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Meet the Editorial Board Member 会见编辑委员会成员
Q3 Engineering Pub Date : 2021-12-01 DOI: 10.2174/187640291304210921115446
L. Yobas
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引用次数: 0
Hydrothermal Synthesis and Photocatalytic Performance of Barium Carbonate/tin Dioxide Nanoparticles 碳酸钡/二氧化锡纳米颗粒的水热合成及其光催化性能
Q3 Engineering Pub Date : 2021-11-10 DOI: 10.2174/1876402913666211110144252
J.F. Huang, F. Tao, C.H. Yu, Y. Mao, Z. Xue, M.C. Wang, C. Fan, L. Pei
Crystal violet dye is stable and difficult to be biodegraded owing to the existence of the multiple aromatic rings of the crystal violet molecules. Removing crystal violet dye fromthe wastewater is a major challenge.The aim of the research is to synthesize barium carbonate/tin dioxide nanoparticles and investigate the photocatalytic performance for the degradation of crystal violet.Barium carbonate/tin dioxide nanoparticles were synthesized via a facile hydrothermal routewithout any surfactants. The crystal structure, micro-morphology, size and optical performance of thebarium carbonate/tin dioxide nanoparticles were investigated by powder X-ray diffraction, scanningelectron microscopy, transmission electron microscopy and solid ultraviolet-visible diffuse reflectancespectrum.The size of the barium carbonate/tin dioxide nanoparticles is 20 nm to 200 nm with the bandgap of 3.71 eV. The photocatalytic activity of the barium carbonate/tin dioxide nanoparticles wasmeasured by the photocatalytic degradation of crystal violet. The crystal violet degradation efficiencyreaches 92.1% with the ultraviolet-visible irradiation time of 8 h using 10 mg barium carbonate/tin dioxide nanoparticles. The crystal violet degradation ratio increases to 96.1% when the dosage of the barium carbonate/tin dioxide nanoparticles increases to 20 mg/10 mL crystal violet dye solution. Activespecies capture photocatalytic experiments showed that the holes, hydroxyl radicals and superoxide ionradicals are the main active species. Reusability experiments displayed that the barium carbonate/tindioxide nanoparticles are stable for the crystal violet dye degradation.The barium carbonate/tin dioxide nanoparticles show good photocatalytic performancetoward crystal violet under ultraviolet light irradiation.
结晶紫染料由于结晶紫分子中存在多个芳环,具有稳定性强、难生物降解的特点。从废水中去除结晶紫染料是一项重大挑战。本研究的目的是合成碳酸钡/二氧化锡纳米颗粒,并研究其光催化降解结晶紫的性能。在不含任何表面活性剂的情况下,通过简单的水热合成了碳酸钡/二氧化锡纳米颗粒。采用粉末X射线衍射、扫描电子显微镜、透射电子显微镜和固体紫外-可见漫反射光谱等方法研究了碳酸钡/二氧化锡纳米颗粒的晶体结构、微观形貌、尺寸和光学性能。碳酸钡/二氧化锡纳米颗粒的尺寸为20nm至200nm,带隙为3.71eV。通过光催化降解结晶紫来测量碳酸钡/三氧化锡纳米粒子的光催化活性。使用10mg碳酸钡/二氧化锡纳米颗粒,紫外-可见光照射8h,结晶紫降解率达到92.1%。当碳酸钡/二氧化锡纳米颗粒的剂量增加到20mg/10mL结晶紫染料溶液时,结晶紫降解率增加到96.1%。活性物质捕获光催化实验表明,空穴、羟基自由基和超氧离子自由基是主要的活性物质。可重复使用性实验表明,碳酸钡/二氧化锡纳米粒子对结晶紫染料的降解是稳定的。碳酸钡/二氧化锡纳米粒子在紫外光照射下对结晶紫表现出良好的光催化性能。
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引用次数: 0
The Environmental Crisis and Nanotechnology 环境危机与纳米技术
Q3 Engineering Pub Date : 2021-10-11 DOI: 10.2174/1876402913666211011095356
R. Yousefi
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引用次数: 5
Facile One-step Preparation of Mesoporous Siliceous phophsomolybdic acid for Proton Exchange Membrane 一步法制备质子交换膜用介孔硅质磷酸
Q3 Engineering Pub Date : 2021-10-06 DOI: 10.2174/1876402913666211006155150
H. Ilbeygi
