A. Kalinkin, E. Kalinkina, E. A. Kruglyak, Alla G. Ivanova
The objective of this study is to perform a comparative analysis of the impact of incorporating alkaline earth metal carbonates (MCO3, where M–Mg, Ca, Sr, Ba) into low-calcium fly ash (FA) on the geopolymerization processes and the resultant properties of composite geopolymers. Mechanical activation was employed to enhance the reactivity of the mixtures. The reactivity of the mechanically activated (FA + alkaline earth carbonate) blends towards NaOH solution was experimentally studied using XRD analysis and FTIR spectroscopy. In agreement with thermodynamic calculations, MgCO3 demonstrated the most active interaction with the alkaline solution, whereas strontium and barium carbonates exhibited little to no chemical interaction, and calcite was situated in the transition region. As the calcite content in the mixture with FA increased, the compressive strength of the geopolymers continuously improved. The addition of Mg, Sr, and Ba carbonates to the FA did not enhance the strength of geopolymers. However, the strength of geopolymers based on these blends was comparable with that of geopolymers based on 100% FA. The strength of geopolymers synthesized from the 100% FA and from the (90% FA + 10% MCO3) blends, mechanically activated for 180 s, at the age of 180 days was 11.0 MPa (0% carbonate), 11.1 MPa (10% MgCO3), 36.5 MPa (10% CaCO3), 13.6 MPa (10% SrCO3), and 12.4 MPa (10% BaCO3) MPa, respectively. The influence of carbonate additives on the properties of the composite geopolymers was examined, highlighting filler, dilution, and chemical effects. The latter determined the unique position of calcite among the carbonates of alkaline earth metals.
本研究的目的是比较分析在低钙粉煤灰（FA）中加入碱土金属碳酸盐（MCO3，其中 M-Mg、Ca、Sr、Ba）对土工聚合过程和复合土工聚合物性能的影响。机械活化被用来提高混合物的反应活性。利用 XRD 分析和傅立叶变换红外光谱对机械活化（FA + 碱土碳酸盐）混合物对 NaOH 溶液的反应性进行了实验研究。与热力学计算结果一致，MgCO3 与碱性溶液的相互作用最为活跃，而碳酸锶和碳酸钡几乎没有化学作用，方解石则处于过渡区域。随着 FA 混合物中方解石含量的增加，土工聚合物的抗压强度不断提高。在 FA 中添加镁、锶和钡碳酸盐并未提高土工聚合物的强度。然而，基于这些混合物的土工聚合物的强度与基于 100% FA 的土工聚合物的强度相当。由 100% FA 和（90% FA + 10% MCO3）混合物合成的土工聚合物在机械活化 180 秒后，180 天的龄期强度分别为 11.0 兆帕（0% 碳酸盐）、11.1 兆帕（10% MgCO3）、36.5 兆帕（10% CaCO3）、13.6 兆帕（10% SrCO3）和 12.4 兆帕（10% BaCO3）。研究了碳酸盐添加剂对复合土工聚合物性能的影响，突出了填料、稀释和化学效应。后者确定了方解石在碱土金属碳酸盐中的独特地位。
{"title":"Synthesis of Geopolymers Incorporating Mechanically Activated Fly Ash Blended with Alkaline Earth Carbonates: A Comparative Analysis","authors":"A. Kalinkin, E. Kalinkina, E. A. Kruglyak, Alla G. Ivanova","doi":"10.3390/min14070726","DOIUrl":"https://doi.org/10.3390/min14070726","url":null,"abstract":"The objective of this study is to perform a comparative analysis of the impact of incorporating alkaline earth metal carbonates (MCO3, where M–Mg, Ca, Sr, Ba) into low-calcium fly ash (FA) on the geopolymerization processes and the resultant properties of composite geopolymers. Mechanical activation was employed to enhance the reactivity of the mixtures. The reactivity of the mechanically activated (FA + alkaline earth carbonate) blends towards NaOH solution was experimentally studied using XRD analysis and FTIR spectroscopy. In agreement with thermodynamic calculations, MgCO3 demonstrated the most active interaction with the alkaline solution, whereas strontium and barium carbonates exhibited little to no chemical interaction, and calcite was situated in the transition region. As the calcite content in the mixture with FA increased, the compressive strength of the geopolymers continuously improved. The addition of Mg, Sr, and Ba carbonates to the FA did not enhance the strength of geopolymers. However, the strength of geopolymers based on these blends was comparable with that of geopolymers based on 100% FA. The strength of geopolymers synthesized from the 100% FA and from the (90% FA + 10% MCO3) blends, mechanically activated for 180 s, at the age of 180 days was 11.0 MPa (0% carbonate), 11.1 MPa (10% MgCO3), 36.5 MPa (10% CaCO3), 13.6 MPa (10% SrCO3), and 12.4 MPa (10% BaCO3) MPa, respectively. The influence of carbonate additives on the properties of the composite geopolymers was examined, highlighting filler, dilution, and chemical effects. The latter determined the unique position of calcite among the carbonates of alkaline earth metals.