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New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XX. Evseevite, Na2Mg(AsO4)F, the first natural arsenate with antiperovskite structure 俄罗斯堪察加托尔巴切克火山Arsenatnaya喷气孔中的新砷酸盐矿物。XX。Evseevite, Na2Mg(AsO4)F,第一个具有反钙钛矿结构的天然砷酸盐
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-06-29 DOI: 10.1180/mgm.2023.50
I. Pekov, N. Zubkova, A. Agakhanov, M. Vigasina, V. Yapaskurt, S. Britvin, A. Turchkova, E. Sidorov, E. Zhitova, D. Pushcharovsky
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引用次数: 1
Groundwater–rock interactions in crystalline rocks: evidence from SIMS oxygen isotope data 结晶岩中地下水-岩石的相互作用:来自SIMS氧同位素数据的证据
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-06-29 DOI: 10.1180/mgm.2023.46
B. Yardley, A. Milodowski, L. Field, R. Wogelius, R. Metcalfe, S. Norris
Abstract The diffusive exchange of dissolved material between fluid flowing in a fracture and the enclosing wallrocks (rock matrix diffusion) has been proposed as a mechanism by which radionuclides derived from a radioactive waste repository may be removed from groundwater and incorporated into the geosphere. To test the effectiveness of diffusive exchange in igneous and metamorphic rocks, we have carried out an investigation of veins formed at low temperatures (<100°C), comparing the oxygen isotopic composition of vein calcite with that of secondary calcite in the wallrocks. Two examples of veins from the Borrowdale Volcanic Group, Cumbria, and one from the Mountsorrel Granodiorite, Leicestershire, UK, have remarkably similar vein calcite compositions, ca. +20‰(SMOW) or greater, substantially heavier than the probable compositions of the host rocks, and these vein calcite compositions are inferred to reflect the infiltrating fluid and the temperature of vein formation. Calcites from the wallrocks are similar to those in veins, with little evidence for exchange with the wallrocks. The results support existing models for this type of vein which suggest low-temperature growth from formation brines originally linked to Permian or Triassic evaporites. The results are consistent with flow through fractures being attenuated through a damage zone adjacent to the fracture and provide no evidence of diffusional exchange with pore waters from wallrocks.
摘要裂缝中流动的流体和围岩之间溶解物质的扩散交换(岩石基质扩散)被认为是一种机制,通过这种机制,来自放射性废物库的放射性核素可以从地下水中去除并融入地圈。为了测试火成岩和变质岩中扩散交换的有效性,我们对低温(<100°C)下形成的矿脉进行了研究,比较了围岩中矿脉方解石和次生方解石的氧同位素组成。坎布里亚郡Borrowdale火山群的两个矿脉和英国莱斯特郡Mountsorrel Granodiorite的一个矿脉具有非常相似的矿脉方解石成分,约+20‰(SMOW)或更大,比宿主岩石的可能成分重得多,推断这些脉状方解石成分反映了渗透流体和脉状形成的温度。围岩中的方解石与矿脉中的方解石相似,几乎没有与围岩交换的证据。这些结果支持了这类矿脉的现有模型,该模型表明,最初与二叠纪或三叠纪蒸发岩有关的地层卤水低温生长。结果与穿过裂缝的水流通过裂缝附近的损伤区衰减一致,并且没有提供与围岩孔隙水扩散交换的证据。
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引用次数: 0
Napoliite, Pb2OFCl, a new mineral from Vesuvius volcano, and its relationship with dimorphous rumseyite 维苏威火山新矿物Napoliite、Pb2OFCl及其与二形态rumseyte的关系
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-06-14 DOI: 10.1180/mgm.2023.43
A. Kasatkin, O. Siidra, F. Nestola, I. Pekov, A. Agakhanov, N. Koshlyakova, N. Chukanov, E. Nazarchuk, Simone Molinari, M. Rossi
