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Study on Inclusions Distribution Across the Thickness of Enameled Steel Slabs 搪瓷钢板各厚度夹杂物分布研究
Pub Date : 2024-09-04 DOI: 10.1007/s11663-024-03263-3
Bo Wang, Lidong Xing, Xin Li, Yanping Bao, Min Wang

Enameled steel is widely used owing to its superior fatigue and strength properties. However, the presence of inclusions formed during the steelmaking process significantly affects these properties. Therefore, this study investigated a factory-enameled steel slab to elucidate its behavior. Additionally, the study analyzed the distribution of inclusions across the slab thickness, and characterized the variation in oxygen, nitrogen, carbon, manganese and sulfur contents. Moreover, the type, number density, size, and morphology of inclusions were examined across the slab thickness. The findings revealed that the center of the slab exhibited the lowest sulfur and manganese contents, which gradually increased toward the edges. Conversely, nitrogen content reached the maximum at the slab center and decreased toward the edges. The oxide inclusions mainly comprised Al2O3–MgO cores. Furthermore, the oxide inclusions in the slab mainly exhibited ellipsoidal morphology, with sizes concentrated between 1 and 5 μm. Moreover, the slab contained MnS and TiN inclusions, which exhibited symmetric variations in number density and average size from the edge to the center of the slab. The number density of MnS first decreased and then increased from the inner arc to the outer arc, while TiN exhibited the opposite trend. Additionally, MnS had a smaller average size than TiN, despite its higher number of inclusions. Furthermore, Ti4C2S2 inclusions were mainly distributed between 1 and 3 μm and clustered in the slab. Additionally, theoretical calculations revealed that the elemental segregation trend followed the order of S > Ti > N > Mn. The sequence of precipitation formation was Ti4C2S2 > TiN > MnS. This indicated a negative correlation between the cooling rate and inclusion size. Particularly, MnS exhibited the smallest size, while TiN featured the largest size at the center of the slab.

搪瓷钢因其卓越的疲劳和强度性能而被广泛使用。然而,在炼钢过程中形成的夹杂物会严重影响这些性能。因此,本研究对工厂搪瓷钢板进行了调查,以阐明其行为。此外,研究还分析了夹杂物在整个板坯厚度上的分布情况,以及氧、氮、碳、锰和硫含量的变化特征。此外,还研究了整个板坯厚度上夹杂物的类型、数量密度、大小和形态。研究结果表明,板坯中心的硫和锰含量最低,向边缘逐渐增加。相反,氮含量在板坯中心达到最高,并向边缘逐渐降低。氧化物夹杂物主要包括 Al2O3-MgO 核心。此外,板坯中的氧化物夹杂物主要呈椭圆形,大小集中在 1 至 5 μm 之间。此外,板坯中还含有 MnS 和 TiN 包裹体,它们的数量密度和平均尺寸从板坯边缘到中心呈对称变化。从内弧到外弧,MnS 的数量密度先减小后增大,而 TiN 则表现出相反的趋势。此外,尽管 MnS 的夹杂物数量较多,但其平均尺寸却小于 TiN。此外,Ti4C2S2夹杂物主要分布在 1 至 3 μm 之间,并聚集在板坯中。此外,理论计算显示,元素偏析趋势遵循 S > Ti > N > Mn 的顺序。沉淀形成的顺序为 Ti4C2S2 > TiN > MnS。这表明冷却速率与包合物尺寸之间存在负相关。特别是,MnS 的尺寸最小,而 TiN 在板坯中心的尺寸最大。
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引用次数: 0
Investigation of Ti Removal in 45Cr9Si3 Valve Steel by CaF2-Al2O3-CaO-SiO2-MgO-TiO2-Type ESR Slags with Different SiO2 Contents and Their Effects on TiN and Oxide Inclusions 不同二氧化硅含量的 CaF2-Al2O3-CaO-SiO2-MgO-TiO2 型 ESR 熔渣在 45Cr9Si3 阀门钢中的脱钛效果及其对 TiN 和氧化物夹杂物影响的研究
Pub Date : 2024-08-29 DOI: 10.1007/s11663-024-03197-w
Zeyou Li, Jing Guo, Hanjie Guo, Jinan Jin, Chang Liu, Chunchun Lu, Yan Yan