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141820903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study focuses on the purification and evaluation of the high-purity quartz (HPQ) potential of vein quartz ore from Pakistan. Vein quartz is grayish-white and translucent, with its mineral composition mainly comprising quartz crystal. Processed quartz sand is obtained from quartz raw ore through purifying technologies, including crushing, ultrasonic desliming, flotation, high-temperature calcination, water quenching, hot pressure acid leaching, and chlorination roasting. The microscopic characteristics show that the vein quartz raw ore has a medium-coarse granular metacrystalline structure, high quartz content, with only a small quantity of fine-grained K-feldspar. The inclusions primarily consist of large-sized primary inclusions and secondary fluid inclusions developed along the micro-fractures, and the content of inclusions in most areas of the crystal is very low or even nonexistent. The quartz ore with such inclusion characteristics is considered a relatively good raw material for quartz. Component analysis shows that the main impurity elements in the quartz ore are Al, K, Ca, Na, Ti, Fe, and Li, with a total impurity element content of 128.86 µg·g−1. After purification, only lattice impurity elements Al, Ti, and Li remain in the processed quartz sand, resulting in a total impurity element content of 24.23 µg·g−1, an impurity removal rate of 81.20%, and the purity of SiO2 reaching 99.998 wt.%. It is suggested that when the quartz raw ore contains high content of lattice impurity elements, such as Al, Li, and Ti, it is difficult to remove them by the current purification method. In industrial production, considering the economic cost, if quartz sand still contains high content of lattice impurity elements Al, Ti, and Li after flotation, it cannot be used as a raw material for high-end HPQ.
{"title":"Preparation of High-Purity Quartz Sand by Vein Quartz Purification and Characteristics: A Case Study of Pakistan Vein Quartz","authors":"Mei Xia, Xiaoyong Yang, Zhenhui Hou","doi":"10.3390/min14070727","DOIUrl":"https://doi.org/10.3390/min14070727","url":null,"abstract":"This study focuses on the purification and evaluation of the high-purity quartz (HPQ) potential of vein quartz ore from Pakistan. Vein quartz is grayish-white and translucent, with its mineral composition mainly comprising quartz crystal. Processed quartz sand is obtained from quartz raw ore through purifying technologies, including crushing, ultrasonic desliming, flotation, high-temperature calcination, water quenching, hot pressure acid leaching, and chlorination roasting. The microscopic characteristics show that the vein quartz raw ore has a medium-coarse granular metacrystalline structure, high quartz content, with only a small quantity of fine-grained K-feldspar. The inclusions primarily consist of large-sized primary inclusions and secondary fluid inclusions developed along the micro-fractures, and the content of inclusions in most areas of the crystal is very low or even nonexistent. The quartz ore with such inclusion characteristics is considered a relatively good raw material for quartz. Component analysis shows that the main impurity elements in the quartz ore are Al, K, Ca, Na, Ti, Fe, and Li, with a total impurity element content of 128.86 µg·g−1. After purification, only lattice impurity elements Al, Ti, and Li remain in the processed quartz sand, resulting in a total impurity element content of 24.23 µg·g−1, an impurity removal rate of 81.20%, and the purity of SiO2 reaching 99.998 wt.%. It is suggested that when the quartz raw ore contains high content of lattice impurity elements, such as Al, Li, and Ti, it is difficult to remove them by the current purification method. In industrial production, considering the economic cost, if quartz sand still contains high content of lattice impurity elements Al, Ti, and Li after flotation, it cannot be used as a raw material for high-end HPQ.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141822493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This article documents the discovery of ‘bismuth white’ on three late eighteenth-century portrait miniatures in the Victoria and Albert Museum collections, painted by renowned English artist George Engleheart. Metallic bismuth and bismuth-containing minerals have been known for centuries and were used on various types of artistic production, from German Wismutmalerei to medieval manuscripts and Renaissance paintings. However, until now they had never been documented on portrait miniatures, despite documentary evidence that suggests their use. The Raman analysis of the three miniatures shows that bismuth oxychloride (BiOCl, corresponding to the mineral bismoclite) is present, and XRF data prove that this material was used as a white pigment in its own right. This work is a pilot study: it represents the first step in the rediscovery of bismuth white as an artist’s pigment, and hopes to provide encouragement to other institutions to look deeper in their collections and map out the use of a relatively rare white material which until now had not been detected or documented in fine art objects.