Abstract Napoliite, ideally Pb2OFCl, is a new fluoroxychloride mineral found in a specimen from a fumarole formed subsequent to the 1944 eruption of Vesuvius volcano, Naples Province, Italy. It occurs as well-shaped lamellar crystals up to 0.25 × 0.25 × 0.01 mm typically forming clusters up to 0.4 × 0.4 mm on the surface of volcanic scoria in association with anglesite, artroeite, atacamite, calcioaravaipaite, cerussite, challacolloite, cotunnite, hephaistosite, manuelarossiite, matlockite and susannite. Napoliite is colourless with white streak and adamantine lustre. It is brittle and has a laminated fracture. Cleavage is perfect on {001}. Dcalc = 7.797 g cm–3. The calculated mean refractive index is 2.10. Chemical composition (wt.%, electron microprobe) is: PbO 91.71, F 3.89, Cl 7.34, –O=(F+Cl) –3.30, total 99.64. The empirical formula calculated on the basis of 3 anions is Pb1.999O0.997F0.996Cl1.007. Raman spectroscopy confirms the absence of OH– groups and H2O molecules in the mineral. Napoliite is tetragonal, space group P42/mcm, a = 5.7418(11), c = 12.524(4) Å, V = 412.9(2) Å3 and Z = 4. The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (hkl)] are: 3.860 (85) (111); 3.139 (20) (004); 2.914 (100) (113); 2.866 (63) (200); 2.118 (19) (204); 2.027 (19) (220); 1.665 (20) (313); and 1.642 (23) (117). The crystal structure was refined to R1 = 0.024 for 222 reflections with F > 4σ(F). It is based on lead oxide blocks derived from that of litharge PbO, which alternate with layers of chloride ions. Napoliite represents a new structure type with a unique order/disorder pattern of fluorine and oxygen atoms. The new mineral is dimorphous with rumseyite. It is named after the city of Naples (Napoli in Italian).
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引用次数: 1
Fluorbritholite-(Nd), Ca2Nd3(SiO4)3F, a new and a key mineral for neodymium sequestration in REE skarns 萤石-(Nd), Ca2Nd3(SiO4)3F,稀土矽卡岩中一种新的关键固钕矿物
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-06-08 DOI: 10.1180/mgm.2023.45
D. Holtstam, Patrick Casey, L. Bindi, H. Förster, A. Karlsson, Oona Appelt
Fluorbritholite-(Nd), ideally Ca 2 Nd 3 (SiO 4 ) 3 F, is an approved mineral (IMA 2023-001) and constitutes a new member of the britholite group of the apatite supergroup. It occurs in skarn from the Malmkärra iron mine, Norberg, Västmanland (one of the Bastnäs-type deposits in Sweden), associated with calcite, dolomite, magnetite, lizardite, talc, fluorite, baryte, scheelite, gadolinite-(Nd) and other REE minerals. Fluorbritholite-(Nd) forms anhedral and small grains, rarely up to 250 µm across. They are brownish pink, transparent with a vitreous to greasy luster. The mineral is brittle, with an uneven or subconchoidal fracture, and lacks a cleavage. In thin section, the mineral is nonpleochroic, uniaxial (-). D calc = 4.92(1) g·cm − 3 and
萤石-(Nd),理想情况下为Ca 2 Nd 3(SiO 4)3F,是一种经批准的矿物(IMA 2023-001),构成磷灰石超群中萤石组的新成员。它存在于Västmanland(瑞典Bastnäs型矿床之一)Norberg的Malmkärra铁矿的矽卡岩中,与方解石、白云石、磁铁矿、锂辉石、滑石、萤石、重晶石、白钨矿、钆石-(Nd)和其他REE矿物有关。萤石-(Nd)形成反角体和小晶粒,直径很少达到250µm。它们呈棕粉色,透明,有玻璃质到油腻的光泽。该矿物很脆,具有不均匀或亚选择性断裂,并且缺乏解理。在薄剖面中,该矿物为非低温、单轴(-)矿物。D计算值=4.92(1)g·cm−3
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引用次数: 1
Bakakinite, Ca2V2O7, a new mineral from fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia Bakakinite, Ca2V2O7,一种来自俄罗斯堪察加托尔巴切克火山喷发的新矿物
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-06-07 DOI: 10.1180/mgm.2023.42