Proton exchange membrane is art of PEM fuel cells, developing active materials with robust structure and high proton conductivity has attained huge attention in recent decade amongst researchers.Here we have developed a novel approach to prepare a siliceous mesoporous heteropoly acid with high stability in polar media and high proton conductivity to be utilized as proton exchange membrane.A highly stable mesoporous siliceous phosphomolybdic acid has been synthesized via a simple self-assembly between phosphomolybdic acid (PMA), the polymeric surfactant, and the silica precursor stabilized by KCl molecules as a proton conducting material for proton exchange membrane application.As prepared siliceous mesoporous phosphomolybdic acids (mPMA-Si) show a high surface area with a highly crystalline structure, however the crystallinity reduced by increasing the silica content. Further analysis proved the Keggin structure remain intact in final materials. mPMA-8 Si shows the highest performance among all the materials studied with proton conductivity of 0.263 S.cm-1 at 70 oC. As prepared mPMA-xSi has shown a very high proton conductivity in a range of temperatures which make them a promising material for proton exchange membrane.
质子交换膜是质子交换膜燃料电池的一门艺术,近十年来,开发结构坚固、质子电导率高的活性材料受到了研究人员的极大关注。在这里,我们开发了一种新的方法来制备在极性介质中具有高稳定性和高质子传导性的硅介孔杂多酸,用作质子交换膜。通过磷钼酸(PMA)、聚合物表面活性剂和KCl分子稳定的二氧化硅前体之间的简单自组装,合成了一种高度稳定的中孔硅磷钼酸,作为质子交换膜应用的质子传导材料。所制备的硅介孔磷钼酸(mPMA-Si)显示出高表面积和高度结晶结构,但结晶度随着二氧化硅含量的增加而降低。进一步的分析证明Keggin结构在最终材料中保持完整。mPMA-8Si在所研究的所有材料中表现出最高的性能,在70℃下质子电导率为0.263 S.cm-1。所制备的mPMA-xSi在一定温度范围内显示出非常高的质子传导性,这使其成为质子交换膜的有前途的材料。
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引用次数: 0
Plasmonic Properties of Al2O3 Nanoshell with a Metallic Core 金属核Al2O3纳米壳的等离子体性质
Q3 Engineering Pub Date : 2021-10-06 DOI: 10.2174/1876402913666211006153430
J. Katyal
Al is the promising candidate for the deep UV and longer wavelength range plasmonic applications. But it is difficult to have the pure Aluminium nanostructure as it is easily oxidized forming a thin layer of Al2O3. In this paper we have evaluated the field enhancement of oxide layer on metallic shell (Al-Al2O3 and Au- Al2O3) for single and dimer core-shell configuration and shown potential of oxide layer in SERS.The Finite Difference Time Domain (FDTD) has been used to evaluated the LSPR and field enhancement of single and dimer Al-Al2O3 and Au- Al2O3 nanostructure.The results exhibit the tunable plasmon resonance on varying the inner and outer radii of the Al2O3 shell. A redshift and decrease in enhancement were observed as shell thickness increases whereas on increasing the core size the enhancement gets increased in the case of Au-Al2O3 and gets a decrease in Al-Al2O3 due to quadrupole contribution. But on comparing the Au-Al2O3 with Al-Al2O3 for the same particle size, Al-Al2O3 shows larger enhancement because Au has to compete with its inter band transition.By optimizing the thickness of the shell and core size, it can be concluded that an ultrathin shell of Al2O3 can give higher enhancement. With Al as a core metal the enhancement increases as compared to Au-Al2O3. Since a single Al-Al2O3 nanoshell has shown a huge enhancement we have considered the multimer configuration of two identical nanoshell. Due to coupling between two nanoshell a huge increase in enhancement factor ~1012 was observed for Al-Al2O3 dimer nanoshell in the UV region.
