In this work, a data-driven model for endpoint prediction of basic oxygen furnace (BOF) steelmaking based on both tabular features (information about hot metal, scrap, additives, blowing practices) and time series (curves of off-gas profiles, sonar slagging, and blowing practices) was developed and implemented. The model was designed with the following distinctive artificial intelligence (AI) characteristics: convolutional neural networks, patching embedding, wavelet decomposition, a parallel structure, a self-attention mechanism, a collaborative attention mechanism, and so on. The model presented in this work is named the self-attention-based convolutional parallel network (SabCP) and was applied to high-carbon steelmaking scenarios. SabCP predicts the endpoint of molten steel temperature (Temp) and chemistry (contents of carbon (C), phosphorus (P), and sulfur (S)). For training, validation, and testing, historical data from 13,656 heats were collected. The testing results show that the mean absolute errors (MAEs) of SabCP for temperature and the contents of carbon, phosphorus, and sulfur are 6.374 °C, 7.192 × 10−3, 2.390 × 10−3, and 2.224 × 10−3 pct, respectively, while the mean square errors (MSEs) are 67.345, 1.132 × 10−4, 1.306 × 10−5, and 1.298 × 10−5, respectively, which are lower than those of other published models with same dataset. Relevant importance analyses for tabular features, time series time steps, and channels are also performed. SabCP has been implemented in a prediction module, and the practical results show its strong robustness and generalizability. This model provides significant feasibility for fully eliminating the conventional physical temperature, sampling, and oxygen test (TSO test), which may greatly decrease the cost of BOF steelmaking.
{"title":"Self-Attention-Based Convolutional Parallel Network: An Efficient Multi-Input Deep Learning Model for Endpoint Prediction of High-Carbon BOF Steelmaking","authors":"Tian-yi Xie, Fei Zhang, Yi-ren Li, Quan Zhang, Yan-wei Wang, Hao Shang","doi":"10.1007/s11663-024-03204-0","DOIUrl":"https://doi.org/10.1007/s11663-024-03204-0","url":null,"abstract":"<p>In this work, a data-driven model for endpoint prediction of basic oxygen furnace (BOF) steelmaking based on both tabular features (information about hot metal, scrap, additives, blowing practices) and time series (curves of off-gas profiles, sonar slagging, and blowing practices) was developed and implemented. The model was designed with the following distinctive artificial intelligence (AI) characteristics: convolutional neural networks, patching embedding, wavelet decomposition, a parallel structure, a self-attention mechanism, a collaborative attention mechanism, and so on. The model presented in this work is named the self-attention-based convolutional parallel network (SabCP) and was applied to high-carbon steelmaking scenarios. SabCP predicts the endpoint of molten steel temperature (Temp) and chemistry (contents of carbon (C), phosphorus (P), and sulfur (S)). For training, validation, and testing, historical data from 13,656 heats were collected. The testing results show that the mean absolute errors (MAEs) of SabCP for temperature and the contents of carbon, phosphorus, and sulfur are 6.374 °C, 7.192 × 10<sup>−3</sup>, 2.390 × 10<sup>−3</sup>, and 2.224 × 10<sup>−3</sup> pct, respectively, while the mean square errors (MSEs) are 67.345, 1.132 × 10<sup>−4</sup>, 1.306 × 10<sup>−5</sup>, and 1.298 × 10<sup>−5</sup>, respectively, which are lower than those of other published models with same dataset. Relevant importance analyses for tabular features, time series time steps, and channels are also performed. SabCP has been implemented in a prediction module, and the practical results show its strong robustness and generalizability. This model provides significant feasibility for fully eliminating the conventional physical temperature, sampling, and oxygen test (TSO test), which may greatly decrease the cost of BOF steelmaking.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wüstite (FeO) has been extensively studied within the context of ironmaking metallurgy and the recycling of industrial waste, owing to its crucial role in high-temperature systems that exhibit softening and melting behaviors. Understanding these behaviors is vital for advancing multi-phase transport and chemical reactions in metallurgical processes. In this work, the Tammann temperature of FeO was identified to be approximately 826 K, a finding confirmed by molecular dynamics simulations and experimental validation. Below this threshold, the atoms' thermal vibration led to a volumetric expansion of the material. Conversely, surpassing 826 K triggered solid-state sintering, resulting in a noticeable shrinkage of FeO granules and the compaction of packed beds under mechanical stress. During softening, the reorganization of FeO grains was observed, with bonding commencing at contact points and the formation of sintering necks as surface atoms migrated and diffused. As temperatures rose further, this mass transfer and atomic diffusion intensified, facilitating the outward migration across grain boundaries, and culminating in the coalescence of smaller grains into larger formations.
