular fracture was found to be more pronounced when the aging duration is prolonged due to the coalescence of fine precipitates at the grain boundary.
研究了人工时效处理对2017A铝合金组织、力学性能和断裂行为的影响。样品从接收的合金中取出,在170°C下时效5、10、15、20和30小时。采用光学显微镜、扫描电镜(SEM)、x射线衍射(XRD)、显微硬度和抗拉强度等测试手段对材料的力学性能和微观组织性能进行表征。显微组织分析表明,随着时效时间的延长,析出相的尺寸和密度增大,析出相数量增多。根据x射线衍射测量,时效处理引起的显微组织演变主要是由于硬化相-Al2Cu析出增加。拉伸试验结果表明,屈服应力随时效时间的延长而增大。拉伸加载失效试样的断口形貌分析表明,时效处理条件对断口形貌和断口模式有显著影响:中等时效时间(170℃时效15和20 h)形成了韧脆混合破坏模式,随着时效时间的延长,晶界处细小析出物聚结,晶间断裂更加明显。
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引用次数: 1
Effect of copper-graphite composite electrode on material removal rate and surface roughness in MONEL 400 during electrical discharge machining 铜-石墨复合电极对电火花加工中MONEL 400材料去除率和表面粗糙度的影响
Pub Date : 2022-06-30 DOI: 10.30544/817
Mustafa. H. Hadi, A. Ibrahim
Electrical Discharge Machining (EDM) is one of the non-traditional machining processes commonly used for machining of hard to cut metals. Monel 400 is a nickel based superalloy used in various applications. The composite electrode is developed and applied to enhance the machining process by reducing the time of the process and the cost of the electrode manufacturing. The presented work is aimed to study the effect of copper, graphite, and copper-graphite composite electrodes with different parameters on the Material Removal Rate and Surface Roughness of Monel 400. Influences of discharge current (Ip), pulse on time (Ton), and pulse off time (Toff) have been investigated. Based on the Taguchi method, experiments were analyzed using ANOVA through Minitab 20. The results have manifested that compared to copper and graphite electrodes, the copper-graphite electrode achieved better values of material removal rate and surface roughness. The lowest value of surface roughness is 3.1413 μm as a result of the added graphite reinforcement particles. 
电火花加工(EDM)是一种用于加工难切削金属的非传统加工方法。蒙乃尔400是一种镍基高温合金,用于各种应用。开发和应用复合电极是为了通过减少加工时间和电极制造成本来提高加工工艺。研究了铜、石墨和不同参数的铜-石墨复合电极对蒙乃尔400材料去除率和表面粗糙度的影响。研究了放电电流(Ip)、脉冲接通时间(Ton)和脉冲断开时间(Toff)的影响。基于田口法,通过Minitab 20对实验进行方差分析。结果表明,与铜电极和石墨电极相比,铜-石墨电极具有更好的材料去除率和表面粗糙度。石墨增强颗粒的加入使表面粗糙度最小值为3.1413 μm。
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引用次数: 2
Wear characterization of Al 7075 alloy hybrid composites Al - 7075合金杂化复合材料的磨损特性
Pub Date : 2022-06-30 DOI: 10.30544/821
Harish R S, Dr. Sreenivasa Reddy M, Dr. Kumaraswamy J
Aluminium alloy hybrid composites are in high demand for advanced scientific applications due to their high strength, low weight, and enhanced tribological properties. A hybrid composite of aluminium alloy (Al7075) and aluminium oxide (Al2O3) and E-glass shot fibres was produced using a sand moulding technique in an electric resistance furnace. The objective of this research was to look at the wear characteristics of Al7075-Al2O3-E-glass hybrid composites with various Al2O3 (3-12%) and E-glass weight percentages (2-6 percent). The sliding distance (500, 1000, and 1500 m), load (10, 20, and 30N), Al2O3 (3, 6, and 9 %), and E-glass (2-6 %) are the wear characteristics that are considered. Wear testing is carried out using pin-on-disc equipment (WTE 165 model, Version-EV00) in line with the Taguchi L9 orthogonal array. Taguchi analysis was done on the collected data to find SN plots. Regression analysis was done along with ANOVA to find relationships between different factors selected. In order to reduce the wear rate of hybrid composites, the optimal wear parameters are determined. As the percentage of reinforcements increased, the rate of deterioration decreased. SEM scans revealed the attachment and displacement of unintended wear debris, as well as the uniform distribution of Al2O3/E-glass particles.
铝合金杂化复合材料由于其高强度、低重量和增强的摩擦学性能,在先进的科学应用中有着很高的需求。在电阻炉中采用砂成型技术制备了铝合金(Al7075)、氧化铝(Al2O3)和e -玻璃丸纤维的混合复合材料。本研究的目的是观察不同Al2O3(3-12%)和e -玻璃重量百分比(2- 6%)的al7075 -Al2O3- e -玻璃杂化复合材料的磨损特性。滑动距离(500、1000和1500米)、载荷(10、20和30N)、Al2O3(3、6和9%)和e -玻璃(2- 6%)是考虑的磨损特性。磨损测试使用针盘式设备(WTE 165型号,Version-EV00)按照田口L9正交阵列进行。对收集到的数据进行田口分析,寻找SN图。采用回归分析和方差分析来分析所选因素之间的关系。为了降低杂化复合材料的磨损率,确定了最优磨损参数。随着增强剂比例的增加,劣化率降低。扫描电镜显示了非预期磨损碎片的附着和位移,以及Al2O3/ e -玻璃颗粒的均匀分布。
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引用次数: 8
期刊
Metallurgical and Materials Engineering
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