首页 > 最新文献

TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr最新文献

英文 中文
Theoretical simulation model of a proton exchange membrane fuel cell 质子交换膜燃料电池的理论仿真模型
S. Tzelepis, K. Kavadias
Current trends in the energy production sector call for alternative energy production methods with a high focus on renewable energy sources. Most of the countries in the world, and especially the developed countries, fund research towards distributed generation and zero energy balance communities. In order to eliminate the consumption of fossil fuels, a crucial role is taken by hydrogen as a fuel, as, if it is produced from renewable energy sources, it could contribute in substituting the fossil fuels used in transport or building's thermal energy sectors. Moreover, it is well known that electrolysis-fuel cells can also be used as a storage medium in autonomous renewable energy systems. In this case, fuel cells need to be carefully sized in order to optimize the storage system both in energy and economic aspects. In this respect, a theoretical model was developed, able to simulate at any time step the operation of a Proton Exchange Membrane Fuel Cell, by using as input data the technical specifications of the cell and the hydrogen flow. The developed model is based on theoretical, experimental and semi-empirical models in order to provide a flexible algorithm in terms of fuel cell sizing. The model is validated with an existing fuel cell experimental system (Nexa 1200) at different hydrogen flow profiles. The results showed high precision which verifies the reliability of the proposed model for using it in optimization procedures.Current trends in the energy production sector call for alternative energy production methods with a high focus on renewable energy sources. Most of the countries in the world, and especially the developed countries, fund research towards distributed generation and zero energy balance communities. In order to eliminate the consumption of fossil fuels, a crucial role is taken by hydrogen as a fuel, as, if it is produced from renewable energy sources, it could contribute in substituting the fossil fuels used in transport or building's thermal energy sectors. Moreover, it is well known that electrolysis-fuel cells can also be used as a storage medium in autonomous renewable energy systems. In this case, fuel cells need to be carefully sized in order to optimize the storage system both in energy and economic aspects. In this respect, a theoretical model was developed, able to simulate at any time step the operation of a Proton Exchange Membrane Fuel Cell, by using as input data the technical specifications of...
能源生产部门目前的趋势要求采用高度重视可再生能源的替代能源生产方法。世界上大多数国家,特别是发达国家,都在资助分布式发电和零能量平衡社区的研究。为了消除化石燃料的消耗,氢作为燃料起着至关重要的作用,因为如果它是由可再生能源生产的,它可以有助于取代运输或建筑热能部门使用的化石燃料。此外,众所周知,电解燃料电池也可以用作自主可再生能源系统的存储介质。在这种情况下,燃料电池的尺寸需要仔细考虑,以便在能源和经济方面优化存储系统。在这方面,开发了一个理论模型,能够通过使用电池的技术规格和氢气流作为输入数据来模拟质子交换膜燃料电池的任何时间步骤的操作。开发的模型是基于理论、实验和半经验模型,以便在燃料电池尺寸方面提供灵活的算法。该模型与现有的燃料电池实验系统(Nexa 1200)在不同的氢气流动剖面上进行了验证。结果表明该模型具有较高的精度,验证了该模型在优化过程中的可靠性。能源生产部门目前的趋势要求采用高度重视可再生能源的替代能源生产方法。世界上大多数国家,特别是发达国家,都在资助分布式发电和零能量平衡社区的研究。为了消除化石燃料的消耗,氢作为燃料起着至关重要的作用,因为如果它是由可再生能源生产的,它可以有助于取代运输或建筑热能部门使用的化石燃料。此外,众所周知,电解燃料电池也可以用作自主可再生能源系统的存储介质。在这种情况下,燃料电池的尺寸需要仔细考虑,以便在能源和经济方面优化存储系统。在这方面,建立了一个理论模型,能够模拟质子交换膜燃料电池在任何时间步的操作,使用技术规范作为输入数据…
{"title":"Theoretical simulation model of a proton exchange membrane fuel cell","authors":"S. Tzelepis, K. Kavadias","doi":"10.1063/1.5138538","DOIUrl":"https://doi.org/10.1063/1.5138538","url":null,"abstract":"Current trends in the energy production sector call for alternative energy production methods with a high focus on renewable energy sources. Most of the countries in the world, and especially the developed countries, fund research towards distributed generation and zero energy balance communities. In order to eliminate the consumption of fossil fuels, a crucial role is taken by hydrogen as a fuel, as, if it is produced from renewable energy sources, it could contribute in substituting the fossil fuels used in transport or building's thermal energy sectors. Moreover, it is well known that electrolysis-fuel cells can also be used as a storage medium in autonomous renewable energy systems. In this case, fuel cells need to be carefully sized in order to optimize the storage system both in energy and economic aspects. In this respect, a theoretical model was developed, able to simulate at any time step the operation of a Proton Exchange Membrane Fuel Cell, by using as input data the technical specifications of the cell and the hydrogen flow. The developed model is based on theoretical, experimental and semi-empirical models in order to provide a flexible algorithm in terms of fuel cell sizing. The model is validated with an existing fuel cell experimental system (Nexa 1200) at different hydrogen flow profiles. The results showed high precision which verifies the reliability of the proposed model for using it in optimization procedures.Current trends in the energy production sector call for alternative energy production methods with a high focus on renewable energy sources. Most of the countries in the world, and especially the developed countries, fund research towards distributed generation and zero energy balance communities. In order to eliminate the consumption of fossil fuels, a crucial role is taken by hydrogen as a fuel, as, if it is produced from renewable energy sources, it could contribute in substituting the fossil fuels used in transport or building's thermal energy sectors. Moreover, it is well known that electrolysis-fuel cells can also be used as a storage medium in autonomous renewable energy systems. In this case, fuel cells need to be carefully sized in order to optimize the storage system both in energy and economic aspects. In this respect, a theoretical model was developed, able to simulate at any time step the operation of a Proton Exchange Membrane Fuel Cell, by using as input data the technical specifications of...","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"67 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114042750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Financially optimum insulation thickness of external building walls 建筑外墙的经济最佳保温厚度
P. Axaopoulos, E. Fylladitakis, Shaislamov Alisher Shabdurakhmanovich, Abdullaev Nodirbek Azatvay Ogli
The building sector accounts for nearly half the energy consumption of Uzbekistan, with the residential energy consumption being much greater than that of even the most developed European countries. This is mainly attributed to the very low cost of energy in the region that, in combination with the lack of subsidies, offered no incentive for energy conservation measures. However, the price of energy has been rising at an alarming pace over the past few years, making building energy saving measures a nationwide concern. In this paper, we investigate the financially optimal insulation thickness for the most common external wall configurations using the two most commonly used building insulations materials in Tashkent, Uzbekistan, expanded polystyrene and mineral wool. Annual heating and cooling transmission loads are being calculated based on transient heat flow through the external walls and by using hourly climatic data. Additionally, we performed a financial analysis for each wall configuration and orientation, as well as for various thicknesses of insulation material. Depending on the wall type and orientation, the optimum insulation thickness was found to be between 3.75 cm and 11.0 cm. Furthermore, a sensitivity analysis indicates whether changes of the economic parameters affect the optimum insulation thickness.
