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Rheology of new lubricating greases made from renewable materials 由可再生材料制成的新型润滑脂的流变学
Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.2478/auoc-2023-0012
Olga V. Săpunaru, Ancaelena E. Sterpu, Cyrille Alode Vodounon, Sibel Osman, Claudia I. Koncsag
Abstract Lubricanting greases from waste frying vegetables oils with natural fibers additives could be the answer to the sustainable production of greases. Also, their biodegradability makes them more acceptable for the environment, having in view increasingly strict regulations in domain. In this experimental work, twenty lubricant formulae were created from waste sunflower oil and waste palm oil with calcium or lithium stearate as thickener and cellulose or lignin additives. All were rheologically tested and characterized as Bingham fluid with good consistency and plasticity. The penetration tests confirmed the good consistency, categorizing these products from normal to firm, very firm and hard lubricant greases comparable to those conventionally obtained from mineral oils.
从废油炸植物油中添加天然纤维添加剂制备润滑脂可能是油脂可持续生产的解决方案。此外,鉴于该领域日益严格的法规,它们的生物降解性使它们更容易为环境所接受。本实验以废葵花籽油和废棕榈油为原料,以硬脂酸钙或锂为增稠剂,纤维素或木质素为添加剂,制备了20种润滑油配方。经流变学测试,均为Bingham流体,具有良好的稠度和可塑性。渗透测试证实了良好的一致性,将这些产品分为普通、坚固、非常坚固和坚硬的润滑脂,与传统的矿物油相媲美。
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引用次数: 0
GC-MS profile and antimicrobial activities of extracts from root of Senna occidentalis Linn. 西番泻根提取物的气相色谱-质谱分析及抑菌活性研究。
Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.2478/auoc-2023-0009
Ngozi Francesca Amako, Mary-Ann Nkoli Mgbemena, Sunday Peter Odo
Abstract We considered the extraction of plant materials from Senna occidentalis root, and its fractionation monitored by bioassay towards isolating its bioactive principles. Pulverized root sample of Senna occidentalis (fam. leguminaceae) was extracted with methanol using a maceration method. The crude methanol extract (MSo) 6.06 g was partitioned into petroleum ether and ethyl acetate to yield their respective fractions viz: petroleum ether fraction (1.20 g), ethyl acetate fraction (1.86 g) and methanol fraction (2.92 g). The crude methanol extract was analyzed using phytochemical screening, infrared spectroscopy, and gas chromatography/mass spectrometry while the fractions were examined for antimicrobial properties. Phytochemical screening indicated the presence of tannins, phenolics, alkaloids, flavonoids, saponins, cardiac glycosides, phlobatannin, and absence of steroids. The infrared spectrum revealed a broad absorption band at 3437.26 cm -1 due to O-H symmetric stretch in polymeric alcohols, and absorption frequency of 1640.51cm -1 of moderate intensity due to C=O stretch. Enols are easily identified by the broad H-bonded O-H stretch absorption and low C=O stretch frequency as in β-keto enolic esters and phenol acetates, -CO-O-C=C-, (1690-1650 cm -1 ). Gas chromatography/mass spectrometry identified the presence of ten compounds including n -hexadecanoic acid (23.76%), linoleic acid (1.64%), E-9-tetradecenoic acid (4.88%), octadecanoic acid, 2-(2 hydroxyethoxy) ethyl ester (6.24%) and E-2-octadecadecen-1-ol (13.74%). Similar broad spectrum antimicrobial activities were manifested by methanol and ethyl acetate fractions. Escherichia coli and Bacillus cereus were the most susceptible with the highest zone of inhibition of 30 mm and 28 mm respectively at minimum inhibition concentration of 1.35 x10 3 μg/ml. The methanol fraction has the highest potency against the tested pathogens whereas the petroleum ether fraction exhibited activity only on gram negative pathogens. The antimicrobial activities observed in these fractions suggest the presence of active chemical components in the crude methanol root extract of Senna occidentalis thus provides a potential source of novel antimicrobial agents. Further work is however, required to isolate and characterize these bioactive principles.
