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Amableite-(Ce), Na15[(Ce1.5Na1.5)Mn3]Mn2Zr3◻Si[Si24O69(OH)3](OH)2⋅H2O, a new eudialyte-group mineral from Saint-Amable Sill, Québec, Canada 产自加拿大魁北克省圣阿梅布尔锡尔的一种新的紫铁矿群矿物--黑云母(Ce),Na15[(Ce1.5Na1.5)Mn3]Mn2Zr3◻Si[Si24O69(OH)3](OH)2⋅H2O
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-04-12 DOI: 10.1180/mgm.2024.26
N. Chukanov, A. A. Zolotarev, C. Schäfer, D. Varlamov, I. Pekov, M. Vigasina, D. I. Belakovskiy, S. Aksenov, S. A. Vozchikova, S. Britvin
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引用次数: 0
Electron density changes accompanying high-pressure phase transition in AlOOH 伴随 AlOOH 高压相变的电子密度变化
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-04-11 DOI: 10.1180/mgm.2024.22
R. Gajda, J. Parafiniuk, Pierre Fertey, Przemysław Dera, Krzysztof Woźniak
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引用次数: 0
Tetrahedrite-(Cu), Cu12Sb4S13, from Bankov near Košice, Slovak Republic: a new member of the tetrahedrite group minerals 斯洛伐克共和国科希策附近Bankov出土的四面体铜矿(Cu)Cu12Sb4S13:四面体类矿物的新成员
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-04-11 DOI: 10.1180/mgm.2024.24
J. Sejkora, C. Biagioni, M. Števko, Silvia Musetti, Dušan Peterec
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引用次数: 0
Composition and paragenesis of daqingshanite from the Kamthai carbothermalite, Rajasthan, India 印度拉贾斯坦邦 Kamthai 碳热岩中的大青山石的成分和成因
IF 2.7 3区 地球科学 Q2 MINERALOGY Pub Date : 2024-04-01 DOI: 10.1180/mgm.2024.18
Roger H. Mitchell

Daqingshanite in the Kamthai REE deposit (India) occurs as two paragenetic types: primary granular coarse grained crystals coexisting with primary carbocernaite, baryte and bastnäsite; and as aligned micro-ovoid globules within clasts of Sr-bearing calcite. Carbocernaite forming trellis-type lamellae in some of these calcite clasts do not represent exsolution and are considered as replacement textures as they formed subsequent to daqingshanite. The origins of the textural relations of the microglobules of daqingshanite to their host Sr-calcite cannot be unambiguously determined, although an exsolution origin is not considered feasible. The textures are similar to those of ‘chalcopyrite disease’ and as such could be interpreted as replacement features formed in a low temperature carbothermal environment which should facilitate replacement. Given that daqingshanite is an early crystallising phase it is also possible that cotectic crystallisation with Sr-calcite occurred, followed by subsolidus re-equilibration with recrystallisation along specific crystallographic planes in the calcite. The Kamthai REE deposit is best described as a low temperature carbothermalite microbreccia consisting of a wide variety of clasts resulting from the autobrecciation of rocks formed during, and after, the magmatic to carbothermal transition of an undetermined parental calcite carbonatite-forming magma. Many clasts have been replaced by late stage La-enriched carbothermal fluids mixed with exogenous water during the final low-temperature stage of evolution of the deposit.

Kamthai REE 矿床(印度)中的大青山岩有两种成因类型:一种是与原生石英、重晶石和钠长石共存的原生颗粒状粗粒晶体;另一种是含硒方解石岩屑中排列整齐的微卵球状晶体。在其中一些方解石岩屑中形成的花架状层状石英并不代表外溶解,而是在大青山岩之后形成的置换纹理。大青山岩微球体与其宿主钙钛矿之间的纹理关系的起源无法明确确定,但外解起源被认为是不可行的。这些纹理与 "黄铜矿病 "的纹理相似,因此可以解释为在低温碳热环境中形成的置换特征,这种环境应有利于置换。鉴于大青山岩是一种早期结晶相,也有可能是与锰方解石发生了共晶,然后沿着方解石中特定的结晶平面发生了重结晶的次固结再平衡。Kamthai REE 矿床最适合描述为低温碳热岩微碎屑岩,由各种碎屑岩组成,这些碎屑岩是在岩浆岩向碳热岩转变期间和之后形成的,其母体方解石碳酸盐岩岩浆尚未确定。在矿床演化的最后低温阶段,许多碎屑被混合了外源水的后期富含 La 的碳热流体所取代。
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引用次数: 0
MGM volume 88 issue 2 Cover MGM 第 88 卷第 2 期封面
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-04-01 DOI: 10.1180/mgm.2024.25
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引用次数: 0
Abundances, Distributions, and Patterns of Discovery of New Minerals 新矿物的丰度、分布和发现模式