建筑部门占乌兹别克斯坦能源消耗的近一半,住宅能源消耗甚至比欧洲最发达的国家都要大得多。这主要是由于该区域的能源成本很低,再加上缺乏补贴,没有采取节约能源措施的动力。然而,在过去几年中,能源价格以惊人的速度上涨,使建筑节能措施成为全国关注的问题。在本文中,我们使用乌兹别克斯坦塔什干最常用的两种建筑保温材料,膨胀聚苯乙烯和矿棉,研究了最常见外墙配置的经济最佳保温厚度。根据通过外墙的瞬时热流和每小时的气候数据,计算每年的供暖和制冷传输负荷。此外,我们对每面墙的结构和朝向以及不同厚度的保温材料进行了财务分析。根据墙体类型和朝向的不同,最佳保温厚度在3.75 cm ~ 11.0 cm之间。此外,敏感性分析表明经济参数的变化是否会影响最佳保温厚度。
{"title":"Financially optimum insulation thickness of external building walls","authors":"P. Axaopoulos, E. Fylladitakis, Shaislamov Alisher Shabdurakhmanovich, Abdullaev Nodirbek Azatvay Ogli","doi":"10.1063/1.5138520","DOIUrl":"https://doi.org/10.1063/1.5138520","url":null,"abstract":"The building sector accounts for nearly half the energy consumption of Uzbekistan, with the residential energy consumption being much greater than that of even the most developed European countries. This is mainly attributed to the very low cost of energy in the region that, in combination with the lack of subsidies, offered no incentive for energy conservation measures. However, the price of energy has been rising at an alarming pace over the past few years, making building energy saving measures a nationwide concern. In this paper, we investigate the financially optimal insulation thickness for the most common external wall configurations using the two most commonly used building insulations materials in Tashkent, Uzbekistan, expanded polystyrene and mineral wool. Annual heating and cooling transmission loads are being calculated based on transient heat flow through the external walls and by using hourly climatic data. Additionally, we performed a financial analysis for each wall configuration and orientation, as well as for various thicknesses of insulation material. Depending on the wall type and orientation, the optimum insulation thickness was found to be between 3.75 cm and 11.0 cm. Furthermore, a sensitivity analysis indicates whether changes of the economic parameters affect the optimum insulation thickness.","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131059416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rain formation by free electron laser pulse system FELPS 自由电子激光脉冲系统造雨
H. Kamil, M. S. Ahmed, T. Al-Aish
At present, several problems and challenges have arisen as a result of human population growth and technological development, including global warming, water shortages and drought, especially in arid zones characterized by high temperatures.The low rainfall leads to increased drought and desertification, which has a negative impact on human life. In this study, a new laser technique was proposed to create rain in the atmosphere. Artificial rain can be formed by the proper energy of the laser pulse that stimulates a series of chemical and physical reactions in the clouds to obtain the appropriate rain drops.This technique is based on the use of a free electron beam with suitable energy and adaptable to the weather conditions by changing the wavelength and intensity of the laser beam and the duration of the pulse, ensuring that water droplets of sufficient size to fall.
目前,由于人口增长和技术发展,出现了一些问题和挑战,包括全球变暖、水资源短缺和干旱,特别是在以高温为特征的干旱地区。少雨导致干旱和沙漠化加剧,给人类生活带来负面影响。在这项研究中,提出了一种新的激光技术来制造大气中的雨。人工降雨可以通过激光脉冲的适当能量来刺激云层中的一系列化学和物理反应来获得适当的雨滴。该技术是基于使用具有适当能量的自由电子束,并通过改变激光束的波长和强度以及脉冲的持续时间来适应天气条件,确保足够大小的水滴落下。
{"title":"Rain formation by free electron laser pulse system FELPS","authors":"H. Kamil, M. S. Ahmed, T. Al-Aish","doi":"10.1063/1.5138570","DOIUrl":"https://doi.org/10.1063/1.5138570","url":null,"abstract":"At present, several problems and challenges have arisen as a result of human population growth and technological development, including global warming, water shortages and drought, especially in arid zones characterized by high temperatures.The low rainfall leads to increased drought and desertification, which has a negative impact on human life. In this study, a new laser technique was proposed to create rain in the atmosphere. Artificial rain can be formed by the proper energy of the laser pulse that stimulates a series of chemical and physical reactions in the clouds to obtain the appropriate rain drops.This technique is based on the use of a free electron beam with suitable energy and adaptable to the weather conditions by changing the wavelength and intensity of the laser beam and the duration of the pulse, ensuring that water droplets of sufficient size to fall.","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"68 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122120573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
The influence of partial substation of antimony & lanthanum oxides on electrical and structural properties for the superconductor compound Bi2-xSbxBa2Ca2-yLayCu3O10+δ 氧化锑和氧化镧对超导体化合物Bi2-xSbxBa2Ca2-yLayCu3O10+δ电学和结构性能的影响
L. Mohammed, H. S. Hussein, Haider M. J. Haider, K. Jasim, A. H. Shaban, Samir G. M. Askar, Fouad Waheed Ali
In this research the Bi2-xSbxBa2Ca2-yLayCu3O10+δ compound was prepared and studied the influence of partial substation of Sb2O3 and La2O3 on the electrical and structural properties Samples synthesis by solid state reaction method. The examination of XRD diffraction shown that all samples have bulk polycrystalline with orthorhombic structure. The results shows that the increasing of the c-axis lattice constant for the samples substation with Sb2O3 and La2O3 as compared with those have no content, It was found that changing in lattice parameters (a,b), ratio c/a, mass density and volume fraction Vphases with increases of (Sb2O3,La2O3) concentration. All samples have highest phase 2223 major relative to the other phases. The electrical properties tested by using four probes technique to calculation critical temperatures, it was found the sample Bi1.6Sb0.4Ba2Ca1.8La0.2Cu3O10+δ has a highest critical temperatures Tc=122.5K.In this research the Bi2-xSbxBa2Ca2-yLayCu3O10+δ compound was prepared and studied the influence of partial substation of Sb2O3 and La2O3 on the electrical and structural properties Samples synthesis by solid state reaction method. The examination of XRD diffraction shown that all samples have bulk polycrystalline with orthorhombic structure. The results shows that the increasing of the c-axis lattice constant for the samples substation with Sb2O3 and La2O3 as compared with those have no content, It was found that changing in lattice parameters (a,b), ratio c/a, mass density and volume fraction Vphases with increases of (Sb2O3,La2O3) concentration. All samples have highest phase 2223 major relative to the other phases. The electrical properties tested by using four probes technique to calculation critical temperatures, it was found the sample Bi1.6Sb0.4Ba2Ca1.8La0.2Cu3O10+δ has a highest critical temperatures Tc=122.5K.