{"title":"Bismuth White (Bismuth Oxychloride) and Its Use in Portrait Miniatures Painted by George Engleheart","authors":"Lucia Burgio","doi":"10.3390/min14070723","DOIUrl":"https://doi.org/10.3390/min14070723","url":null,"abstract":"This article documents the discovery of ‘bismuth white’ on three late eighteenth-century portrait miniatures in the Victoria and Albert Museum collections, painted by renowned English artist George Engleheart. Metallic bismuth and bismuth-containing minerals have been known for centuries and were used on various types of artistic production, from German Wismutmalerei to medieval manuscripts and Renaissance paintings. However, until now they had never been documented on portrait miniatures, despite documentary evidence that suggests their use. The Raman analysis of the three miniatures shows that bismuth oxychloride (BiOCl, corresponding to the mineral bismoclite) is present, and XRF data prove that this material was used as a white pigment in its own right. This work is a pilot study: it represents the first step in the rediscovery of bismuth white as an artist’s pigment, and hopes to provide encouragement to other institutions to look deeper in their collections and map out the use of a relatively rare white material which until now had not been detected or documented in fine art objects.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141823820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Super-reduced phases (SRPs), such as silicon carbide (SiC) and metal silicides, have increasingly been reported in various geological environments. However, their origin remains controversial. SRP inclusions (e.g., metal silicides and metallic silicon (Si0)) within SiC are commonly believed to indicate a natural origin. Here, we identified an unusual SRP assemblage (SiC, (Fe,Ni)Si2, and Si0) in situ in an H5-type Jingshan ordinary chondrite. Simultaneously, our analysis showed that the SiC abrasives contain (Fe,Ni)Si2 and Si0 inclusions. Other inclusions in the artificial SiC were similar to those in natural SiC (moissanite) reported in reference data, including diverse metal silicides (e.g., FeSi, FeSi2, Fe3Si7, and Fe5Si3), as well as a light rare earth element-enriched SiO phase and Fe-Mn-Cr alloys. These inclusions were produced by the in situ reduction of silica and the interaction between Si-containing coke and hot metals during the synthesis of the SiC abrasives. The results demonstrate that the SRP assemblage in the Jingshan chondrite originates from abrasive contamination and that the SRP inclusions (with a low content of Ca, Al, Ti, and Zr) cannot be used as a conclusive indicator for natural SiC. Additionally, the morphologies, biaxiality, and polytypes (determined by Raman spectroscopy) of SiC abrasives bear resemblance to those reported for natural SiC, and caution must be exercised when identifying the origin of SRP in samples processed by conventional methods using SiC abrasives. At the end of this paper, we propose more direct and reliable methods for distinguishing between natural and synthetic SiC.
在各种地质环境中，碳化硅（SiC）和金属硅化物等超还原相（SRP）的报道越来越多。然而，它们的来源仍存在争议。人们普遍认为碳化硅中的 SRP 包裹体（如金属硅化物和金属硅 (Si0)）表明了其天然来源。在这里，我们在一块H5型景山普通软玉中就地发现了一种不寻常的SRP组合（SiC、（Fe,Ni）Si2和Si0）。同时，我们的分析表明，SiC磨料中含有（Fe,Ni）Si2和Si0包裹体。人造碳化硅中的其他包裹体与参考数据中报道的天然碳化硅（莫桑石）中的包裹体相似，包括各种金属硅化物（如FeSi、FeSi2、Fe3Si7和Fe5Si3），以及轻稀土元素富集的SiO相和Fe-Mn-Cr合金。这些夹杂物是在合成碳化硅磨料的过程中，通过二氧化硅的原位还原以及含硅焦炭和热金属之间的相互作用产生的。研究结果表明，景山软玉中的SRP组合源于磨料污染，SRP包裹体（Ca、Al、Ti和Zr含量较低）不能作为天然SiC的确凿指标。此外，SiC 磨料的形态、双轴性和多型性（通过拉曼光谱确定）与报告的天然 SiC 相似，因此在确定使用 SiC 磨料的传统方法加工的样品中 SRP 的来源时必须谨慎。在本文的最后，我们提出了区分天然和合成碳化硅的更直接、更可靠的方法。
{"title":"Clarification of Distinguishing Natural Super-Reduced Phase from Synthetics Based on Inclusions","authors":"Yutong Ma, Mengqi Miao, Ming Chen, Shan Qin","doi":"10.3390/min14070722","DOIUrl":"https://doi.org/10.3390/min14070722","url":null,"abstract":"Super-reduced phases (SRPs), such as silicon carbide (SiC) and metal silicides, have increasingly been reported in various geological environments. However, their origin remains controversial. SRP inclusions (e.g., metal silicides and metallic silicon (Si0)) within SiC are commonly believed to indicate a natural origin. Here, we identified an unusual SRP assemblage (SiC, (Fe,Ni)Si2, and Si0) in situ in an H5-type Jingshan ordinary chondrite. Simultaneously, our analysis showed that the SiC abrasives contain (Fe,Ni)Si2 and Si0 inclusions. Other inclusions in the artificial SiC were similar to those in natural SiC (moissanite) reported in reference data, including diverse metal silicides (e.g., FeSi, FeSi2, Fe3Si7, and Fe5Si3), as well as a light rare earth element-enriched SiO phase and Fe-Mn-Cr alloys. These inclusions were produced by the in situ reduction of silica and the interaction between Si-containing coke and hot metals during the synthesis of the SiC abrasives. The results demonstrate that the SRP assemblage in the Jingshan chondrite originates from abrasive contamination and that the SRP inclusions (with a low content of Ca, Al, Ti, and Zr) cannot be used as a conclusive indicator for natural SiC. Additionally, the morphologies, biaxiality, and polytypes (determined by Raman spectroscopy) of SiC abrasives bear resemblance to those reported for natural SiC, and caution must be exercised when identifying the origin of SRP in samples processed by conventional methods using SiC abrasives. At the end of this paper, we propose more direct and reliable methods for distinguishing between natural and synthetic SiC.