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Supercapacitors for storing energy from coffee bean waste 储存咖啡豆废料能量的超级电容器
Pub Date : 2022-07-08 DOI: 10.56845/rebs.v2i2.23
E. Del Angel-Meraz, A. Pérez-Aguirre
Activated carbon (AC) was made from coffee bean waste, which was prepared by chemical activation, using potassium hydroxide (KOH) at 2 M as activating agent, with impregnation times of 24 and 48 h, temperatures carbonization of 600 and 700 ° C, once the activated carbon samples were obtained, they were doped with nickel oxide (NiO), in order to modify the electrical properties of CA, later they were characterized (physical adsorption of N2, FT-IR, XRD). The CA / NiO composites were prepared by the chemical method and electrodes were compacted into forms of self-consistent tablets, which were placed in a two-electrode cell using sulfuric acid (H2SO4) as electrolyte at 2 M. The electrochemical part was evaluated by means of Cyclic voltammetry and galvanostatic chronopotentiometry, obtaining the electrical behavior of the electrodes for their application in supercapacitors (SCS). Finally, the specific capacitance of the SCS was determined from CA / NiO, as a result it was obtained that the CA / NiO-48-700 ° C-KOH samples showed a maximum capacitance of: 405.405 F / g respectively. This proves that nickel oxide improved the properties of AC for use as electrodes in supercapacitors.
以咖啡渣为原料,采用化学活化法制备活性炭(AC),以2 M的氢氧化钾(KOH)为活化剂,浸渍时间分别为24和48 h,炭化温度分别为600和700℃,得到的活性炭样品中掺杂氧化镍(NiO),以修饰CA的电学性能,随后对其进行表征(N2物理吸附、FT-IR、XRD)。采用化学法制备了CA / NiO复合材料,将电极压实成自溶片剂,置于以硫酸(H2SO4)为电解液的双电极电池中,温度为2 m。电化学部分采用循环伏安法和恒流计时电位法进行了评价,获得了用于超级电容器(SCS)的电极的电学行为。最后,用CA / NiO测定了SCS的比电容,结果表明CA / NiO-48-700°C-KOH样品的最大电容分别为:405.405 F / g。这证明了氧化镍改善了用作超级电容器电极的交流电的性能。
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引用次数: 0
Bioenergy potential from agroindustrial wastes of the state of Veracruz 韦拉克鲁斯州农业工业废弃物的生物能源潜力
Pub Date : 2022-07-08 DOI: 10.56845/rebs.v2i2.22
E. S. Rosas-Mendoza, Diana Nava-Pacheco, Inés Adriana Juárez-García, Ofelia Landeta-Escamilla, S. del Moral
The use of fossil fuels is losing versus the use renewable energy sources such as biomass and biogas, due to the environmental impacts that they generate. In Mexico, Veracruz has an area of 7.24 x 106 hectares, representing 3.7% of the national area, being the main provider of agroindustrial products due to its diversity of ecosystems. The objective of this paper is to evaluate the bioenergy potential of organic solid waste generated from the main agroindustrial products of the state of Veracruz. To carry out this research, ten main crops of Veracruz were selected through a literature review, determining the percentage of waste generation and heating value of each of them. With the previous data, the tons of agroindustrial waste and the bioenergy potential were estimated. Finally, the total bioenergy potential of agroindustrial wastes was calculated. As part of the results, Veracruz produces approximately 25.5 x 106 tons of agroindustrial products made up of sugarcane, orange, lemon, pineapple, coffee, banana, grapefruit, watermelon, rice and pear. Derived from the ago-industrial activity, 6.97 x 106 tons of waste are generated annually, being the sugarcane waste the most with 75% equivalent to 5.28 x 106 tons, followed by citrus around 0.98 x 106 tons. Likewise, and as a consequence of agroindustrial waste, Veracruz has a bioenergy potential close to 130.00 PJ per year, which would place it as the largest supplier of renewable energy from biomass.
