A large amount of pyrite concentrate slag washing solution is produced in China every year, and this contains valuable components such as Cu2+ and Au. The traditional treatment method not only pollutes the environment but also wastes metal resources. For the washing solution containing Cu2+ 437 mg/L and Au 0.13 mg/L, two new processes comprehensive recovery schemes were developed and compared in this paper, namely iron powder replacement pore filtration and neutralization precipitation pore filtration. When the iron powder replacement pore filtration process was adopted, Cu2+ and Au were mainly comprehensively recovered in the form of a mixture of sponge copper and particulate gold. The test results showed that the replacement optimal conditions involved a pH of 3.0, iron powder dosage of 6 g/L, and replacement time of 3.0 h. After replacement, the filter cloth with below 1 μm pore size was used for filtration. The recovery rate of Cu2+ in the washing solution was 98.13 and the total recovery rate of Au was 95.83%. Otherwise, when the neutralization precipitation pore filtration process was adopted, Cu2+ and Au were mainly comprehensively recovered in the form of a mixture of copper hydroxide and particulate gold. The test results showed that sodium hydroxide was used as the precipitant and the optimum neutralization pH value was 6.5. After precipitation, the filter cloth with a below 1 μm pore size was used for filtration. The recovery rate of Cu2+ in the washing solution was 97.35% and the total recovery rate of Au was 93.54%. The economic benefit estimation of the two processes showed that the neutralization precipitation pore filtration process had the advantages of low material consumption, low cost and high economic benefit.
{"title":"Comparative Analysis of the Recovery of Cu2+ and Au from Washing Solution of Pyrite Concentrate Slag by Two Processes","authors":"Kun Zhu, Lei Qi, Libo Zhang","doi":"10.3390/min14090921","DOIUrl":"https://doi.org/10.3390/min14090921","url":null,"abstract":"A large amount of pyrite concentrate slag washing solution is produced in China every year, and this contains valuable components such as Cu2+ and Au. The traditional treatment method not only pollutes the environment but also wastes metal resources. For the washing solution containing Cu2+ 437 mg/L and Au 0.13 mg/L, two new processes comprehensive recovery schemes were developed and compared in this paper, namely iron powder replacement pore filtration and neutralization precipitation pore filtration. When the iron powder replacement pore filtration process was adopted, Cu2+ and Au were mainly comprehensively recovered in the form of a mixture of sponge copper and particulate gold. The test results showed that the replacement optimal conditions involved a pH of 3.0, iron powder dosage of 6 g/L, and replacement time of 3.0 h. After replacement, the filter cloth with below 1 μm pore size was used for filtration. The recovery rate of Cu2+ in the washing solution was 98.13 and the total recovery rate of Au was 95.83%. Otherwise, when the neutralization precipitation pore filtration process was adopted, Cu2+ and Au were mainly comprehensively recovered in the form of a mixture of copper hydroxide and particulate gold. The test results showed that sodium hydroxide was used as the precipitant and the optimum neutralization pH value was 6.5. After precipitation, the filter cloth with a below 1 μm pore size was used for filtration. The recovery rate of Cu2+ in the washing solution was 97.35% and the total recovery rate of Au was 93.54%. The economic benefit estimation of the two processes showed that the neutralization precipitation pore filtration process had the advantages of low material consumption, low cost and high economic benefit.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"3 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A high-resolution seismic survey (HRSS) is often used in coal exploration to bridge the data gap between two consecutive boreholes and avoid ambiguity in geological interpretation. The application of high-resolution seismic surveys in the Indian context is challenging as the delineation of thin non-coal layers within the coal layer requires a very high seismic data resolution. However, conventional seismic processing techniques fail to resolve thin coal/non-coal layers and faults, which is crucial for the precise estimation of coal resources and mine economics. To address these issues, we applied the inverse continuous wavelet transform deconvolution (ICWT-Decon) technique to post-stack depth-migrated seismic sections. We examined the feasibility of the ICWT-Decon technique in both a synthetic post-stack depth-migrated model and 2D/3D seismic data from the North Karanpura and Talcher Coalfields in Eastern India. The results offered enhanced seismic sections, attributes (similarity and sweetness), and acoustic inversion that aided in the precise positioning of faults and the delineation of a thin non-coal layer of 4.68 m within a 16.7 m coal seam at an approximate depth of 450 m to 550 m. This helped in the refinement of the resource estimation from 74.96 MT before applying ICWT-Decon to 55.92 MT afterward. Overall, the results of the study showed enhancements in the seismic data resolution, the better output of seismic attributes, and acoustic inversion, which could enable more precise lithological and structural interpretation.