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141827239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study investigates the impact of dissolved carboxymethyl cellulose (CMC) and agar on the dolomitization reaction of calcite at 200 °C. Previous studies have suggested that CMC and agar promote dolomite precipitation at room temperature. However, this study found that their decomposition products hinder the reaction at 200 °C, with uncertainty about their role at other temperatures. The inhibitory effect of the decomposition products could be attributed to their adsorption onto calcite surfaces, which hinders their dissolution. This results in a longer reaction induction period and replacement period. Regression analysis demonstrates that the 0.1 g/L agar and 0.2 g/L CMC series decrease the cation ordering rate of dolomite produced from synthetic calcite when compared with series without polysaccharides. In contrast, the 0.1 g/L CMC series shows a slight increase in the cation ordering rate compared with series without polysaccharides. The findings of this study suggest a notable potential impact of the decomposition products of polysaccharides on the ordering of dolomite, although it is uncertain whether they inhibit this ordering process. The inhibitory effect observed in the decomposition products of CMC and agar could also exist in the decomposition products of the extracellular polymeric substances (EPS) and bacteria cell walls found in sedimentary rocks during burial diagenesis. Therefore, further research is necessary to understand the role of EPS and bacteria cell walls in dolomitization, since their impact is not always predictable.
{"title":"Inhibitory Effects of Polysaccharides on the Dolomitization Reaction of Calcite at 200 °C","authors":"Yang Wei, Hiromi Konishi","doi":"10.3390/min14070721","DOIUrl":"https://doi.org/10.3390/min14070721","url":null,"abstract":"This study investigates the impact of dissolved carboxymethyl cellulose (CMC) and agar on the dolomitization reaction of calcite at 200 °C. Previous studies have suggested that CMC and agar promote dolomite precipitation at room temperature. However, this study found that their decomposition products hinder the reaction at 200 °C, with uncertainty about their role at other temperatures. The inhibitory effect of the decomposition products could be attributed to their adsorption onto calcite surfaces, which hinders their dissolution. This results in a longer reaction induction period and replacement period. Regression analysis demonstrates that the 0.1 g/L agar and 0.2 g/L CMC series decrease the cation ordering rate of dolomite produced from synthetic calcite when compared with series without polysaccharides. In contrast, the 0.1 g/L CMC series shows a slight increase in the cation ordering rate compared with series without polysaccharides. The findings of this study suggest a notable potential impact of the decomposition products of polysaccharides on the ordering of dolomite, although it is uncertain whether they inhibit this ordering process. The inhibitory effect observed in the decomposition products of CMC and agar could also exist in the decomposition products of the extracellular polymeric substances (EPS) and bacteria cell walls found in sedimentary rocks during burial diagenesis. Therefore, further research is necessary to understand the role of EPS and bacteria cell walls in dolomitization, since their impact is not always predictable.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141827244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this study, the evolution behavior of the particle size distribution during the grinding process was examined with fractal theory. According to the distribution index k of the Rosin–Rammler–Benne model, the relationship between the fractal dimension D of the fractal theory and the distribution index k is discussed. The fractal dimension D was used to evaluate the uniformity of the particle size distribution of the grinding product. In addition, the population balance model was used to simulate the breakage behavior of each size interval. The result indicates that the non-first-order model presented a better fitting performance in the breakage behavior of the coarse size and the desired size when compared with the other type of model. It can be found that the breakage rate increased with the solid concentration. However, the breakage distribution function is independent of the solid concentration in this study. These results suggest that the effect of the solid concentration on the fraction of the coarse size broken into the desired size was not significant. Furthermore, the simulated data are discussed and analyzed with the attainable region method as well as the difference in the change rate of the desired size and the overgrinding size. It can be found that to produce a higher fraction of the desired size in the grinding products, the residence time of the material in the mill needs be shortened with a higher solid concentration.