在炼铁冶金和工业废弃物回收利用方面,人们对伍司特(FeO)进行了广泛的研究,因为它在高温系统中扮演着至关重要的角色,表现出软化和熔化行为。了解这些行为对于推进冶金过程中的多相传输和化学反应至关重要。在这项工作中,确定了氧化铁的塔曼温度约为 826 K,分子动力学模拟和实验验证证实了这一发现。低于这一临界值时,原子的热振动会导致材料体积膨胀。相反,超过 826 K 会引发固态烧结,导致氧化铁颗粒明显收缩,并在机械应力作用下压实堆积床。在软化过程中,观察到了氧化铁颗粒的重组,接触点开始结合,随着表面原子的迁移和扩散,形成了烧结颈。随着温度的进一步升高,这种质量转移和原子扩散加剧,促进了晶界的向外迁移,最终使较小的晶粒凝聚成较大的晶粒。
{"title":"Softening and Melting of Wüstite: Insights from a Multiscale Study","authors":"Qinghui Wu, Panshuai Ma, Kaihui Ma, Fuchuan Zhang, Jian Xu","doi":"10.1007/s11663-024-03242-8","DOIUrl":"https://doi.org/10.1007/s11663-024-03242-8","url":null,"abstract":"<p>Wüstite (FeO) has been extensively studied within the context of ironmaking metallurgy and the recycling of industrial waste, owing to its crucial role in high-temperature systems that exhibit softening and melting behaviors. Understanding these behaviors is vital for advancing multi-phase transport and chemical reactions in metallurgical processes. In this work, the Tammann temperature of FeO was identified to be approximately 826 K, a finding confirmed by molecular dynamics simulations and experimental validation. Below this threshold, the atoms' thermal vibration led to a volumetric expansion of the material. Conversely, surpassing 826 K triggered solid-state sintering, resulting in a noticeable shrinkage of FeO granules and the compaction of packed beds under mechanical stress. During softening, the reorganization of FeO grains was observed, with bonding commencing at contact points and the formation of sintering necks as surface atoms migrated and diffused. As temperatures rose further, this mass transfer and atomic diffusion intensified, facilitating the outward migration across grain boundaries, and culminating in the coalescence of smaller grains into larger formations.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-15DOI: 10.1007/s11663-024-03235-7
Hedda Pousette, Niklas Kojola, Oscar Hessling
Direct reduction, with reducing gases containing CO and H2, is becoming an increasingly important process for reduction of iron ore to iron. There is a need for understanding reduction and carburization mechanisms for CO + H2 gases in shaft-like conditions. The experimental setup includes a column of pellets, where ingoing gas of 40 pct CO and 60 pct H2 and known temperature enters at the bottom and exits at the top. Experiments are carried out at 600 °C, 700 °C, 800 °C, and 900 °C for 1, 2.5, or 5 hours with gas flow rate of 4 or 6 nL/min. After reduction, pellets are removed, taking note of vertical position, and analyzed for reduction degree, total carbon, and cementite content. Results show that there is a gradient in reduction and carburization over the column height, which decreases with increasing time. Comparison of thermodynamic calculations with experimental results shows that kinetic factors have a strong influence on reduction and carburization. Consumption of gas by reduction or carburization reactions limits gas suitability at the local reaction sites. It could therefore be of interest to design the shaft process so that reduction and carburization take place in two steps.
