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The oxidation state and distribution of Fe in pumpellyite from the Northern Chichibu Belt in the Hijikawa district, western Shikoku, Japan 日本四国西部Hijikawa地区北秩父带中铁的氧化态和分布
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-10-16 DOI: 10.1180/mgm.2023.80
Masahide Akasaka, Yumi Goishi (Imaizumi), Masayuki Sakakibara, Yoshihiro Nakamuta
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引用次数: 0
Okruginite, Cu2SnSe3, a new mineral from the Ozernovskoe deposit, Kamchatka peninsula, Russia 俄罗斯堪察加半岛Ozernovskoe矿床新矿物Cu2SnSe3 - Okruginite
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-10-16 DOI: 10.1180/mgm.2023.78
Anna Vymazalová, Vladimir V. Kozlov, František Laufek, Chris J. Stanley, Ilya A. Shkilev, Sharapat Kudaeva, Filip Košek
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引用次数: 0
Kalyuzhnyite-(Ce), NaKCaSrCeTi(Si8O21)OF(H2O)3, a new mineral from the Darai-Pioz alkaline massif, Tien-Shan mountains, Tajikistan: mineral description, crystal structure and a new double (Si8O21) sheet 塔吉克斯坦天山Darai-Pioz碱性丘陵的新矿物Kalyuzhnyite-(Ce),NaKCaSrCeTi(Si8O21)OF(H2O)3:矿物描述、晶体结构和新的双(Si8O21)薄片
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-10-13 DOI: 10.1180/mgm.2023.74
Atali A. Agakhanov, Elena Sokolova, Vladimir Yu. Karpenko, Frank C. Hawthorne, Leonid A. Pautov, Anatoly V. Kasatkin, Igor V. Pekov, Vitaliya A. Agakhanova

Kalyuzhnyite-(Ce), ideally NaKCaSrCeTi(Si8O21)OF(H2O)3, is a new mineral from the Darai-Pioz alkaline massif, Tien-Shan mountains, Tajikistan. It occurs as equant grains up to 0.05 × 0.07 mm in a quartz–pectolite aggregate in a silexite-like peralkaline pegmatite. Associated minerals are quartz, fluorite, pectolite, baratovite, aegirine, leucosphenite, neptunite, reedmergnerite, orlovite, sokolovaite, mendeleevite-(Ce), odigitriaite, pekovite, zeravshanite, kirchhoffite and garmite. The mineral is colourless with a vitreous lustre and a white streak, and Dcalc. is 3.120 g/cm3. Kalyuzhnyite-(Ce) is monoclinic, P2/c, a = 18.647(4), b = 11.214(2), c = 14.642(3) Å, β = 129.55(3)° and V = 2360.9(11) Å3. The chemical composition of kalyuzhnyite-(Ce) is Nb2O5 0.53, TiO2 0.16, SiO2 43.85, Er2O3 0.13, Ho2O3 0.10, Gd2O3 0.09, Sm2O3 0.47, Nd2O3 6.22, Pr2O3 1.21, Ce2O3 6.34, La2O3 0.82, PbO 4.90, BaO 0.85, SrO 11.39, CaO 1.86, Cs2O 3.80, K2O 1.59, Na2O 2.99, H2O 5.24, F 1.55, O = F –0.65, total 100.31 wt.%. The empirical formula calculated on 26.11 (O + F) apfu is Na1.07K0.37Cs0.30Sr1.21Ca0.37Pb0.24Ba0.06(Ce0.43Nd0.41Pr0.08La0.06Sm0.03Gd0.01Er0.01Ho0.01)Σ1.04(Ti0.97Nb0.04)Σ1.01Si8.06O25.21F0.90H6.42, Z = 4. The simplified formula is (Na,□)(K,Сs)(Ca,Pb,Sr,Na)SrLn3+Ti(Si8O21)OF(H2O)3, where Ce is the dominant lanthanoid. The crystal structure was solved by direct methods and refined to an R1 index of 2.74%. In kalyuzhnyite-(Ce), the main structural units are a heteropolyhedral Na–Sr–Ce–Ti sheet, ideally [NaSrCeTiOF]7+, and a double (Si8O21)10– sheet parallel to (010). In the Si–O sheet, the Si tetrahedra form ten-membered rings. This is the first occurrence of such a double Si–O sheet in a mineral. The two sheets connect via common vertices of Na-, Sr-, Ce- and Ti-polyhedra and SiO4 tetrahedra to form a framework. The interstitial cations and H2O groups, ideally [(CaK)(H2O)3]3+, occur within the Si–O sheet. The mineral is named in honour