{"title":"Enhancing Thin Coal Seam Detection in Eastern Indian Coalfields Using ICWT-Decon-Based Seismic Attributes and Acoustic Impedance Inversion","authors":"Naresh Kumar Seelam, Thinesh Kumar, Santosh Dhubia, Gangumalla Srinivasa Rao, Sanjit Kumar Pal","doi":"10.3390/min14090920","DOIUrl":"https://doi.org/10.3390/min14090920","url":null,"abstract":"A high-resolution seismic survey (HRSS) is often used in coal exploration to bridge the data gap between two consecutive boreholes and avoid ambiguity in geological interpretation. The application of high-resolution seismic surveys in the Indian context is challenging as the delineation of thin non-coal layers within the coal layer requires a very high seismic data resolution. However, conventional seismic processing techniques fail to resolve thin coal/non-coal layers and faults, which is crucial for the precise estimation of coal resources and mine economics. To address these issues, we applied the inverse continuous wavelet transform deconvolution (ICWT-Decon) technique to post-stack depth-migrated seismic sections. We examined the feasibility of the ICWT-Decon technique in both a synthetic post-stack depth-migrated model and 2D/3D seismic data from the North Karanpura and Talcher Coalfields in Eastern India. The results offered enhanced seismic sections, attributes (similarity and sweetness), and acoustic inversion that aided in the precise positioning of faults and the delineation of a thin non-coal layer of 4.68 m within a 16.7 m coal seam at an approximate depth of 450 m to 550 m. This helped in the refinement of the resource estimation from 74.96 MT before applying ICWT-Decon to 55.92 MT afterward. Overall, the results of the study showed enhancements in the seismic data resolution, the better output of seismic attributes, and acoustic inversion, which could enable more precise lithological and structural interpretation.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"12 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cone crushers have a central role in the processing of quarry rocks, besides coarser ore preparation in several mineral processing plants. This is particularly true in the case of Itabirite iron ore preparation plants in Brazil, so optimizing their performance is of central importance for reaching maximum productivity of the circuit. The work presents results of modeling the HP500 cone crusher in operation in an industrial plant in Brazil (Minas Rio), from surveys carried out over a few years with different feeds and crushing conditions. A version of the Andersen–Whiten cone crusher model was implemented in the Integrated Extraction Simulator featuring a non-normalizable breakage response and a fit-for-purpose throughput model. The results demonstrate the good ability of the model to predict crusher performance when dealing with different closed-side settings and feed size distributions.
{"title":"Fit-for-Purpose Model of HP500 Cone Crusher in Size Reduction of Itabirite Iron Ore","authors":"Brena Karolyne Nunes da Rocha, Túlio Moreira Campos, Júlio Silva, Luís Marcelo Tavares","doi":"10.3390/min14090919","DOIUrl":"https://doi.org/10.3390/min14090919","url":null,"abstract":"Cone crushers have a central role in the processing of quarry rocks, besides coarser ore preparation in several mineral processing plants. This is particularly true in the case of Itabirite iron ore preparation plants in Brazil, so optimizing their performance is of central importance for reaching maximum productivity of the circuit. The work presents results of modeling the HP500 cone crusher in operation in an industrial plant in Brazil (Minas Rio), from surveys carried out over a few years with different feeds and crushing conditions. A version of the Andersen–Whiten cone crusher model was implemented in the Integrated Extraction Simulator featuring a non-normalizable breakage response and a fit-for-purpose throughput model. The results demonstrate the good ability of the model to predict crusher performance when dealing with different closed-side settings and feed size distributions.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"2 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ore collection devices are important for the collection of deep-sea polymetallic nodules. Based on the CFD-DEM solid–liquid two-phase flow coupling calculation method, this paper simulated the rise and transport phases of polymetallic nodules using the Coanda effect ore collection device. The validity of the numerical simulation method was confirmed through experimental testing. On this basis, the effects of different working and structural parameters on the collection rate were studied. The results indicate that the flow rate of the collection jet and the bottom clearance were the primary factors affecting the collection rate of the polymetallic nodules. An increase in the collection jet flow rate leads to a substantial rise in the collection rate of polymetallic nodules. Conversely, an increase in bottom clearance results in a decrease in the collection rate. A collection rate exceeding 90% can be achieved in both scenarios: a 10 mm bottom clearance with an 8 m/s collection jet flow rate, and a 30 mm bottom clearance with a 10 m/s collection jet flow rate. The collection nozzle slant angle has no substantial impact on the collection rate, and the recommended collection nozzle slant angle is 35° to reduce energy loss.
