Minerals最新文献

{"title":"Boron Enrichment in Salinized Lacustrine Organic-Rich Shale of the Paleogene Biyang Depression, East China: Occurrence and Geological Controlling Factors","authors":"Yu Song, Paerzhana Paerhati, Shilin Xu, Bo Gao, Shu Jiang, Shuifu Li, Yuchen Wang, Hecun Lv","doi":"10.3390/min14090904","DOIUrl":"https://doi.org/10.3390/min14090904","url":null,"abstract":"Although boron (B) is widely applied as a paleosalinity indicator for ancient lakes, the occurrence and geological controls of B enrichment in salinized lacustrine organic-rich shale (SLORS) are poorly understood. This study addresses this issue by comparing the mineral and element compositions of high-boron shale (HBS) and low-boron shale (LBS) from the Paleogene Biyang Depression, using integrated XRD, XRF, and ICP-MS analyses. The mineral composition of HBS is dominated by illite, whereas LBS primarily consists of albite; both are of detrital origin. Compared to the element composition of UCC, HBS is extremely enriched in Mo and W, whereas LBS is extremely enriched in W and U. Boron is positively correlated with Al2O3 and negatively correlated with Na2O, suggesting that B primarily occurs in illite. An enhanced extent of chemical weathering prevailed during the deposition of HBS, providing a greater supply of illite to the basin. Higher pH levels and greater reduction during HBS deposition encouraged illite absorption of B, ultimately leading to B enrichment in shale. Our findings suggest that pH and redox conditions, as well as the mineral compositions of shale, should be fully considered during the application of B and related ratios as paleosalinity indicators.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"59 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Flotation Tailings from Cu-Au Mining (Bor, Serbia) as a Potential Secondary Raw Material for Valuable Metals Recovery","authors":"Vanja Trifunović, Ljiljana Avramović, Dragana Božić, Marija Jonović, Dragan Šabaz, Dejan Bugarin","doi":"10.3390/min14090905","DOIUrl":"https://doi.org/10.3390/min14090905","url":null,"abstract":"The increased exploitation of ores leads to the generation of mining waste, which has a negative impact on the environment and human health. For this reason, it is necessary to take care of it in an adequate way by applying some of the possible treatments. In addition to protecting the environment by applying appropriate treatment, there is also the possibility of making a profit by valorizing useful elements from mining waste. In order to choose the most adequate treatment, it is necessary to perform the characterization of mining waste. This paper contains a detailed characterization of the flotation tailings deposited at the Old Flotation Tailings in eastern Serbia, originating from copper ore processing. Characterization includes physico-chemical analysis, polarizing microscope analysis, X-ray Diffraction analysis (XRD) and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM-EDS) analysis analysis. The obtained results indicate that the investigated flotation tailings can be used as a secondary raw material for metal recovery, in this case primarily copper (whose content is about 0.24%), gold (with a content of about 0.43 ppm) and silver (with a content of about 1.7 ppm). Considering that the content of valuable elements is quite low, it is suggested to apply hydrometallurgical treatment for their recovery.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"19 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A New Mineral Calcioveatchite, SrCaB11O16(OH)5·H2O, and the Veatchite–Calcioveatchite Isomorphous Series","authors":"Igor V. Pekov, Natalia V. Zubkova, Vladimir N. Apollonov, Vasiliy O. Yapaskupt, Sergey N. Britvin, Dmitry Yu. Pushcharovsky","doi":"10.3390/min14090901","DOIUrl":"https://doi.org/10.3390/min14090901","url":null,"abstract":"The new mineral calcioveatchite, ideally SrCaB11O16(OH)5·H2O, is a Ca-Sr-ordered analogue of veatchite. It was found at the Nepskoe potassium salt deposit, Irkutsk Oblast, Siberia, Russia in halite-sylvite and sylvite-carnallite rocks, with boracite, hilgardite, kurgantaite, hydroboracite, volkovskite, veatchite, anhydrite, magnesite, and quartz. Calcioveatchite forms prismatic or tabular crystals up to 1 × 1.5 × 3 mm3 and crystal clusters up to 3 mm across. It is transparent and colourless with vitreous lustre. Calcioveatchite is brittle, cleavage is perfect on {010}, the Mohs’ hardness is ca 2, Dmeas is 2.58(1), and Dcalc is 2.567 g cm−3. Calcioveatchite is optically biaxial (+), α = 1.543(2), β = 1.550(5), γ = 1.626(2), 2Vmeas = 30(10)°, and 2Vcalc = 35°. The average chemical composition (wt.