I. Pekov, A. Agakhanov, N. Koshlyakova, N. Zubkova, V. Yapaskurt, S. Britvin, M. Vigasina, A. Turchkova, M. Nazarova
Abstract The new mineral bakakinite, ideally Ca2V2O7, was found in the high-temperature (not lower than 500°C) exhalations of the Arsenatnaya fumarole at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia. It is associated with anhydrite, svabite, pliniusite, schäferite, berzeliite, diopside, hematite, powellite, baryte, fluorapatite, calciojohillerite, ludwigite, magnesioferrite, anorthite, titanite and esseneite. Bakakinite forms flattened crystals up to 30 × 5 μm, typically distorted. The mineral is transparent, colourless or pale yellow, with strong vitreous lustre. Electron microprobe analysis gave (wt.%): CaO 37.04, SrO 0.26, SiO2 0.16, P2O5 1.48, V2O5 49.47, As2O5 10.85, SO3 0.35, total 99.61. The empirical formula calculated on the basis of 7 O apfu is (Ca1.99Sr0.01)Σ2.00(V1.64As0.28P0.06Si0.01S0.01)Σ2.00O7. The Dcalc is 3.463 g cm–3. Bakakinite is triclinic, P$bar{1}$, unit-cell parameters are: a = 6.64(2), b = 6.92(2), c = 7.01(2) Å, α = 86.59(7), β = 63.77(7), γ = 83.47(6)°, V = 287.0(5) Å3 and Z = 2. The strongest reflections of the powder X-ray diffraction pattern [d,Å(I)(hkl)] are: 4.647(27)(111, 0$bar{1}$1), 3.138(76)(002), 3.103(100)(120, 121), 3.027(20)(021), 2.960(81)(200), 2.158(19)(031, 302), 1.791(16)(320), 1.682(16)(114) and 1.584(17)(1$bar{3}$3, 403). Bakakinite is a natural analogue of synthetic Ca2V2O7. The mineral is named in honour of the outstanding Russian crystallographer and crystal chemist Vladimir Vasilievich Bakakin (born 1933).
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引用次数: 0
Reply to Bosi et al. (2023) 对Bosi等人的答复(2023)
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-06-01 DOI: 10.1180/mgm.2023.35
F. Hawthorne
to XXII meeting of the IMA, Melbourne, Australia, 2018, 354. Bosi F., Hatert F, Hålenius U., Pasero M., Miyawaki R. and Mills S.J. (2019a) On the application of the IMA−CNMNC dominant-valency rule to complex mineral compositions. Mineralogical Magazine, 83, 627–632. Bosi F., Biagioni C. and Oberti R. (2019b) On the chemical identification and classification of minerals. Minerals, 9, 591–603. Bosi F., Hatert F., Pasero M., Mills S.J., Miyawaki R. and Halenius U. (2023) A brief comment on Hawthorne (2023): “On the definition of distinct mineral species: A critique of current IMA-CNMNC procedures”.Mineralogical Magazine, 87, 505–507, doi:10.1180/mgm.2023.33 Gagné O. and Hawthorne F.C. (2016) Chemographic exploration of the milarite-type structure. The Canadian Mineralogist, 54, 1229–1247. Hatert F. and Burke E.A.J. (2008) The IMA–CNMNC dominant-constituent rule revisited and extended. The Canadian Mineralogist, 46, 717–728. Hawthorne F.C. (2002) The use of end-member charge-arrangements in defining new mineral species and heterovalent substitutions in complex minerals. The Canadian Mineralogist, 40, 699–710. Hawthorne F.C. (2021) Proof that a dominant endmember formula can always be written for a mineral or a crystal structure. The Canadian Mineralogist, 59, 159–167. Hawthorne F.C. (2023) On the definition of distinct mineral species: A critique of current IMA-CNMNC procedures. Mineralogical Magazine, 87, 494– 504, doi:10.1180/mgm.2023.8 Hawthorne F.C., Sokolova E., Agakhanov A.A., Pautov L.A., Karpenko V.Yu. and