本研究制备了Bi2-xSbxBa2Ca2-yLayCu3O10+δ化合物,并研究了Sb2O3和La2O3的部分变位对固相反应法制备样品的电学和结构性能的影响。XRD衍射分析表明,所有样品均具有正交结构的块状多晶。结果表明:与未添加Sb2O3和La2O3的样品相比,添加Sb2O3和La2O3的样品的c轴晶格常数增加,晶格参数(a、b)、c/a比、质量密度和v相体积分数随(Sb2O3、La2O3)浓度的增加而变化。所有样品相对于其他相具有最高的2223 major相。电学性能测试采用四探针技术计算临界温度,发现样品Bi1.6Sb0.4Ba2Ca1.8La0.2Cu3O10+δ具有最高临界温度Tc=122.5K。本研究制备了Bi2-xSbxBa2Ca2-yLayCu3O10+δ化合物,并研究了Sb2O3和La2O3的部分变位对固相反应法制备样品的电学和结构性能的影响。XRD衍射分析表明,所有样品均具有正交结构的块状多晶。结果表明:与未添加Sb2O3和La2O3的样品相比,添加Sb2O3和La2O3的样品的c轴晶格常数增加,晶格参数(a、b)、c/a比、质量密度和v相体积分数随(Sb2O3、La2O3)浓度的增加而变化。所有样品相对于其他相具有最高的2223 major相。电学性能测试采用四探针技术计算临界温度,发现样品Bi1.6Sb0.4Ba2Ca1.8La0.2Cu3O10+δ具有最高临界温度Tc=122.5K。
{"title":"The influence of partial substation of antimony & lanthanum oxides on electrical and structural properties for the superconductor compound Bi2-xSbxBa2Ca2-yLayCu3O10+δ","authors":"L. Mohammed, H. S. Hussein, Haider M. J. Haider, K. Jasim, A. H. Shaban, Samir G. M. Askar, Fouad Waheed Ali","doi":"10.1063/1.5138504","DOIUrl":"https://doi.org/10.1063/1.5138504","url":null,"abstract":"In this research the Bi2-xSbxBa2Ca2-yLayCu3O10+δ compound was prepared and studied the influence of partial substation of Sb2O3 and La2O3 on the electrical and structural properties Samples synthesis by solid state reaction method. The examination of XRD diffraction shown that all samples have bulk polycrystalline with orthorhombic structure. The results shows that the increasing of the c-axis lattice constant for the samples substation with Sb2O3 and La2O3 as compared with those have no content, It was found that changing in lattice parameters (a,b), ratio c/a, mass density and volume fraction Vphases with increases of (Sb2O3,La2O3) concentration. All samples have highest phase 2223 major relative to the other phases. The electrical properties tested by using four probes technique to calculation critical temperatures, it was found the sample Bi1.6Sb0.4Ba2Ca1.8La0.2Cu3O10+δ has a highest critical temperatures Tc=122.5K.In this research the Bi2-xSbxBa2Ca2-yLayCu3O10+δ compound was prepared and studied the influence of partial substation of Sb2O3 and La2O3 on the electrical and structural properties Samples synthesis by solid state reaction method. The examination of XRD diffraction shown that all samples have bulk polycrystalline with orthorhombic structure. The results shows that the increasing of the c-axis lattice constant for the samples substation with Sb2O3 and La2O3 as compared with those have no content, It was found that changing in lattice parameters (a,b), ratio c/a, mass density and volume fraction Vphases with increases of (Sb2O3,La2O3) concentration. All samples have highest phase 2223 major relative to the other phases. The electrical properties tested by using four probes technique to calculation critical temperatures, it was found the sample Bi1.6Sb0.4Ba2Ca1.8La0.2Cu3O10+δ has a highest critical temperatures Tc=122.5K.","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129778585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Investigation of some phenolic-type antioxidants compounds extracted from biodiesel as green natural corrosion inhibitors; DFT and molecular dynamic simulation, comparative study 从生物柴油中提取的酚类抗氧化剂作为绿色天然缓蚀剂的研究DFT与分子动力学模拟,比较研究
Djamel Daouda, T. Douadi, Djillali Ghobrini, N. Lahouel, Hanane Hamani
To solve the problem of environmental pollution during the metal cleaning process, new compounds extracted from biodiesel such as Pyropyl-Gallate (L1), Pyrogallol (L2), 4-Methyl-catecho (L3) and Protocatechuic-acid (L4) were investigated as green corrosion inhibitors by using density functional theory (DFT) and Molecular dynamic simulation (MDS) methods. The computed quantum chemical parameters obtained from DFT for instance the total energy (ET), the energy of the highest occupied molecular orbital (EHOMO), the energy of the lowest unoccupied molecular orbital (ELUMO), the dipole moment (µ) and the polarizability (α) indicate that those examined molecules were efficient corrosion inhibitor. The tested molecules present a general planar structure. This structure unit may be in favor of the important interaction zone if the molecule adsorbed on the metal surface at nearly 0° contact angle. As can be seen from Molecular electrostatic potential (MEP), it is clear that more electron rich regions are largely located around the heteroatoms and the conjugated double bonds, means that L1, L2, L3 and L4 can promote the formation of a complex on the metal surface by transferring electrons and forming a coordinate covalent bond through the chemical adsorption. From MDS study, the binding energy of the adsorption system (Inhibitor-Fe) is more important, showing that this adsorption system is very stable, and has high inhibitory efficiency. According to the study of quantum chemistry, the oxygen atoms of the molecules tested can give electrons to the unoccupied iron orbital “d” to form coordination bonds while the orbital π of aromatic rings can accept electrons from the iron orbital “d” to form coordination bonds. A good agreement was found between DFT and MDS methods.To solve the problem of environmental pollution during the metal cleaning process, new compounds extracted from biodiesel such as Pyropyl-Gallate (L1), Pyrogallol (L2), 4-Methyl-catecho (L3) and Protocatechuic-acid (L4) were investigated as green corrosion inhibitors by using density functional theory (DFT) and Molecular dynamic simulation (MDS) methods. The computed quantum chemical parameters obtained from DFT for instance the total energy (ET), the energy of the highest occupied molecular orbital (EHOMO), the energy of the lowest unoccupied molecular orbital (ELUMO), the dipole moment (µ) and the polarizability (α) indicate that those examined molecules were efficient corrosion inhibitor. The tested molecules present a general planar structure. This structure unit may be in favor of the important interaction zone if the molecule adsorbed on the metal surface at nearly 0° contact angle. As can be seen from Molecular electrostatic potential (MEP), it is clear that more electron rich regions are largely l...