The aim of this study was to control large TiN inclusions in 45Cr9Si3 martensitic valve steel in ESR. For this purpose, the effects of different SiO2 contents in CaF2-Al2O3-CaO-SiO2- MgO-TiO2-type slags on Ti removal and TiN inclusions in steel have been investigated through laboratory-scale experiments, thermodynamic analysis, and industrial tests. The results showed that SiO2 in slag is a good de-Ti agent. The increase of SiO2 content in slag reduces the ratio of TiO2 activity to SiO2 activity, a high SiO2 content (15.21 pct) can significantly reduce the Ti content in steel, and at the same time, the Al content also decreases correspondingly, and the O content in steel changes little, which makes the number and size of TiN and MgAl2O4 decrease sharply. The optimum content of SiO2 in slag is 15.0 pct, which has good effect of removing Ti from steel and controlling Al and O contents. Combined with industrial optimization test, it is found that smelting with 20 pct SiO2 in ESR can control the size of TiN within 5 μm, and the amount of MgAl2O4 is greatly reduced.

本研究旨在控制 ESR 中 45Cr9Si3 马氏体阀门钢中的大量 TiN 夹杂。为此,通过实验室规模的实验、热力学分析和工业测试,研究了 CaF2-Al2O3-CaO-SiO2- MgO-TiO2 型炉渣中不同 SiO2 含量对脱钛和钢中 TiN 夹杂的影响。结果表明,炉渣中的 SiO2 是一种良好的脱钛剂。炉渣中 SiO2 含量的增加降低了 TiO2 活性与 SiO2 活性之比,高 SiO2 含量(15.21 pct)可显著降低钢中的 Ti 含量,同时 Al 含量也相应降低,钢中的 O 含量变化不大,这使得 TiN 和 MgAl2O4 的数量和尺寸急剧下降。炉渣中 SiO2 的最佳含量为 15.0 pct,对去除钢中 Ti 和控制 Al、O 含量有良好效果。结合工业优化试验发现,在 ESR 中加入 20 pct 的 SiO2 进行冶炼,可将 TiN 的尺寸控制在 5 μm 以内,且 MgAl2O4 的含量大大降低。
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引用次数: 0
Numerical Modeling and Plant Trial on the Optimization of SEN Designs in a Large Round Billet Mold 大型圆坯模具中 SEN 设计优化的数值建模和工厂试验
Pub Date : 2024-08-28 DOI: 10.1007/s11663-024-03238-4
Bangming Qin, Jiangshan Zhang, Shufeng Yang, Xiaotan Zuo, Qing Liu

Numerical models were built and validated to analyze the flow and heat transfer in three submerged entry nozzles (SEN) and a large round billet mold. A comparative investigation of a single-port SEN and two types of four-port SEN was conducted using numerical simulation and industrial experiments, considering the effect of mold electromagnetic stirring (M-EMS). The findings indicate that the upper part of the mold exhibits increased surface activity using upward and downward four-port SENs. Single-port SEN demonstrates significantly lower velocity at the free surface (0.001 m/s) compared to four-port SENs (0.087 m/s for upward and 0.065 m/s for downward). The introduction of M-EMS activates the horizontal flow inside the mold. Additionally, the four-port SENs achieve a higher free surface temperature and demonstrate a significantly higher inclusion escape percentage than the single-port SEN. The shell thickness uniformity under four-port SENs is lower due to the convection of the steel jet. Industrial tests reveal no significant difference in corrosion among the three SENs. Moreover, the advantage of increasing the proportion of equiaxed crystals and reducing inclusion number density is observed using the four-port SENs in plant trials.

建立并验证了数值模型,以分析三个浸没式入口喷嘴(SEN)和大型圆坯模具中的流动和传热。考虑到模具电磁搅拌(M-EMS)的影响,利用数值模拟和工业实验对单孔 SEN 和两种四孔 SEN 进行了比较研究。研究结果表明,使用向上和向下的四端口 SEN,模具上部的表面活性增加。与四端口 SEN(向上为 0.087 m/s,向下为 0.065 m/s)相比,单端口 SEN 在自由表面的速度(0.001 m/s)明显较低。M-EMS 的引入激活了模具内部的水平流动。此外,与单孔 SEN 相比,四孔 SEN 的自由表面温度更高,夹杂物逸出率也显著提高。由于钢液喷射的对流作用,四孔 SEN 下的外壳厚度均匀性较低。工业试验表明,三种 SEN 在腐蚀方面没有明显差异。此外,在工厂试验中,四端口 SEN 还具有增加等轴晶粒比例和降低夹杂物数量密度的优势。
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引用次数: 0
Decarburization and Gas Formation During Sintering of Alloyed PM Steel Components 合金 PM 钢部件烧结过程中的脱碳和气体形成
Pub Date : 2024-08-27 DOI: 10.1007/s11663-024-03237-5
Peter Quadbeck, Alexander Strauß, Thomas Weißgärber