Grew E.S. (2018) Chemographic exploration of the hyalotekite structure-type. Mineralogical Magazine, 82, 929–937. Hawthorne F.C., Mills S.J., Hatert F. and Rumsey M.S. (2021) Ontology, archetypes and the definition of “mineral species”. Mineralogical Magazine, 85, 125–131; erratum, 85, 830. Nickel E.H. (1992) Solid solutions in mineral nomenclature. The Canadian Mineralogist, 30, 231–234. Nickel E.H. and Grice J.D. (1998) The IMA commission on new minerals and mineral names: procedures and guidelines on mineral nomenclature. The Canadian Mineralogist, 36, 913–926. 510 Frank C. Hawthorne
出席IMA第二十二次会议,澳大利亚墨尔本,2018年,354。Bosi F.、Hatert F.、Hålenius U.、Pasero M.、Miyawaki R.和Mills S.J.(2019a)关于IMA−CNMNC显性价态规则在复杂矿物组成中的应用。矿物学杂志,86627-632。Bosi F.,Biagioni C.和Oberti R.(2019b)关于矿物的化学鉴定和分类。矿产,9591-603。Bosi F.、Hatert F.、Pasero M.、Mills S.J.、Miyawaki R.和Halenius U.(2023)对Hawthorne的简短评论(2023年):“关于不同矿物种类的定义:对当前IMA-CNMNC程序的批判”。Mineralogical Magazine,87505-507,doi:10.1180/mgm.2023.33 GagnéO.和Hawthonne F.C.(2016)milarite型结构的化学勘探。加拿大矿物学家,541229-1247。Hatert F.和Burke E.A.J.(2008)对IMA–CNMNC主导成分规则进行了重新审视和扩展。加拿大矿物学家,46717-728。Hawthorne F.C.(2002)在定义复杂矿物中的新矿物种类和杂价取代时使用末端成员电荷排列。加拿大矿物学家,40699-710。Hawthorne F.C.(2021)证明一种矿物或晶体结构总是可以写出一个占主导地位的端元公式。加拿大矿物学家,59159–167。Hawthorne F.C.(2023)关于不同矿物种类的定义:对当前IMA-CNMNC程序的批判。矿物学杂志,87494–504,doi:10.1180/mgm.2023.8霍索恩F.C.、索科洛娃E.、阿加汉诺夫A.A.、Pautov L.A.、Karpenko V.Yu.和Grew E.S.(2018)透明质岩结构类型的化学勘探。矿物学杂志,82929-937。Hawthorne F.C.、Mills S.J.、Hatert F.和Rumsey M.S.(2021)本体论、原型和“矿物物种”的定义。矿物学杂志,85125-131;勘误表,85830。Nickel E.H.(1992)矿物命名中的固体溶液。加拿大矿物学家,30231-234。Nickel E.H.和Grice J.D.(1998)IMA新矿物和矿物名称委员会:矿物命名程序和指南。加拿大矿物学家,36913–926。510 Frank C.Hawthorne
{"title":"Reply to Bosi et al. (2023)","authors":"F. Hawthorne","doi":"10.1180/mgm.2023.35","DOIUrl":"https://doi.org/10.1180/mgm.2023.35","url":null,"abstract":"to XXII meeting of the IMA, Melbourne, Australia, 2018, 354. Bosi F., Hatert F, Hålenius U., Pasero M., Miyawaki R. and Mills S.J. (2019a) On the application of the IMA−CNMNC dominant-valency rule to complex mineral compositions. Mineralogical Magazine, 83, 627–632. Bosi F., Biagioni C. and Oberti R. (2019b) On the chemical identification and classification of minerals. Minerals, 9, 591–603. Bosi F., Hatert F., Pasero M., Mills S.J., Miyawaki R. and Halenius U. (2023) A brief comment on Hawthorne (2023): “On the definition of distinct mineral species: A critique of current IMA-CNMNC procedures”.Mineralogical Magazine, 87, 505–507, doi:10.1180/mgm.2023.33 Gagné O. and Hawthorne F.C. (2016) Chemographic exploration of the milarite-type structure. The Canadian Mineralogist, 54, 1229–1247. Hatert F. and Burke E.A.J. (2008) The IMA–CNMNC dominant-constituent rule revisited and extended. The Canadian Mineralogist, 46, 717–728. Hawthorne F.C. (2002) The use of end-member charge-arrangements in defining new mineral species and heterovalent substitutions in complex minerals. The Canadian Mineralogist, 40, 699–710. Hawthorne F.C. (2021) Proof that a dominant endmember formula can always be written for a mineral or a crystal structure. The Canadian Mineralogist, 59, 159–167. Hawthorne F.C. (2023) On the definition of distinct mineral species: A critique of current IMA-CNMNC procedures. Mineralogical Magazine, 87, 494– 504, doi:10.1180/mgm.2023.8 Hawthorne