{"title":"Reduction and Carburization Mechanisms for CO + H2 Reduction in Shaft Furnace Conditions","authors":"Hedda Pousette, Niklas Kojola, Oscar Hessling","doi":"10.1007/s11663-024-03235-7","DOIUrl":"https://doi.org/10.1007/s11663-024-03235-7","url":null,"abstract":"<p>Direct reduction, with reducing gases containing CO and H<sub>2</sub>, is becoming an increasingly important process for reduction of iron ore to iron. There is a need for understanding reduction and carburization mechanisms for CO + H<sub>2</sub> gases in shaft-like conditions. The experimental setup includes a column of pellets, where ingoing gas of 40 pct CO and 60 pct H<sub>2</sub> and known temperature enters at the bottom and exits at the top. Experiments are carried out at 600 °C, 700 °C, 800 °C, and 900 °C for 1, 2.5, or 5 hours with gas flow rate of 4 or 6 nL/min. After reduction, pellets are removed, taking note of vertical position, and analyzed for reduction degree, total carbon, and cementite content. Results show that there is a gradient in reduction and carburization over the column height, which decreases with increasing time. Comparison of thermodynamic calculations with experimental results shows that kinetic factors have a strong influence on reduction and carburization. Consumption of gas by reduction or carburization reactions limits gas suitability at the local reaction sites. It could therefore be of interest to design the shaft process so that reduction and carburization take place in two steps.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-14DOI: 10.1007/s11663-024-03243-7
Yong-jiao Zhang, Xi-min Zang, Ling-zhong Kong, Jie Yang, Shi-sen Li, Guo-cheng Wang
The crystallization behaviors of CaF2–CaO–Al2O3–MgO–B2O3 slag for electroslag remelting of B-containing rack steel was investigated through a series of non-isothermal and isothermal crystallization experiments. The techniques employed for this determination included differential scanning calorimetry, X-ray diffraction, scanning electron microscopy-energy dispersive spectroscopy, and FactSage 8.2. The results indicated that an increase in B2O3 content suppressed the crystallization of CaF2–CaO–Al2O3–MgO slag. The crystallization temperature decreased as the B2O3 content in the slag increased from 2 to 7 mass pct. In the slag containing 2 mass pct B2O3, spherical CaF2 precipitates first, followed by reticulate Ca12Al14F2O32 phase. Increasing B2O3 addition promoted the formation of Ca5(BO3)3F and calcium aluminate (Ca12Al14O33 or CaAl4O7), and decreased the crystallization of Ca12Al14F2O32 phase. The crystallization sequence transformed into CaF2 → CaAl4O7 → MgAl2O4 + Ca5(BO3)3F in the case of 7 mass pct B2O3. B2O3 addition inhibits the crystallization of the dominated phase CaF2, which would improving the lubrication and heat transfer performance of ESR-type CaF2–CaO–Al2O3–MgO slags.
{"title":"Crystallization Behaviors of CaF2–CaO–Al2O3–MgO–B2O3 Slag for Electroslag Remelting of B-Containing Rack Steel","authors":"Yong-jiao Zhang, Xi-min Zang, Ling-zhong Kong, Jie Yang, Shi-sen Li, Guo-cheng Wang","doi":"10.1007/s11663-024-03243-7","DOIUrl":"https://doi.org/10.1007/s11663-024-03243-7","url":null,"abstract":"<p>The crystallization behaviors of CaF<sub>2</sub>–CaO–Al<sub>2</sub>O<sub>3</sub>–MgO–B<sub>2</sub>O<sub>3</sub> slag for electroslag remelting of B-containing rack steel was investigated through a series of non-isothermal and isothermal crystallization experiments. The techniques employed for this determination included differential scanning calorimetry, X-ray diffraction, scanning electron microscopy-energy dispersive spectroscopy, and FactSage 8.2. The results indicated that an increase in B<sub>2</sub>O<sub>3</sub> content suppressed the crystallization of CaF<sub>2</sub>–CaO–Al<sub>2</sub>O<sub>3</sub>–MgO slag. The crystallization temperature decreased as the B<sub>2</sub>O<sub>3</sub> content in the slag increased from 2 to 7 mass pct. In the slag containing 2 mass pct B<sub>2</sub>O<sub>3</sub>, spherical CaF<sub>2</sub> precipitates first, followed by reticulate Ca<sub>12</sub>Al<sub>14</sub>F<sub>2</sub>O<sub>32</sub> phase. Increasing B<sub>2</sub>O<sub>3</sub> addition promoted the formation of Ca<sub>5</sub>(BO<sub>3</sub>)<sub>3</sub>F and calcium aluminate (Ca<sub>12</sub>Al<sub>14</sub>O<sub>33</sub> or CaAl<sub>4</sub>O<sub>7</sub>), and decreased the crystallization of Ca<sub>12</sub>Al<sub>14</sub>F<sub>2</sub>O<sub>32</sub> phase. The crystallization sequence transformed into CaF<sub>2</sub> → CaAl<sub>4</sub>O<sub>7</sub> → MgAl<sub>2</sub>O<sub>4</sub> + Ca<sub>5</sub>(BO<sub>3</sub>)<sub>3</sub>F in the case of 7 mass pct B<sub>2</sub>O<sub>3</sub>. B<sub>2</sub>O<sub>3</sub> addition inhibits the crystallization of the dominated phase CaF<sub>2</sub>, which would improving the lubrication and heat transfer performance of ESR-type CaF<sub>2</sub>–CaO–Al<sub>2</sub>O<sub>3</sub>–MgO slags.