This study investigates the delubrication, reduction, and decarburization processes of powder metallurgical steel alloys (CrM, CrL, AHC, Mo85, SintD 35) and an unalloyed steel during sintering in a pure hydrogen atmosphere. Utilizing in-situ FTIR gas phase analysis, components with ethylenebisstearamide (EBS) as a lubricant are analyzed. EBS decomposition in steel components yields CO, CO2, H2O, and CH4, with dominant CH groups observed in the 230 °C to 480 °C range. In the temperature range between 750 °C and 850 °C, where CO formation is expected due to the reduction of surface iron oxides, CH4 is present instead, indicating that an “internal getter effect” also occurs in pre-alloyed powders. In addition, with high carbon activity, the reduction of internal iron oxides and the reduction of chromium oxides also trigger an internal getter effect. Depending on the carbon potential, these processes cause a considerable reduction in the carbon content of the powder metallurgical components. The study therefore shows that the decarburization of powder metallurgical components during the heat treatment phases prior to sintering in a 100 pct hydrogen atmosphere is less due to the mechanism of delubrication, but rather to mechanisms of carbothermal reduction.

本研究调查了粉末冶金钢合金(CrM、CrL、AHC、Mo85、SintD 35)和非合金钢在纯氢气氛中烧结时的脱脂、还原和脱碳过程。利用原位傅立叶变换红外气相分析法,对使用乙烯双硬脂酸酰胺(EBS)作为润滑剂的部件进行了分析。EBS 在钢部件中分解产生 CO、CO2、H2O 和 CH4,在 230 °C 至 480 °C 范围内观察到主要的 CH 基团。在 750 °C 至 850 °C 的温度范围内,由于表面铁氧化物的还原,预计会产生 CO,但却出现了 CH4,这表明在预合金粉末中也会出现 "内部获得者效应"。此外,在碳活性较高的情况下,内部铁氧化物的还原和铬氧化物的还原也会引发内部脱碳效应。根据碳势的不同,这些过程会导致粉末冶金成分的碳含量大幅降低。因此,这项研究表明,粉末冶金部件在 100 pct 氢气环境中烧结前的热处理阶段中的脱碳过程不是由于脱润滑机制,而是由于碳热还原机制。
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引用次数: 0
Effect of MgO on Crystallization Behavior of CaO–SiO2–Al2O3 Inclusions in Si–Mn Deoxidized Steel During Solidification Stage 氧化镁对硅锰脱氧钢中 CaO-SiO2-Al2O3 夹杂物凝固阶段结晶行为的影响
Pub Date : 2024-08-26 DOI: 10.1007/s11663-024-03247-3
Qi Xu, Yaoqing Meng, Jianli Li

To avoid coarse crystallization of CaO–SiO2–Al2O3 inclusions during the solidification stage of continuous casting process, the effect of MgO on crystallization behavior of these inclusions is investigated. The single hot thermocouple technology experiment results show that the low melting point CaO–SiO2–Al2O3 inclusions do not easily crystallize during the solidification stage. However, with increasing the MgO content from 4.5 to 15.7 wt pct, the initial crystallization temperature of inclusions increases from 1376 K to 1431 K (1103 °C to 1158 °C) and the crystallization ratio increases from 35.45 to 100 pct. The crystallization ability of the inclusions can be predicted by the initial crystallization potential and the viscosity at the melting point. With increasing the MgO content from 0 to 15.7 wt pct, the initial crystallization potential of the inclusions increases from 0.28 to 0.87 and the viscosity of the inclusions at the melting point decreases from 4.47 to 0.56 Pa s. The higher the initial crystallization potential and the lower the viscosity near the melting point, the easier the crystallization of the inclusions occurs. Al2O3 mainly acts as the network former and participates in the construction of the network structure. With the increase of MgO content, the crystallization ability of inclusions increases gradually, which is mainly related to the increase of melt structure depolymerization.