摘要:本文研究了从西泻根中提取植物物质,并对其进行生物测定监测,以分离其生物活性成分。西番泻根粉碎样品。豆科植物,用甲醇浸渍法提取。将粗甲醇提取物(MSo) 6.06 g拆分为石油醚和乙酸乙酯,分别得到石油醚(1.20 g)、乙酸乙酯(1.86 g)和甲醇(2.92 g)馏分,采用植物化学筛选、红外光谱、气相色谱/质谱等方法对粗甲醇提取物进行分析,并对各馏分进行抗菌性能测定。植物化学筛选表明存在单宁、酚类、生物碱、黄酮类、皂苷、心糖苷、酞菁蛋白,不存在类固醇。红外光谱显示,在3437.26 cm -1处,聚合物醇由于O- h对称拉伸形成了较宽的吸收波段;在1640.51cm -1处,由于C=O拉伸形成了中等强度的吸收频率。烯醇具有宽的h键O- h拉伸吸收和低的C=O拉伸频率,如β-酮烯醇酯和酚乙酸酯,- co -O-C=C-, (1690-1650 cm -1)。气相色谱/质谱分析鉴定出n-十六烷酸(23.76%)、亚油酸(1.64%)、e -9-十四烯酸(4.88%)、十八烷酸、2-(2 -羟基乙氧基)乙酯(6.24%)和e -2-十八烯-1-醇(13.74%)等10种化合物。甲醇和乙酸乙酯组分具有相似的广谱抗菌活性。对大肠杆菌和蜡样芽孢杆菌最敏感,最小抑制浓度为1.35 × 10.3 μg/ml,最大抑制区分别为30 mm和28 mm。甲醇组分对被试病原菌的活性最高,而石油醚组分仅对革兰氏阴性病原菌有活性。在这些馏分中观察到的抗菌活性表明,在西叶麻粗甲醇根提取物中存在有效的化学成分,从而提供了一种新型抗菌药物的潜在来源。然而,需要进一步的工作来分离和表征这些生物活性原理。
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引用次数: 0
Solubility of acetaminophen in the ethanol and glycerol mixtures at different temperatures 对乙酰氨基酚在不同温度下乙醇和甘油混合物中的溶解度
Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.2478/auoc-2023-0013
Nafiseh Gholizadeh, Jalal Hanaee, Elaheh Rahimpour, Abolghasem Jouyban
Abstract Acetaminophen solubility in the glycerol and ethanol mixture was determined by a simple shake-flask technique at different temperatures and fitted to some mathematical models and the models’ accuracy was investigated by the computation of the mean relative deviations. The densities of acetaminophen saturated mixtures were also studied by the Jouyban-Acree model. Moreover, the Gibbs and van’t Hoff equations were utilized to compute apparent thermodynamic parameters of the acetaminophen dissolving.
摘要采用简单摇瓶法测定了对乙酰氨基酚在不同温度下在甘油和乙醇混合物中的溶解度,并拟合了数学模型,计算了模型的平均相对偏差,考察了模型的准确性。对乙酰氨基酚饱和混合物的密度也用Jouyban-Acree模型进行了研究。利用Gibbs方程和van 't Hoff方程计算了对乙酰氨基酚溶解的表观热力学参数。
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引用次数: 0
End-of-life mobile phones parts contain toxic metals that make them hazardous, but can also serve as resource reserves for such metals 报废的手机零件含有有毒金属,使它们变得危险,但也可以作为这些金属的资源储备
Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.2478/auoc-2023-0011
Bukola Omoyemi Abiodun, Paschal Okiroro Iniaghe
Abstract In this study, the concentration of some toxic metals in different parts of end-of-life mobile phones was assessed. Twenty end-of-life mobile phones of different brands and countries of origin, which were widely in use up to the year 2011, were collected from phone repair workshops in Lagos, Nigeria. The collected mobile phones were disassembled into the phone screens, printed wiring boards, plastic casings and batteries. Disassembled parts were individually milled and pulverized, and digested using HCl, HNO 3 and H 2 O 2 . Flame atomic absorption spectrometry was used to quantify some toxic metals (Pb, Cd and Ni) in the digested samples, and the determined concentrations were compared with permissible limits. The average metals concentration in the disassembled parts followed the order: printed wiring boards > batteries > plastic casings > phone screens. The concentrations of Pb and Ni exceeded their toxicity threshold limit concentration in printed wiring boards, while Ni exceeded the limit concentration in batteries. Based on the maximum permissible concentration required by the Restriction of Hazardous Substances (RoHS) Directives, all Cd concentrations were below the limit concentration; Pb and Ni in printed wiring boards exceeded their limit concentrations, while Ni exceeded its permissible concentration in batteries. The results of this study indicate that printed wiring boards and batteries of end-of-life mobile phones are hazardous, and their improper disposal of could cause environmental and health problems. However, considering the very high concentrations of Pb and Ni, these mobile phone parts could serve as resource reserves for these metals.