为解决金属清洗过程中的环境污染问题,采用密度泛函数理论(DFT)和分子动力学模拟(MDS)方法,对从生物柴油中提取的新型化合物邻苯三酚没食子酸酯(L1)、邻苯三酚(L2)、4-甲基catecho (L3)和原儿茶酸(L4)作为绿色缓蚀剂进行了研究。计算得到的总能量(ET)、最高占据轨道能量(EHOMO)、最低未占据轨道能量(ELUMO)、偶极矩(µ)和极化率(α)等量子化学参数表明,所测分子是有效的缓蚀剂。所测分子呈一般平面结构。当分子以接近0°的接触角吸附在金属表面时,这种结构单元可能有利于重要的相互作用区。从分子静电势(MEP)可以看出,更多的富电子区明显位于杂原子和共轭双键周围,说明L1、L2、L3和L4通过化学吸附作用转移电子,形成配位共价键,从而促进金属表面形成配合物。从MDS研究来看,吸附体系的结合能(inhibittor - fe)更为重要,说明该吸附体系非常稳定,具有较高的抑制效率。根据量子化学的研究,被测分子的氧原子可以将电子给予未占据的铁轨道“d”形成配位键,而芳香环的轨道π可以接受铁轨道“d”的电子形成配位键。DFT方法与MDS方法有很好的一致性。为解决金属清洗过程中的环境污染问题,采用密度泛函数理论(DFT)和分子动力学模拟(MDS)方法,对从生物柴油中提取的新型化合物邻苯三酚没食子酸酯(L1)、邻苯三酚(L2)、4-甲基catecho (L3)和原儿茶酸(L4)作为绿色缓蚀剂进行了研究。计算得到的总能量(ET)、最高占据轨道能量(EHOMO)、最低未占据轨道能量(ELUMO)、偶极矩(µ)和极化率(α)等量子化学参数表明,所测分子是有效的缓蚀剂。所测分子呈一般平面结构。当分子以接近0°的接触角吸附在金属表面时,这种结构单元可能有利于重要的相互作用区。从分子静电势(MEP)可以看出,显然更多的富电子区大部分是l…
{"title":"Investigation of some phenolic-type antioxidants compounds extracted from biodiesel as green natural corrosion inhibitors; DFT and molecular dynamic simulation, comparative study","authors":"Djamel Daouda, T. Douadi, Djillali Ghobrini, N. Lahouel, Hanane Hamani","doi":"10.1063/1.5138584","DOIUrl":"https://doi.org/10.1063/1.5138584","url":null,"abstract":"To solve the problem of environmental pollution during the metal cleaning process, new compounds extracted from biodiesel such as Pyropyl-Gallate (L1), Pyrogallol (L2), 4-Methyl-catecho (L3) and Protocatechuic-acid (L4) were investigated as green corrosion inhibitors by using density functional theory (DFT) and Molecular dynamic simulation (MDS) methods. The computed quantum chemical parameters obtained from DFT for instance the total energy (ET), the energy of the highest occupied molecular orbital (EHOMO), the energy of the lowest unoccupied molecular orbital (ELUMO), the dipole moment (µ) and the polarizability (α) indicate that those examined molecules were efficient corrosion inhibitor. The tested molecules present a general planar structure. This structure unit may be in favor of the important interaction zone if the molecule adsorbed on the metal surface at nearly 0° contact angle. As can be seen from Molecular electrostatic potential (MEP), it is clear that more electron rich regions are largely located around the heteroatoms and the conjugated double bonds, means that L1, L2, L3 and L4 can promote the formation of a complex on the metal surface by transferring electrons and forming a coordinate covalent bond through the chemical adsorption. From MDS study, the binding energy of the adsorption system (Inhibitor-Fe) is more important, showing that this adsorption system is very stable, and has high inhibitory efficiency. According to the study of quantum chemistry, the oxygen atoms of the molecules tested can give electrons to the unoccupied iron orbital “d” to form coordination bonds while the orbital π of aromatic rings can accept electrons from the iron orbital “d” to form coordination bonds. A good agreement was found between DFT and MDS methods.To solve the problem of environmental pollution during the metal cleaning process, new compounds extracted from biodiesel such as Pyropyl-Gallate (L1), Pyrogallol (L2), 4-Methyl-catecho (L3) and Protocatechuic-acid (L4) were investigated as green corrosion inhibitors by using density functional theory (DFT) and Molecular dynamic simulation (MDS) methods. The computed quantum chemical parameters obtained from DFT for instance the total energy (ET), the energy of the highest occupied molecular orbital (EHOMO), the energy of the lowest unoccupied molecular orbital (ELUMO), the dipole moment (µ) and the polarizability (α) indicate that those examined molecules were efficient corrosion inhibitor. The tested molecules present a general planar structure. This structure unit may be in favor of the important interaction zone if the molecule adsorbed on the metal surface at nearly 0° contact angle. As can be seen from Molecular electrostatic potential (MEP), it is clear that more electron rich regions are largely l...","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"54 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122397497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Cu doping effect on characterization of nano crystalline SnSe thin films 铜掺杂对纳米晶体SnSe薄膜表征的影响
G. Ahmed, B. K. Al-Maiyaly