为避免 CaO-SiO2-Al2O3 夹杂物在连铸工艺凝固阶段出现粗大结晶,研究了氧化镁对这些夹杂物结晶行为的影响。单热热电偶技术实验结果表明,低熔点的 CaO-SiO2-Al2O3 夹杂物在凝固阶段不易结晶。然而,随着氧化镁含量从 4.5 wt pct 增加到 15.7 wt pct,夹杂物的初始结晶温度从 1376 K 上升到 1431 K(1103 ℃ 上升到 1158 ℃),结晶比例从 35.45 pct 增加到 100 pct。夹杂物的结晶能力可通过初始结晶势和熔点粘度来预测。随着氧化镁含量从 0 wt pct 增加到 15.7 wt pct,包裹体的初始结晶势从 0.28 增加到 0.87,包裹体在熔点处的粘度从 4.47 Pa s 降低到 0.56 Pa s。Al2O3 主要充当网络前体,参与网络结构的构建。随着氧化镁含量的增加,包裹体的结晶能力逐渐增强,这主要与熔体结构解聚作用的增强有关。
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引用次数: 0
Reduction Behavior in Large-Sized Round Bloom During Continuous Casting by Numerical Simulation 通过数值模拟研究连铸过程中大尺寸圆形 Bloom 的还原行为
Pub Date : 2024-08-26 DOI: 10.1007/s11663-024-03246-4
Peng Lan, Liang Li, Yifan Lu, Haijie Wang, Hao Geng, Jiaquan Zhang

Solidification end reduction is an effective approach to control the central porosity during continuous casting of round bloom, although it is not widely reported. In the present work, a three-dimensional finite element model has been developed with coupling heat transfer and mechanical deformation for a φ690 mm continuously cast round bloom, and verified by the surface temperature, shrinkage zone width, reduction crack location, and deformed contour shape. It is found that the contact width between roller and the bloom increases with the increase of reduction amount and approximately in a parabolic relationship. To cover the whole range of the shrinkage zone, the total reduction amount should not be smaller than 25 mm as the width of the shrinkage zone is about 120 mm. The bulge width along the horizontal direction during reduction increases as the total reduction amount increases, and the relationship can be fitted by a parabolic equation. The reduction thickness in the shrinkage zone is larger when the reduction amount is higher, and it also follows parabolic relationship. The deformation in the shrinkage zone is more obvious when the reduction is conducted before crater end. The reduction efficiency for φ690 mm round bloom before solidification is between 20 and 30 pct, while after solidification is roughly between 12 and 20 pct. It increases with the increase of apparent reduction amount, mainly related to the increase of the strain rate. The deformation of the shrinkage zone in φ690 mm round bloom with 30 mm apparent reduction in continuous casting and hot rolling has been compared. The equivalent strain in the shrinkage zone of the round bloom in continuous casting is about 0.047 to 0.052, while that in hot rolling is about 0.031 to 0.036, indicating the reduction efficiency of the former is about 1.5 times higher than the latter.

凝固末端减薄是控制圆坯连铸过程中中心气孔的一种有效方法,但相关报道并不多。本研究针对 φ690 mm 连铸圆坯建立了传热和机械变形耦合的三维有限元模型,并通过表面温度、收缩区宽度、减径裂纹位置和变形轮廓形状进行了验证。研究发现,轧辊与大方坯的接触宽度随着减薄量的增加而增加,并近似呈抛物线关系。要覆盖整个收缩区范围,总减薄量不应小于 25 毫米,因为收缩区的宽度约为 120 毫米。随着总缩减量的增加,缩减过程中沿水平方向的隆起宽度也会增加,这种关系可以用抛物线方程来拟合。减薄量越大,收缩区的减薄厚度也越大,同样遵循抛物线关系。在陨石坑末端之前进行减径时,收缩区的变形更为明显。凝固前,φ690 毫米圆形大方坯的还原效率在 20-30% 之间,而凝固后大致在 12-20% 之间。它随着表观减薄量的增加而增加,这主要与应变速率的增加有关。比较了连铸和热轧表观减薄量为 30 mm 的 φ690 mm 圆形大方坯收缩区的变形。连铸中圆坯收缩区的等效应变约为 0.047 至 0.052,而热轧中的等效应变约为 0.031 至 0.036,表明前者的减薄效率约为后者的 1.5 倍。
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引用次数: 0
Effect of Ferrosilicon Deoxidation on the Evolution and Removal of Oxide Inclusions in 55SiCr Spring Steel 硅铁脱氧对 55SiCr 弹簧钢中氧化物夹杂物的演变和清除的影响
Pub Date : 2024-08-21 DOI: 10.1007/s11663-024-03196-x
Shuai Ma, Yang Li, Zhouhua Jiang, Meng Sun, Yunqie Mao, Dengyunfei Nie, Boyang Li, Changyong Chen