F.C., Sokolova E., Agakhanov A.A., Pautov L.A., Karpenko V.Yu. and Grew E.S. (2018) Chemographic exploration of the hyalotekite structure-type. Mineralogical Magazine, 82, 929–937. Hawthorne F.C., Mills S.J., Hatert F. and Rumsey M.S. (2021) Ontology, archetypes and the definition of “mineral species”. Mineralogical Magazine, 85, 125–131; erratum, 85, 830. Nickel E.H. (1992) Solid solutions in mineral nomenclature. The Canadian Mineralogist, 30, 231–234. Nickel E.H. and Grice J.D. (1998) The IMA commission on new minerals and mineral names: procedures and guidelines on mineral nomenclature. The Canadian Mineralogist, 36, 913–926. 510 Frank C. Hawthorne","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":null,"pages":null},"PeriodicalIF":2.7,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42131174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MGM volume 87 issue 3 Cover and Front matter 米高梅87卷第3期封面和封面问题
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-06-01 DOI: 10.1180/mgm.2023.47
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引用次数: 0
Vrančiceite, Cu10Hg3S8, a new Cu-Hg sulfide mineral from Vrančice, Czech Republic Vrančiceite,Cu10Hg3S8,一种来自捷克共和国Vranćice的新型铜汞硫化物矿物
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-05-31 DOI: 10.1180/mgm.2023.40
J. Sejkora, C. Biagioni, P. Škácha, D. Mauro
Abstract Vrančiceite is a new mineral species discovered in a sample collected from the old mine dumps of the abandoned Vrančice deposit near Příbram, central Bohemia, Czech Republic. Vrančiceite occurs as rare anhedral grains, up to 100 μm in size, in a calcite gangue, associated with cinnabar, djurleite, galena and hedyphane. Vrančiceite is black, with metallic lustre. Mohs hardness is ca. 2–3, calculated density is 6.652 g.cm–3. In reflected light, vrančiceite is light grey with a yellowish shade; bireflectance, pleochroism and anisotropy are all weak. Internal reflections were not observed. Reflectance values for the four Commission on Ore Mineralogy wavelengths of vrančiceite in air [Rmax, Rmin (%) (λ in nm)] are: 33.6, 31.2 (470); 33.9, 30.6 (546); 31.1, 30.0 (589); and 32.1, 29.1 (650). The empirical formula, based on electron-microprobe analyses, is Cu10.11(4)Ag0.01(1)Hg2.87(4)Sb0.01(1)Bi0.01(1)S7.99(8). The ideal formula is Cu10Hg3S8 (Z = 2), which requires (in wt.%) Cu 42.54, Hg 40.29 and S 17.17, total 100.00. Vrančiceite is triclinic, P$bar{1}$, with unit-cell parameters a = 7.9681(2), b = 9.7452(3), c = 10.0710(3) Å, α = 77.759(1), β = 76.990(1), γ = 79.422(1)°, V = 737.01(4) Å3 and Z = 2. The strongest reflections of the calculated powder X-ray diffraction pattern [d, Å (I) hkl] are: 3.354 (76) $bar{2}$01, 3.111 (68) 222, 2.833 (100) 213, 2.733 (93) 231, 2.705 (76) 2$bar{2}$1 and 2.647 (71) $bar{2}bar{1}$2. According to the single-crystal X-ray diffraction data (R1 = 0.0262), the crystal structure of vrančiceite can be described as comprising Cu–S layers, connected through CuS3 polyhedra, giving rise to a three-dimensional framework with channels running along the a axis and hosting linearly coordinated Hg atoms. Structural relations with gortdrumite are discussed. Vrančiceite is named after its type locality, the Vrančice deposit near Příbram. The mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA2022–114).