A thin film of (SnSe) and SnSe:Cu with various Cu ratio (0,3,5 and 7)% have been prepared by thermal evaporation technique with thickness 400±20 nm on glass substrate at (R.T). The effect of Cu dopants concentration on the structural, morphological, optical and electrical properties of (SnSe) Nano crystalline thin films was explored by using X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), energy dispersive spectroscopy (EDS), UV–Vis absorption spectroscopy and Hall Effect measurement respectively. X-ray diffraction analysis reveal the polycrystalline nature of the all films deposited with orthorhombic structure which possess a preferred orientation along the (111) plane. The crystalline sizes of the films vary in the range of (18.167– 25.91) nm, depending on the Cu doping ratio. The SEM study show that the film exhibit growth of small grains and the morphologies of SnSe could be changed from spherical grains to platelet-like particles. The AFM investigations show that the films grain size vary in the range (60.12 to 70.59) nm with increasing Cu doping ratio. The optical measurements on un doped and Cu doped SnSe thin films indicate that the samples have direct transition with an optical band gap of (1.3 –1. 5) eV and the absorption coefficient ≥104 cm−1, which is make these films suitable for photovoltaic devices. Hall Effect measurement illustrate that all samples have p-type conductivity and the carrier concentration of the thin films was of the order of 1014/cm3A thin film of (SnSe) and SnSe:Cu with various Cu ratio (0,3,5 and 7)% have been prepared by thermal evaporation technique with thickness 400±20 nm on glass substrate at (R.T). The effect of Cu dopants concentration on the structural, morphological, optical and electrical properties of (SnSe) Nano crystalline thin films was explored by using X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), energy dispersive spectroscopy (EDS), UV–Vis absorption spectroscopy and Hall Effect measurement respectively. X-ray diffraction analysis reveal the polycrystalline nature of the all films deposited with orthorhombic structure which possess a preferred orientation along the (111) plane. The crystalline sizes of the films vary in the range of (18.167– 25.91) nm, depending on the Cu doping ratio. The SEM study show that the film exhibit growth of small grains and the morphologies of SnSe could be changed from spherical grains to platelet-like particles. The AFM investigations sho...
采用热蒸发技术在温度为(R.T)的玻璃基板上制备了厚度为400±20 nm的(SnSe)和SnSe:Cu薄膜,其Cu比分别为(0、3、5和7)%。采用x射线衍射(XRD)、扫描电镜(SEM)、原子力显微镜(AFM)、能谱(EDS)、紫外可见吸收光谱(UV-Vis absorption spectroscopy, EDS)和霍尔效应(Hall effect)测量等方法,探讨了Cu掺杂浓度对(SnSe)纳米晶体薄膜结构、形貌、光学和电学性能的影响。x射线衍射分析表明,所有薄膜都具有沿(111)平面优先取向的正交结构,具有多晶性质。薄膜的晶粒尺寸随Cu掺杂比的不同而变化,范围为(18.167 ~ 25.91)nm。SEM研究表明,薄膜呈现小颗粒生长,SnSe的形貌可以由球形颗粒转变为血小板状颗粒。AFM研究表明,随着Cu掺杂比的增加,膜的晶粒尺寸在60.12 ~ 70.59 nm范围内变化。对未掺杂和Cu掺杂SnSe薄膜的光学测量表明,样品具有直接跃迁,光学带隙为(1.3 -1)。5) eV和吸收系数≥104 cm−1,这使得这些薄膜适用于光伏器件。霍尔效应测试表明,所有样品均具有p型电导率,载流子浓度均在1014/cm3左右,采用热蒸发技术在玻璃基板上制备了厚度为400±20 nm的(SnSe)和SnSe:Cu薄膜,其Cu比分别为(0、3、5和7)%。采用x射线衍射(XRD)、扫描电镜(SEM)、原子力显微镜(AFM)、能谱(EDS)、紫外可见吸收光谱(UV-Vis absorption spectroscopy, EDS)和霍尔效应(Hall effect)测量等方法,探讨了Cu掺杂浓度对(SnSe)纳米晶体薄膜结构、形貌、光学和电学性能的影响。x射线衍射分析表明,所有薄膜都具有沿(111)平面优先取向的正交结构,具有多晶性质。薄膜的晶粒尺寸随Cu掺杂比的不同而变化,范围为(18.167 ~ 25.91)nm。SEM研究表明,薄膜呈现小颗粒生长,SnSe的形貌可以由球形颗粒转变为血小板状颗粒。AFM的调查显示……
{"title":"Cu doping effect on characterization of nano crystalline SnSe thin films","authors":"G. Ahmed, B. K. Al-Maiyaly","doi":"10.1063/1.5138505","DOIUrl":"https://doi.org/10.1063/1.5138505","url":null,"abstract":"A thin film of (SnSe) and SnSe:Cu with various Cu ratio (0,3,5 and 7)% have been prepared by thermal evaporation technique with thickness 400±20 nm on glass substrate at (R.T). The effect of Cu dopants concentration on the structural, morphological, optical and electrical properties of (SnSe) Nano crystalline thin films was explored by using X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), energy dispersive spectroscopy (EDS), UV–Vis absorption spectroscopy and Hall Effect measurement respectively. X-ray diffraction analysis reveal the polycrystalline nature of the all films deposited with orthorhombic structure which possess a preferred orientation along the (111) plane. The crystalline sizes of the films vary in the range of (18.167– 25.91) nm, depending on the Cu doping ratio. The SEM study show that the film exhibit growth of small grains and the morphologies of SnSe could be changed from spherical grains to platelet-like particles. The AFM investigations show that the films grain size vary in the range (60.12 to 70.59) nm with increasing Cu doping ratio. The optical measurements on un doped and Cu doped SnSe thin films indicate that the samples have direct transition with an optical band gap of (1.3 –1. 5) eV and the absorption coefficient ≥104 cm−1, which is make these films suitable for photovoltaic devices. Hall Effect measurement illustrate that all samples have p-type conductivity and the carrier concentration of the thin films was of the order of 1014/cm3A thin film of (SnSe) and SnSe:Cu with various Cu ratio (0,3,5 and 7)% have been prepared by thermal evaporation technique with thickness 400±20 nm on glass substrate at (R.T). The effect of Cu dopants concentration on the structural, morphological, optical and electrical properties of (SnSe) Nano crystalline thin films was explored by using X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), energy dispersive spectroscopy (EDS), UV–Vis absorption spectroscopy and Hall Effect measurement respectively. X-ray diffraction analysis reveal the polycrystalline nature of the all films deposited with orthorhombic structure which possess a preferred orientation along the (111) plane. The crystalline sizes of the films vary in the range of (18.167– 25.91) nm, depending on the Cu doping ratio. The SEM study show that the film exhibit growth of small grains and the morphologies of SnSe could be changed from spherical grains to platelet-like particles. The AFM investigations sho...","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"82 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123092874","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
A new PV soiling monitoring device for optimized cleaning strategy 一种用于优化清洗策略的新型PV污染监测装置