Al是深紫外和更长波长范围等离子体应用的有前途的候选者。但是很难具有纯铝纳米结构,因为它很容易被氧化形成Al2O3薄层。本文评估了金属壳(Al-Al2O3和Au-Al2O3)上氧化物层对单核壳和二聚体核壳结构的场增强,并展示了氧化物层在SERS中的潜力。用时域有限差分法(FDTD)评估了单核和二聚物Al-Al2O3以及Au-Al2O3纳米结构的LSPR和场增强。结果表明,在改变Al2O3壳层的内外半径时,等离子体共振是可调谐的。随着壳层厚度的增加,观察到红移和增强的减少,而随着核尺寸的增加,在Au-Al2O3的情况下,增强增加,并且由于四极的贡献,Al-Al2O3减少。但是,在比较相同粒度的Au-Al2O3和Al-Al2O3时,Al-Al2O3表现出更大的增强,因为Au必须与其带间跃迁竞争。通过优化壳的厚度和核的尺寸,可以得出结论,Al2O3的超薄壳可以给予更高的增强。与Au-Al2O3相比,Al作为核心金属的增强作用增加。由于单个Al-Al2O3纳米壳显示出巨大的增强,我们考虑了两个相同纳米壳的多聚体构型。由于两个纳米壳之间的耦合,在UV区域观察到Al-Al2O3二聚体纳米壳的增强因子大幅增加~1012。
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引用次数: 0
Structural and Impedance Analysis of 0.7Pb(Mg1/3Nb2/3)O3- 0.3PbTiO3 Ceramic 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3陶瓷的结构与阻抗分析
Q3 Engineering Pub Date : 2021-09-29 DOI: 10.2174/1876402913666210929125515
J. K. Mishra, Khusboo Agrawal, B. Behera
Since (1-x)[Pb(Mg1/3Nb2/3)O3]-(x)PbTiO3 (PMN-PT) ceramic has high dielectric constant and piezoelectric coefficient, it has been widely investigated for profound applications in electro-optical devices, sensors, multilayer capacitors and actuators.The aim is to study the structural and electrical properties of 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (0.7PMN-0.3PT) ceramic to understand the biphasic structural nature using Rietveld Refinement. Also, it characterises on the basis of electrical properties such as impedance and modulus to understand the relaxation process, type of conduction process as well as the role of grain and grain boundary resistance in the material. 0.7PMN-0.3PT is synthesised by mixed oxide method using PbO, MgO, Nb2O5 and TiO2 as precursor materials. The XRD data reveals the biphasic structure of tetragonal phase with the space group of P4mm and monoclinic phase with the space group of Pm. The complex impedance analysis clearly represents the effect of grain on the overall resistance and departs from normal Debye type behaviour. Also, the resistance is found to decrease with temperature, thereby confirming the semiconducting nature of the sample. The presence of long as well as short-range mobility of charge carriers is confirmed from the modulus and impedance analysis. The influence of long-range motion is observed at high temperature and of short-range motion at low temperatures. XRD analysis confirmed the biphasic structure of M+T phase. The frequency-dependent modulus and impedance spectroscopy show the presence of a relaxation effect in the ceramic which is found to increase with temperature. The Nyquist plot shows that the resistance is decreased with temperature, thereby confirming the NTCR behaviour in the studied sample.