{"title":"Numerical Simulation and Experimental Study of a Deep-Sea Polymetallic Nodule Collector Based on the Coanda Effect","authors":"Yan Li, Zhibin Han, Ziyuan Li","doi":"10.3390/min14090915","DOIUrl":"https://doi.org/10.3390/min14090915","url":null,"abstract":"Ore collection devices are important for the collection of deep-sea polymetallic nodules. Based on the CFD-DEM solid–liquid two-phase flow coupling calculation method, this paper simulated the rise and transport phases of polymetallic nodules using the Coanda effect ore collection device. The validity of the numerical simulation method was confirmed through experimental testing. On this basis, the effects of different working and structural parameters on the collection rate were studied. The results indicate that the flow rate of the collection jet and the bottom clearance were the primary factors affecting the collection rate of the polymetallic nodules. An increase in the collection jet flow rate leads to a substantial rise in the collection rate of polymetallic nodules. Conversely, an increase in bottom clearance results in a decrease in the collection rate. A collection rate exceeding 90% can be achieved in both scenarios: a 10 mm bottom clearance with an 8 m/s collection jet flow rate, and a 30 mm bottom clearance with a 10 m/s collection jet flow rate. The collection nozzle slant angle has no substantial impact on the collection rate, and the recommended collection nozzle slant angle is 35° to reduce energy loss.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"272 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Moyagabo Rapetsoa, Musa Manzi, Ian James, Mpofana Sihoyiya, Raymond Durrheim, Michelle Pienaar
Maseve Mine is located in the western limb of the Bushveld Complex, recognized as the largest layered igneous intrusion in the world. The study shows results from surface (SP1, SP2, and SP3) and tunnel (T3a, T3b, and TP4b) reflection seismic profiles, totaling 4150 m. Tunnel seismic data were acquired using a seismic landstreamer and spiked geophones with 5 m receiver and shot spacing, as well as a sledgehammer for shots due to space constraints and safety. The profiles, 10–50 m above mineral deposits, crossed major geological structures. Surface seismic profiles used cabled systems and wireless sensors with 5 m and 10 m receiver spacing, respectively, and a 500 kg drop hammer as a source with 10 m shot spacing. Despite high noise levels from mine infrastructure and power cables, a careful processing workflow enhanced target reflections. Interpretation was constrained using borehole data, geological models, and 2D/3D seismic modeling. The processed data exhibit gently dipping reflections associated with faults and dykes, imaging the target mineralization (Merensky Reef and Upper Group 2) and a possible extension. Tunnel seismic experiments demonstrated the application of seismic methods using in-mine infrastructure, while surface experiments proved efficient, illustrating small-scale seismic surveys’ capability to image the subsurface, adding value in active mining environments for exploration with cost-effective seismic equipment.