%, electron microprobe, H2O calculated by stoichiometry) is: CaO 7.05, SrO 20.70, B2O3 61.96, H2O 10.22, and total 99.93. The empirical formula, calculated based on 22 O apfu = O16(OH)5(H2O) pfu, is Sr1.23Ca0.78B10.99O16(OH)5·H2O. Calcioveatchite is monoclinic, space group P21, a = 6.7030(3), b = 20.6438(9), c = 6.6056(3) Å, β = 119.153(7)°, V = 798.26(8) Å3, and Z = 2. Polytype: 1M. The strongest reflections of the powder XRD pattern [d,Å(I,%)(hkl)] are: 10.35(100)(020), 5.633(12)(110), 5.092(10)(120), 3.447(14)(060), 3.362(13)(101, 051), 3.309(38)(–102), 2.862(10)(012), and 2.585(19)(080). The crystal structure was solved based on single-crystal XRD data, R1 = 0.0420. Calcioveatchite (calcioveatchite-1M) is an isostructural analogue of veatchite-1M with the 11-fold cation polyhedron occupied mainly by Sr [Sr0.902(8)Ca0.098(8)] whereas the 10-fold polyhedron is Ca dominant [Ca0.686(7)Sr0.314(7)]. The chemical composition of veatchite from five localities in Russia (Nepskoe), Kazakhstan (Shoktybay and Chelkar in the North Caspian Region), and the USA (Tick Canyon and Billie Mine in California) was studied, and it is shown to exist in nature as a continuous, almost complete isomorphous series which extends from Ca-free veatchite, Sr2B11O16(OH)5·H2O, to calcioveatchite with the composition Sr1.14Ca0.87B10.99O16(OH)5·H2O.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"2 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Open-Circuit Technology of Zinc Oxide Ore Flotation with Ternary Collector and Its Adsorption Characteristics on Smithsonite Surface","authors":"Zhiwei Li, Qicheng Feng, Qian Zhang, Shuming Wen","doi":"10.3390/min14090902","DOIUrl":"https://doi.org/10.3390/min14090902","url":null,"abstract":"The sulfidization-amine flotation method is commonly used for the beneficiation of zinc oxide ores. Lanping zinc oxide ores contains 8.40% zinc, with the main mineral being smithsonite; additionally, they have a high mud content. Conventional sulfidization–ammonium flotation presents a low flotation index and unsatisfactory flotation froth. A new open-circuit technology is employed to treat Lanping zinc oxide ores, where Na2S, KG-248, and dodecyl amine + sodium isoamyl xanthate + ammonium dibutyl dithiophosphate are used as the regulator, depressant, and ternary collector, respectively. Consequently, the flotation indices for the zinc grade and recovery are 28.71% and 86.24%, respectively, and the flotation froth becomes more stable. Subsequently, the flotation behavior and adsorption mechanism of smithsonite with a ternary collector are investigated. The flotation recovery of smithsonite increases to 94.40% after treatment with the ternary collector. Surface-analysis results indicate that the ternary collector can synergistically adsorb onto the sulfidized smithsonite surface to enhance its hydrophobicity, thus increasing the floatability of smithsonite. Meanwhile, the total consumption of the collector in the ternary-collector system is lower than that in the binary- or unitary-collector system.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"8 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dissolution Mechanisms and Surface Charge of Clay Mineral Nanoparticles: Insights from Kinetic Monte Carlo Simulations","authors":"Inna Kurganskaya","doi":"10.3390/min14090900","DOIUrl":"https://doi.org/10.3390/min14090900","url":null,"abstract":"The widespread use of clay minerals and clays in environmental engineering, industry, medicine, and cosmetics largely stems from their adsorption properties and surface charge, as well as their ability to react with water. The dissolution and growth of minerals as a function of pH are closely related to acid–base reactions at their surface sites and their surface charge. The vivid tapestry of different types of surface sites across different types of clay minerals generates difficulties in experimental studies of structure–property relationships. The aim of this paper is to demonstrate how a mesoscale stochastic kinetic Monte Carlo (kMC) approach altogether with atomistic acid-base models and empirical data can be used for understanding the mechanisms of dissolution and surface charge behavior of clay minerals. The surface charge is modeled based on equilibrium equations for de/protonated site populations, which are defined by the pH and site-specific acidity constants (pKas). Lowered activation energy barriers for these sites in de/protonated states introduce pH-dependent effects into the dissolution kinetics. The V-shaped curve observed in laboratory experiments is reproduced with the new kMC model. A generic rate law for clay mineral dissolution as a function of pH is derived from this study. Thus, the kMC approach can be used as a hypothesis-testing tool for the verification of acid–base models for clay and other minerals and their influence on the kinetics of mineral dissolution and growth.