由于化石燃料产生的环境影响,与使用生物质和沼气等可再生能源相比,化石燃料的使用正在减少。在墨西哥,韦拉克鲁斯州的面积为7.24 x 106公顷,占全国面积的3.7%,由于其生态系统的多样性,成为农工产品的主要供应地。本文的目的是评估维拉克鲁斯州主要农工产品产生的有机固体废物的生物能源潜力。为了进行这项研究,通过文献综述,选择了韦拉克鲁斯州的十种主要作物,确定了每种作物的废物产生率和热值。在此基础上,对我国农工废弃物吨数和生物能源潜力进行了估算。最后,计算了工农业废弃物的总生物能源潜力。作为成果的一部分,韦拉克鲁斯州生产了大约25.5 x 106吨的农业工业产品,包括甘蔗、橙子、柠檬、菠萝、咖啡、香蕉、葡萄柚、西瓜、大米和梨。源自农业工业活动,每年产生6.97 x 106吨废物,其中甘蔗废物最多,占75%,相当于5.28 x 106吨,其次是柑橘,约0.98 x 106吨。同样,由于农业工业废弃物的影响,韦拉克鲁斯的生物能源潜力接近每年130.00 PJ,这将使其成为最大的生物质可再生能源供应商。
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引用次数: 1
Use of nanotubular TiO2 films for the photo-degradation of emerging contaminants (drugs) in water 纳米管TiO2薄膜用于水中新出现的污染物(药物)的光降解
Pub Date : 2022-07-08 DOI: 10.56845/rebs.v2i2.24
Kendra Martínez-Flores, S. Ortíz-Gómez, P. Mijaylova-Nacheva, C. Cuevas-Arteaga
 Provide in a single paragraph of 300 words maximum an overview of the work, including background, methodology, main results, and conclusions.  One of the biggest problems of the 21st century is perhaps the need to provide water for the growing world population. Faced with this global problem around water, pollution is a factor of great importance, since the pollutants generated by industrial and domestic activity can be accumulated and transported by both surface and underground waters, deteriorating their quality. Therefore, it is necessary to study the behavior of these pollutants in water and propose treatment techniques that can eliminate them. Regarding water treatment techniques, it has been shown that heterogeneous photocatalysis with TiO2 is a clearly effective and environmentally an advantageous alternative for the removal of organic substances in aqueous media. In photocatalysis degradation processes, the analysis of the influence of the surface phenomena on the degradation reactions is of special interest. In the present work, the preparation of TiO2 self-ordered nanotubular films was carried out by means of the electrochemical anodization technique using the electrolyte: 50% Vol. Glycerol + 50% Vol. H2O + NH4F [0.27M), to be utilized in a Photocatalytic Reactor (FR) for the photodegradation of Metoprolol in order to evaluate the efficiency of the heterogeneous photocatalytic as an Advanced Oxidation Processes (AOP) through the photodegradation of the emerging pollutant under study and determine the efficiency of the photodegradation through the technique of gas chromatography coupled to mass spectrometry (GC-MS).