The effects of pure silicon deoxidation (Si group) and ferrosilicon deoxidation (FeSi group) on the evolution of oxide inclusions in 55SiCr spring steel are methodically examined using OTSInca, SEM-EDS, and FactSage 8.0. Compared with the Si group, the FeSi group is more favorable for controlling the total oxygen content in steel, and the total oxygen content in ingots is only 0.0012 pct. The average equivalent diameter of inclusions in the Si group continuously lessens with the melting process, while it is exactly the opposite in the FeSi group, and the average equivalent diameter of the inclusions in the ingots reaches 3.64 μm. The evolution of inclusions in the Si group is essentially provided by SiO2 → SiO2–MnO–Al2O3 → SiO2–MnO–Al2O3–MgO, whereas the evolution process of inclusions in the FeSi group is mainly characterized by Al2O3–CaO → Al2O3–CaO–SiO2 → Al2O3–CaO–SiO2–MgO. However, MgO–Al2O3 and MgO–SiO2 inclusions are precipitated in the inclusions because of the uneven distribution of inclusions in the ingot. In continuing, the Gibbs free energy of chemical reaction is utilized to explain the evolution of inclusions. FactSage calculation results reveal that the main inclusions in the Si group under equilibrium solidification conditions are 2Al2O3·2MgO·5SiO2, 5Al2O3·4MgO·2SiO2, and Al2O3·SiO2. Additionally, the inclusions in the FeSi group are obtained as CaO·2MgO·8Al2O3, MgO·Al2O3, and 2CaO·MgO·2SiO2. The deformability of inclusions in the FeSi group is not as good as in the Si group. The calculated results of the complete melting temperature and Young’s modulus of inclusions indicate that reducing the proportion of Al2O3 and MgO in inclusions leads to the improvement of the deformability of inclusions. This study is aimed to provide a fairly solid reference for controlling and removing inclusions in spring steel.

使用 OTSInca、SEM-EDS 和 FactSage 8.0 方法研究了纯硅脱氧(Si 组)和硅铁脱氧(FeSi 组)对 55SiCr 弹簧钢中氧化物夹杂物演变的影响。与 Si 组相比,FeSi 组更有利于控制钢中的总氧含量,钢锭中的总氧含量仅为 0.0012 pct。硅组夹杂物的平均当量直径随着熔化过程不断减小,而铁硅组则恰恰相反,钢锭中夹杂物的平均当量直径达到 3.64 μm。硅组夹杂物的演化过程主要由 SiO2 → SiO2-MnO-Al2O3 → SiO2-MnO-Al2O3-MgO 实现,而 FeSi 组夹杂物的演化过程主要由 Al2O3-CaO → Al2O3-CaO-SiO2 → Al2O3-CaO-SiO2-MgO 实现。然而,由于夹杂物在铸锭中分布不均,夹杂物中会析出 MgO-Al2O3 和 MgO-SiO2。继续利用化学反应的吉布斯自由能来解释夹杂物的演变。FactSage 计算结果表明,在平衡凝固条件下,Si 组的主要夹杂物为 2Al2O3-2MgO-5SiO2、5Al2O3-4MgO-2SiO2 和 Al2O3-SiO2。此外,在 FeSi 组中得到的包裹体有 CaO-2MgO-8Al2O3、MgO-Al2O3 和 2CaO-MgO-2SiO2。FeSi 组夹杂物的变形能力不如 Si 组。夹杂物完全熔化温度和杨氏模量的计算结果表明,降低 Al2O3 和 MgO 在夹杂物中的比例可改善夹杂物的变形性。这项研究旨在为控制和去除弹簧钢中的夹杂物提供可靠的参考。
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引用次数: 0
The Effect of Solute Suppressed Nucleation Effect and Latent Heat on the Grain Refinement of Cast Aluminum Alloy 溶质抑制成核效应和潜热对铸铝合金晶粒细化的影响
Pub Date : 2024-08-21 DOI: 10.1007/s11663-024-03166-3
Li Jun, Jiang Haitao, Wu Xiaoyan, Liu Wenqiang, Lu Hongzhou