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-03-21 DOI: 10.1180/mgm.2024.19
Carl N. Drummond
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引用次数: 0
The mineralogy of the historical Mochalin Log REE deposit, South Urals, Russia. Part V. Zilbermintsite-(La), (CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3, a new mineral with ET2 type structure and a definition of radekškodaite group. 俄罗斯南乌拉尔莫查林 Log 历史性 REE 矿床的矿物学。第五部分:Zilbermintsite-(La),(CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3,一种具有 ET2 型结构的新矿物,以及 radekškodaite 组的定义。
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-03-21 DOI: 10.1180/mgm.2024.17
A. Kasatkin, N. Zubkova, R. Škoda, I. Pekov, A. Agakhanov, Vladislav V. Gurzhiy, D. A. Ksenofontov, D. Belakovskiy, Aleksey M. Kuznetsov
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引用次数: 0
Škáchaite, CaCo(CO3)2, a new member of the dolomite group, from the Brod deposit near Příbram, Czech Republic 捷克共和国普里布拉姆附近布罗德矿床出土的白云石族新成员--Škáchaite,CaCo(CO3)2
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-03-21 DOI: 10.1180/mgm.2024.21
J. Sejkora, J. Plášil, Z. Dolníček, Jana Ulmanová, R. Škoda
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引用次数: 0
Hydroxylbenyacarite, (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10⋅4H2O, a new paulkerrite-group mineral, from the El Criollo mine, Cordoba Province, Argentina. 来自阿根廷科尔多瓦省 El Criollo 矿的羟基苯铈镧矿((H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10⋅4H2O)是一种新的泡桐石类矿物。
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-03-19 DOI: 10.1180/mgm.2024.16
R. Hochleitner, Christian Rewitzer, Ian E. Grey, A. R. Kampf, Colin M. MacRae, Robert W. Gable, W. G. Mumme
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引用次数: 0
The crystal structure of charmarite – the first case of a 11 × 11 Å superstructure mesh in layered double hydroxides 查理石的晶体结构--层状双氢氧化物中首个 11 × 11 Å 超结构网格的实例
IF 2.7 3区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-03-08 DOI: 10.1180/mgm.2024.11
Elena S. Zhitova, Andrey A. Zolotarev, Anatoly V. Kasatkin, Rezeda M. Sheveleva, Sergey V. Krivovichev, Igor V. Pekov, Vladimir N. Bocharov

Charmarite, Mn4Al2(OH)12CO3⋅3H2O, is a hydrotalcite supergroup member (or layered double hydroxide, LDH) with a previously unknown crystal structure and a Mn2+-analogue of quintinite (commonly erroneously reported as ‘2:1 hydrotalcite’). The single-crystal X-ray diffraction (XRD) data were obtained from the specimen from Mont Saint-Hilaire, Québec, Canada and are best processed in the space group P$bar{3}$, a = 10.9630(4), c = 15.0732(5) Å and V = 1568.89(12) Å3. The crystal structure has been solved by direct methods and refined to R1 = 0.0750 for 3801 unique reflections with Fo > 2σ(Fo). The charmarite structure has long-range periodicity in the xy plane due to $2sqrt 3$a’ × $2sqrt 3$a’ scheme (or 11 × 11 Å) determined for LDHs for the first time (where a’ is a subcell parameter ≈ 3.2 Å). This periodicity is produced by the combination of two superstructures formed by: (1) Mn2+ and Al3+ ordering in the metal-hydroxide layers [Mn4Al2(OH)12]2+ according to the $sqrt 3$a’ × $sqrt 3$a’ pattern and (2) the (CO3)2– ordering according to the 2a’ × 2a’ pattern in the [CO3(H2O)3]2– interlayer sheet in order to avoid close contacts b

Charmarite(Mn4Al2(OH)12CO3⋅3H2O)是一种水滑石超群成员(或层状双氢氧化物,LDH),其晶体结构以前不为人知,是一种 Mn2+-类似物(通常被错误地报道为 "2:1 水滑石")。单晶 X 射线衍射(XRD)数据取自加拿大魁北克省圣希莱尔山(Mont Saint-Hilaire)的标本,最佳空间群为 P$bar{3}$,a = 10.9630(4),c = 15.0732(5) Å,V = 1568.89(12) Å3。该晶体结构已通过直接方法求解,并在 3801 次独特反射中精制为 R1 = 0.0750,Fo > 2σ(Fo)。由于首次为 LDHs 确定了 $2sqrt 3$a' × $2sqrt 3$a' 方案(或 11 × 11 Å)(其中 a' 为子晶胞参数 ≈ 3.2 Å),霞石结构在 xy 平面上具有长程周期性。这种周期性是由以下两种超结构组合而成的:(1) 金属氢氧化物层 [Mn4Al2(OH)12]2+ 中的 Mn2+ 和 Al3+ 按照 $sqrt 3$a' × $sqrt 3$a' 模式排序;以及 (2) [CO3(H2O)3]2- 层间薄片中的 (CO3)2- 按照 2a' × 2a' 模式排序,以避免相邻碳酸盐基团之间的紧密接触。2sqrt 3$a' × 2sqrt 3$a' 的上层结构是层间空间各组分适应金属羟基层电荷分布的一个例子。Mn2+ 和 Al3+ 阳离子的尺寸差异很大,这显然导致它们作为二价和三价阳离子的有序程度相当高,从而导致层间成分的统计有序程度较高。粉末和单晶 XRD 数据都表明,所研究的样品属于双层多晶型(2T 或 2H)的六方分支,d00n ≈ 7.57 Å。报告中还给出了查理石的拉曼光谱和波段赋值。