由于(1-x)[Pb(Mg1/3Nb2/3)O3]-(x)PbTiO3 (PMN-PT)陶瓷具有较高的介电常数和压电系数,在电光器件、传感器、多层电容器和执行器等领域有着广泛的应用前景。目的是研究0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (0.7PMN-0.3PT)陶瓷的结构和电学性能,以了解其双相结构性质。此外,它还根据阻抗和模量等电学性质进行表征,以了解弛豫过程,传导过程的类型以及晶粒和晶界电阻在材料中的作用。以PbO、MgO、Nb2O5和TiO2为前驱体材料,采用混合氧化法制备了0.7PMN-0.3PT。XRD数据显示,该材料的双相结构为P4mm空间群的四方相和Pm空间群的单斜相。复合阻抗分析清楚地反映了晶粒对总电阻的影响,与正常的德拜型行为不同。此外,发现电阻随温度降低,从而确认样品的半导体性质。通过模量和阻抗分析,证实了载流子的长距离和短程迁移率的存在。在高温下观察到远距离运动的影响,在低温下观察到短程运动的影响。XRD分析证实了M+T相的双相结构。频率相关模量和阻抗谱显示陶瓷中存在随温度升高而增加的弛豫效应。奈奎斯特图显示电阻随温度的升高而降低,从而证实了所研究样品中的NTCR行为。
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引用次数: 0
Assessing the Grip of Solar Energy Systems on Environmental Sustainability-A Review 评估太阳能系统对环境可持续性的影响-综述
Q3 Engineering Pub Date : 2021-09-08 DOI: 10.2174/1876402913666210908122052
S. Srivastava, A. Behera, R. Biswal
A sustainable energy production system fulfills its goal while being environmentally, socially, and technically sound. The intermittent availability and viability of renewable energy makes this vision a gradual and long-suffering process. In the rapid result-oriented economy, concerns regarding the environment are treated with desperate solutions that may add fuel to the fire. Although substantial research has been going on in the development of emerging technologies and refinement of established systems, we need to be reminded of the larger goal in mind: a benign and sustainable environment. Closing a door on a problem and not opening several new ones is what we must yearn to achieve. Renewable energy systems and their utility may unintentionally harm a different subset of the ecosystem. Solar energy systems are a more recent candidate with a high annual growth rate and thus, are still in the nascent stage to realise the bruised potential of the technology. By 2050, 60 million tons of solar waste will be produced if it is not resolved efficiently. To achieve environmental sustainability, it is imperative to work towards recycling redundant systems, establishing producer responsibility, fulfilling social needs and optimising future technology. By integrating aspects of the research on solar energy systems, their environmental risks, and their potential to create a sustainable ecosystem, this review article attempts to cater to environmental decision making and direct the eventual research and analysis towards their original unified objective.
一个可持续的能源生产系统既能实现其目标,又能在环境、社会和技术上健全。可再生能源的间歇性可用性和可行性使这一愿景成为一个渐进和长期的过程。在快速发展的以结果为导向的经济中,人们对环境问题的关注往往采用铤而走险的解决办法,这可能会火上浇油。尽管在开发新兴技术和完善现有系统方面进行了大量研究,但我们需要记住更大的目标:一个良性和可持续的环境。在一个问题上关上一扇门,而不打开几个新的问题,这是我们必须渴望实现的。可再生能源系统及其效用可能会无意中损害生态系统的另一个子集。太阳能系统是一个较新的候选,具有较高的年增长率,因此,仍处于初级阶段,以实现该技术的巨大潜力。到2050年,如果不能有效解决,将产生6000万吨太阳能废物。为了实现环境的可持续性,必须努力回收多余的系统,建立生产者责任,满足社会需求和优化未来的技术。通过整合太阳能系统研究的各个方面,其环境风险及其创造可持续生态系统的潜力,这篇综述文章试图迎合环境决策,并将最终的研究和分析引向其最初的统一目标。
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引用次数: 0
Thermal energy storage property and temperature control performance of phase change materials eutectic mixture nanocomposite 相变材料共晶混合纳米复合材料的储热性能和控温性能
Q3 Engineering Pub Date : 2021-09-03 DOI: 10.2174/1876402913666210903162938
Seyed Mostapha Musavi, G. Roudini, Farahnaz Barahuie, S. Masuri
The utilization of high-performance phase change materials (PCMs) that can reversibly store thermal energy is of immense interest and strategy for effective energy conservation and management. In this work, a new PCM nanocomposite, consisting of a eutectic mixture of stearic acid and n-nonadecane as core and SiO2 as shell, was prepared by direct impregnation method. Additionally, a laboratory scaled test room was designed to investigate the intelligent temperature control function of the nanocomposite in building materials.The optimized nanocomposite was characterized using Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), X-ray diffraction (XRD), and scanning electron microscopy (SEM) techniques. The DSC data demonstrated that the PCMs eutectic mixture content in the stearic acid- n-nonadecane–SiO2 nanocomposite was 52.8 wt.% and the melting temperatures and latent heats of stearic acid - n-nonadecane eutectic mixture and optimized nanocomposite were 45.1 and 44.0 °C, and 163.7 and 86.5 J/g, respectively. Furthermore, the accelerated thermal cycling test confirmed the excellent thermal cycling stability of the nanocomposite after 500 heating-cooling cycles. Moreover, the laboratory scaled test room results showed that the incorporation of the resulting nanocomposite in the gypsum could reduce indoor temperature fluctuation, and the performance was improved with the increase in the mass percentage of the nanocomposite in the gypsum composite. The obtained nanocomposite had good thermal reliability and temperature control performance and thus can be a promising candidate for hi-tech applications in intelligent temperature control and precise thermal management.