Grain refinement is the key to developing high-quality cast aluminum alloys. Based on the solute conservation theory and dendritic growth kinetics model, this paper developed a cellular automaton (CA) numerical model and fully considered the complex evolutionary processes, such as nucleation particle characteristics, nucleation-growth process, dynamic solute diffusion, and latent heat release during the solidification process of aluminum alloys. The CA model was used to quantify the role of solidification latent heat and solute diffusion in the grain nucleation process. The influence of solute suppressed nucleation (SSN) and solidification latent heat on the grain refinement effect of aluminum alloys are systematically studied. The results showed that when only considering the SSN effect, with the increase of nucleation density, the refinement efficiency decreases from 81.2 to 45.98 pct, and the decrease gradually decreases. This was mainly due to the increase of number of particles in the solute diffusion layer. The grain separation distance (GSD) became smaller than the size of the invisible nucleus region, reducing in the nucleation efficiency of the particles there. When the model further considered the effect of latent heat, the refinement efficiency was sharply dropped to 7 pct. The re-glow phenomenon caused by latent heat release limited the possibility of nucleation of small-sized particles and particles located in the SSN zone. Therefore, latent heat was fond to be the main factor restricting grain refinement.

晶粒细化是开发高质量铸造铝合金的关键。本文基于溶质守恒理论和树枝状生长动力学模型,建立了细胞自动机(CA)数值模型,充分考虑了铝合金凝固过程中晶核颗粒特征、晶核生长过程、溶质动态扩散和潜热释放等复杂的演化过程。CA 模型用于量化凝固潜热和溶质扩散在晶粒成核过程中的作用。系统研究了溶质抑制成核(SSN)和凝固潜热对铝合金晶粒细化效应的影响。结果表明,当仅考虑 SSN 的影响时,随着成核密度的增加,细化效率从 81.2 pct 下降到 45.98 pct,且下降幅度逐渐减小。这主要是由于溶质扩散层中颗粒数量的增加。晶粒分离距离(GSD)变得小于隐形晶核区域的尺寸,从而降低了该区域颗粒的成核效率。当模型进一步考虑潜热的影响时,细化效率急剧下降到 7%。潜热释放引起的再辉光现象限制了小尺寸颗粒和位于 SSN 区域的颗粒成核的可能性。因此,潜热被认为是限制晶粒细化的主要因素。
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引用次数: 0
Self-Attention-Based Convolutional Parallel Network: An Efficient Multi-Input Deep Learning Model for Endpoint Prediction of High-Carbon BOF Steelmaking 基于自注意力的卷积并行网络:用于高碳转炉炼钢终点预测的高效多输入深度学习模型
Pub Date : 2024-08-19 DOI: 10.1007/s11663-024-03204-0
Tian-yi Xie, Fei Zhang, Yi-ren Li, Quan Zhang, Yan-wei Wang, Hao Shang

In this work, a data-driven model for endpoint prediction of basic oxygen furnace (BOF) steelmaking based on both tabular features (information about hot metal, scrap, additives, blowing practices) and time series (curves of off-gas profiles, sonar slagging, and blowing practices) was developed and implemented. The model was designed with the following distinctive artificial intelligence (AI) characteristics: convolutional neural networks, patching embedding, wavelet decomposition, a parallel structure, a self-attention mechanism, a collaborative attention mechanism, and so on. The model presented in this work is named the self-attention-based convolutional parallel network (SabCP) and was applied to high-carbon steelmaking scenarios. SabCP predicts the endpoint of molten steel temperature (Temp) and chemistry (contents of carbon (C), phosphorus (P), and sulfur (S)). For training, validation, and testing, historical data from 13,656 heats were collected. The testing results show that the mean absolute errors (MAEs) of SabCP for temperature and the contents of carbon, phosphorus, and sulfur are 6.374 °C, 7.192 × 10−3, 2.390 × 10−3, and 2.224 × 10−3 pct, respectively, while the mean square errors (MSEs) are 67.345, 1.132 × 10−4, 1.306 × 10−5, and 1.298 × 10−5, respectively, which are lower than those of other published models with same dataset. Relevant importance analyses for tabular features, time series time steps, and channels are also performed. SabCP has been implemented in a prediction module, and the practical results show its strong robustness and generalizability. This model provides significant feasibility for fully eliminating the conventional physical temperature, sampling, and oxygen test (TSO test), which may greatly decrease the cost of BOF steelmaking.