摘要本研究对废旧手机不同部位的有毒金属浓度进行了评估。从尼日利亚拉各斯的手机维修车间收集了20部不同品牌和原产国的报废手机,这些手机在2011年之前被广泛使用。收集到的手机被拆解成手机屏幕、印刷线路板、塑料外壳和电池。将拆下的零件分别进行研磨和粉碎,用HCl、hno3和h2o2消化。采用火焰原子吸收光谱法对消化样品中的有毒金属(Pb、Cd、Ni)进行了定量分析,并将测定浓度与允许限量进行了比较。拆解零件中的平均金属浓度顺序为:印制板>电池比;塑料外壳;手机屏幕。印刷线路板中Pb、Ni浓度超过毒性阈值,电池中Ni浓度超过毒性阈值。根据有害物质限制(RoHS)指令要求的最大允许浓度,所有Cd浓度均低于限制浓度;印刷线路板中铅、镍超标,电池中镍超标。这项研究的结果表明,报废手机的印刷线路板和电池是危险的,它们的不当处理可能会造成环境和健康问题。然而,考虑到铅和镍的浓度非常高,这些手机部件可以作为这些金属的资源储备。
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引用次数: 0
Novel chalcone analogs derived from 4-(benzyloxy)benzaldehyde 源自 4-(苄氧基)苯甲醛的新型查尔酮类似物
IF 0.9 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.2478/auoc-2023-0015
Mihaela Balan-Porcăraşu, Gheorghe Roman
Abstract Eight chalcone analogs were prepared through an aldol condensation starting from 4-(benzyloxy)benzaldehyde and either less common acetophenones or a few selected heteroaryl methyl ketones. The reaction has been performed through the classical approach that employs an alkali as catalyst for five chalcone analogs, while a variant that uses piperidine as basic catalyst was employed for the other three chalcone analogs. The structure of the resulting enones has been established by NMR spectroscopy. Photoinduced dimerization of a selected benzyloxy-substituted chalcone analog under irradiation with UV light for periods of time ranging from 30 minutes to 24 h has also been monitored using NMR spectroscopy. Analysis of the results demonstrated the presence of the E isomer of the chalcone analog along with three regioisomeric cyclobutanes in the irradiated sample.
摘要 以 4-(苄氧基)苯甲醛和不太常见的苯乙酮或一些精选的杂芳基甲基酮为起始原料,通过醛醇缩合反应制备了八种查尔酮类似物。五种查尔酮类似物的经典反应方法是使用碱作为催化剂,而另外三种查尔酮类似物则使用哌啶作为碱性催化剂。核磁共振光谱确定了所生成烯酮的结构。此外,还利用核磁共振光谱监测了在紫外光照射 30 分钟至 24 小时期间,选定的苄氧基取代查尔酮类似物的光诱导二聚化情况。对结果的分析表明,在辐照样品中存在查尔酮类似物的 E 异构体和三种 Regioisomeric cyclobutanes。
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引用次数: 0
Eco-friendly and efficient monitoring of physico-chemical parameters of some mineral water from Slanic Moldova (Romania) during storage in different conditions – a case study 对来自罗马尼亚Slanic Moldova的一些矿泉水在不同条件下储存期间的物理化学参数进行生态友好和有效的监测-一个案例研究
Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.2478/auoc-2023-0010
Lavinia Misaila, Narcis Barsan, Dumitra Raducanu, Luminita Grosu, Oana-Irina Patriciu, Irina-Claudia Alexa, Adriana-Luminita Finaru
Abstract In this study, six natural mineral waters (from sources named 1bis, 5, 10, 14, 15, “Sonda 2”) with therapeutic potential from Slanic Moldova area (Romania) were assessed for physico-chemical parameters during storage in different conditions (bottled in PET or glass containers and kept at 20-22 °C or 4 °C) for a period of maximum 360 days. The main parameters investigated were pH, conductivity, total dissolved solids, salinity, as well as the major ions (Na + , K + , Ca 2+ , Mg 2+ , F − , Cl − , SO 4 2− , HCO 3 − ), using fast and environmentally friendly instrumental techniques (electrochemical and spectrometric / UV-Vis and ICP-MS). The physico-chemical indicators were measured at six time intervals (within 24 hours, after 7, 30, 90, 180 and 360 days) and the results obtained indicated that the pH variation was significant for the majority of samples kept at room temperature in PET containers (between 0.4 pH units - Spring 15 and over 2 pH units - springs 10, 14, 1bis and 5), while cold storage is most favorable for all natural mineral water samples. The monitoring of the chemical parameters determined during cold storage in glass containers did not reveal statistically significant variations and therefore it can be considered that these natural mineral waters are characterized by the stability of the chemical composition. For the entire analyzed period, the smallest variations of all twelve analyzed parameters were recorded for “Sonda 2”, in all storage conditions, followed by springs 1bis, 15, 14, 10 and 5 stored at 4 °C in glass containers.