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Quantifying the degree of element transfer within the droplet zone during submerged arc welding (SAW) remains challenging due to the coverage of the droplet zone by fluxes and the presence of arc plasma, which are characterized by exceedingly high temperatures and short lifetime. This present study has investigated element transfer behaviors within the droplet zone during SAW by employing fused CaO–SiO2–MnO fluxes with varying MnO contents and welding current intensities. An apparatus designed for capturing droplets in SAW was employed. The results indicate that, as the welding current increases from 200 to 400 A, the average transfer levels of Si, Mn, and O in the fluxes to the droplet increase by 1.81, 2.52, and 1.42 times, respectively. As the MnO content increases from 10 to 60 wt pct, the average transfer levels of Si, Mn, and O in the fluxes to the droplet increase by 24.97, 3.01, and 2.22 times, respectively. Our current findings may facilitate elucidating the influence of arc plasma on element transfer within the droplet zone, thereby establishing a theoretical framework for comprehensively understanding the contribution of individual reaction zones during SAW.
{"title":"Unveiling Droplet Zone Element Transfer Behaviors of CaO–SiO2–MnO Fluxes in the EH36 Shipbuilding Steel Subject to Submerged Arc Welding","authors":"Guanyi Wang, Yanyun Zhang, Yanqing Zhao, Hangyu Bai, Imants Kaldre, Cong Wang","doi":"10.1007/s11663-024-03231-x","DOIUrl":"https://doi.org/10.1007/s11663-024-03231-x","url":null,"abstract":"<p>Quantifying the degree of element transfer within the droplet zone during submerged arc welding (SAW) remains challenging due to the coverage of the droplet zone by fluxes and the presence of arc plasma, which are characterized by exceedingly high temperatures and short lifetime. This present study has investigated element transfer behaviors within the droplet zone during SAW by employing fused CaO–SiO<sub>2</sub>–MnO fluxes with varying MnO contents and welding current intensities. An apparatus designed for capturing droplets in SAW was employed. The results indicate that, as the welding current increases from 200 to 400 A, the average transfer levels of Si, Mn, and O in the fluxes to the droplet increase by 1.81, 2.52, and 1.42 times, respectively. As the MnO content increases from 10 to 60 wt pct, the average transfer levels of Si, Mn, and O in the fluxes to the droplet increase by 24.97, 3.01, and 2.22 times, respectively. Our current findings may facilitate elucidating the influence of arc plasma on element transfer within the droplet zone, thereby establishing a theoretical framework for comprehensively understanding the contribution of individual reaction zones during SAW.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-14DOI: 10.1007/s11663-024-03241-9
Shi-bo Wang, Zhao-zhen Cai, Miao-yong Zhu
The excellent water-cooling structure contributes to achieve efficient and reasonable heat transfer in the mold, which is essential for achieving the ultra-large beam blank continuous casting (ULBBCC). Therefore, this work designed different ultra-large beam blank mold (ULBBM) which were composed of three wide face copper plates with different water-cooling structures and two narrow face copper plates with different water-cooling structures, on the basis of which a three-dimensional heat transfer model of the copper plate coupling with the cooling water flow in the water-cooling structure was developed with the consideration of fluid-solid coupling interaction. Then, the accuracy of the model was verified by comparing the model-predicted and measured water temperatures. Finally, the focus is comparing the