在不超过300字的一段话内概述工作,包括背景、方法、主要结果和结论。21世纪最大的问题之一可能是需要为不断增长的世界人口提供水。面对这个围绕水的全球性问题,污染是一个非常重要的因素,因为工业和家庭活动产生的污染物可以通过地表水和地下水积累和运输,从而使其质量恶化。因此,有必要研究这些污染物在水中的行为,并提出可以消除它们的处理技术。在水处理技术方面,研究表明,TiO2的多相光催化是一种明显有效且环境有利的水介质中有机物去除方法。在光催化降解过程中,分析表面现象对降解反应的影响具有特殊的意义。在本工作中,利用电解液,采用电化学阳极氧化技术制备TiO2自有序纳米管薄膜:50% Vol. Glycerol + 50% Vol. H2O + NH4F [0.27M],在光催化反应器(FR)中进行美托洛尔的光降解,以评价多相光催化作为一种高级氧化工艺(AOP)通过光降解所研究的新兴污染物的效率,并通过气相色谱-质谱联用(GC-MS)技术确定光降解效率。
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引用次数: 0
Influence of light intensity on growth and flowering ornamental plants in constructed wetlands 光照强度对人工湿地开花观赏植物生长的影响
Pub Date : 2022-07-08 DOI: 10.56845/rebs.v2i2.25
Luis Carlos Sandoval-Herazo, A. Alvarado-Lassman, Graciela Nani, Carlos Nakase-Rodríguez
Light is an indispensable source for the photosynthesis of plants, but also for their growth and development. On the other hand, the production of ornamental plants requires multiple nutrients for their proper development, a source available in high concentrations in wastewater. Recent research on constructed wetlands (CWs) that use ornamental plants to treat wastewater and at the same time are used as a means of growth, is considered a sustainable alternative. This study evaluated the influence of light intensity on the growth and flowering of ornamental plants (Lavandula sp., Anthurium sp., Zantedeschia aethiopica and Spathiphyllum wallisii) in constructed wetlands, fed with domestic wastewater. 30 mesocosms of constructed wetlands were used as a culture medium for ornamental plants, the effect of light intensity on the development of the plants was measured, as well as the removal of Nitrogen (N-NO3), phosphate (P-PO4) and biochemical demand of oxygen (DBQ5). The plants were able to adapt and grew healthy in the three-support media with the exception of  Lavandula sp., which did not survive in any of the systems, showing that in the months when the light intensity was higher, a higher growth rate was reached to 9.5 % on average. In terms of the removal of N-NO3 (45- 60%), P-PO4 (20-23%) and COD5 (60-85%), no significant differences were found between any of the substrates. The above allows us to affirm that CWs, are suitable means for cultivation of ornamental plants and the development of them is favored with intensities of light in ranges from 720 to 856 µmol · m −2 · s −1, On the other hand, the substrates used proved to be efficient to remove contaminants, but at the same time to facilitate the healthy development of the used ornamental vegetation, with the exception of the lavender sp. Research is required to evaluate the effects of light intensity on the production of ornamental plants in controlled environments.
光是植物光合作用不可缺少的来源,也是植物生长发育的必要条件。另一方面,观赏植物的生产需要多种营养物质才能正常发育,这是废水中高浓度的一种来源。人工湿地(CWs)利用观赏植物处理废水,同时作为一种生长手段,被认为是一种可持续的替代方案。本研究以生活污水为饵料,研究了光照强度对人工湿地观赏植物Lavandula sp., Anthurium sp., Zantedeschia aethiopica和Spathiphyllum wallisii生长和开花的影响。以30个人工湿地为培养基,研究了不同光照强度对观赏植物生长发育的影响,以及对氮(N-NO3)、磷酸盐(P-PO4)和生化需氧量(DBQ5)的去除情况。除Lavandula sp.不能在任何一种体系中存活外,植株都能适应并健康生长,表明在光照强度较高的月份,植株的平均生长率达到9.5%。在N-NO3(45- 60%)、P-PO4(20-23%)和COD5(60-85%)去除率方面,不同底物间无显著差异。综上所述,在720 ~ 856µmol·m−2·s−1的光照强度范围内,CWs是一种适宜的观赏植物栽培手段,有利于观赏植物的生长发育。另一方面,所使用的基质在有效去除污染物的同时,也有利于观赏植物的健康发育。在受控环境下,光强对观赏植物生产的影响需要进行研究。
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引用次数: 1
Improved bio-oil yield and quality through fast pyrolysis and fractional condensation concepts 通过快速热解和分馏冷凝的概念提高了生物油的收率和质量
Pub Date : 2022-07-07 DOI: 10.56845/rebs.v2i1.21
Brenda J. Alvarez-Chavez, S. Godbout, Étienne Le Roux, J. Palacios, V. Raghavan
Fast pyrolysis is a thermochemical process capable of producing biofuels that can replace fossil fuels. Pyrolytic oil can be used for electricity production, heating and chemical extraction (Fu et al., 2017; Kalargaris et al., 2017). However, the quality of bio-oil is limited by its low chemical stability associated with aging, low calorific value, high water content, high viscosity and high acidity (Alvarez-Chavez et al., 2019; Carpenter et al., 2014). Therefore, it is necessary to improve the quality of bio-oil before its use in our daily life. This study provides the evaluation of the effect of the operating conditions of a pyrolyzer reactor and its condensing system on the quality and yield of bio-oil. Response surface analysis was applied to optimize the quality and yield of bio-oil using four operational variables of the pyrolyzer. As a result, statistical models corresponding to the studied responses were obtained.