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引用次数: 0
Tennantite-(Ni), Cu6(Cu4Ni2)As4S13, from Luobusa ophiolite, Tibet, China: a new Ni member of the tetrahedrite group 西藏罗布萨蛇绿岩的Tennante-(Ni),Cu6(Cu4Ni2)As4S13:四面体群中的一个新的Ni成员
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-05-31 DOI: 10.1180/mgm.2023.41
Yanjuan Wang, Rujun Chen, X. Gu, Z. Hou, F. Nestola, Zhusen Yang, Guang Fan, G. Dong, Lijuan Ye, Kai Qu
Abstract The new mineral tennantite-(Ni), Cu6(Cu4Ni2)As4S13, has been discovered from the Luobusa Chromitite, Tibet, southwestern China. Tennantite-(Ni) occurs as anhedral grains ranging from 2 to 20 μm in size. In reflected light microscopy, tennantite-(Ni) is isotropic and appears yellow-greenish grey. Reflectance data for Commission on Ore Mineralogy wavelengths in air for tennantite-(Ni) are: 31.0 (470 nm), 29.6 (546 nm), 29.6 (589 nm) and 29.3 (650 nm). Electron microprobe analysis for holotype material gave the empirical formula (on basis of total cations = 16 apfu): M(2)Cu6 M(1)[Cu4.00(Ni0.97Cu0.53Fe0.50)Σ2.00]Σ6.00X(3)(As2.94Sb1.06)Σ4S12.77. Tennantite-(Ni) is cubic, with space group I$bar{ 4}$3m (#217), a =10.2957(9) Å, V = 1091.4(3) Å3 and Z = 2. By using single-crystal X-ray diffraction, the crystal structure has been determined and refined to a final R1 = 0.0423 on the basis of 163 independent reflections [Fo > 4σ (Fo)]. The calculated seven strongest powder X-ray diffraction lines [d in Å (I) (hkl)] are: 2.972 (100) (222), 1.820 (83) (440), 2.574 (28) (400), 1.552 (18) (622), 3.640 (10) (220), 1.880 (10) (521) and 1.287 (7) (800). Tennantite-(Ni) is isostructural with other tetrahedrite-group minerals, and nickel is hosted at the tetrahedrally coordinated M(1) site, along with Cu and minor Fe. The mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA2021-018).