heat transfer behavior of the mold under different water-cooling structures, as well as the temperature and flow evolution of the cooling water, and the most optimal water-cooling structure was proposed. The results show that the water-cooling structure of water slots with semicircular roots (Mold II) contributes the narrow face copper plate of ULBBM to obtain excellent temperature uniformity and achieve homogenization of heat transfer. The water-cooling structure of small hole water channel with a diameter of 10 mm (Mold III) decreases the maximum temperature at the fillet of wide face copper plate of ULBBM to 582.9 K and the maximum circumferential temperature difference near the meniscus to 103.3 K, and which contributes the wide face copper plate to obtain higher temperature uniformity and lower fillet temperature, and achieve homogenization of heat transfer.
{"title":"The Heat Transfer Behavior of Ultra-Large Beam Blank Continuous Casting Mold with Different Water-Cooling Structure","authors":"Shi-bo Wang, Zhao-zhen Cai, Miao-yong Zhu","doi":"10.1007/s11663-024-03241-9","DOIUrl":"https://doi.org/10.1007/s11663-024-03241-9","url":null,"abstract":"<p>The excellent water-cooling structure contributes to achieve efficient and reasonable heat transfer in the mold, which is essential for achieving the ultra-large beam blank continuous casting (ULBBCC). Therefore, this work designed different ultra-large beam blank mold (ULBBM) which were composed of three wide face copper plates with different water-cooling structures and two narrow face copper plates with different water-cooling structures, on the basis of which a three-dimensional heat transfer model of the copper plate coupling with the cooling water flow in the water-cooling structure was developed with the consideration of fluid-solid coupling interaction. Then, the accuracy of the model was verified by comparing the model-predicted and measured water temperatures. Finally, the focus is comparing the heat transfer behavior of the mold under different water-cooling structures, as well as the temperature and flow evolution of the cooling water, and the most optimal water-cooling structure was proposed. The results show that the water-cooling structure of water slots with semicircular roots (Mold II) contributes the narrow face copper plate of ULBBM to obtain excellent temperature uniformity and achieve homogenization of heat transfer. The water-cooling structure of small hole water channel with a diameter of 10 mm (Mold III) decreases the maximum temperature at the fillet of wide face copper plate of ULBBM to 582.9 K and the maximum circumferential temperature difference near the meniscus to 103.3 K, and which contributes the wide face copper plate to obtain higher temperature uniformity and lower fillet temperature, and achieve homogenization of heat transfer.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-12DOI: 10.1007/s11663-024-03239-3
Wei-Tong Du, Ting-Feng Yao, Hai-Ming Cheng, Dian-Chun Ju, Zhuo Chen
This study investigates the influence of spinel crystallization characteristics on vanadium extraction during the converter vanadium slag-cooling process through thermodynamic calculations and experimental investigations. The phase evolution and micro-morphology variations of V-containing slag at different quenching temperatures are characterized via X-ray diffraction and scanning electron microscopy-energy dispersive X-ray spectroscopy, and the grain size of spinel phases is measured using an image processing software. Results indicate that the crystallization sequence in V-containing slag during the cooling process is V-spinel → Ti-spinel → olivine → rhodonite. When the temperature is reduced from 1400 °C to 1000 °C, the grain sizes of spinel exhibit a log-normal distribution, with the mean diameter and leaching rate of vanadium increasing from 15.11 to 27.27 μm and from 82.65 pct to 92.06 pct, respectively. The restrictive step in the crystallization process is the interfacial reaction. When cooled from 1000 °C to 25 °C, Ostwald ripening-type grain size distribution is observed, and the mean diameter increased to 41.9 μm. The vanadium leaching rate decreased to 85 pct due to the encapsulation of V-spinel by Ti-spinel and olivine, and the crystallization process is observed to be controlled by diffusion.