本研究利用分形理论研究了研磨过程中粒度分布的演变行为。根据 Rosin-Rammler-Benne 模型的分布指数 k，讨论了分形理论的分形维数 D 与分布指数 k 之间的关系。分形维数 D 用于评价研磨产品粒度分布的均匀性。此外，还利用种群平衡模型模拟了每个粒度区间的破碎行为。结果表明，与其他类型的模型相比，非一阶模型在粗粒度和理想粒度的破碎行为方面具有更好的拟合性能。可以发现，破碎率随固体浓度的增加而增加。然而，本研究中的破碎分布函数与固体浓度无关。这些结果表明，固体浓度对粗粒度破碎成所需粒度的部分影响不大。此外，还用可实现区域法以及期望粒度和过磨粒度变化率的差异对模拟数据进行了讨论和分析。可以发现，要在研磨产品中生产出更多的所需粒度，就需要在提高固体浓度的情况下缩短物料在磨机中的停留时间。
{"title":"Effect of Solid Concentration on Particle Size Distribution and Grinding Kinetics in Stirred Mills","authors":"Wang Guo, Keqi Guo","doi":"10.3390/min14070720","DOIUrl":"https://doi.org/10.3390/min14070720","url":null,"abstract":"In this study, the evolution behavior of the particle size distribution during the grinding process was examined with fractal theory. According to the distribution index k of the Rosin–Rammler–Benne model, the relationship between the fractal dimension D of the fractal theory and the distribution index k is discussed. The fractal dimension D was used to evaluate the uniformity of the particle size distribution of the grinding product. In addition, the population balance model was used to simulate the breakage behavior of each size interval. The result indicates that the non-first-order model presented a better fitting performance in the breakage behavior of the coarse size and the desired size when compared with the other type of model. It can be found that the breakage rate increased with the solid concentration. However, the breakage distribution function is independent of the solid concentration in this study. These results suggest that the effect of the solid concentration on the fraction of the coarse size broken into the desired size was not significant. Furthermore, the simulated data are discussed and analyzed with the attainable region method as well as the difference in the change rate of the desired size and the overgrinding size. It can be found that to produce a higher fraction of the desired size in the grinding products, the residence time of the material in the mill needs be shortened with a higher solid concentration.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141719876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shi-Chang Wang, Yu-Jie Hao, Lu Shi, Zhen Tang, Shuang Zhu
The Lengjimanda plate is situated in the middle section of the Da Hinggan mountains, in the eastern section of the Tianshan Xingmeng orogenic belt. To determine the formation age of the volcanic rocks in the Longjiang formation in this area, to explore their origin and tectonic background, and to reconstruct the geodynamic evolution of the region, this study conducted petrological, zircon U–Pb geochronological, geochemical, and isotopic analyses of the volcanic rocks in the Longjiang formation. The Longjiang formation’s volcanic rocks are primarily composed of trachyandesite, trachyte trachydacite, and andesite, which are intermediate basic volcanic rocks. They are enriched in large-ion lithophile elements, are depleted in high-field-strength elements, are significantly fractionated between light and heavy rare earth elements, and exhibit a moderate negative Eu anomaly in most samples. The results of the LA–ICP–MS zircon U–Pb dating indicate that the volcanic rocks in this group were formed in the Early Cretaceous period at 129.1 ± 0.82 Ma. The zircon εHf(t) ranges from +1.13 to +43.77, the tDM2 ranges from +655 to +1427 Ma, the initial Sr ratio (87Sr/86Sr)i ranges from 0.7030 to 0.7036, and the εNd(t) ranges from +2.1 to +6.6. Based on the geochemical compositions and isotopic characteristics of the rocks, the initial magma of the volcanic rocks in the Longjiang formation originated from the partial melting of basaltic crustal materials, with a source material inferred to be depleted mantle-derived young crustal. These rocks were formed in a superimposed post-collisional and continental arc environment, possibly associated with the Mongol-Okhotsk Ocean closure and the oblique subduction of the Pacific plate. This study addresses a research gap regarding the volcanic rocks of the Longjiang formation in this area. Its findings can be applied to exploration and prospecting in the region.