摘要在西藏罗布萨铬铁矿中发现了一种新矿物tennantite-(Ni),Cu6(Cu4Ni2)As4S13。Tennante-(Ni)以二面体晶粒的形式出现,其尺寸范围为2至20μm。在反射光显微镜下,tennantite-(Ni)是各向同性的,呈现黄-绿-灰色。tennantite-(Ni)在空气中矿石矿物学委员会波长的反射率数据为:31.0(470 nm)、29.6(546 nm)、2.96(589 nm)和29.3(650 nm)。正模材料的电子探针分析给出了M(2)Cu6M(1)[Cu4.00(Ni0.97Cu0.53Fe0.50)∑2.00]∑6.00X(3)(As2.94Sb1.06)∑4S12.77的经验公式。Tennante-(Ni)是立方的,空间群I$bar{4}$3m(#217),a=102.957(9)Å,V=109.14(3)Å3和Z=2。通过使用单晶X射线衍射,在163次独立反射[Fo>4σ(Fo)]的基础上,确定并细化了晶体结构,最终R1=0.0423。计算出的七条最强粉末X射线衍射线[d inÅ(I)(hkl)]分别为:2.972(100)(222)、1.820(83)(440)、2.574(28)(400)、1.552(18)(622)、3.640(10)(220)、1.880(10)和1.287(7)(800)。Tennante-(Ni)与其他四面体族矿物具有同构性,镍与Cu和少量Fe一起存在于四面体配位的M(1)位。该矿物及其名称已获得国际矿物学协会新矿物、命名和分类委员会(IMA2021-018)的批准。
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引用次数: 0
Mineral chemistry and genesis of monazite-(Sm) and monazite-(Nd) from the Blue Beryl Dyke of the Julianna pegmatite system at Piława Górna, Lower Silesia, Poland 波兰下西里西亚Piława Górna Julianna伟晶岩系蓝绿柱石脉中独居石(Sm)和独居石-(Nd)的矿物化学和成因
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-05-29 DOI: 10.1180/mgm.2023.38
Diana Twardak, A. Pieczka, J. Kotowski, K. Nejbert
Abstract Monazites are one of the most interesting groups of accessory mineral components of crystalline rocks due to the information on geochemical evolution of the crystallisation environment coded in their chemical compositions, in addition to comprising one of the most valuable objects for geochronology studies. This paper presents monazite-(Sm) and monazite-(Nd) from the Blue Beryl Dyke of the Julianna system of rare-element pegmatites at Piława Górna, Lower Silesia, Poland. These monazites are unique due to their unusually high Sm and Nd contents, reaching 33.22 wt.% Sm2O3 and 34.12 wt.% Nd2O3, respectively. We consider the most significant factors of the enrichment in Sm and Nd to be the occurrence of highly fractionated pegmatite-forming melts during the final stages of solidification and associated hydrothermal fluids that were strongly enriched in rare earth element REE–Cl and REE–F complexes. Local disequilibria allowed for the rapid growth of accessory phases under supercooling conditions associated with the scavenging of selected elements, leading to their local depletion, which was not balanced by diffusion processes. As a consequence, the depletion of light rare earth elements (LREE) led to the incorporation of available middle rare earth elements (MREE, Sm–Dy) in the case of Sm and Nd, which could occupy an acceptable structural position in minerals of the monazite group.
摘要独居石是结晶岩中最有趣的副矿物组分之一,因为其化学成分编码了结晶环境的地球化学演化信息,此外还构成了地质年代研究最有价值的对象之一。本文介绍了波兰下西里西亚Piława Górna的Julianna稀有元素伟晶岩系蓝Beryl岩脉中的独居石-(Sm)和独居岩-(Nd)。这些独居石是独特的,因为它们的Sm和Nd含量异常高,分别达到33.22 wt.%Sm2O3和34.12 wt.%Nd2O3。我们认为,Sm和Nd富集的最重要因素是在凝固的最后阶段出现了高度分馏的伟晶岩形成熔体,以及强烈富集稀土元素REE–Cl和REE–F络合物的相关热液流体。局部不平衡允许辅助相在与所选元素的清除相关的过冷条件下快速生长,导致其局部耗尽,而扩散过程无法平衡。因此,在Sm和Nd的情况下,轻稀土元素(LREE)的耗尽导致了可用的中间稀土元素(MREE,Sm–Dy)的结合,这可能在独居石族矿物中占据可接受的结构位置。
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Mineralogical Magazine
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