在本研究中,研究人员对来自罗马尼亚Slanic Moldova地区的6种具有治疗潜力的天然矿泉水(来源分别为1bis、5、10、14、15、“Sonda 2”)在不同条件下(瓶装于PET或玻璃容器中,在20-22°C或4°C下保存)最长360天的物理化学参数进行了评估。研究的主要参数是pH、电导率、总溶解固形物、盐度以及主要离子(Na +、K +、ca2 +、Mg 2+、F−、Cl−、so_2−、HCO 3−),采用快速环保的仪器技术(电化学和光谱/ UV-Vis和ICP-MS)。在6个时间间隔(24小时内,7、30、90、180和360天)测量了理化指标,结果表明,室温下保存在PET容器中的大多数样品(pH值在0.4单位之间- Spring 15和超过2单位- Spring 10、14、1bis和5)的pH值变化显著,而冷藏对所有天然矿泉水样品最有利。在玻璃容器冷藏期间测定的化学参数的监测没有显示统计学上显著的变化,因此可以认为这些天然矿泉水的特征是化学成分的稳定性。在整个分析期间,“Sonda 2”在所有储存条件下记录的所有12个分析参数的变化最小,其次是弹簧1bis、15、14、10和5在4°C的玻璃容器中储存。
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引用次数: 0
Xylopia aethiopica HPLC-DAD polyphenol profiling and antioxidant status from South-South region of Nigeria 尼日利亚南部地区的 Xylopia aethiopica HPLC-DAD 多酚分析和抗氧化状况
IF 0.9 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.2478/auoc-2023-0014
J. Okpoghono, E. Osioma, Sandra Oghenekohwo Metie, Udoka Bessie Igue, Endurance Fegor Isoje, S. U. Okom
Abstract To fill nutrient gaps, supplements are employed in the field of nutrition. The spice Xylopia aethiopica grows wild in many African countries and has been used as flavouring for soups. This study evaluates the polyphenols and antioxidant profile of different fractions of X. aethiopica methanol extract. Powdered sample of X. aethiopica (250 g) was suspended in methanol (1.5 litre) for 48 hours and the extract was concentrated at 45 °C using water bath to obtain methanol crude extract which was fractionated into n-hexane (n-Hex), chloroform (Chl), diethyl ether (DEE), n-butanol (n-Bu) and aqueous fractions using liquid- liquid partition separation technique. Antioxidant properties were investigated using standard methods and the polyphenols were estimated using high performance liquid chromatography with diodearray detector (HPLC-DAD). Results revealed that the DEE fraction had significantly (p < 0.05) high total phenol content (TPC), proanthocyanidins, anthocyanins, 1,1-diphenyl-2-picrylhidrazyl (DPPH) radical scavenging, ferric reducing antioxidant power (FRAP) and total antioxidant capacity (TAC) as compared with other fractions. The highest luteolin and taxifolin content was detected in n-Hex fraction. Polyphenols found in DEE fraction in the established HPLC-DAD assay were p-anisic acid (0.07 ng/g), caffeic acid (0.56 ng/g), vanillic acid (0.91 ng/g), salicylic acid (1.64 ng/g), gallic acid (3.09 ng/mL), ferulic acid (3.64 ng/g), p-coumaric acid (5.15 ng/g), sinapinic acid (6.63 ng/g) and protocatechuic acid (24.89 ng/g). The different fractions of X. aethiopica displayed various polyphenols potential with probable antioxidant activity, which may be useful in neutralizing free radicals and the treatment of chronic inflammatory associated metabolic ailments, such as obesity and diabetes.