{"title":"Innovative Seismic Imaging of the Platinum Deposits, Maseve Mine: Surface and In-Mine","authors":"Moyagabo Rapetsoa, Musa Manzi, Ian James, Mpofana Sihoyiya, Raymond Durrheim, Michelle Pienaar","doi":"10.3390/min14090913","DOIUrl":"https://doi.org/10.3390/min14090913","url":null,"abstract":"Maseve Mine is located in the western limb of the Bushveld Complex, recognized as the largest layered igneous intrusion in the world. The study shows results from surface (SP1, SP2, and SP3) and tunnel (T3a, T3b, and TP4b) reflection seismic profiles, totaling 4150 m. Tunnel seismic data were acquired using a seismic landstreamer and spiked geophones with 5 m receiver and shot spacing, as well as a sledgehammer for shots due to space constraints and safety. The profiles, 10–50 m above mineral deposits, crossed major geological structures. Surface seismic profiles used cabled systems and wireless sensors with 5 m and 10 m receiver spacing, respectively, and a 500 kg drop hammer as a source with 10 m shot spacing. Despite high noise levels from mine infrastructure and power cables, a careful processing workflow enhanced target reflections. Interpretation was constrained using borehole data, geological models, and 2D/3D seismic modeling. The processed data exhibit gently dipping reflections associated with faults and dykes, imaging the target mineralization (Merensky Reef and Upper Group 2) and a possible extension. Tunnel seismic experiments demonstrated the application of seismic methods using in-mine infrastructure, while surface experiments proved efficient, illustrating small-scale seismic surveys’ capability to image the subsurface, adding value in active mining environments for exploration with cost-effective seismic equipment.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"41 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In order to examine further the characteristics of micropore-throat structures of the tight oil reservoir in the Jiufotang Formation in the Houhe region, this study used whole rock X-ray diffraction, routine physical property analysis, and routine thin section observations to analyze the material composition and physical properties of the tight oil reservoir. CT scanning, high-pressure mercury infiltration, and other test methods were employed to analyze the characteristics of the pore-throat structures in the tight oil reservoir. In addition, the Pearson correlation coefficients quantified the relationships between nine parameters and pore-throat structures. The parameters with high correlations were optimized for analysis, and a comprehensive classification scheme for micropore-throat structures in the tight oil reservoir in the study area was established. The results show that the reservoir in the Jiufotang Formation in the Houhe region is composed of feldspathic and lithic arkosic sandstone, with feldspar and clast pore dissolution pores as the main type of reservoir pore space. The tight oil reservoir has small pore-throat radius, complex structures, poor connectivity, and high heterogeneity. It generally contains micron-sized pores with submicron to nanometer throat widths and small- and medium-sized pores to fine micropore-throat structures. Porosity, permeability, coefficient of variation, skewness coefficient, and average pore-throat radius, were selected for k-means cluster analysis. The micropore-throat structures of the tight oil reservoir were divided into three categories: classes I, II, and III. The study area is dominated by class II pore throats, accounting for 58%. Diagenesis mainly controls the pore-throat structure. These results provide an effective reference for the identification and evaluation of favorable sweet spots in tight oil reservoirs in similar blocks in China.
为进一步研究后河地区九佛堂地层致密油藏微孔-咽喉结构特征，本研究采用全岩X射线衍射、常规物性分析、常规薄片观察等方法分析了致密油藏的物质组成和物性。采用 CT 扫描、高压水银渗入等测试方法分析致密油藏孔喉结构特征。此外，还用皮尔逊相关系数量化了九个参数与孔喉结构之间的关系。对相关性较高的参数进行了优化分析，建立了研究区致密油藏微孔-喉道结构的综合分类方案。结果表明，后河地区九佛堂地层储层由长石岩性和碎屑岩性弧光砂岩组成，储层孔隙主要类型为长石孔隙和碎屑孔溶蚀孔隙。致密油藏孔喉半径小，结构复杂，连通性差，异质性高。致密油藏一般含有微米级孔隙、亚微米至纳米级喉宽、中小型孔隙和细微孔喉结构。选取孔隙度、渗透率、变异系数、偏度系数和平均孔喉半径进行 k-means 聚类分析。致密油藏的微孔-咽喉结构分为三类：Ⅰ类、Ⅱ类和Ⅲ类。研究区域以 II 类孔隙喉道为主，占 58%。成因主要控制着孔喉结构。这些结果为中国类似区块致密油藏有利甜点的识别和评价提供了有效参考。