A. Azouzoute, Mostafa Chouitar, M. Garoum, E. Bennouna, A. Ghennioui
Solar PV technology is now widely exploited as a source of energy production. However, the PV panels are generally affected by a variety of factors that decrease the efficiency of the system especially those related to the dust deposition. Therefore, in this study, a new methodology to quantify the drop of transmittance of the glass on the surface of a PV panel was investigated. The basic of this method is using the Brewster angle to evaluate the intensity of the reflected ray from the surface of the glass in the presence of different amount of density of dust deposition. The results showed that the intensity of the reflected ray using Brewster angle decrease with the increase of the density of deposition on the surface of the glass sample. The experiment elucidated that this new method can be a significant methodology to quantify the effect of dust deposition and to optimize the cleaning on the solar PV plant.Solar PV technology is now widely exploited as a source of energy production. However, the PV panels are generally affected by a variety of factors that decrease the efficiency of the system especially those related to the dust deposition. Therefore, in this study, a new methodology to quantify the drop of transmittance of the glass on the surface of a PV panel was investigated. The basic of this method is using the Brewster angle to evaluate the intensity of the reflected ray from the surface of the glass in the presence of different amount of density of dust deposition. The results showed that the intensity of the reflected ray using Brewster angle decrease with the increase of the density of deposition on the surface of the glass sample. The experiment elucidated that this new method can be a significant methodology to quantify the effect of dust deposition and to optimize the cleaning on the solar PV plant.
太阳能光伏技术现在作为一种能源生产方式被广泛利用。然而,光伏板通常受到各种因素的影响,这些因素会降低系统的效率,特别是与粉尘沉积有关的因素。因此,在本研究中,研究了一种量化光伏电池板表面玻璃透射率下降的新方法。该方法的基础是利用布鲁斯特角来评价在不同粉尘密度下玻璃表面反射光线的强度。结果表明:随着玻璃表面沉积密度的增加,布鲁斯特角反射光线的强度减小;实验结果表明,该方法可作为一种重要的方法来量化粉尘沉积的影响,并优化太阳能光伏电站的清洁。太阳能光伏技术现在作为一种能源生产方式被广泛利用。然而,光伏板通常受到各种因素的影响,这些因素会降低系统的效率,特别是与粉尘沉积有关的因素。因此,在本研究中,研究了一种量化光伏电池板表面玻璃透射率下降的新方法。该方法的基础是利用布鲁斯特角来评价在不同粉尘密度下玻璃表面反射光线的强度。结果表明:随着玻璃表面沉积密度的增加,布鲁斯特角反射光线的强度减小;实验结果表明,该方法可作为一种重要的方法来量化粉尘沉积的影响,并优化太阳能光伏电站的清洁。
{"title":"A new PV soiling monitoring device for optimized cleaning strategy","authors":"A. Azouzoute, Mostafa Chouitar, M. Garoum, E. Bennouna, A. Ghennioui","doi":"10.1063/1.5138554","DOIUrl":"https://doi.org/10.1063/1.5138554","url":null,"abstract":"Solar PV technology is now widely exploited as a source of energy production. However, the PV panels are generally affected by a variety of factors that decrease the efficiency of the system especially those related to the dust deposition. Therefore, in this study, a new methodology to quantify the drop of transmittance of the glass on the surface of a PV panel was investigated. The basic of this method is using the Brewster angle to evaluate the intensity of the reflected ray from the surface of the glass in the presence of different amount of density of dust deposition. The results showed that the intensity of the reflected ray using Brewster angle decrease with the increase of the density of deposition on the surface of the glass sample. The experiment elucidated that this new method can be a significant methodology to quantify the effect of dust deposition and to optimize the cleaning on the solar PV plant.Solar PV technology is now widely exploited as a source of energy production. However, the PV panels are generally affected by a variety of factors that decrease the efficiency of the system especially those related to the dust deposition. Therefore, in this study, a new methodology to quantify the drop of transmittance of the glass on the surface of a PV panel was investigated. The basic of this method is using the Brewster angle to evaluate the intensity of the reflected ray from the surface of the glass in the presence of different amount of density of dust deposition. The results showed that the intensity of the reflected ray using Brewster angle decrease with the increase of the density of deposition on the surface of the glass sample. The experiment elucidated that this new method can be a significant methodology to quantify the effect of dust deposition and to optimize the cleaning on the solar PV plant.","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134467864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Manufacture of C-TABCCO superconducting system and study the electrical and magnetic properties C-TABCCO超导体系的制备及电、磁性能研究
A. K. D. Ali, Ismaeel K. Jasim, K. Jasim, Maher A. Hassan
The present study includes the calculation of the electrical and magnetic properties of the C-TABCCO superconducting system in solid-state interaction by adding silver to the first system under pressure of 7 ton / cm2 and the thermodynamic temperature (800 K). The electrical properties are measured using The LCR meter shows that the dielectric constant (K) and the loss factor (D) decrease with increasing frequency and the alternating electrical conductivity (AC) increases with increasing frequency. Therefore, we deduce that the inertial properties and all the samples depend on the addition ratios. The higher the frequency, the better the connectivity and the lower the density. The Using the technique of (vibration sample Magnometer) (VSM) where the hysteric rings were extracted, magnetic properties of the hysterical ring forms of magnetic