{"title":"The crystal structure of charmarite – the first case of a 11 × 11 Å superstructure mesh in layered double hydroxides","authors":"Elena S. Zhitova, Andrey A. Zolotarev, Anatoly V. Kasatkin, Rezeda M. Sheveleva, Sergey V. Krivovichev, Igor V. Pekov, Vladimir N. Bocharov","doi":"10.1180/mgm.2024.11","DOIUrl":"https://doi.org/10.1180/mgm.2024.11","url":null,"abstract":"<p>Charmarite, Mn<span>4</span>Al<span>2</span>(OH)<span>12</span>CO<span>3</span>⋅3H<span>2</span>O, is a hydrotalcite supergroup member (or layered double hydroxide, LDH) with a previously unknown crystal structure and a Mn<span>2+</span>-analogue of quintinite (commonly erroneously reported as ‘2:1 hydrotalcite’). The single-crystal X-ray diffraction (XRD) data were obtained from the specimen from Mont Saint-Hilaire, Québec, Canada and are best processed in the space group <span>P</span><span><span><span data-mathjax-type=\"texmath\"><span>$bar{3}$</span></span><img data-mimesubtype=\"png\" data-type=\"\" src=\"https://static.cambridge.org/binary/version/id/urn:cambridge.org:id:binary:20240412100051135-0894:S0026461X24000112:S0026461X24000112_inline1.png\"/></span></span>, <span>a</span> = 10.9630(4), <span>c</span> = 15.0732(5) Å and <span>V</span> = 1568.89(12) Å<span>3</span>. The crystal structure has been solved by direct methods and refined to <span>R</span><span>1</span> = 0.0750 for 3801 unique reflections with <span>F</span><span>o</span> &gt; 2σ(<span>F</span><span>o</span>). The charmarite structure has long-range periodicity in the <span>xy</span> plane due to <span><span><span data-mathjax-type=\"texmath\"><span>$2sqrt 3$</span></span><img data-mimesubtype=\"png\" data-type=\"\" src=\"https://static.cambridge.org/binary/version/id/urn:cambridge.org:id:binary:20240412100051135-0894:S0026461X24000112:S0026461X24000112_inline2.png\"/></span></span><span>a</span>’ × <span><span><span data-mathjax-type=\"texmath\"><span>$2sqrt 3$</span></span><img data-mimesubtype=\"png\" data-type=\"\" src=\"https://static.cambridge.org/binary/version/id/urn:cambridge.org:id:binary:20240412100051135-0894:S0026461X24000112:S0026461X24000112_inline3.png\"/></span></span><span>a</span>’ scheme (or 11 × 11 Å) determined for LDHs for the first time (where <span>a</span>’ is a subcell parameter ≈ 3.2 Å). This periodicity is produced by the combination of two superstructures formed by: (1) Mn<span>2+</span> and Al<span>3+</span> ordering in the metal-hydroxide layers [Mn<span>4</span>Al<span>2</span>(OH)<span>12</span>]<span>2+</span> according to the <span><span><span data-mathjax-type=\"texmath\"><span>$sqrt 3$</span></span><img data-mimesubtype=\"png\" data-type=\"\" src=\"https://static.cambridge.org/binary/version/id/urn:cambridge.org:id:binary:20240412100051135-0894:S0026461X24000112:S0026461X24000112_inline4.png\"/></span></span><span>a</span>’ × <span><span><span data-mathjax-type=\"texmath\"><span>$sqrt 3$</span></span><img data-mimesubtype=\"png\" data-type=\"\" src=\"https://static.cambridge.org/binary/version/id/urn:cambridge.org:id:binary:20240412100051135-0894:S0026461X24000112:S0026461X24000112_inline5.png\"/></span></span><span>a</span>’ pattern and (2) the (CO<span>3</span>)<span>2–</span> ordering according to the 2<span>a</span>’ × 2<span>a</span>’ pattern in the [CO<span>3</span>(H<span>2</span>O)<span>3</span>]<span>2–</span> interlayer sheet in order to avoid close contacts b","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":null,"pages":null},"PeriodicalIF":2.7,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140575965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Mineralogical Magazine
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