{"title":"Characteristics of Micropore-Throat Structures in Tight Oil Reservoirs: A Case Study of the Jiufotang Formation in the Houhe Region, NE China","authors":"Guolong Zhang, Chenglong Ma","doi":"10.3390/min14090918","DOIUrl":"https://doi.org/10.3390/min14090918","url":null,"abstract":"In order to examine further the characteristics of micropore-throat structures of the tight oil reservoir in the Jiufotang Formation in the Houhe region, this study used whole rock X-ray diffraction, routine physical property analysis, and routine thin section observations to analyze the material composition and physical properties of the tight oil reservoir. CT scanning, high-pressure mercury infiltration, and other test methods were employed to analyze the characteristics of the pore-throat structures in the tight oil reservoir. In addition, the Pearson correlation coefficients quantified the relationships between nine parameters and pore-throat structures. The parameters with high correlations were optimized for analysis, and a comprehensive classification scheme for micropore-throat structures in the tight oil reservoir in the study area was established. The results show that the reservoir in the Jiufotang Formation in the Houhe region is composed of feldspathic and lithic arkosic sandstone, with feldspar and clast pore dissolution pores as the main type of reservoir pore space. The tight oil reservoir has small pore-throat radius, complex structures, poor connectivity, and high heterogeneity. It generally contains micron-sized pores with submicron to nanometer throat widths and small- and medium-sized pores to fine micropore-throat structures. Porosity, permeability, coefficient of variation, skewness coefficient, and average pore-throat radius, were selected for k-means cluster analysis. The micropore-throat structures of the tight oil reservoir were divided into three categories: classes I, II, and III. The study area is dominated by class II pore throats, accounting for 58%. Diagenesis mainly controls the pore-throat structure. These results provide an effective reference for the identification and evaluation of favorable sweet spots in tight oil reservoirs in similar blocks in China.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"8 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215202","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Basem Zoheir, Astrid Holzheid, Aliaa Diab, Azza Ragab, Fatma Deshesh, Amr Abdelnasser
Gold, along with other highly siderophile elements, is hosted by Fe-Ni sulfide phases within peridotites and mantle melts. In this context, the lithospheric mantle emerges as a principal reservoir, providing materials crucial for the inception, augmentation, conveyance, and genesis of auriferous CO2-rich mantle fluids. EPMA and laser ablation ICP-MS data, integrated with petrographic and SEM studies, were used to assess the transfer of base and precious metals into the Earth’s crust, discerning between inputs from subduction-related processes and post-formation metasomatism. The study focuses on sulfide minerals in serpentinized peridotites of the Abu Dahr ophiolite in the Eastern Desert of Egypt. Originating in a supra-subduction setting during the Neoproterozoic era, the Abu Dahr peridotites underwent serpentinization and contain discrete sulfide minerals, including pentlandite, nickeloan pyrrhotite, millerite, chalcopyrite, and violarite. The uneven distribution of calcite ± magnesite ± serpentine veins throughout the host ophiolitic rocks reflects the intricate interplay of serpentinization and carbonation, as fO2 and fCO2 conditions fluctuated. Geochemical data of the host rocks reveal a progressive geochemical evolution marked by concurrent silicification and carbonate alteration, driven by the interaction of ultramafic rocks with hydrothermal fluids, ultimately leading to the extensive silicification and formation of birbirite. The ICP-MS data show that pentlandite contains up to 6.11 ppm of Au, pyrrhotite up to 0.41 ppm, millerite 0.34 ppm, and violarite 0.12 ppm. The gold concentration in pentlandite is significantly higher than in pyrrhotite, millerite, and violarite, which exhibit lower but detectable levels of Au. Desulfurization reactions of sulfide minerals during progressive serpentinization triggered the release and redistribution of Au as well as base metals and highly siderophile elements. Published thermodynamic modeling at temperatures below 300 °C and pressures of 50 MPa closely replicates the mineral assemblage observed in the Abu Dahr ophiolites, including sulfide assemblages and variations in major elements such as Mg and Fe. This suggests that the serpentinization process, along with associated hydrothermal fluids, played a crucial role in the mobilization and redistribution of gold, particularly affecting its incorporation into secondary sulfides. The mobilization of Au and other highly siderophile elements during serpentinization occurred in an environment marked by strong oxidation, as indicated by the presence of acicular antigorite, magnetite, millerite, and goethite intergrowths.