affectivity (M s) and magnetic susceptibility (M s) and magnetic delay (M r) relative permeability (μ r) of magnetismThe present study includes the calculation of the electrical and magnetic properties of the C-TABCCO superconducting system in solid-state interaction by adding silver to the first system under pressure of 7 ton / cm2 and the thermodynamic temperature (800 K). The electrical properties are measured using The LCR meter shows that the dielectric constant (K) and the loss factor (D) decrease with increasing frequency and the alternating electrical conductivity (AC) increases with increasing frequency. Therefore, we deduce that the inertial properties and all the samples depend on the addition ratios. The higher the frequency, the better the connectivity and the lower the density. The Using the technique of (vibration sample Magnometer) (VSM) where the hysteric rings were extracted, magnetic properties of the hysterical ring forms of magnetic affectivity (M s) and magnetic susceptibility (M s) and magnetic delay (M r) relative permeability (μ r) of magnetism
在压力为7 ton / cm2,热力学温度为800 K的条件下,在第一体系中加入银,计算了C-TABCCO超导体系在固态相互作用下的电学和磁学性质。电学性质用LCR计测量表明,介电常数(K)和损耗因子(D)随频率的增加而减小,交变电导率(AC)随频率的增加而增大频率。因此,我们推断出惯性性质和所有样品都取决于添加比。频率越高,连接越好,密度越低。采用振动样品磁强计(VSM)技术提取磁滞环,磁滞环形式的磁化率(M s)、磁化率(M s)和磁延迟(M r)、相对磁导率(μ r)。本研究包括在压力为7吨/平方厘米、热力学温度为800 K的条件下,通过在第一体系中加入银,计算固态相互作用下C-TABCCO超导体系的电学和磁学性质,并用LCR仪测量电学性质电介质常数(K)和损耗因子(D)随频率的增加而减小,交变电导率(AC)随频率的增加而增大。因此,我们推断出惯性性质和所有样品都取决于添加比。频率越高,连接越好,密度越低。利用振动样品磁强计(VSM)技术提取磁滞环,得到磁滞环的磁性能形式为磁化率(M s)、磁化率(M s)和磁延迟(M r)相对磁导率(μ r)
{"title":"Manufacture of C-TABCCO superconducting system and study the electrical and magnetic properties","authors":"A. K. D. Ali, Ismaeel K. Jasim, K. Jasim, Maher A. Hassan","doi":"10.1063/1.5138506","DOIUrl":"https://doi.org/10.1063/1.5138506","url":null,"abstract":"The present study includes the calculation of the electrical and magnetic properties of the C-TABCCO superconducting system in solid-state interaction by adding silver to the first system under pressure of 7 ton / cm2 and the thermodynamic temperature (800 K). The electrical properties are measured using The LCR meter shows that the dielectric constant (K) and the loss factor (D) decrease with increasing frequency and the alternating electrical conductivity (AC) increases with increasing frequency. Therefore, we deduce that the inertial properties and all the samples depend on the addition ratios. The higher the frequency, the better the connectivity and the lower the density. The Using the technique of (vibration sample Magnometer) (VSM) where the hysteric rings were extracted, magnetic properties of the hysterical ring forms of magnetic affectivity (M s) and magnetic susceptibility (M s) and magnetic delay (M r) relative permeability (μ r) of magnetismThe present study includes the calculation of the electrical and magnetic properties of the C-TABCCO superconducting system in solid-state interaction by adding silver to the first system under pressure of 7 ton / cm2 and the thermodynamic temperature (800 K). The electrical properties are measured using The LCR meter shows that the dielectric constant (K) and the loss factor (D) decrease with increasing frequency and the alternating electrical conductivity (AC) increases with increasing frequency. Therefore, we deduce that the inertial properties and all the samples depend on the addition ratios. The higher the frequency, the better the connectivity and the lower the density. The Using the technique of (vibration sample Magnometer) (VSM) where the hysteric rings were extracted, magnetic properties of the hysterical ring forms of magnetic affectivity (M s) and magnetic susceptibility (M s) and magnetic delay (M r) relative permeability (μ r) of magnetism","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133342467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study the effect of nanoic indium oxide (In2O3) on electrical properties of ZnO- based varistor 研究了纳米氧化铟(In2O3)对ZnO基压敏电阻电性能的影响
M. Abbas, A. Ibraheem
In this present work, we studied the influence of nanoic (In2O3) Doping of ZnO varistors’ electrical characteristics, I-V nonlinear coefficient, the leakage current, break down voltage and grain size, have been studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), electrical measurements, with different sintering temperatures (1000, 1050, 1100) °C for 2h. The results exhibit the nonlinear coefficient (α) gradually increased by increasing concentrations of (In2O3), Sintered varistor leakage current reduced with increased dopant concentration of nanoic (In2O3), the breakdown voltage values reduced with increased the sintering temperature. With the increasing (In2O3), The average grain size slightly reduced, which are improving the voltage gradient.In this present work, we studied the influence of nanoic (In2O3) Doping of ZnO varistors’ electrical characteristics, I-V nonlinear coefficient, the leakage current, break down voltage and grain size, have been studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), electrical measurements, with different sintering temperatures (1000, 1050, 1100) °C for 2h. The results exhibit the nonlinear coefficient (α) gradually increased by increasing concentrations of (In2O3), Sintered varistor leakage current reduced with increased dopant concentration of nanoic (In2O3), the breakdown voltage values reduced with increased the sintering temperature. With the increasing (In2O3), The average grain size slightly reduced, which are improving the voltage gradient.