利用能够可逆存储热能的高性能相变材料(PCM)对于有效的节能和管理具有巨大的兴趣和战略意义。本工作采用直接浸渍法制备了一种新的PCM纳米复合材料,该材料由硬脂酸和正壬烷的共晶混合物作为核,SiO2作为壳组成。此外,还设计了一个实验室规模的试验室来研究纳米复合材料在建筑材料中的智能温度控制功能。利用傅立叶变换红外光谱(FTIR)、差示扫描量热法(DSC)、X射线衍射(XRD)和扫描电子显微镜(SEM)技术对优化的纳米复合材料进行了表征。DSC数据表明,在硬脂酸-正九烷-SiO2纳米复合材料中,PCMs共晶混合物的含量为52.8wt.%,硬脂酸-正九烷共晶混合物和优化的纳米复合材料的熔融温度和潜热分别为45.1和44.0°C,163.7和86.5J/g。此外,加速热循环测试证实了纳米复合材料在500次加热-冷却循环后具有优异的热循环稳定性。此外,实验室规模的试验室结果表明,将所得纳米复合材料掺入石膏中可以减少室内温度波动,并且随着纳米复合材料在石膏复合材料中质量百分比的增加,性能得到改善。所制备的纳米复合材料具有良好的热可靠性和温度控制性能,在智能温度控制和精确热管理方面具有很好的应用前景。
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引用次数: 2
The Challenges of Biomedical Waste Management During the Ongoing Coronavirus Disease-19 (COVID-19) Pandemic: The Current Scenario 正在进行的冠状病毒病-19 (COVID-19)大流行期间生物医学废物管理的挑战:当前情景
Q3 Engineering Pub Date : 2021-09-03 DOI: 10.2174/1876402913666210903164056
Sabitha Vadakedath, V. Kandi, Tarun Kumar Suvvari, L. Kutikuppala, Vikram Godishala, P. Shahapur
The novel Coronavirus (SARS-CoV-2) that has emerged and spread throughout the world causing CoV disease-19 (COVID-19) has since its discovery affected not only humans and animals but also the environment. Because of the highly infectious nature of the virus, and the respiratory aerosol transmission route, face masks and personal protective equipment have become mandatory for public and healthcare workers, respectively. Also, the complex nature of the pathogenicity of the virus, wherein, it has been associated with mild, moderate, and severe life-threatening infections, has warranted increased laboratory testing and placing the infected people in isolation and under constant observation in quarantine centers or at dedicated hospitals. Some infected people, who are generally healthy, and do not show symptoms have been placed in home quarantines. At this juncture, there has been increased amount of biomedical waste (BMW), and infectious general waste along with plastic disposable recyclable and non-recyclable waste. The increased BMW along with the potentially hazardous plastic waste collection, segregation, transport, and disposal has assumed increased significance during the ongoing pandemic. Therefore, this review attempts to investigate the current scenario of BMW management and strategies to minimize BMW and prevent potential environmental pollution.