本研究通过热力学计算和实验研究,探讨了转炉钒渣冷却过程中尖晶石结晶特性对提钒的影响。通过 X 射线衍射和扫描电子显微镜-能量色散 X 射线光谱对不同淬火温度下的含钒炉渣的相演化和微观形态变化进行了表征,并利用图像处理软件测量了尖晶石相的晶粒尺寸。结果表明,含 V 矿渣在冷却过程中的结晶顺序为 V-尖晶石→Ti-尖晶石→橄榄石→菱铁矿。当温度从 1400 °C 降低到 1000 °C 时,尖晶石的晶粒大小呈现对数正态分布,钒的平均直径和浸出率分别从 15.11 μm 和 82.65 pct 增加到 27.27 μm 和 92.06 pct。结晶过程的限制步骤是界面反应。从 1000 °C 冷却到 25 °C 时,观察到奥斯特瓦尔德熟化型晶粒尺寸分布,平均直径增加到 41.9 μm。由于 V-尖晶石被 Ti-尖晶石和橄榄石包裹,钒浸出率下降到 85%,而且观察到结晶过程受扩散控制。
{"title":"Effects of Spinel Crystallization Characteristics on Leaching Vanadium from Vanadium-Containing Slag","authors":"Wei-Tong Du, Ting-Feng Yao, Hai-Ming Cheng, Dian-Chun Ju, Zhuo Chen","doi":"10.1007/s11663-024-03239-3","DOIUrl":"https://doi.org/10.1007/s11663-024-03239-3","url":null,"abstract":"<p>This study investigates the influence of spinel crystallization characteristics on vanadium extraction during the converter vanadium slag-cooling process through thermodynamic calculations and experimental investigations. The phase evolution and micro-morphology variations of V-containing slag at different quenching temperatures are characterized <i>via</i> X-ray diffraction and scanning electron microscopy-energy dispersive X-ray spectroscopy, and the grain size of spinel phases is measured using an image processing software. Results indicate that the crystallization sequence in V-containing slag during the cooling process is V-spinel → Ti-spinel → olivine → rhodonite. When the temperature is reduced from 1400 °C to 1000 °C, the grain sizes of spinel exhibit a log-normal distribution, with the mean diameter and leaching rate of vanadium increasing from 15.11 to 27.27 <i>μ</i>m and from 82.65 pct to 92.06 pct, respectively. The restrictive step in the crystallization process is the interfacial reaction. When cooled from 1000 °C to 25 °C, Ostwald ripening-type grain size distribution is observed, and the mean diameter increased to 41.9 <i>μ</i>m. The vanadium leaching rate decreased to 85 pct due to the encapsulation of V-spinel by Ti-spinel and olivine, and the crystallization process is observed to be controlled by diffusion.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The bottom blowing element is critical for ensuring the effectiveness of top and bottom blowing in converter steelmaking process. Investigating the influence of different bottom blowing elements on the stirring properties of molten bath contributes to the optimization of the bottom blowing system. The effects of structural variations in dispersive, circular seam and straight cylinder types of bottom blowing elements on molten bath fluid dynamics, turbulent kinetic energy and multiphase flow properties of gas-slag-metal were investigated through numerical simulations. In addition, physical simulations were used to measure the mixing time of molten bath, observe changes in the flow field, and validate and analyze the results of the numerical simulations. The results show that the dispersive type element has a wider dispersion range of the flow jets, while the straight cylinder type has the smallest dispersion range. When the bottom blowing intensity is below 0.05 Nm3/t·min, the dispersive type has the longest mixing time, while the circular seam type has the shortest mixing time. Conversely, at more than 0.08 Nm3/t·min, the dispersive type shows the shortest mixing time and the straight cylinder type shows the longest. The dispersive type significantly influences the bottom flow field and disperses tracers from the interior of molten bath. The circular seam type mainly affects the middle flow field and directs tracers along the central area. The straight cylinder type, on the other hand, has a significant influence on the surface flow field and directs tracers along the pool surface.