快速热解是一种热化学过程,能够生产出替代化石燃料的生物燃料。热解油可用于发电、加热和化工提取(Fu et al., 2017;Kalargaris et al., 2017)。然而,生物油的质量受到老化相关的低化学稳定性、低热值、高含水量、高粘度和高酸度的限制(Alvarez-Chavez et al., 2019;Carpenter et al., 2014)。因此,在我们日常生活中使用生物油之前,有必要提高生物油的质量。研究了热解反应器及其冷凝系统的操作条件对生物油质量和产率的影响。采用响应面分析法对热解装置的4个操作变量进行了优化。得到了与所研究的响应相对应的统计模型。
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引用次数: 0
Development of regio-regular poly(3-hexylthiophene) by direct arylation using Fagnou's conditions. 利用 Fagnou 条件通过直接芳基化技术开发出区域规则聚(3-己基噻吩)。
Pub Date : 2022-07-07 DOI: 10.56845/rebs.v2i1.20
Itzel Argemi Cacique-Espinoza, M. Güizado-Rodríguez, Miriam Rangel-Ayala, V. Barba, J. Maldonado-Rivera
Semiconducting polymers are widely studied due to their applications in photovoltaic devices, the predominant conjugated polymer used in organic solar cells (OSCs) is semicrystalline poly(3-hexylthiophene) P3HT, which can be produced by easy, low-cost and environmentally friendly methods such as direct arylation polymerization (DArP) (N.S. Gobalasingham et al. 2018). Due to its solution processing, deposition on different types of substrates, even flexible, with technologies such as spin coating and roll to roll, it is a feasible option for large-scale production. In this work we present the synthesis, physicochemical characterization of a regio- regular P3HT by the direct arylation method using Fagnou conditions and its evaluation on the active layer of OSCs with bulk heterojunction architecture.
半导体聚合物因其在光伏设备中的应用而被广泛研究,有机太阳能电池(OSC)中使用的主要共轭聚合物是半结晶聚(3-己基噻吩)P3HT,它可以通过直接芳基化聚合(DArP)等简单、低成本和环保的方法生产(N.S. Gobalasingham 等人,2018 年)。由于其溶液加工、在不同类型基底上沉积(甚至是柔性基底)以及旋涂和卷对卷等技术,它是大规模生产的可行选择。在这项工作中,我们介绍了在法格努条件下通过直接芳基化方法合成的规整 P3HT 及其物理化学特性,并对其在具有体异质结结构的 OSC 活性层上的应用进行了评估。
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引用次数: 0
Biosorption of hexavalent chromium using nanche (Byrsonima crassifolia L.) by-product 南树副产物对六价铬的生物吸附
Pub Date : 2022-07-07 DOI: 10.56845/rebs.v2i1.14
J. M. Sanchez-Silva, Ángel Fonseca-Cantabrana, R. González-Estrada, F. Blancas-Benitez
Water contamination by heavy metals is generally caused by anthropic activities, with industry being the main source of contamination. The tannery is one of them, since it uses hexavalent chromium salts [Cr (VI)] in the process, and when its effluents are poorly treated, they irremediably damage water bodies and their consumption can have negative effects on human health, such as renal dysfunction and cancer of the digestive tract. Biosorption is an alternative method for the treatment of effluents contaminated with Cr (VI), which consists of using biomass as adsorbent, preferably agro-industrial wastes which, possessing functional groups on their surface and pores, are susceptible to binding with Cr (VI) through mechanisms such as complexation (Al-Homaidan et al., 2018). The nanche fruit (Byrsonima crassifolia L.) has economic importance due to its commercial production, the Agroindustrial and Fisheries Information Service (SIAP) reported in 2016 a production of 7.1 thousand tons of which 0.781 thousand tons of waste were generated considering that 11% of the fruit corresponds to the endocarp which is considered a byproduct (SIAP, 2018), according to the above; using the byproduct as a bioadsorbent develops a new route for its utilization.