新型冠状病毒(SARS-CoV-2)在世界各地出现并传播,导致CoV疾病19(新冠肺炎),自发现以来,不仅影响了人类和动物,还影响了环境。由于病毒的高度传染性,以及呼吸道气溶胶传播途径,公众和医护人员必须分别佩戴口罩和个人防护装备。此外,该病毒的致病性复杂,与轻度、中度和重度危及生命的感染有关,因此需要加强实验室检测,并将感染者隔离,并在隔离中心或专门医院进行持续观察。一些总体健康、没有症状的感染者已被居家隔离。在这个关键时刻,生物医学废物(宝马)、传染性一般废物以及一次性可回收和不可回收塑料废物的数量有所增加。在持续的疫情期间,宝马汽车的增加以及潜在危险的塑料垃圾收集、分离、运输和处置变得更加重要。因此,本综述试图调查宝马管理的现状和策略,以最大限度地减少宝马并防止潜在的环境污染。
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引用次数: 0
Green Synthesis, Characterization and Antimicrobial Activity of Silver Nanoparticles using Uraria picta Leaves Extract 画眉草叶提取物制备纳米银的绿色合成、表征及抗菌活性
Q3 Engineering Pub Date : 2021-09-02 DOI: 10.2174/1876402913666210902161849
S. Mishra, S. Kumavat
The rapid synthesis and antimicrobial activity of silver nanoparticles (AgNPs) synthesized using Uraria picta extract were investigated in this paper, and AgNPs were examined for antimicrobial activity against a variety of pathogenic organisms, including bacteria and fungi.Green synthesis of AgNPs from Uraria picta leaves extract for antimicrobial evaluation against bacteria and fungi using MIC studies.The AgNPs were created by treating an aqueous extract of Uraria picta leaves with silver nitrate (1 mM) solution and then synthesizing nanoparticles for various studies.The Uraria picta leaves extract can be used to make green synthesis AgNPs effectively. The absorption band at 425 nm in the UV-Vis spectrum confirmed the synthesis of AgNPs. Silver nanoparticles show antimicrobial and antifungal action, according to MIC tests. This work gives a better understanding of how new antimicrobial and antifungal activity develops.AgNPs was synthesized from Uraria picta using a green, cost-effective, rapid, single-step, and simple process that, for the first time in this plant nanoparticles synthesis, showed antimicrobial activity. AgNPs were found to be spherical and oval, with average particle sizes ranging from 12.54 to 25.58 nm. The strong zone of inhibition of AgNPs against Salmonella Typhi, Escherichia coli, Bacillus subtilis, and Staphylococcus aureus demonstrated their antimicrobial activity.
本文研究了用画藻提取物合成的银纳米粒子(AgNPs)的快速合成及其抗菌活性,并检测了AgNPs对包括细菌和真菌在内的多种病原生物的抗菌活性。利用MIC研究从画眉草叶提取物中绿色合成AgNPs,用于细菌和真菌的抗菌评价。AgNP是通过用硝酸银(1mM)溶液处理画藻叶的水提取物,然后合成用于各种研究的纳米颗粒而产生的。画眉草叶提取物可以有效地制备绿色合成AgNPs。UV-Vis光谱中425nm处的吸收带证实了AgNPs的合成。根据MIC测试,银纳米粒子显示出抗菌和抗真菌作用。这项工作使我们更好地了解新的抗菌和抗真菌活性是如何发展的。AgNPs是用一种绿色、成本效益高、快速、一步到位、简单的方法从画藻中合成的,在这种植物纳米颗粒的合成中首次显示出抗菌活性。发现AgNPs是球形和椭圆形的,平均粒径在12.54至25.58nm之间。AgNPs对伤寒沙门氏菌、大肠杆菌、枯草芽孢杆菌和金黄色葡萄球菌的强抑制区显示了它们的抗菌活性。
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引用次数: 3
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Micro and Nanosystems
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