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"32 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sandstone Porosity Evolution and Reservoir Formation Models of the Paleogene Huagang Formation in Yuquan Structure of West Lake Sag, East China Sea Basin","authors":"Yonghuang Cai, Zhengxiang Lv, Yuanhua Qing, Cheng Xie, Bingjie Cheng, Zheyuan Liao, Bing Xu","doi":"10.3390/min14090899","DOIUrl":"https://doi.org/10.3390/min14090899","url":null,"abstract":"The West Lake Sag is abundant in oil and gas reserves, primarily in the Huagang Formation reservoir which serves as the primary source of production. The level of exploration is rather high, but there are still some unresolved issues, such as an unclear understanding of pore evolution features and reservoir growth mode. To tackle the aforementioned problems, this study employs optical microscopic examination, scanning electron microscope analysis, inclusion analysis, isotope analysis, X-ray diffraction analysis, and other techniques to elucidate the primary factors governing reservoir development and establish an analytical model regarding the cause of the sandstone reservoir. The results are as follows: (1) The sandstone reservoirs of the Huagang Formation of the Yuquan (abbreviated to YQ) Structure are now in the mesomorphic A stage as a whole, and minerals such as 4-phase authigenic quartz, 2-phase illite, 2-phase chlorite, 1-phase kaolinite, 1-phase ammonite mixing layer and 2-phase carbonate were formed during the diagenesis. (2) Feldspar and carbonate solution pores make up the majority of the reservoir space. About 10% of the porosity is made up of carbonate solution pores, which are the most prevalent reservoir space. Carbonate solution pores are primarily made up of metasomatic carbonate solution pores and cemented carbonate solution pores. Feldspar solution pores come next, contributing roughly 6.2% of the porosity. At 1.8%, residual intergranular holes are the least common. (3) The four main processes listed below are responsible for the creation of pores in the sandstone of the Huagang creation. The early carbonate cements resist the destruction of mechanical compaction and effectively preserve intergranular volume. The high content of feldspar provided a material basis for later dissolution. Early chlorite surrounding the edges of particles reduced the damage of authigenic minerals to porosity. The faults and cracks formed by the later structural inversion connected to the acidic water in the atmosphere, causing the dissolution of carbonate minerals and feldspar in the sandstone of the Huagang Formation. (4) Carbonate dissolution + feldspar dissolution type, carbonate dissolution type, and feldspar dissolution type are the three main types of reservoir formation in the Huagang Formation; the first two types mainly develop in the Upper Huagang Formation, while the latter mainly develops in the lower part of the Huagang Formation. The research results are conducive to the establishment of a geological prediction model for high-quality reservoirs of different geneses in the Huagang Formation and promote the exploration process of deep-seated hydrocarbons in the West Lake Sag.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"1 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Research on Prediction of Ash Content in Flotation-Recovered Clean Coal Based on NRBO-CNN-LSTM","authors":"Yujiao Li, Haizeng Liu, Fucheng Lu","doi":"10.3390/min14090894","DOIUrl":"https://doi.org/10.3390/min14090894","url":null,"abstract":"Ash content is an important production indicator of flotation performance, reflecting the current operating conditions of the flotation system and the recovery rate of clean coal. It also holds significant importance for the intelligent control of flotation. In recent years, the development of machine vision and deep learning has made it possible to detect ash content in flotation-recovered clean coal. Therefore, a prediction method for ash content in flotation-recovered clean coal based on image processing of the surface characteristics of flotation froth is studied. A convolutional neural network –long short-term memory (CNN-LSTM) model optimized by Newton–Raphson is proposed for predicting the ash content of flotation froth. Initially, the collected flotation froth video is preprocessed to extract the