本文研究了纳米(In2O3)掺杂对ZnO压敏电阻电学特性、I-V非线性系数、漏电流、击穿电压和晶粒尺寸的影响,采用x射线衍射(XRD)、扫描电镜(SEM)、电学测量等方法,在不同烧结温度(1000、1050、1100)℃下烧结2h进行了研究。结果表明:随着(In2O3)浓度的增加,非线性系数(α)逐渐增大,烧结压敏电阻泄漏电流随着掺杂纳米(In2O3)浓度的增加而减小,击穿电压值随着烧结温度的升高而减小。随着(In2O3)含量的增加,平均晶粒尺寸略有减小,这都改善了电压梯度。本文研究了纳米(In2O3)掺杂对ZnO压敏电阻电学特性、I-V非线性系数、漏电流、击穿电压和晶粒尺寸的影响,采用x射线衍射(XRD)、扫描电镜(SEM)、电学测量等方法,在不同烧结温度(1000、1050、1100)℃下烧结2h进行了研究。结果表明:随着(In2O3)浓度的增加,非线性系数(α)逐渐增大,烧结压敏电阻泄漏电流随着掺杂纳米(In2O3)浓度的增加而减小,击穿电压值随着烧结温度的升高而减小。随着(In2O3)含量的增加,平均晶粒尺寸略有减小,这都改善了电压梯度。
{"title":"Study the effect of nanoic indium oxide (In2O3) on electrical properties of ZnO- based varistor","authors":"M. Abbas, A. Ibraheem","doi":"10.1063/1.5138501","DOIUrl":"https://doi.org/10.1063/1.5138501","url":null,"abstract":"In this present work, we studied the influence of nanoic (In2O3) Doping of ZnO varistors’ electrical characteristics, I-V nonlinear coefficient, the leakage current, break down voltage and grain size, have been studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), electrical measurements, with different sintering temperatures (1000, 1050, 1100) °C for 2h. The results exhibit the nonlinear coefficient (α) gradually increased by increasing concentrations of (In2O3), Sintered varistor leakage current reduced with increased dopant concentration of nanoic (In2O3), the breakdown voltage values reduced with increased the sintering temperature. With the increasing (In2O3), The average grain size slightly reduced, which are improving the voltage gradient.In this present work, we studied the influence of nanoic (In2O3) Doping of ZnO varistors’ electrical characteristics, I-V nonlinear coefficient, the leakage current, break down voltage and grain size, have been studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), electrical measurements, with different sintering temperatures (1000, 1050, 1100) °C for 2h. The results exhibit the nonlinear coefficient (α) gradually increased by increasing concentrations of (In2O3), Sintered varistor leakage current reduced with increased dopant concentration of nanoic (In2O3), the breakdown voltage values reduced with increased the sintering temperature. With the increasing (In2O3), The average grain size slightly reduced, which are improving the voltage gradient.","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"6 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114246845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of dielectric barrier discharge on sperm motility and influence on oxidative stress in patient with asthenospermia 介质屏障放电对弱精子症患者精子活力及氧化应激的影响
Marwa S. Hanon, S. N. Mazhir, E. Hussein
In this study, the biomedical applications of the cold Plasma physics technique were investigated. Dielectric Barrier Discharges (DBD) plasma at atmospheric pressure is used for studying the cold plasma effect on human sperm motility. Patients how had sperms with low spermatozoal motility (Asthenozoospermia) were included in this study. Focusing on the results of motility and DNA integrity before and after exposing to plasma system, it is concluded that the sperms motility of the semen samples shows a good response to the cold plasma by increasing the sperm motility.In this study, the biomedical applications of the cold Plasma physics technique were investigated. Dielectric Barrier Discharges (DBD) plasma at atmospheric pressure is used for studying the cold plasma effect on human sperm motility. Patients how had sperms with low spermatozoal motility (Asthenozoospermia) were included in this study. Focusing on the results of motility and DNA integrity before and after exposing to plasma system, it is concluded that the sperms motility of the semen samples shows a good response to the cold plasma by increasing the sperm motility.
本研究探讨了冷等离子体物理技术在生物医学上的应用。用常压介质阻挡放电等离子体研究了低温等离子体对人类精子活力的影响。精子活力低(弱精子症)的患者被纳入本研究。结合血浆系统暴露前后精子活力和DNA完整性的结果,认为精子活力通过提高精子活力对低温等离子体有较好的响应。本研究探讨了冷等离子体物理技术在生物医学上的应用。用常压介质阻挡放电等离子体研究了低温等离子体对人类精子活力的影响。精子活力低(弱精子症)的患者被纳入本研究。结合血浆系统暴露前后精子活力和DNA完整性的结果,认为精子活力通过提高精子活力对低温等离子体有较好的响应。
{"title":"Effect of dielectric barrier discharge on sperm motility and influence on oxidative stress in patient with asthenospermia","authors":"Marwa S. Hanon, S. N. Mazhir, E. Hussein","doi":"10.1063/1.5138577","DOIUrl":"https://doi.org/10.1063/1.5138577","url":null,"abstract":"In this study, the biomedical applications of the cold Plasma physics technique were investigated. Dielectric Barrier Discharges (DBD) plasma at atmospheric pressure is used for studying the cold plasma effect on human sperm motility. Patients how had sperms with low spermatozoal motility (Asthenozoospermia) were included in this study. Focusing on the results of motility and DNA integrity before and after exposing to plasma system, it is concluded that the sperms motility of the semen samples shows a good response to the cold plasma by increasing the sperm motility.In this study, the biomedical applications of the cold Plasma physics technique were investigated. Dielectric Barrier Discharges (DBD) plasma at atmospheric pressure is used for studying the cold plasma effect on human sperm motility. Patients how had sperms with low spermatozoal motility (Asthenozoospermia) were included in this study. Focusing on the results of motility and DNA integrity before and after exposing to plasma system, it is concluded that the sperms motility of the semen samples shows a good response to the cold plasma by increasing the sperm motility.","PeriodicalId":186251,"journal":{"name":"TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr","volume":"45 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129374922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES19Gr
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1