{"title":"Recycling of Au during Serpentinization of Ultramafic Rocks: A Case Study from Neoproterozoic Forearc Ophiolites, Egypt","authors":"Basem Zoheir, Astrid Holzheid, Aliaa Diab, Azza Ragab, Fatma Deshesh, Amr Abdelnasser","doi":"10.3390/min14090916","DOIUrl":"https://doi.org/10.3390/min14090916","url":null,"abstract":"Gold, along with other highly siderophile elements, is hosted by Fe-Ni sulfide phases within peridotites and mantle melts. In this context, the lithospheric mantle emerges as a principal reservoir, providing materials crucial for the inception, augmentation, conveyance, and genesis of auriferous CO2-rich mantle fluids. EPMA and laser ablation ICP-MS data, integrated with petrographic and SEM studies, were used to assess the transfer of base and precious metals into the Earth’s crust, discerning between inputs from subduction-related processes and post-formation metasomatism. The study focuses on sulfide minerals in serpentinized peridotites of the Abu Dahr ophiolite in the Eastern Desert of Egypt. Originating in a supra-subduction setting during the Neoproterozoic era, the Abu Dahr peridotites underwent serpentinization and contain discrete sulfide minerals, including pentlandite, nickeloan pyrrhotite, millerite, chalcopyrite, and violarite. The uneven distribution of calcite ± magnesite ± serpentine veins throughout the host ophiolitic rocks reflects the intricate interplay of serpentinization and carbonation, as fO2 and fCO2 conditions fluctuated. Geochemical data of the host rocks reveal a progressive geochemical evolution marked by concurrent silicification and carbonate alteration, driven by the interaction of ultramafic rocks with hydrothermal fluids, ultimately leading to the extensive silicification and formation of birbirite. The ICP-MS data show that pentlandite contains up to 6.11 ppm of Au, pyrrhotite up to 0.41 ppm, millerite 0.34 ppm, and violarite 0.12 ppm. The gold concentration in pentlandite is significantly higher than in pyrrhotite, millerite, and violarite, which exhibit lower but detectable levels of Au. Desulfurization reactions of sulfide minerals during progressive serpentinization triggered the release and redistribution of Au as well as base metals and highly siderophile elements. Published thermodynamic modeling at temperatures below 300 °C and pressures of 50 MPa closely replicates the mineral assemblage observed in the Abu Dahr ophiolites, including sulfide assemblages and variations in major elements such as Mg and Fe. This suggests that the serpentinization process, along with associated hydrothermal fluids, played a crucial role in the mobilization and redistribution of gold, particularly affecting its incorporation into secondary sulfides. The mobilization of Au and other highly siderophile elements during serpentinization occurred in an environment marked by strong oxidation, as indicated by the presence of acicular antigorite, magnetite, millerite, and goethite intergrowths.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"79 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wenbin Xu, Yalun Zhang, Wei Chen, Tong Sun, Yilin Sang
Layered cemented filling leads to a layered composite structure of cemented tailings backfill (CTB) composed of high-strength top and bottom layers, as well as a low-strength middle layer. To solve the problem of the low mechanical properties of the middle layer caused by layered filling, this study proposes the concept of an enhance layer, that is, an enhance layer is added to the middle weak layer to improve its overall mechanical properties. To explore the characteristics of strength, failure modes, energy dissipation, and progressive damage of stratified cemented tailings backfill (SCTB) with varying layered structures, the uniaxial compressive tests of SCTB specimens with enhance layers c/t of 1:15, 1:10, and 1:6, as well as height proportions of 0.1, 0.2, and 0.3, are examined. The results show that the elastic modulus and uniaxial compressive strength (UCS) of SCTB samples increase with the height ratio and cement-to-tailings ratio of the enhance layer. The elastic modulus and strength of SCTB specimens is more sensitive to the height ratio of the enhance layer than the c/t ratio. Moreover, the SCTB specimens mainly manifested as tensile failure of the upper layer and lower layer, but they did not penetrate the entire specimen. The propagation of cracks is limited by the addition of the enhance layer. The SCTB specimens have stronger plastic deformation ability, and a large part of the all-strain energy is dissipated in the shape of plastic failure. In addition, a constitutive model for damage in SCTB samples has been developed. The SCTB samples with a reasonable structure can also achieve sufficient strength compared to directly increasing the c/t ratio of CTB specimens while reducing the cost of cemented tailings backfill preparation. This approach reduces the carbon footprint of the mining industry and improved the overall mechanical properties and stability of the stratified cemented tailings backfill. This study provides a new approach for high-stage subsequent stope backfilling. The findings will offer guidance for the design of a layered filling mining method.