Kalyuzhnyite-(Ce),理想状态为 NaKCaSrCeTi(Si8O21)OF(H2O)3,是一种产自塔吉克斯坦天山Darai-Pioz碱性地块的新矿物。它以最大 0.05 × 0.07 毫米的等粒形式出现在石英-埃洛石集合体中,位于一个类似围岩的伟晶岩中。伴生矿物有石英、萤石、pectolite、baratovite、aegirine、leucosphenite、neptunite、reedmergnerite、orlovite、sokolovaite、mendeleevite-(Ce)、odigitriaite、pekovite、zeravshanite、kirchhoffite 和 garmite。该矿物无色,具有玻璃光泽和白色条纹,密度为 3.120 克/立方厘米。Kalyuzhnyite-(Ce)呈单斜,P2/c,a = 18.647(4),b = 11.214(2),c = 14.642(3)埃,β = 129.55(3)°,V = 2360.9(11)埃3。kalyuzhnyite-(Ce)的化学成分为 Nb2O5 0.53、TiO2 0.16、SiO2 43.85、Er2O3 0.13、Ho2O3 0.10、Gd2O3 0.09、Sm2O3 0.47、Nd2O3 6.22、Pr2O3 1.21, Ce2O3 6.34, La2O3 0.82, PbO 4.90, BaO 0.85, SrO 11.39, CaO 1.86, Cs2O 3.80, K2O 1.59, Na2O 2.99, H2O 5.24, F 1.55, O = F -0.65, 总计 100.31 wt.%。根据 26.11 (O + F) apfu 计算得出的经验公式为 Na1.07K0.37Cs0.30Sr1.21Ca0.37Pb0.24Ba0.06(Ce0.43Nd0.41Pr0.08La0.06Sm0.03Gd0.01Er0.01Ho0.01)Σ1.04(Ti0.97Nb0.04)Σ1.01Si8.06O25.21F0.90H6.42, Z = 4.简化公式为 (Na,□)(K,Сs)(Ca,Pb,Sr,Na)SrLn3+Ti(Si8O21)OF(H2O)3,其中 Ce 是主要的镧系元素。该晶体结构是通过直接方法求解的,其 R1 指数为 2.74%。在 kalyuzhnyite-(Ce)中,主要的结构单元是异多面体 Na-Sr-Ce-Ti 片(理想状态为 [NaSrCeTiOF]7+)和平行于 (010) 的双 (Si8O21)10- 片。在 Si-O 片层中,Si 四面体形成十元环。这是矿物中首次出现这种双 Si-O 片层。两个薄片通过 Na-、Sr-、Ce- 和 Ti- 多面体以及 SiO4 四面体的共同顶点连接起来,形成一个框架。间隙阳离子和 H2O 基团(理想情况下为[(CaK)(H2O)3]3+)出现在 Si-O 片层中。该矿物以 Vasily Avksentievich Kalyuzhny(1899-1993 年)命名,以表彰他对苏联科米共和国矿床地质学和塔吉克斯坦花岗伟晶岩矿物学的贡献。
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引用次数: 0
Newsletter 75 75年时事通讯
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-10-11 DOI: 10.1180/mgm.2023.76
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, Stuart J. Mills
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引用次数: 0
Letnikovite-(Ce), (Nao)Ca2Ce2[Si7O17(OH)]F4(H2O)4, a new mineral from the Darai-Pioz alkaline massif, Tajikistan: mineral description, crystal structure and a new single [Si7O17(OH)] sheet 塔吉克斯坦达莱-皮奥兹碱性地块新矿物Letnikovite-(Ce), (Nao)Ca2Ce2[Si7O17(OH)]F4(H2O)4:矿物描述、晶体结构及新单片[Si7O17(OH)
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-10-09 DOI: 10.1180/mgm.2023.65
Atali A. Agakhanov, Elena Sokolova, Fernando Cámara, Vladimir Yu. Karpenko, Frank C. Hawthorne, Leonid A. Pautov, Anatoly V. Kasatkin, Igor V. Pekov, Vitaliya A. Agakhanova
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Secondary uranyl arsenates-phosphates and Sb-Bi-rich minerals of the segnitite-philipsbornite series in the oxidation zone at the Prakovce-Zimná Voda REE-U-Au quartz vein mineralization, Western Carpathians, Slovakia 斯洛伐克西喀尔巴阡山脉prakovce - zimn<e:1> Voda REE-U-Au石英脉矿化氧化带重辉岩- philipsnite系列次生富锑铋矿物
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-10-04 DOI: 10.1180/mgm.2023.75
Martin Ondrejka, Štefan Ferenc, Juraj Majzlan, Martin Števko, Richard Kopáčik, Bronislava Voleková, Stanislava Milovská, Jörg Göttlicher, Ralph Steininger, Tomáš Mikuš, Pavel Uher, Adrián Biroň, Jiří Sejkora, Alexandra Molnárová
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引用次数: 0
MGM volume 87 issue 5 Cover 米高梅87卷第5期封面
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-10-01 DOI: 10.1180/mgm.2023.84
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A re-evaluation of stannopalladinite using modern analytical techniques 用现代分析技术对锡钯石的再评价
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-09-20 DOI: 10.1180/mgm.2023.73
Anatoly V. Kasatkin, Anna Vymazalová, Fabrizio Nestola, Vladislav V. Gurzhiy, Atali A. Agakhanov, Radek Škoda, Dmitry I. Belakovskiy, Mikhail E. Generalov