摘要 为了填补营养缺口,营养学领域使用了补充剂。香料 Xylopia aethiopica 野生生长在许多非洲国家,一直被用作汤的调味料。本研究评估了 X. aethiopica 甲醇提取物不同部分的多酚和抗氧化特性。将 X. aethiopica 的粉末样品(250 克)悬浮在甲醇(1.5 升)中 48 小时,然后在 45 °C 水浴条件下浓缩提取物,得到甲醇粗提取物,再利用液-液分离技术将其分成正己烷(n-Hex)、氯仿(Chl)、二乙醚(DEE)、正丁醇(n-Bu)和水馏分。采用标准方法对其抗氧化性进行了研究,并使用高效液相色谱法和二极管射线检测器(HPLC-DAD)对多酚进行了估算。结果显示,与其他馏分相比,DEE馏分的总酚含量(TPC)、原花青素、花青素、1,1-二苯基-2-苦基肼(DPPH)自由基清除能力、铁还原抗氧化能力(FRAP)和总抗氧化能力(TAC)都明显较高(p < 0.05)。正己烷馏分中的木犀草素和紫杉叶素含量最高。在已建立的 HPLC-DAD 试验中,DEE 部分的多酚含量分别为对甲氧基苯甲酸(0.07 纳克/克)、咖啡酸(0.56 纳克/克)、香草酸(0.91 纳克/克)、水杨酸(1.64 纳克/克)、没食子酸(3.09 纳克/毫升)、阿魏酸(3.64 纳克/克)、对香豆酸(5.15 纳克/克)、山奈酸(6.63 纳克/克)和原儿茶酸(24.89 纳克/克)。X. aethiopica 的不同馏分显示出各种多酚的潜力,可能具有抗氧化活性,可用于中和自由基和治疗与慢性炎症相关的代谢疾病,如肥胖症和糖尿病。
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引用次数: 0
Unlocking the chemistry and properties of oil-containing sludge for potential utilization 揭示含油污泥的化学性质及其潜在利用价值
IF 0.9 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.2478/auoc-2023-0005
S. Tang, Lin Zhi Lee, A. Arsad, Z. Zakaria, Muhammad Abbas Ahmad-Zaini
Abstract At present, possible utilization of oil-containing sludge so as to achieve the sustainable environment has become a subject of considerable interest. The oleochemical factory generates nearly two metric tons of sludge per day from the effluent processing plant. Its disposal is costly and strenuous towards the environment, therefore different alternatives to handling and utilization were studied. The sludge and its derivatives were characterized for elemental composition, proximate analysis, ash and oil constituents, surface analysis, leaching tests and calorific value. Results show that the oil-containing sludge is rich in carbon, calcium, and iron. It has a high calorific value of 33.8 MJ/kg, that is partly attributed to the oil content of 68 %. These preliminary characteristics data offer insight into several promising applications of converting “trash” into “treasure” towards sustainable environment.