{"title":"Mechanical Properties, Failure Modes, and Damage Development of Stratified Cemented Tailings Backfill under Uniaxial Compression","authors":"Wenbin Xu, Yalun Zhang, Wei Chen, Tong Sun, Yilin Sang","doi":"10.3390/min14090917","DOIUrl":"https://doi.org/10.3390/min14090917","url":null,"abstract":"Layered cemented filling leads to a layered composite structure of cemented tailings backfill (CTB) composed of high-strength top and bottom layers, as well as a low-strength middle layer. To solve the problem of the low mechanical properties of the middle layer caused by layered filling, this study proposes the concept of an enhance layer, that is, an enhance layer is added to the middle weak layer to improve its overall mechanical properties. To explore the characteristics of strength, failure modes, energy dissipation, and progressive damage of stratified cemented tailings backfill (SCTB) with varying layered structures, the uniaxial compressive tests of SCTB specimens with enhance layers c/t of 1:15, 1:10, and 1:6, as well as height proportions of 0.1, 0.2, and 0.3, are examined. The results show that the elastic modulus and uniaxial compressive strength (UCS) of SCTB samples increase with the height ratio and cement-to-tailings ratio of the enhance layer. The elastic modulus and strength of SCTB specimens is more sensitive to the height ratio of the enhance layer than the c/t ratio. Moreover, the SCTB specimens mainly manifested as tensile failure of the upper layer and lower layer, but they did not penetrate the entire specimen. The propagation of cracks is limited by the addition of the enhance layer. The SCTB specimens have stronger plastic deformation ability, and a large part of the all-strain energy is dissipated in the shape of plastic failure. In addition, a constitutive model for damage in SCTB samples has been developed. The SCTB samples with a reasonable structure can also achieve sufficient strength compared to directly increasing the c/t ratio of CTB specimens while reducing the cost of cemented tailings backfill preparation. This approach reduces the carbon footprint of the mining industry and improved the overall mechanical properties and stability of the stratified cemented tailings backfill. This study provides a new approach for high-stage subsequent stope backfilling. The findings will offer guidance for the design of a layered filling mining method.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"1 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gold grains are observed in a variety of forms, such as coarse-liberated native gold grains, and ultra-fine grains associated with sulfide or non-sulfide mineral particles, in the form of solid solution in sulfide minerals, mainly pyrite. In the flotation of gold ores, bulk sulfide mineral flotation is generally applied to maximize gold recovery. This approach gives high gold recoveries, but it also causes the recovery of barren sulfide minerals (i.e., sulfide mineral particles with no gold content), which increases concentrate tonnage and transportation costs and reduces the grade sometimes to below the saleable limit (approx. 10 g/t Au). This study addresses the differences between gold-bearing and barren pyrite particles taken from various ore deposits and utilizes these differences for the selective flotation of gold-bearing pyrite. The laboratory scale flotation tests conducted on three pyrite samples having different cyanide soluble gold contents show that a selective separation between gold-bearing pyrite and barren pyrite particles could be achieved under specific flotation conditions. Gold recovery is correlated directly with the cyanide-soluble gold in the ore samples. Electrochemical experiments were conducted to elucidate the differences in surface properties of the two types of pyrite. The barren pyrite particles were more cathodic and prone to cathodic reduction of OH− and depressant ions on the surface, and they could be depressed effectively without significantly affecting the gold-bearing particles.