Abstract An investigation of sample 41647 from the Platinum Placer of Ugol'nyi Ruchei, Norilsk Cu–Ni deposit, Russia, stored in the systematic collection of the Fersman Mineralogical Museum, revealed that it contained a mineral that can be identified as the original stannopalladinite described in 1947. As the literature information on the latter is controversial, the mineral was re-investigated using modern analytical techniques. Stannopalladinite occurs as spherical and ovoid-shaped grains up to 0.08 mm, closely intergrown with tetraferroplatinum as part of flattened, prismatic crystals up to 6 mm long. The micro-indentation hardness of stannopalladinite (VHN, 30 g load) is 244 kg/mm 2 (range 233–266, n = 4), corresponding to a Mohs hardness of 4. The calculated density is 9.781 g/cm 3 . In reflected light, stannopalladinite is pale pink. The bireflectance is noticeable only in oil immersion. In crossed nicols the mineral exhibits strong anisotropy with colour effects changing from reddish purple to greyish blue and polysynthetic twinning of grains. The reflectance curves show distinct anomalous dispersion. The chemical composition (wt.%, electron microprobe data, mean of 11 analyses) is: Cu 8.48, Pd 61.21, Pt 0.89, Sn 25.87, Pb 3.70, total 100.15. The empirical formula calculated on the basis of 4 atoms per formula unit is (Pd 2.42 Cu 0.56 Pt 0.02 ) Σ3.00 (Sn 0.92 Pb 0.08 ) Σ1.00 . The ideal chemical formula of stannopalladinite is therefore proposed as (Pd,Cu) 3 Sn instead of Pd 3 Sn 2 used in the official IMA List of Minerals. The strongest powder X-ray diffraction lines are [ d obs , Å ( I , %) ( hkl ) ]: 2.292 (42) (231), 2.166 (100) (331), 2.034 (10) (710), 1.916 (15) (141) and 1.851 (15) (630). The powder X-ray data are indexed in the orthorhombic unit cell with a = 14.634(2), b = 8.5253(6), c = 4.5946(3) Å and V = 573.24(7) Å 3 ( Z = 8). Stannopalladinite can be reliably identified among all other minerals belonging to the binary Pd–Sn and ternary Pd–Cu–Sn systems by a combination of chemical, optical and X-ray data.
摘要对Fersman矿物学博物馆系统收藏的俄罗斯诺里尔斯克铜镍矿床Ugol’nyi Ruchei铂矿41647号样品进行了研究,发现其中含有一种矿物,可被鉴定为1947年描述的原始锡帕长石。由于关于后者的文献资料存在争议,因此使用现代分析技术对该矿物进行了重新研究。Stannopalladinite以高达0.08 mm的球形和卵形晶粒形式出现,与四铁铂紧密共生,成为长达6 mm的扁平棱柱状晶体的一部分。锡钯石(VHN, 30 g载荷)的微压痕硬度为244 kg/mm 2(范围233-266,n = 4),对应莫氏硬度为4。计算密度为9.781 g/ cm3。在反射光下,锡钯辉石呈淡粉色。双反射只有在油浸时才明显。在杂交镍中,矿物表现出较强的各向异性,颜色效果从红紫色变为灰蓝色,晶粒呈多合成孪晶。反射率曲线表现出明显的异常色散。化学成分(wt.%,电子探针数据,11次分析的平均值)为:Cu 8.48, Pd 61.21, Pt 0.89, Sn 25.87, Pb 3.70,总计100.15。以4个原子为单位计算得到的经验公式为(Pd 2.42 Cu 0.56 Pt 0.02) Σ3.00 (Sn 0.92 Pb 0.08) Σ1.00。因此,提出了锡钯铅矿的理想化学式为(Pd,Cu) 3sn,而不是IMA官方矿物清单中使用的Pd 3sn 2。最强的粉末x射线衍射线为[d obs, Å (I, %) (hkl)]: 2.292(42)(231)、2.166(100)(331)、2.034(10)(710)、1.916(15)(141)和1.851(15)(630)。粉末x射线数据在正交晶胞中进行标引,a = 14.634(2), b = 8.5253(6), c = 4.5946(3) Å, V = 573.24(7) Å 3(Z = 8)。结合化学、光学和x射线数据,可以在二元Pd-Sn和三元Pd-Cu-Sn体系的所有矿物中可靠地识别出Stannopalladinite。
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引用次数: 0
Can lithium contents in mica be correctly calculated? Tischendorf´s proposal (Mineralogical Magazine 61/1997) 25 years after 云母中锂的含量可以正确计算吗?Tischendorf的建议(矿物学杂志61/1997)25年后
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-09-18 DOI: 10.1180/mgm.2023.72
Karel Breiter, Michaela Vašinová Galiová, Zuzana Korbelová, Michaela Hložková
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Narsarsukite in peralkaline granites from the Papanduva Pluton, Graciosa Province, south Brazil: Insights from textural and chemical features 巴西南部Graciosa省帕潘杜瓦岩体过碱性花岗岩中的Narsarsukite:来自结构和化学特征的见解
3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-09-12 DOI: 10.1180/mgm.2023.70
Silvio R.F. Vlach, Frederico C.J. Vilalva
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引用次数: 0
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Mineralogical Magazine
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