目前,如何利用含油污泥实现环境的可持续发展已成为人们非常感兴趣的课题。油脂化工厂每天从污水处理厂产生近两吨污泥。其处理成本高,对环境影响大,因此研究了不同的处理和利用方法。对污泥及其衍生物进行了元素组成、近似分析、灰分和油成分、表面分析、浸出试验和热值表征。结果表明,含油污泥中含有丰富的碳、钙、铁。它具有33.8 MJ/kg的高热值,这部分归因于68%的含油量。这些初步的特征数据为我们提供了一些有前景的将“垃圾”转化为“财富”以实现可持续环境的应用。
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引用次数: 0
Chemical coagulation and biological techniques for wastewater treatment 废水的化学混凝和生物处理技术
IF 0.9 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.2478/auoc-2023-0003
S. O. Akinnawo, P. O. Ayadi, M. Oluwalope
Abstract This paper reports the effectiveness of chemical coagulation and biological techniques for the treatment of wastewater from industrial and agricultural operations. Agricultural husbandry has been reported to produce wastewater that has high content of chemical oxygen demand (COD), biological oxygen demand (BOD), turbidity as well as organic and inorganic pollutants. A comparison on the use of organic and inorganic based coagulants as well as the optimum conditions required for high percentage removal efficiency of pollutants from wastewater has been reviewed. At optimum experimental condition, ferric chloride coagulants were reported to yield 98, 95, 93 and 50 % removal of color, turbidity, iron and manganese. Moreover, chemical coagulation, electrocoagulation and biological methods have been reported to display a close range in their capacities for removing pollutants from wastewater. However, biological method was observed to be highly effective in the removal of pollutants from wastewater but requires more time and produces lesser volume of sludge, when compared to chemical method in the treatment of wastewater.
摘要本文报道了化学混凝和生物技术处理工农业生产废水的效果。据报道,农业养殖产生的废水具有高含量的化学需氧量(COD)、生物需氧量(BOD)、浊度以及有机和无机污染物。对有机混凝剂和无机混凝剂的使用进行了比较,并对废水中污染物的高去除率所需的最佳条件进行了综述。在最佳实验条件下,氯化铁混凝剂的色度、浊度、铁和锰去除率分别为98%、95%、93%和50%。此外,据报道,化学混凝、电混凝和生物方法在去除废水中污染物的能力方面表现得很接近。然而,与化学处理废水的方法相比,生物方法在去除废水中的污染物方面非常有效,但需要更多的时间和产生较少的污泥量。
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引用次数: 3
Evaluation of the inhibitory action of essential oil from Eucalyptus globulus leaves on the corrosion of mild carbon steel in 1M HCl medium 桉叶精油对低碳钢在1M HCl介质中腐蚀抑制作用的评价
IF 0.9 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.2478/auoc-2023-0001
Malick Bathily, B. Ngom, Malick Mbengue, D. Gassama
Abstract The present work aims to valorize an aromatic and medicinal plant of Eucalyptus globulus found in the region of Dakar, Senegal. To do so, we first extracted the essential oil contained in the leaves of the plant harvested in October 2020. We obtained the essential oil by hydrodistillation using a Clevenger type extractor with a yield of 1.70% of the dry plant mass. This value is quite appreciable compared to the different values in the literature. The essential oil extracted from the leaves of Eucalyptus globulus was tested as a green inhibitor on carbon steel type XC38 in 1M HCl acid medium by the mass loss method. The results obtained led to a maximum inhibitory efficiency of 89.03% for a concentration of 1.6 g/L of essential oil at room temperature of 298 K. The effect of temperature on the inhibitory behavior of the essential oil was also studied over a range of 298 K to 338 K. In this temperature range, a loss of efficiency was observed with increasing temperature, reaching a value of 15.33% at 338 K. Thermodynamic quantities were then determined. The plot of the different isotherms showed that the adsorption of the essential oil obeys the Langmuir isotherm. The results obtained showed a physical character of adsorption of this essential oil.
摘要:本研究旨在鉴定一种在塞内加尔达喀尔地区发现的球形桉(Eucalyptus globulus)芳香和药用植物。为此,我们首先提取了2020年10月收获的植物叶子中含有的精油。用Clevenger型萃取器加氢蒸馏得到精油,得率为干植物质量的1.70%。这个值与文献中不同的值相比是相当可观的。采用质量损失法对巨桉叶精油在1M盐酸介质中作为XC38型碳钢的绿色缓蚀剂进行了试验。结果表明,当挥发油浓度为1.6 g/L时,室温温度为298 K,最大抑菌率为89.03%。在298 ~ 338k的温度范围内研究了温度对挥发油抑制行为的影响。在此温度范围内,随着温度的升高,效率损失显著,在338 K时达到15.33%。然后确定热力学量。不同等温线曲线表明,精油的吸附符合Langmuir等温线。结果表明,该精油具有吸附的物理性质。
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引用次数: 0
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Ovidius University Annals of Chemistry
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