{"title":"Geochronology, Geochemical Characterization and Tectonic Background of Volcanic Rocks of the Longjiang Formation in the Lengjimanda Plate Area, Middle Da Hinggan Mountains","authors":"Shi-Chang Wang, Yu-Jie Hao, Lu Shi, Zhen Tang, Shuang Zhu","doi":"10.3390/min14070719","DOIUrl":"https://doi.org/10.3390/min14070719","url":null,"abstract":"The Lengjimanda plate is situated in the middle section of the Da Hinggan mountains, in the eastern section of the Tianshan Xingmeng orogenic belt. To determine the formation age of the volcanic rocks in the Longjiang formation in this area, to explore their origin and tectonic background, and to reconstruct the geodynamic evolution of the region, this study conducted petrological, zircon U–Pb geochronological, geochemical, and isotopic analyses of the volcanic rocks in the Longjiang formation. The Longjiang formation’s volcanic rocks are primarily composed of trachyandesite, trachyte trachydacite, and andesite, which are intermediate basic volcanic rocks. They are enriched in large-ion lithophile elements, are depleted in high-field-strength elements, are significantly fractionated between light and heavy rare earth elements, and exhibit a moderate negative Eu anomaly in most samples. The results of the LA–ICP–MS zircon U–Pb dating indicate that the volcanic rocks in this group were formed in the Early Cretaceous period at 129.1 ± 0.82 Ma. The zircon εHf(t) ranges from +1.13 to +43.77, the tDM2 ranges from +655 to +1427 Ma, the initial Sr ratio (87Sr/86Sr)i ranges from 0.7030 to 0.7036, and the εNd(t) ranges from +2.1 to +6.6. Based on the geochemical compositions and isotopic characteristics of the rocks, the initial magma of the volcanic rocks in the Longjiang formation originated from the partial melting of basaltic crustal materials, with a source material inferred to be depleted mantle-derived young crustal. These rocks were formed in a superimposed post-collisional and continental arc environment, possibly associated with the Mongol-Okhotsk Ocean closure and the oblique subduction of the Pacific plate. This study addresses a research gap regarding the volcanic rocks of the Longjiang formation in this area. Its findings can be applied to exploration and prospecting in the region.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141719916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Haijie Li, Gauti Asbjörnsson, K. Bhadani, Magnus Evertsson
The dynamics of milling circuits, particularly those involving Semi-Autogenous Grinding (SAG) mills, are not adequately studied, despite their critical importance in mineral processing. This paper aims to investigate the dynamic behavior of an SAG mill pebble recycling circuit under varying feed ore conditions, focusing on both uncontrollable parameters (such as ore hardness) and controllable parameters (including circuit layout and pebble crusher configurations). The study is carried out with Simulink dynamic simulations. Our findings reveal several key insights. Firstly, plant designs based solely on static simulations may not be adequate for large or complex circuits, as they fail to account for the dynamic nature of milling processes. Second, incorporating stockpiles after pebble crushing can effectively mitigate the impact of dynamic fluctuations, leading to more stable circuit performance. Third, different circuit layouts can facilitate easier maintenance and operational flexibility. Notably, finer pebble crushing can enhance circuit throughput by 5% to 10%.
尽管磨矿回路，尤其是涉及半自磨机（SAG）的磨矿回路在矿物加工中至关重要，但对其动态特性的研究却并不充分。本文旨在研究 SAG 磨机卵石循环回路在不同给矿条件下的动态行为，重点关注不可控参数（如矿石硬度）和可控参数（包括回路布局和卵石破碎机配置）。研究是通过 Simulink 动态模拟进行的。我们的研究结果揭示了几个关键问题。首先，仅基于静态模拟的工厂设计可能无法满足大型或复杂回路的要求，因为它们无法考虑到磨矿过程的动态性质。其次，在鹅卵石破碎后加入堆料可有效减轻动态波动的影响，使回路性能更加稳定。第三，不同的回路布局可方便维护和提高操作灵活性。值得注意的是，更精细的鹅卵石破碎可将回路吞吐量提高 5%至 10%。
{"title":"Investigating Dynamic Behavior in SAG Mill Pebble Recycling Circuits: A Simulation Approach","authors":"Haijie Li, Gauti Asbjörnsson, K. Bhadani, Magnus Evertsson","doi":"10.3390/min14070716","DOIUrl":"https://doi.org/10.3390/min14070716","url":null,"abstract":"The dynamics of milling circuits, particularly those involving Semi-Autogenous Grinding (SAG) mills, are not adequately studied, despite their critical importance in mineral processing. This paper aims to investigate the dynamic behavior of an SAG mill pebble recycling circuit under varying feed ore conditions, focusing on both uncontrollable parameters (such as ore hardness) and controllable parameters (including circuit layout and pebble crusher configurations). The study is carried out with Simulink dynamic simulations. Our findings reveal several key insights. Firstly, plant designs based solely on static simulations may not be adequate for large or complex circuits, as they fail to account for the dynamic nature of milling processes. Second, incorporating stockpiles after pebble crushing can effectively mitigate the impact of dynamic fluctuations, leading to more stable circuit performance. Third, different circuit layouts can facilitate easier maintenance and operational flexibility. Notably, finer pebble crushing can enhance circuit throughput by 5% to 10%.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141642317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Over the past two decades, significant deposit discoveries were made in Northeastern China, including the super-large Chalukou, Daheishan, and Luming porphyry Mo deposits. The discovery of the Luming deposit was accomplished through verification of stream sediment anomalies, with mineralization closely associated with early Jurassic monzogranite and granite porphyry. Previous studies primarily focused on the mineralization mechanisms of these deposits without adequately addressing the exploration methods and prospecting criteria. This study involved a comprehensive re-evaluation of geological observations, analysis of rock primary halo, gravity and magnetic surveys, and induced polarization surveys conducted during exploration campaigns at the Luming porphyry Mo deposit. The results suggest that hydrothermal breccias play a critical role in controlling the mineralization by forming a central low-grade core within the deposit while the Mo mineralization and hydrothermal alteration exhibit a donut-shaped distribution around it. The primary halo shows a distinct metal zonation moving from a central W-Bi-Mo-(Sb) to a peripheral Cu-Co-Ni and a distal Pb-Zn-Ag-In. The mineralization zone exhibits a low Bouguer gravity anomaly, negative magnetic anomaly, medium to low resistivity, and moderate to high chargeability, indicating the effectiveness of geophysical methods in defining the extent of the ore body. The Luming porphyry Mo deposit and distal skarn-epithermal Pb-Zn mineralization are parts of a porphyry-related magmatic-hydrothermal system. The results of this study offer valuable insights into the genesis of porphyry Mo deposits and their implications for prospecting in the forested region of Northeastern China.