{"title":"Comparison of Bottom Blowing Element Based on the Characteristics of Gas Stream and Stirring Ability in 120t Converter","authors":"Yijie Hao, Ming Lv, Fuqing Hou, Shiwu Ruan, Zhaohui Zhang, Xiangdong Xing","doi":"10.1007/s11663-024-03240-w","DOIUrl":"https://doi.org/10.1007/s11663-024-03240-w","url":null,"abstract":"<p>The bottom blowing element is critical for ensuring the effectiveness of top and bottom blowing in converter steelmaking process. Investigating the influence of different bottom blowing elements on the stirring properties of molten bath contributes to the optimization of the bottom blowing system. The effects of structural variations in dispersive, circular seam and straight cylinder types of bottom blowing elements on molten bath fluid dynamics, turbulent kinetic energy and multiphase flow properties of gas-slag-metal were investigated through numerical simulations. In addition, physical simulations were used to measure the mixing time of molten bath, observe changes in the flow field, and validate and analyze the results of the numerical simulations. The results show that the dispersive type element has a wider dispersion range of the flow jets, while the straight cylinder type has the smallest dispersion range. When the bottom blowing intensity is below 0.05 Nm<sup>3</sup>/t·min, the dispersive type has the longest mixing time, while the circular seam type has the shortest mixing time. Conversely, at more than 0.08 Nm<sup>3</sup>/t·min, the dispersive type shows the shortest mixing time and the straight cylinder type shows the longest. The dispersive type significantly influences the bottom flow field and disperses tracers from the interior of molten bath. The circular seam type mainly affects the middle flow field and directs tracers along the central area. The straight cylinder type, on the other hand, has a significant influence on the surface flow field and directs tracers along the pool surface.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208116","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
40Cr10Si2Mo steel is widely utilized because of its excellent mechanical properties, with grain size being a critical factor determining subsequent phase transformation processes and material microstructure performance. This paper reports the use of high-temperature laser scanning confocal microscopy (HT-LSCM) for in situ observation experiments to systematically investigate the growth of austenite grains and the martensitic phase transformation mechanism in 40Cr10Si2Mo steel during an 1800-second isothermal hold at temperatures ranging from 900 °C to 1250 °C. A dynamic model of austenite grain growth is established to optimize the parameters of the austenitic process. The results indicate that the austenite grain size increases continuously with increasing temperature and prolonged time. The Dong model predicts grain sizes that align well with experimental values. Austenite grains grow through grain boundary migration and grain annexation, whereas the precipitation and dissolution of M(Cr, Mo)23C6 affect grain growth. With prolonged time, some grain boundaries extend into new boundaries through subgrain rotation. The fine grains at lower temperatures reduce the initial temperature of the martensite transition (Ms), and the primary martensite nucleates along the grain boundaries of the prior austenite. The secondary martensite is attached to the primary martensite nucleus at a certain angle and grows in parallel while inhibiting the phase transition of the surrounding untransformed austenite.