水体重金属污染一般是人为活动造成的,工业是污染的主要来源。制革厂就是其中之一,因为它在生产过程中使用六价铬盐[Cr (VI)],当其废水处理不当时,它们会对水体造成不可挽回的损害,并且它们的消耗会对人体健康产生负面影响,例如肾功能障碍和消化道癌症。生物吸附是一种处理被Cr (VI)污染的废水的替代方法,它包括使用生物质作为吸附剂,最好是农业工业废物,其表面和孔隙上具有官能团,容易通过络合等机制与Cr (VI)结合(al - homaidan等人,2018)。由于其商业化生产,南车水果(Byrsonima crassifolia L.)具有经济重要性,农业工业和渔业信息服务处(SIAP)在2016年报告了71000吨的产量,其中产生了0.781万吨废物,考虑到11%的水果对应于被认为是副产品的内果皮(SIAP, 2018)。利用副产物作为生物吸附剂为其开发利用开辟了一条新的途径。
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引用次数: 0
Obtaining humic substances from a carbonaceous industrial residue 从含碳工业残渣中提取腐殖质物质
Pub Date : 2022-07-07 DOI: 10.56845/rebs.v2i1.17
V. Suárez-Toriello, Z. Y. Méndez-Martínez, J. I. Cervantes-Arista, M. F. López-Núñez, Liliana Villafaña-López, Juan José Quiroz- Ramírez, R. Guerra-Sánchez
In the refining of bio- and petro-oils, solid carbonaceous residues are obtained whose final destination is combustion. It is possible to take advantage of these residues through the oxidation technique in an aqueous medium, producing soluble oxygenated organic compounds, analogous to humic substances: humic acids, fulvic acids and humins (Ashtari, et al., 2016). Humic substances possess a large amount of phenolic and carboxylic groups, which provide them with characteristics for crop development. These include colloidal action on clays, ion exchange capacity, chelating action for metal capture and stimulation of soil micro-fauna and -flora. Additionally, they can be used in the formulation of lubricants, adsorbents and fuels (Martinez et al., 2013). This work explores the transformation of the carbonaceous residue of heavy oil coking, through its oxidation in an aqueous medium for the production of soluble organic compounds, with potential application in soil improvement and other applications, in such a way that it contributes to increase sustainability in the hydrocarbon production chain.
在生物油和石油的精炼过程中,得到固体碳质残留物,其最终归宿是燃烧。可以通过在水介质中的氧化技术利用这些残留物,产生可溶性含氧有机化合物,类似于腐植酸物质:腐植酸、黄腐酸和腐植酸(Ashtari, et al., 2016)。腐殖质具有大量的酚基和羧基,为作物的发育提供了特性。这些包括对粘土的胶体作用、离子交换能力、金属捕获的螯合作用和对土壤微动植物群的刺激。此外,它们还可用于润滑油、吸附剂和燃料的配方中(Martinez et al., 2013)。这项工作探索了重油焦化后碳质残渣的转化,通过其在水介质中的氧化产生可溶性有机化合物,在土壤改良和其他应用中具有潜在的应用前景,从而有助于提高碳氢化合物生产链的可持续性。
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引用次数: 0
Life extension of biobeds for the remediation of pesticide-contaminated wastewater in banana crops 香蕉作物农药污染废水修复中生物床延长寿命的研究
Pub Date : 2022-07-07 DOI: 10.56845/rebs.v2i1.19
E. Baltierra-Trejo, R. Adams, V. Domínguez-Rodríguez
For the control of the fungus Mycosphaerella fijiensis in banana crops, between 42 to 50 applications of 2 kg ha-1 yr-1 of the fungicide ethylenebisdithiocarbamate (EBDC) are made. However, due to occasional spills during handling, there is a risk of contamination of surface and groundwater (Geissen et al. 2010). One mitigation alternative is the use of biobeds that facilitate adsorption and degradation of the contaminant (Torstensson 2000). However, research is required on the parameters that affect the degradation of xenobiotics within biobeds, such as the appropriate proportion of substrates in the bio-mixture (Karanasios et al. 2012). The objective of this research was to evaluate the reduction of toxicity in EBDC-contaminated leachates using mixtures based on organic substrates available at the cultivation sites.