{"title":"Discovery and Exploration of the Luming Porphyry Mo Deposit, Northeastern China: Implications for Regional Prospecting","authors":"Bangfei Gao, Minghua Dong, Hui Xie, Zhiliang Liu, Yihang Li, Tong Zhou","doi":"10.3390/min14070718","DOIUrl":"https://doi.org/10.3390/min14070718","url":null,"abstract":"Over the past two decades, significant deposit discoveries were made in Northeastern China, including the super-large Chalukou, Daheishan, and Luming porphyry Mo deposits. The discovery of the Luming deposit was accomplished through verification of stream sediment anomalies, with mineralization closely associated with early Jurassic monzogranite and granite porphyry. Previous studies primarily focused on the mineralization mechanisms of these deposits without adequately addressing the exploration methods and prospecting criteria. This study involved a comprehensive re-evaluation of geological observations, analysis of rock primary halo, gravity and magnetic surveys, and induced polarization surveys conducted during exploration campaigns at the Luming porphyry Mo deposit. The results suggest that hydrothermal breccias play a critical role in controlling the mineralization by forming a central low-grade core within the deposit while the Mo mineralization and hydrothermal alteration exhibit a donut-shaped distribution around it. The primary halo shows a distinct metal zonation moving from a central W-Bi-Mo-(Sb) to a peripheral Cu-Co-Ni and a distal Pb-Zn-Ag-In. The mineralization zone exhibits a low Bouguer gravity anomaly, negative magnetic anomaly, medium to low resistivity, and moderate to high chargeability, indicating the effectiveness of geophysical methods in defining the extent of the ore body. The Luming porphyry Mo deposit and distal skarn-epithermal Pb-Zn mineralization are parts of a porphyry-related magmatic-hydrothermal system. The results of this study offer valuable insights into the genesis of porphyry Mo deposits and their implications for prospecting in the forested region of Northeastern China.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141722302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jingsheng Chen, Yi Tian, Zhonghui Gao, Bin Li, Chen Zhao, Weiwei Li, Chao Zhang, Yan Wang
Petrological, geochronological, and geochemical analyses of mafic rocks in northern Liaoning were conducted to constrain the formation age of the Proterozoic strata, and to further study the source characteristics, genesis, and tectonic setting. The mafic rocks in northern Liaoning primarily consist of basalt, diabase, gabbro, and amphibolite. Results of zircon U-Pb chronology reveal four stages of mafic magma activities in northern Liaoning: the first stage of basalt (2209 ± 12 Ma), the second stage of diabase (2154 ± 15 Ma), the third stage of gabbro (2063 ± 7 Ma), and the fourth stage of magmatic protolith of amphibolite (2018 ± 13 Ma). Combined with the unconformity overlying Neoproterozoic granite, the formation age of the Proterozoic strata in northern Liaoning was found to be Paleoproterozoic rather than Middle Neoproterozoic by the geochronology of these mafic rocks. A chronological framework of mafic magmatic activities in the eastern segment of the North China Craton (NCC) is proposed. The mafic rocks in northern Liaoning exhibit compositional ranges of 46.39–50.33 wt% for SiO2, 2.95–5.08 wt% for total alkalis (K2O + Na2O), 6.17–7.50 wt% for MgO, and 43.32–52.02 for the Mg number. TiO2 contents lie between 1.61 and 2.39 wt%, and those of MnO between 0.17 and 0.21 wt%. The first basalt and the fourth amphibolite show low total rare earth element contents. Normalized against primitive mantle, they are enriched in large ion lithophile elements (Rb, Ba, K), depleted in high field strength elements (Th, U, Nb, Ta, Zr, Ti), and exhibit negative anomalies in Sr and P, as well as slight positive anomalies in Zr and Hf. The second diabase and the third gabbro have similar average total rare earth element contents. The diabase shows slight negative Eu anomalies (Eu/Eu* = 0.72–0.88), enrichment in large ion lithophile elements (Ba), depletion in Rb, and slight positive anomalies in high field strength elements (Th, U, Nb, Ta, Zr, Hf, Ti), with negative anomalies in K, Sr, and P. The gabbro is enriched in large ion lithophile elements (Rb, Ba, K), depleted in high field strength elements (Th, U, Nb, Ta, Zr, Hf), and exhibits positive anomalies in Eu (Eu/Eu* = 1.31–1.37). The contents of Cr, Co, and Ni of these four stages of mafic rocks are higher than those of N-MORB. The characteristics of trace element ratios indicate that the mafic rocks belong to the calc-alkaline series and originate from the transitional mantle. During the process of magma ascent and emplacement, it is contaminated by continental crustal materials. There are residual hornblende and spinel in the magma source of the first basalt. The other three magma sources contain residual garnet and spinel. The third gabbro was formed in an island arc environment, and the other three stages of mafic rocks originated from the Dupal OIB and were formed in an oceanic island environment. The discovery of mafic rocks in northern Liaoning suggests that the Longgang Block underwent oceanic subdu
{"title":"Geochronology and Geochemistry of Paleoproterozoic Mafic Rocks in Northern Liaoning and Their Geological Significance","authors":"Jingsheng Chen, Yi Tian, Zhonghui Gao, Bin Li, Chen Zhao, Weiwei Li, Chao Zhang, Yan Wang","doi":"10.3390/min14070717","DOIUrl":"https://doi.org/10.3390/min14070717","url":null,"abstract":"Petrological, geochronological, and geochemical analyses of mafic rocks in northern Liaoning were conducted to constrain the formation age of the Proterozoic strata, and to further study the source characteristics, genesis, and tectonic setting. The mafic rocks in northern Liaoning primarily consist of basalt, diabase, gabbro, and amphibolite. Results of zircon U-Pb chronology reveal four stages of mafic magma activities in northern Liaoning: the first stage of basalt (2209 ± 12 Ma), the second stage of diabase (2154 ± 15 Ma), the third stage of gabbro (2063 ± 7 Ma), and the fourth stage of magmatic protolith of amphibolite (2018 ± 13 Ma). Combined with the unconformity overlying Neoproterozoic granite, the formation age of the Proterozoic strata in northern Liaoning was found to be Paleoproterozoic rather than Middle Neoproterozoic by the geochronology of these mafic rocks. A chronological framework of mafic magmatic activities in the eastern segment of the North China Craton (NCC) is proposed. The mafic rocks in northern Liaoning exhibit compositional ranges of 46.39–50.33 wt% for SiO2, 2.95–5.08 wt% for total alkalis (K2O + Na2O), 6.17–7.50 wt% for MgO, and 43.32–52.02 for the Mg number. TiO2 contents lie between 1.61 and 2.39 wt%, and those of MnO between 0.17 and 0.21 wt%. The first basalt and the fourth amphibolite show low total rare earth element contents. Normalized against primitive mantle, they are enriched in large ion lithophile elements (Rb, Ba, K), depleted in high field strength elements (Th, U, Nb, Ta, Zr, Ti), and exhibit negative anomalies in Sr and P, as well as slight positive anomalies in Zr and Hf. The second diabase and the third gabbro have similar average total rare earth element contents. The diabase shows slight negative Eu anomalies (Eu/Eu* = 0.72–0.88), enrichment in large ion lithophile elements (Ba), depletion in Rb, and slight positive anomalies in high field strength elements (Th, U, Nb, Ta, Zr, Hf, Ti), with negative anomalies in K, Sr, and P. The gabbro is enriched in large ion lithophile elements (Rb, Ba, K), depleted in high field strength elements (Th, U, Nb, Ta, Zr, Hf), and exhibits positive anomalies in Eu (Eu/Eu* = 1.31–1.37). The contents of Cr, Co, and Ni of these four stages of mafic rocks are higher than those of N-MORB. The characteristics of trace element ratios indicate that the mafic rocks belong to the calc-alkaline series and originate from the transitional mantle. During the process of magma ascent and emplacement, it is contaminated by continental crustal materials. There are residual hornblende and spinel in the magma source of the first basalt. The other three magma sources contain residual garnet and spinel. The third gabbro was formed in an island arc environment, and the other three stages of mafic rocks originated from the Dupal OIB and were formed in an oceanic island environment. The discovery of mafic rocks in northern Liaoning suggests that the Longgang Block underwent oceanic subdu","PeriodicalId":18601,"journal":{"name":"Minerals","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141641425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：