{"title":"Research on the Austenite Grain Growth Behavior and Martensitic Phase Transformation Mechanism of 40Cr10Si2Mo Steel via In Situ Observation","authors":"Tongyao Yang, Qingjuan Wang, Zhongze Du, Wen Wang, Longxin Li, Zhiyi Li, Bofan Xu","doi":"10.1007/s11663-024-03229-5","DOIUrl":"https://doi.org/10.1007/s11663-024-03229-5","url":null,"abstract":"<p>40Cr10Si2Mo steel is widely utilized because of its excellent mechanical properties, with grain size being a critical factor determining subsequent phase transformation processes and material microstructure performance. This paper reports the use of high-temperature laser scanning confocal microscopy (HT-LSCM) for <i>in situ</i> observation experiments to systematically investigate the growth of austenite grains and the martensitic phase transformation mechanism in 40Cr10Si2Mo steel during an 1800-second isothermal hold at temperatures ranging from 900 °C to 1250 °C. A dynamic model of austenite grain growth is established to optimize the parameters of the austenitic process. The results indicate that the austenite grain size increases continuously with increasing temperature and prolonged time. The Dong model predicts grain sizes that align well with experimental values. Austenite grains grow through grain boundary migration and grain annexation, whereas the precipitation and dissolution of M(Cr, Mo)<sub>23</sub>C<sub>6</sub> affect grain growth. With prolonged time, some grain boundaries extend into new boundaries through subgrain rotation. The fine grains at lower temperatures reduce the initial temperature of the martensite transition (<i>M</i><sub>s</sub>), and the primary martensite nucleates along the grain boundaries of the prior austenite. The secondary martensite is attached to the primary martensite nucleus at a certain angle and grows in parallel while inhibiting the phase transition of the surrounding untransformed austenite.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-12DOI: 10.1007/s11663-024-03236-6
Leila Ghasemi, Seyed Hossein Seyedein, Mandana Adeli, Mohammad Reza Aboutalebi
In this study, the reduction kinetics of ilmenite concentrate from a domestic mine (Kahnuj, Kerman, Iran) in pure hydrogen in the temperature range of 500 °C to 1100 °C was investigated. From the non-isothermal reduction results corresponding kinetic parameters for the as-received and pre-oxidized concentrates were calculated using the Coats-Redfern method. The reduction process in both raw and pre-oxidized ilmenite, at 800 °C was controlled by diffusion through the product layer. The kinetic analysis for ilmenite pre-oxidized at 1000 °C indicated that the reduction process followed a chemical reaction and nucleation and growth mechanism. The samples pre-oxidized at 800 °C and 1000 °C exhibited higher mass loss values and reduction degrees compared to the raw ilmenite. The promoting effect of pre-oxidation on the reduction of ilmenite is attributed to the phase changes in pre-oxidized ilmenite and the porous structure created during the reduction process after the pre-oxidation process. X-ray diffraction (XRD) patterns confirmed the presence of pseudorutile, rutile, and hematite after oxidation at 800 °C, and pseudobrookite and rutile were stable phases after oxidation at 1000 °C.
{"title":"Constitutive Model and Experimental Verification of Kinetics of Non-isothermal Hydrogen Reduction of Ilmenite: A Case Study on Kahnuj Ilmenite","authors":"Leila Ghasemi, Seyed Hossein Seyedein, Mandana Adeli, Mohammad Reza Aboutalebi","doi":"10.1007/s11663-024-03236-6","DOIUrl":"https://doi.org/10.1007/s11663-024-03236-6","url":null,"abstract":"<p>In this study, the reduction kinetics of ilmenite concentrate from a domestic mine (Kahnuj, Kerman, Iran) in pure hydrogen in the temperature range of 500 °C to 1100 °C was investigated. From the non-isothermal reduction results corresponding kinetic parameters for the as-received and pre-oxidized concentrates were calculated using the Coats-Redfern method. The reduction process in both raw and pre-oxidized ilmenite, at 800 °C was controlled by diffusion through the product layer. The kinetic analysis for ilmenite pre-oxidized at 1000 °C indicated that the reduction process followed a chemical reaction and nucleation and growth mechanism. The samples pre-oxidized at 800 °C and 1000 °C exhibited higher mass loss values and reduction degrees compared to the raw ilmenite. The promoting effect of pre-oxidation on the reduction of ilmenite is attributed to the phase changes in pre-oxidized ilmenite and the porous structure created during the reduction process after the pre-oxidation process. X-ray diffraction (XRD) patterns confirmed the presence of pseudorutile, rutile, and hematite after oxidation at 800 °C, and pseudobrookite and rutile were stable phases after oxidation at 1000 °C.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}