在这项工作中,开发并实现了基于表格特征(有关热金属、废钢、添加剂、吹炼方法的信息)和时间序列(废气曲线、声纳造渣和吹炼方法的曲线)的数据驱动型碱性氧气炉(BOF)炼钢终点预测模型。该模型的设计具有以下鲜明的人工智能(AI)特征:卷积神经网络、补丁嵌入、小波分解、并行结构、自我关注机制、协同关注机制等。本研究提出的模型被命名为基于自我注意的卷积并行网络(SabCP),并被应用于高碳炼钢场景。SabCP 预测钢水温度(Temp)和化学成分(碳(C)、磷(P)和硫(S)的含量)的终点。为进行培训、验证和测试,收集了 13 656 次加热的历史数据。测试结果表明,SabCP 对温度和碳、磷、硫含量的平均绝对误差(MAEs)分别为 6.374 °C、7.192 × 10-3、2.390 × 10-3 和 2.224 × 10-3 pct,而均方误差(MSEs)分别为 67.345、1.132 × 10-4、1.306 × 10-5 和 1.298 × 10-5,低于其他已发表的具有相同数据集的模型。此外,还对表格特征、时间序列时间步长和通道进行了相关重要性分析。SabCP 已在预测模块中实现,实际结果表明其具有很强的鲁棒性和普适性。该模型为完全取消传统的物理温度、取样和氧气测试(TSO 测试)提供了重要的可行性,可大大降低转炉炼钢的成本。
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引用次数: 0
Softening and Melting of Wüstite: Insights from a Multiscale Study 绿柱石的软化和熔化:多尺度研究的启示
Pub Date : 2024-08-19 DOI: 10.1007/s11663-024-03242-8
Qinghui Wu, Panshuai Ma, Kaihui Ma, Fuchuan Zhang, Jian Xu

Wüstite (FeO) has been extensively studied within the context of ironmaking metallurgy and the recycling of industrial waste, owing to its crucial role in high-temperature systems that exhibit softening and melting behaviors. Understanding these behaviors is vital for advancing multi-phase transport and chemical reactions in metallurgical processes. In this work, the Tammann temperature of FeO was identified to be approximately 826 K, a finding confirmed by molecular dynamics simulations and experimental validation. Below this threshold, the atoms' thermal vibration led to a volumetric expansion of the material. Conversely, surpassing 826 K triggered solid-state sintering, resulting in a noticeable shrinkage of FeO granules and the compaction of packed beds under mechanical stress. During softening, the reorganization of FeO grains was observed, with bonding commencing at contact points and the formation of sintering necks as surface atoms migrated and diffused. As temperatures rose further, this mass transfer and atomic diffusion intensified, facilitating the outward migration across grain boundaries, and culminating in the coalescence of smaller grains into larger formations.

在炼铁冶金和工业废弃物回收利用方面,人们对伍司特(FeO)进行了广泛的研究,因为它在高温系统中扮演着至关重要的角色,表现出软化和熔化行为。了解这些行为对于推进冶金过程中的多相传输和化学反应至关重要。在这项工作中,确定了氧化铁的塔曼温度约为 826 K,分子动力学模拟和实验验证证实了这一发现。低于这一临界值时,原子的热振动会导致材料体积膨胀。相反,超过 826 K 会引发固态烧结,导致氧化铁颗粒明显收缩,并在机械应力作用下压实堆积床。在软化过程中,观察到了氧化铁颗粒的重组,接触点开始结合,随着表面原子的迁移和扩散,形成了烧结颈。随着温度的进一步升高,这种质量转移和原子扩散加剧,促进了晶界的向外迁移,最终使较小的晶粒凝聚成较大的晶粒。
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Metallurgical and Materials Transactions B
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