feature dataset of flotation froth images. Subsequently, a hybrid CNN-LSTM network architecture is constructed. Convolutional neural networks are employed to extract image features, while long short-term memory networks capture time series information, enabling the prediction of ash content. Experimental results indicate that the prediction accuracy on the training set achieves an R value of 0.9958, mean squared error (MSE) of 0.0012, root mean square error (RMSE) of 0.0346, and mean absolute error (MAE) of 0.0251. On the test set, the prediction accuracy attains an R value of 0.9726, MSE of 0.0028, RMSE of 0.0530, and MAE of 0.0415. The proposed model effectively extracts flotation froth features and accurately predicts ash content. This study provides a new approach for the intelligent control of the flotation process and holds broad application prospects.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"2 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assessing Mining Performance Indicators in Relation to the SDGs: Development of a Guided Methodology and Its Application in an Iron Ore Mine","authors":"Rhaymá do Carmo Silva, Anna Luiza Marques Ayres da Silva","doi":"10.3390/min14090887","DOIUrl":"https://doi.org/10.3390/min14090887","url":null,"abstract":"The concept of sustainability has gained significant recognition across all industrial sectors, particularly in response to the potential global environmental crisis. In mining, sustainability ensures responsible operations by addressing environmental, social, and economic aspects. Performance indicators, categorized into environmental, social, economic, and governance groups, are monitored to oversee these aspects. In 2015, the UN established 17 Sustainable Development Goals (SDGs) as a global agenda for achieving equitable economic and social development. This study presents a methodology to evaluate performance indicators in an iron ore mine in southeast Pará, Brazil, to understand whether and how these indicators guide the mine’s operations toward fulfilling the SDGs. This study was based on the application of a methodology specifically developed for this purpose, where a seven-step application was defined, with each step involving an activity to be carried out to verify the correlation performance indicators with the SDGs. By applying the proposed methodology, the assessment of 286 performance indicators was conducted, revealing that 55.24% aligned the mine’s operation with the SDGs. Furthermore, the developed methodology may be applied to other mining enterprises, supporting their sustainability reports and compliance with the sector’s regulatory standards and mine closure plan requirements.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"5 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"NaClO3 Crystal Growth and Dissolution by Temperature Cycling in a Sessile Droplet","authors":"Alexis Leborgne, Woo-Sik Kim, Bum Jun Park, Morgane Sanselme, Gérard Coquerel","doi":"10.3390/min14090898","DOIUrl":"https://doi.org/10.3390/min14090898","url":null,"abstract":"Abstract: Sodium chlorate is the most popular compound used to study spontaneous symmetry breaking by means of crystallization. Therefore, it is important to know the behavior of the solid particles. NaClO3 crystal growth and dissolution are investigated in an aqueous sessile droplet subjected to numerous temperature cycles. On cooling, in addition to the classical formation of repeated elongated fluid inclusions, there is a reproducible appearance of prismatic fluid inclusions (PFIs) at the corners of single crystals. The underlying mechanism involves the complete termination of the (110) face growth and the propagation of the {100} faces, which can close the PFIs. This study reports that on heating, transient donut-like single crystals formed, which could lead to their segmentation, even without stirring the suspension. The systematic addition of other sodium salts with chlorine atoms at different oxidation states did not change these observations.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"7 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Correction: Leeman et al. U-Pb LA-ICP-MS Zircon Dating of Crustal Xenoliths: Evidence of the Archean Lithosphere Beneath the Snake River Plain. Minerals 2024, 14, 578","authors":"William P. Leeman, Jeffrey D. Vervoort, S. Andrew DuFrane","doi":"10.3390/min14090886","DOIUrl":"https://doi.org/10.3390/min14090886","url":null,"abstract":"There were three errors in the original publication [...]","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"7 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}