为了控制香蕉作物中的斐济真菌,杀菌剂乙二硫代氨基甲酸乙酯(EBDC)每年施用42至50次,每次2公斤/年。然而,由于在处理过程中偶尔发生泄漏,有污染地表和地下水的风险(Geissen et al. 2010)。一种缓解办法是使用生物床,促进污染物的吸附和降解(Torstensson, 2000年)。然而,需要对影响生物床内异种生物降解的参数进行研究,例如生物混合物中底物的适当比例(Karanasios et al. 2012)。本研究的目的是评估在种植场地使用基于有机基质的混合物来降低ebdc污染的渗滤液的毒性。
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引用次数: 0
Is informal charcoal production necessarily unsustainable? A comparison of three oak management systems in the central Mexican Sierras. 非正式的木炭生产一定不可持续吗?墨西哥中部塞拉斯三种橡树管理系统的比较。
Pub Date : 2022-07-07 DOI: 10.56845/rebs.v2i1.18
Javier Guzmán-Sánchez, T. Mwampamba
A steady increase in charcoal production as an energy source is expected (FAO, 2017). Its negative effects due to above-ground biomass removal (BSS) suggest favoring conservation (Lee and Lautenbach, 2016; Monárrez- González, et.al., 2018). However, sustainable forest management [SFM] allows considering charcoal as a renewable source of energy (Antinori and Rausser, 2010; Camou-Guerrero, et.al., 2014; Sist, et.al., 2014; Aguirre-Calderón, 2015; FAO, 2017; Ramírez, 2017). Mexican regulations focus SFM on functionality, industrialization and large scale (Antinori and Rausser, 2010; Deschamps and Madrid, 2018; Cravioto, 2019); informality is considered unsustainable due to irregular and poor management practices (Sist, et.al., 2014; Monárrez- González, et.al., 2018). We analyzed impacts of three oak management systems on tons of BSS: [1] conservation, [2] formal production, and [3] informal production; influenced by [1] advantageous (nursery), and [2] disadvantageous (drying shed) biophysical conditions. We focused on verifying the existence of differences in BSS and structure between systems and conditions. With such analysis, we reconsider the bias towards conserving and the dismissal of informality as unsustainable.
预计作为能源的木炭产量将稳步增长(粮农组织,2017年)。由于地上生物量去除(BSS),其负面影响表明有利于保护(Lee和Lautenbach, 2016;Monárrez- González等。, 2018)。然而,可持续森林管理[SFM]允许将木炭视为可再生能源(Antinori和Rausser, 2010;Camou-Guerrero,出版社。, 2014;认定,出版社。, 2014;Aguirre-Calderon, 2015;粮农组织,2017;拉米雷斯,2017)。墨西哥法规将SFM重点放在功能性、工业化和大规模(Antinori和Rausser, 2010;德尚和马德里,2018;Cravioto, 2019);由于不规范和不良的管理做法,非正式被认为是不可持续的(Sist等)。, 2014;Monárrez- González等。, 2018)。我们分析了三种橡木管理制度对BSS吨数的影响:[1]保护、[2]正规生产和[3]非正规生产;受[1]有利(苗圃)和[2]不利(干棚)生物物理条件的影响。我们的重点是验证系统和条件之间的BSS和结构是否存在差异。有了这样的分析,我们重新考虑对保护和解雇非正式的不可持续的偏见。
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引用次数: 0
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