{"title":"Surface Chemistry and Flotation of Gold-Bearing Pyrite","authors":"Seda Özçelik, Zafir Ekmekçi","doi":"10.3390/min14090914","DOIUrl":"https://doi.org/10.3390/min14090914","url":null,"abstract":"Gold grains are observed in a variety of forms, such as coarse-liberated native gold grains, and ultra-fine grains associated with sulfide or non-sulfide mineral particles, in the form of solid solution in sulfide minerals, mainly pyrite. In the flotation of gold ores, bulk sulfide mineral flotation is generally applied to maximize gold recovery. This approach gives high gold recoveries, but it also causes the recovery of barren sulfide minerals (i.e., sulfide mineral particles with no gold content), which increases concentrate tonnage and transportation costs and reduces the grade sometimes to below the saleable limit (approx. 10 g/t Au). This study addresses the differences between gold-bearing and barren pyrite particles taken from various ore deposits and utilizes these differences for the selective flotation of gold-bearing pyrite. The laboratory scale flotation tests conducted on three pyrite samples having different cyanide soluble gold contents show that a selective separation between gold-bearing pyrite and barren pyrite particles could be achieved under specific flotation conditions. Gold recovery is correlated directly with the cyanide-soluble gold in the ore samples. Electrochemical experiments were conducted to elucidate the differences in surface properties of the two types of pyrite. The barren pyrite particles were more cathodic and prone to cathodic reduction of OH− and depressant ions on the surface, and they could be depressed effectively without significantly affecting the gold-bearing particles.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"59 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Coal extraction in China is increasingly moving towards colder regions such as Xinjiang and Inner Mongolia. However, these mines face land restoration challenges due to a scarcity of fertile topsoil. This study explores the potential of coal gangue, a mining byproduct, as a viable substitute for topsoil. The study examines the effects of humidity fluctuations and freeze–thaw cycles, both individually and in combination, on the weathering disintegration of coal gangue. Coal gangue samples were subjected to controlled laboratory conditions simulating environmental factors. Fourteen interventions were analyzed, and the findings indicated that the combined application of humidity and freeze–thaw cycles significantly accelerated the disintegration process, outperforming the individual interventions. In addition, it was found that significant temperature variations caused the moisture and salts within the gangue to expand, which affected the rate of disintegration. The study showed that the rate of weathering disintegration was significantly higher in conditions of saturated humidity–freeze–thaw cycles compared to unsaturated humidity conditions. This highlights the essential role of ice crystals in accelerating the weathering process during temperature fluctuations. This study highlights the importance of humidity over temperature in the weathering and disintegration of coal gangue. It also suggests that freeze–thaw cycles can enhance this process. The study provides valuable insights for the management and utilization of coal gangue in cold and arid regions.
{"title":"Impact of Humidity and Freeze–Thaw Cycles on the Disintegration Rate of Coal Gangue in Cold and Arid Regions: A Case Study from Inner Mongolia, China","authors":"Chuangang Gong, Liya Yang","doi":"10.3390/min14090911","DOIUrl":"https://doi.org/10.3390/min14090911","url":null,"abstract":"Coal extraction in China is increasingly moving towards colder regions such as Xinjiang and Inner Mongolia. However, these mines face land restoration challenges due to a scarcity of fertile topsoil. This study explores the potential of coal gangue, a mining byproduct, as a viable substitute for topsoil. The study examines the effects of humidity fluctuations and freeze–thaw cycles, both individually and in combination, on the weathering disintegration of coal gangue. Coal gangue samples were subjected to controlled laboratory conditions simulating environmental factors. Fourteen interventions were analyzed, and the findings indicated that the combined application of humidity and freeze–thaw cycles significantly accelerated the disintegration process, outperforming the individual interventions. In addition, it was found that significant temperature variations caused the moisture and salts within the gangue to expand, which affected the rate of disintegration. The study showed that the rate of weathering disintegration was significantly higher in conditions of saturated humidity–freeze–thaw cycles compared to unsaturated humidity conditions. This highlights the essential role of ice crystals in accelerating the weathering process during temperature fluctuations. This study highlights the importance of humidity over temperature in the weathering and disintegration of coal gangue. It also suggests that freeze–thaw cycles can enhance this process. The study provides valuable insights for the management and utilization of coal gangue in cold and arid regions.","PeriodicalId":18601,"journal":{"name":"Minerals","volume":"12 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142215036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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